Enhanced Elevated-Temperature Strength in Refractory Complex Concentrated Alloys via Temperature-Induced Transition from Screw-to-Edge Dislocation Control
Refractory complex concentrated alloys (RCCAs) show promise for high-temperature applications but often lose strength due to screw-dislocation-controlled plasticity. We demonstrate a temperature-driven transition from screw- to edge-dislocation-controlled deformation in a single-phase NbTaTiV RCCA. Tensile tests from 298-1573 K reveal a pronounced intermediate-temperature strength plateau and yield strengths surpassing other ductile RCCAs and the Ni-based superalloy CMSX-4 above 1273 K. In-situ neutron diffraction, TEM, and molecular dynamics identify a crossover near ~900 K, where edge dislocation glide stabilized by V-induced lattice distortion dominates, enabling enhanced strength retention and a clear design strategy for ultrahigh-temperature applications.