SearcharxivSearch

arXiv subjects

Juraj Kosek

Publications and source records attributed to Juraj Kosek.

2 recordsLinked to original sources

Triboelectric Charging Model for Particles with Rough Surfaces

The triboelectric charging of particles depends on the contact area of the particle and the contacting surface. Even though the surface topology determines the real contact area, particle charging models do not account for surface roughness. In this paper, we combine contact mechanics and triboelectrification models to predict the charging of rough particles. First, a laser confocal microscope measured the statistical descriptors of polyethylene (PE) particles surface topology. Then, we descriptors particle surfaces by distributing spheroidal asperities on the smooth particle core until the surface roughness reaches the measured value. The Hertz contact mechanics model predicts the deformation of the asperity-covered particle and the resulting real contact area in dependence on impact velocity. Finally, we introduced the real contact area into the condenser model for triboelectric particle charging. The accuracy of the new model predictions was demonstrated by comparing it to a more complex surface reconstructions that account for the fractal surface topology. Furthermore, the model's predicted particle saturation charges agree well with our shaker experiments and with experimental data in the literature on the charging of plane surfaces. The developed triboelectric charging model for particles with rough surfaces is simple and requires only standard descriptors of the surface topology; thus, it suits large-scale simulations of electrifying powder flows.

cond-mat.soft

On the thermodynamic derivation of Nernst relation

What is the maximum voltage of a cell with a given electrochemical reaction? The answer to this question has been given more than a century ago by Walther Nernst and bears his name. Unfortunately, the assumptions behind the answer have been forgotten by many authors, which leads to wrong forms of the Nernst relation. Such mistakes can be overcome by applying a correct thermodynamic derivation independently of the form in which the reaction is written. The correct form of Nernst relation is important for instance in modelling of vanadium redox flow batteries or zinc-air batteries. In particular, the presence of corrosion can impact the OCV in the case of zinc-air batteries.

physics.chem-ph