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K. M. Menten

Publications and source records attributed to K. M. Menten.

At least 19 recordsLinked to original sources

Unveiling the enigma of the Nakashima-Deguchi object (IRAS 19312+1950): a candidate Orion KL analog

The Nakashima-Deguchi object (NDO; aka IRAS 19312+1950) has been recognized as an enigmatic object, exhibiting characteristics of both an evolved star and a star-forming region. However, the actual nature of this object remains a topic of ongoing debate. We conducted observations of this object in (sub)millimeter continuum and molecular line emission using the IRAM-30m and APEX telescopes as well as the SMA. Based on SED fitting of single-dish continuum observations, we determined that the cloud hosting NDO has a dust temperature of $25\pm2$ K, a source-averaged (24$^{\prime\prime}$) H$_2$ column density of $(4.4\pm 0.6) \times 10^{22}$ cm$^{-2}$, a dust emissivity index of $1.7\pm0.2$, and a total gas mass of $220\pm21 M_{\odot}$. SMA continuum observations resolve the cloud into at least four dust continuum cores. The centrally peaked core MM1, associated with an SiO maser, is the primary mass reservoir. Single-dish spectroscopic observations of NDO led to the detection of 59 spectral lines attributed to 12 species and their isotopologues. This includes the first detection of deuterated molecules, DCO$^{+}$, DCN, DNC, and HDCO, indicating substantial deuterium abundance. SMA spectroscopic observations detected 75 spectral lines toward MM1, assigned to 12 species and their isotopologues. These lines exhibit diverse morphologies on a scale of $\sim$0.1 pc, likely due to outflow feedback. The observed high-velocity outflow is inconsistent with a spherical morphology and rather resembles a wide-angle bipolar outflow. The presence of deuterated species, and the overall large mass of the complex, the surrounding material of NDO appears more naturally associated with a star-forming environment than with a purely evolved-star scenario. Our investigations led us to postulate that this enigmatic object may represent an Orion KL analog about ten times farther away.

astro-ph.GA

Kinetic temperature of massive star-forming molecular clumps measured with formaldehyde VI. The photodissociation region M17SW

The kinetic temperature structure of the photodissociation region M17SW was mapped using the IRAM 30 m telescope. This mapping employed the para-H2CO triplet (J(KaKc) = 303-202, 322-221, and 321-220) near 218 GHz on a scale of ~0.2 pc. The kinetic temperatures were derived by modeling the average H2CO line ratios (322-221/303-202 + 321-220/303-202) with the RADEX non-local thermodynamic equilibrium approach. These temperatures range from 28 to 181 K with an average of 54.2 +/- 0.3 K at a spatial density of 5.5x10^5 cm^-3. Comparing with the temperature measurements obtained from multiple transitions of NH3 (1,1)-(6,6) and the far infrared (FIR) dust continuum, the H2CO lines show temperatures similar to those measured by NH3 but slightly higher than values derived from FIR observations. The high kinetic temperatures observed from H2CO are associated with the ultracompact H II region UC1, dense clumps, as well as H2O and CH3OH masers, showing a similar distribution as NH3. This indicates that dense gas in the M17SW region is heated by star formation activity. The presence of a significant gas temperature gradient across the M17SW region, as measured by H2CO and NH3, provides direct evidence for gas heated predominantly by radiation emitted from the OB star cluster NGC 6618. On a smaller scale, the dense gas surrounding the dense clumps experiences significant heating from internal protostars and/or young stellar objects. Higher temperatures traced by H2CO are linked to turbulence on a scale of ~0.2 pc. The complex temperature structure of the M17SW region is revealed by H2CO and NH3, which may be attributed to both large-scale external radiative heating and small-scale internal radiative and turbulent heating.

astro-ph.GA

Velocity-resolved [O I] 63,145 um, [C II] 158 um, and OH mapping along the Orion BN/KL explosive outflow and irradiated shocks

Stellar mergers produce explosive outflows that serve as transient sources of IR line luminosity and inject mechanical energy early into the natal molecular cloud. We present the first velocity-resolved maps of the [O I] 63 and 145 um fine-structure line emission from the wide-angle outflow in Orion BN/KL, the nearest explosive outflow. The data were obtained with SOFIA and include sensitive [C II] 158 um and OH maps. They allowed us to disentangle the quiescent cloud gas from the outflow, traced by a broader [O I] component with a line FWHM of about 20-30 km/s and exhibiting a spatial distribution similar to that of the shock-excited H2 emission seen with JWST. The OH 119 um line shows a prominent P-Cygni profile covering 160 km/s, similar to the very broad CO lines. The total [O I] 63 and 145 line luminosity is remarkably high, 86.5 L_sun, comparable to the H2 and CO line luminosities, implying an outflow mass-loss rate of (9.1+/-2.6)x10^-3 M_sun/yr and a mass of 3.3-5.9 M_sun. The [O I] 63 / 145 and [O I] 63 / [C II] 158 intensity ratios reach very high values in the line wings (20-30 and 40-60, respectively), exceeding those found in PDRs. These ratios are consistent with the presence of dense (10^5 to 10^6 cm^-3 ) and warm (~500 K) postshock gas. We analyzed the fine-structure line-wing intensities using magnetized shock models that include UV irradiation, to which the [C II] 158 line intensity is particularly sensitive. We find that the [O I] and [C II] intensities are consistent with emission from dissociative J-type shocks with velocities of 30-40 km/s and preshock gas densities of a few 10^4 cm^-3, illuminated by external UV radiation generated by surrounding fast shocks and possibly by massive (proto)stars in the region. We also report a broad [O I] emission feature around the BN star, which we attribute to an unresolved outflow or wind bow shock.

astro-ph.GA

HyGAL: Characterizing the Galactic ISM with observations of hydrides and other small molecules. III. The absorption lines of [O I], CH, and OH

The HyGAL Stratospheric Observatory for Infrared Astronomy (SOFIA) legacy program aims at characterizing the interstellar medium in the Milky Way using hydrides, [C II], and [O I] absorption lines with the 2.7 m SOFIA telescope toward twenty-five submillimeter-bright Galactic star-forming regions. As part of HyGAL, we investigated correlations among the known H$_2$ tracers -- CH and OH from SOFIA observations, and HCO$^+$ and CCH from ancillary absorption line data from ground-based telescopes. We also examined the abundance variation of neutral atomic oxygen, [O I], observed in absorption. CH, OH, HCO$^+$, and CCH all exhibit strong mutual correlations. OH in particular shows tight correlations with HCO$^+$ and CCH, reflecting their linked chemical and physical pathways. Column density ratios among these H$_2$ tracers are consistent with previous measurements in local diffuse clouds and remain uniform across Galactic environments and velocity intervals. The gas phase oxygen abundance relative to total hydrogen, $\langle X$(O)$\rangle=N$(O)/$N$(H$_{\rm total}$), is $(3.09\pm0.64)\times10^{-4}$, slightly below the elemental solar value but consistent with the previous observations measuring gas-phase abundances. We also find that $N$(HI) decreases toward the regions where the molecular fraction exceeds $f_{H_2}^N \sim 0.5$, marking the onset of the molecular phase. While the atomic oxygen abundance remains roughly constant, the abundances of OH, HCO$^+$, and CCH increase with the molecular fraction. Gas traced by the HCO$^+$ absorption corresponds to higher molecular fractions than that traced by HI and hydride ions, highlighting density variations in the diffuse-to-translucent ISM along different lines of sight.

astro-ph.GA

Massive star formation at the Galactic crossroads: Insights from G358.69+0.03 in the Galactic center

We investigated the high-mass star formation activity in a subregion of the Sagittarius E star-forming complex, centered at (l,b) = (358.69 deg, 0.03 deg), where infrared and radio sources trace a prominent U-shaped structure that has not been identified in previous studies. We used radio continuum data from the Global View on Star Formation (GLOSTAR) survey, which is a wide-band radio (4-8 GHz) survey of the Milky Way that combines data from the Karl G. Jansky Very Large Array and the Effelsberg 100 m telescope. Using BLOBCAT source extraction software, we identified 49 compact radio sources. Based on multiwavelength associations and spectral index estimates, we identified GLOSTAR counterparts to 27 previously confirmed HII regions, detected radio emission from 3 WISE "radio-quiet" candidates, and report 5 new HII region candidates. The derived physical properties indicate that most are relatively evolved HII regions. We find around 50 cold dust clumps, predominantly toward the south and southeast. Mid-infrared flux-ratio maps ([4.5]/[3.6]) show localized shock enhancements along the arc and adjacent clumps, and 15 clumps exhibit SiO emission with broad components indicative of shocks. Together with CO data, the SiO velocity components delineate a continuous (>100 km/s) velocity bridge that links the far dust-lane inflow to the central molecular zone (CMZ) stream. The largest concentration of clumps and compact HII regions lies at this interface. These combined diagnostics favor a scenario in which bar-driven cloud-cloud collision at the far dust-lane-CMZ interface compressed the gas and triggered the observed high-mass star formation.

astro-ph.GA

AMKID -- a large KID-based camera at the APEX telescope

The thermal emission at sub-millimeter wavelengths carries unique information in many astronomical applications ranging from disks and planet formation around young stars, to galaxy evolution studies at cosmological distances. Advancing on the mapping speed to detect this faint emission in ground-based astronomy has been a technical challenge for decades. The APEX Microwave Kinetic Inductance Detector (AMKID) camera was designed to accomplish this task. The instrument is a wide field-of-view camera based on kinetic inductance detectors. It is installed on the 12~meter APEX telescope in Chile at 5.100~meters above see level. The instrument operates dual color, covering simultaneously the 350~GHz and 850~GHz atmospheric windows. It has a large field-of-view of 15.3'x15.3', and an unprecedented number of pixels: 13.952~detectors in the high frequency band and 3.520~detectors in the low frequency band. Here we present a complete description of the instrument design and construction together with results of the successful low frequency array (LFA) commissioning campaign executed during the last year. The LFA performance is in good agreement with design parameters, with detector sensitivity of 2.2~mK$\sqrt{s}$ and diffraction limited beam sizes of 17.0''. On-sky measurements demonstrate a sensitivity of 70-90~mJy$\sqrt{s}$ per detector when operating under good atmospheric conditions (PWV below 1.0mm). With this performance the LFA regularly achieve a mapping sensitivity of 25~mJy when mapping a square degree in an hour. AMKID on APEX with its dual color observing capabilities, high sensitivity, large field-of-view and high angular resolution holds the promise to open a new range of science with the APEX telescope.

astro-ph.IM

Exploring the interplay between molecular and ionized gas in HII regions

We aim to constrain the kinetic temperature and H$_2$ volume density of massive star-forming clumps associated with HII regions using multiple para-H$_2$CO transitions. In addition, we investigate the interplay between ionized gas, molecular gas, and dust to probe how massive stars influence their parental clumps. We observed the $J_{K_aK_c}$ transitions of para-H2CO (within its J = 3-2 and 4-3 states) with the Atacama Pathfinder EXperiment (APEX) 12 m submillimeter telescope using the nFLASH230 and SEPIA345 receivers towards a sample of 61 HII regions. Spectral line parameters are derived via multi-component Gaussian fitting, which was then used to constrain the physical conditions determined using PyRADEX, a non-local thermodynamic equilibrium (LTE) radiative transfer code in combination with Markov Chain Monte Carlo (MCMC) analysis. The non-LTE analysis yielded kinetic temperatures ($T_{kin}$) ranging from 33.7 K to 265 K and H2 densities (n(H$_2$)) between 0.8 X $10^4$ to 1.05 X $10^7$ cm$^{-3}$, providing a detailed characterization of the dense molecular gas contained in these clumps. In addition to the para-H$_2$CO emission arising from the targeted clump a large fraction (57%) of the sources exhibit multiple para-H$_2$CO components, with the secondary components being characterized by higher $T_{kin}$ and broader linewidths. Investigating the nature of the secondary component revealed its association with supersonic non-thermal motions and turbulent gas. When comparing the physical properties of the molecular gas and dust components with those of the ionizing gas, we find that parameters directly linked to the central high-mass star such as bolometric luminosity and Lyman continuum photon rate, show stronger and more systematic correlations. Emphasizing the role of the central star in governing the interplay between the molecular and ionized gas.(Abridged)

astro-ph.GA

A global view on star formation: The GLOSTAR Galactic plane survey XII. Effelsberg's continuum view and data release

Extended radio continuum emission and its linear polarization play a key role in probing large-scale structures of synchrotron and free-free emission in the Milky Way. Despite the existence of many radio continuum surveys, sensitive and high-angular-resolution single-dish surveys of extended radio continuum emission remain scarce. As part of the GLObal view of STAR formation (GLOSTAR) survey, we will also crucially complement the existing data from the Karl G. Jansky Very Large Array (VLA) by addressing the missing zero-spacing gap. Within the framework of the GLOSTAR Galactic plane survey, we performed large-scale radio continuum imaging observations toward the Galactic plane in the range $-2^{\circ}< \ell <60^{\circ}$ and $|b|<1.1^{\circ}$, as well as the Cygnus X region with the Effelsberg 100-m radio telescope. We present the Effelsberg continuum survey at 4.89GHz and 6.82GHz including linear polarization with angular resolutions of 145$^{\prime\prime}$ and 106$^{\prime\prime}$, respectively. The survey has been corrected for missing large-scale emission using available low-angular-resolution surveys. Comparison with previous single-dish surveys indicates that our continuum survey represents the highest-quality single-dish data collected to date at this frequency. More than 90\% of the flux density missed by the VLA D-array data is effectively recovered by the Effelsberg continuum survey. The improved sensitivity and angular resolution of our survey enable reliable mapping of Galactic magnetic field structures, with polarization data that are less affected by depolarization than in previous surveys. The GLOSTAR single-dish continuum data will be released publicly, offering a valuable resource for studying extended objects including HII regions, supernova remnants, diffuse interstellar medium, and Galactic structure. (Abridged)

astro-ph.GA

A sub-ppm upper limit on the cosmological variations of the fine structure constant alpha

Absorption spectroscopy toward high-redshift quasars provides strong constraints on the putative variation of fundamental constants of physics on cosmological time scales. The submillimeter ground-state transitions of methylidyne (CH) and water (H2O), both molecules widespread and coeval in the interstellar medium, provide a sensitive test for variations of alpha, the fine structure constant, and mu, the proton-to-electron mass ratio, taking advantage of the unmatched spectral resolution and frequency reliability of radio techniques. We used ALMA simultaneous observations of the two species to constrain any velocity offset between their absorption profiles toward the radio-bright lensed quasars PKS1830-211 (z_abs=0.88582) and B0218+357 (z_abs=0.68466). Our observational setup minimizes instrumental errors and known sources of systematics, such as time variability of the absorption profile and frequency-dependent morphology of the background quasar. The excellent correlation between CH and H2O opacities, the large number of individual narrow velocity components, and the number of independent spectra obtained due to the intrinsic time variability of the absorption profiles ensure that even the chemical segregation bias is minimized. We obtained bulk velocity shifts delta_v = -0.048 pm 0.028 km/s and -0.13 pm 0.14 km/s (1 sigma confidence level) between CH and H2O in the direction of PKS1830-211(NE) and B0218+357(SW), respectively. These values convert into the 3sigma upper limits |Delta_alpha/alpha| < 0.55 ppm and 1.5 ppm, respectively, taking into account the independent upper limits on |Delta_mu/mu| previously obtained for these systems. These constraints on |Delta_alpha/alpha|, at look-back times of about half the present age of the Universe, are two to four times deeper than previous constraints on any other single high-z system.

astro-ph.CO

CASCADE: Filamentary accretion flows in Cygnus X DR20

Aims. We investigate the role of filaments in high-mass star formation, whether gas flows from large to small scales along them, and what their properties might reveal about the region they are found in. Methods. The Max Planck IRAM Observatory Program (MIOP), the Cygnus Allscale Survey of Chemistry and Dynamical Environments (CASCADE), includes high spatial resolution (~3'') data of HCO+(1-0) and H13CO+(1-0) emission in the star-forming DR20 region in the Cygnus X complex. In this data we identify filaments with the structure identification algorithm DisPerSE. We further analyze these filaments using Gaussian fits to the spectra to determine the line peak velocity and full width half maximum along them. The Python package FilChaP was used to determine filament widths. Results. We find projected velocity gradients inside several filaments between 0.4 to 2.4km/s over projected length-scales of 0.1pc toward star-forming cores. This can be interpreted as a sign of gas flowing along the filaments toward the cores. The filament width distributions exhibit median values between 0.06 and 0.14pc depending on the core, the tracer, and the method. Standard deviations are approximately 0.02 to 0.06pc. These values are roughly in agreement with the filament width of 0.1pc typically found in nearby low-mass star-forming regions. Conclusions. This first analysis of filamentary properties within the Cygnus X CASCADE program reveals potential signatures of gas flows along filaments onto star-forming cores. Furthermore, the characteristics of the filaments in this high-mass star-forming region can be compared to those of filaments in low-mass star-forming regions typically studied before. Extending such studies to the entire CASCADE survey will enhance our knowledge of high-mass filament properties on solid statistical grounds.

astro-ph.GA

A targeted radio survey of infrared-selected bow shock candidates

Bow shocks around massive stars have primarily been detected in IR emission, but radio detections are becoming more frequent with the commissioning of sensitive and large field-of-view interferometers. Radio data probes both thermal and non-thermal emission, thereby constraining the relativistic electron population. We undertook a radio survey for bow shocks based on IR catalogues of candidates, using the VLA and the 100-m Effelsberg Telescope, aiming for new detections and to better characterise the multi-wavelength emission. We used Gaia DR3 to re-calculate spatial motion of the driving stars with respect to the surrounding stellar population. We studied the radio emission from bow shocks using emission maps and spectral-index measurements, and compared our results with data from catalogues and multi-wavelength emission. Of the 24 targets observed with the VLA in the 4-12 GHz band, six were clearly detected (including two previously reported) and 5 possibly detected. A subset of these were also observed and detected with Effelsberg at 4-8 GHz. The VLA-derived spectral index maps indicate non-thermal emission for most sources, but the statistical uncertainties are large for most sources and all Effelsberg observations indicate thermal emission. Assuming thermal emission, we obtain upper limits on the electron density within the shocked layer. We obtained upper limits on radio emission from the bow shock of Zeta Oph at a similar flux level to predictions from MHD simulations. Our survey marks a significant addition to the ca. 10 previously known radio-emitting bow shocks in the literature, and demonstrates that deep, targeted radio surveys can effectively detect IR-selected bow shocks. Follow-up observations of these targets at lower and higher frequencies are encouraged to determine whether any are non-thermal emitters like the bow shocks of BD+43, BD+60 and LS2355. (abridged)

astro-ph.GA

The Nearby Evolved Stars Survey III: First data release of JCMT CO-line observations

Low- to intermediate-mass ($\sim$0.8$-$8 M$_\odot$) evolved stars contribute significantly to the chemical enrichment of the interstellar medium in the local Universe, making accurate mass-return estimates in their final stages crucial. The Nearby Evolved Stars Survey (NESS) is a large multi-telescope project targeting a volume-limited sample of $\sim$850 stars within 3 kpc in order to derive the dust and gas return rates in the Solar Neighbourhood, and to constrain the physics underlying these processes. We present an initial analysis of the CO-line observations, including detection statistics, carbon isotopic ratios, initial mass-loss rates, and gas-to-dust ratios. We describe a new data reduction pipeline to analyse the available NESS CO data from the JCMT, measuring line parameters and calculating empirical gas mass-loss rates. We present the first release of the available data on 485 sources, one of the largest homogeneous samples of CO data to date. Comparison with a large literature sample finds that high mass-loss rate and especially carbon-rich sources are over-represented in literature, while NESS is probing significantly more sources at low mass-loss rates, detecting 59 sources in CO for the first time and providing useful upper limits. CO line detection rates are 81% for the CO (2--1) line and 75% for CO (3--2). The majority (82%) of detected lines conform to the expected soft parabola shape, while eleven sources show a double wind. Calculated mass-loss rates show power-law relations with both the dust-production rates and expansion velocities up to $\sim 5 \times 10^{-6}$~\msunyr. Median gas-to-dust ratios of 250 and 680 are found for oxygen-rich and carbon-rich sources, respectively. Our analysis of CO observations in this first data release highlights the importance of our volume-limited approach in characterizing the local AGB population as a whole.

astro-ph.GA

ATOMIUM: Continuum emission and evidence of dust enhancement from binary motion

Low- and intermediate-mass stars on the asymptotic giant branch (AGB) account for a significant portion of the dust and chemical enrichment in their host galaxy. Here we present ALMA observations of the continuum emission at 1.24 mm around a sample of 17 stars from the ATOMIUM survey. From our analysis of the stellar contributions to the continuum flux, we find that the semi-regular variables all have smaller physical radii and fainter monochromatic luminosities than the Mira variables. Comparing these properties with pulsation periods, we find a positive trend between stellar radius and period only for the Mira variables with periods above 300 days and a positive trend between the period and the monochromatic luminosity only for the red supergiants and the most extreme AGB stars with periods above 500 days. We find that the continuum emission at 1.2 mm can be classified into four groups. "Featureless" continuum emission is confined to the (unresolved) regions close to the star for five stars in our sample, relatively uniform extended flux is seen for four stars, tentative elongated features are seen for three stars, and the remaining five stars have unique or unusual morphological features in their continuum maps. These features can be explained by binary companions to 10 out of the 14 AGB stars in our sample. Based on our results we conclude that there are two modes of dust formation: well established pulsation-enhanced dust formation and our newly proposed companion-enhanced dust formation. If the companion is located close to the AGB star, in the wind acceleration region, then additional dust formed in the wake of the companion can increase the mass lost through the dust driven wind. This explains the different dust morphologies seen around our stars and partly accounts for a large scatter in literature mass-loss rates, especially among semiregular stars with small pulsation periods.

astro-ph.SR

Shared-optical-path VLBI frequency phase transfer from 86 to 258 GHz on an 8600 km baseline: Demonstrated with the APEX and IRAM 30 m telescopes

The receiver N3AR operating at a frequency range between 67 and 116 GHz has been commissioned at the APEX telescope in October 2024. This adds a new low-frequency band for APEX, with the capability of simultaneous dual-frequency observations using a dichroic beamsplitter. The 3 mm receiver also allows APEX to join the existing 3 mm global VLBI network. One of our commissioning goals was to perform simultaneous dual-band VLBI observations at 86 and 258 GHz using receivers with shared-optical-paths (SOP) to correct the atmospheric phase fluctuations using the frequency phase transfer (FPT) technique. This was possible together with the IRAM 30 m telescope, which has already developed such a capability. We aimed to verify the expected phase coherence and sensitivity improvement at the higher frequency achievable by applying FPT. With the dual-band, single baseline data, we applied the FPT method, which uses the lower frequency data to correct the simultaneously observed higher-frequency data. We evaluate the improvement compared to the conventional single-band observing mode by analyzing the coherence factor in the higher frequency data. Our results show that the phase fluctuations at the two bands are well correlated. After applying FPT, the interferometric phases at the higher frequency vary much slower and the coherence factor is significantly improved. Our analysis confirms the feasibility of applying FPT to frequencies above 250 GHz with SOP receivers. Future observations in this mode could dramatically improve the sensitivity and imaging fidelity of high-frequency VLBI.

astro-ph.IM

SCOTCH III: Complete search for Hypercompact HII regions in the fourth quadrant

We present high-frequency (18-24 GHz) radio continuum observations towards 335 methanol masers, excellent signposts for young, embedded high-mass protostars. These complete the search for hypercompact HII (HCHII) regions towards young high-mass star-forming clumps within the fourth quadrant of the Galactic plane. HCHII regions are the earliest observable signatures of radio continuum emission from high-mass stars ionizing their surroundings, though their rarity and short lifetimes make them challenging to study. We have observed methanol maser sites at 20-arcsec resolution and identified 121 discrete high-frequency radio sources. Of these, 42 compact sources are embedded in dense clumps and coincide with methanol masers, making them as excellent HCHII region candidates. These sources were followed up at higher resolution (0.5-arcsec) for confirmation. We constructed spectral energy distributions across 5-24 GHz to determine their physical properties, fitting either a simple HII region model or a power-law as needed. This analysis identified 20 HCHII regions, 9 intermediate objects, 3 UCHII regions, and 3 radio jet candidates. Combining these results with previous findings, the SCOTCH survey has identified 33 HCHII regions, 15 intermediate objects, 9 UCHII regions, and 4 radio jet candidates, tripling the known number of HCHII regions. Eleven of these sources remain optically thick at 24 GHz. This survey provides a valuable sample of the youngest HII regions and insights into early massive star formation.

astro-ph.GA

Reexploring Molecular Complexity with ALMA: Insights into chemical differentiation from the molecular composition of hot cores in Sgr B2(N2)

We used ALMA to perform a line survey of the high-mass star forming region Sgr B2(N), called ReMoCA. We modeled under the assumption of LTE the spectra obtained toward the sources embedded in the secondary hot core Sgr B2(N2). We compared the chemical composition of these sources to that of sources from the literature and to predictions of the chemical kinetics model MAGICKAL. We detected up to 58 molecules toward Sgr B2(N2)'s hot cores, including up to 24 COMs, as well as many less abundant isotopologs. The compositions of some pairs of sources are well correlated, but differences also exist in particular for HNCO and NH2CHO. The abundances of series of homologous molecules drop by about one order of magnitude at each further step in complexity. The nondetection of radicals yields stringent constraints on the models. The comparison to the chemical models confirms previous evidence of a high cosmic-ray ionization rate in Sgr B2(N). The comparison to sources from the literature gives new insight into chemical differentiation. The composition of most hot cores of Sgr B2(N2) is tightly correlated to that of the hot core G31.41+0.31 and the hot corino IRAS 16293-2422B after normalizing the abundances by classes of molecules (O-, N-, O+N-, and S-bearing). There is no overall correlation between Sgr B2(N2) and the shocked region G+0.693-0.027 also located in Sgr B2, and even less with the cold starless core TMC-1. The class of N-bearing species reveals the largest variance among the four classes of molecules. The S-bearing class shows in contrast the smallest variance. These results imply that the class of N-bearing molecules reacts more sensitively to shocks, low-temperature gas phase chemistry after non-thermal desorption, or density. The abundance shifts observed between the N- and O-bearing molecules may indicate how violently and completely the ice mantles are desorbed. [abridged]

astro-ph.GA

Molecular Clouds at the Edge of the Galaxy I. Variation of CO J=2-1/1-0 Line Ratio

The Galactic edge at Galactocentric distances of 14\,--\,22\,kpc provides an ideal laboratory to study molecular clouds in an environment that is different from the solar neighborhood, due to its lower gas density, lower metallicity, and little or no perturbation from the spiral arms. Observations of CO\,($J$\,=\,2--1) spectral lines were carried out towards 72 molecular clouds located at the Galactic edge using the IRAM\,30\,m telescope. Combined with CO\,($J$\,=\,1--0) data from the MWISP project, we investigate the variations of $R_{21}$ across these Galactic edge clouds, with $R_{21}$ representing CO(2-1)/CO(1-0) integrated intensity ratios. These are found to range from 0.3 to 3.0 with a mean of 1.0\,$\pm$\,0.1 in the Galactic edge clouds. The proportions of very low ratio gas (VLRG; $R_{21}$\,<\,0.4), low ratio gas (LRG; 0.4\,$\le$\,$R_{21}$\,<\,0.7), high ratio gas (HRG; 0.7\,$\le$\,$R_{21}$\,<\,1.0), and very high ratio gas (VHRG; $R_{21}$\,$\ge$\,1.0) are 6.9\%, 29.2\%, 26.4\%, and 37.5\%, respectively, indicating a significant presence of high $R_{21}$ ratio molecular gas within these regions. In our Galaxy, the $R_{21}$ ratio exhibits a gradient of initial radial decline followed by a high dispersion with increasing Galacticentric distance and a prevalence for high ratio gas. There is no apparent systematic variation within the Galactocentric distance range of 14 to 22\,kpc. A substantial proportion of HRG and VHRG is found to be associated with compact clouds and regions displaying star-forming activity, suggesting that the high $R_{21}$ ratios may stem from dense gas concentrations and recent episodes of star formation.

astro-ph.GA

Shock-induced HCNH+ abundance enhancement in the heart of the starburst galaxy NGC 253 unveiled by ALCHEMI

Understanding the chemistry of molecular clouds is pivotal to elucidate star formation and galaxy evolution. As one of the important molecular ions, HCNH+ plays an important role in this chemistry. Yet, its behavior and significance under extreme conditions, such as in the CMZs of external galaxies, are still largely unexplored. We aim to reveal the physical and chemical properties of the CMZ in the starburst galaxy NGC253 with multiple HCNH+ transitions to shed light on the molecule's behavior under the extreme physical conditions of a starburst. We employ molecular line data including results for four rotational transitions of HCNH+ from the ALCHEMI large program to investigate underlying physical and chemical processes. Despite weak intensities, HCNH+ emission is widespread throughout NGC253's CMZ, which suggests that this molecular ion can effectively trace large-scale structures within molecular clouds. Using the quantum mechanical coupled states approximation, we computed rate coefficients for collisions of HCNH+ with para-H2 and ortho-H2 at kinetic temperatures up to 500 K. Using these coefficients in a non-LTE modeling framework and employing a Monte Carlo Markov chain analysis, we find that HCNH+ emission originates from regions with H2 number densities of $\sim10^{2.80}-10^{3.55}$~cm$^{-3}$, establishing HCNH+ as a tracer of low-density environments. Our analysis reveals that most of the HCNH+ abundances in the CMZ of NGC253 are higher than all reported values in the Milky Way. We performed static, PDR, and shock modeling, and found that recurrent shocks could potentially account for the elevated HCNH+ abundances observed in this CMZ. We propose that the unexpectedly high HCNH+ abundances may result from chemical enhancement, primarily driven by the elevated gas temperatures and cosmic ray ionization rates of shocked, low-density gas in the nuclear starburst regions of NGC253.

astro-ph.GA