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Kai Chang

Publications and source records attributed to Kai Chang.

At least 19 recordsLinked to original sources

Symmetry-enforced third-order nonlinear thermal Hall effects in altermagnets

Thermal Hall effect (THE) is a powerful probe of material properties, even in insulators. Here we investigate the thermal response of altermagnets by developing a theory on Berry curvature driven nonlinear THE from both electrons and magnons. We identify symmetry conditions under which the third-order THE dominates while linear and second-order contributions vanish. Notably, d-wave and i-wave altermagnets with out-of-plane Neel order satisfy these conditions, whereas in-plane order yields a dominant linear THE. Using KV2Se2O (a d-wave altermagnetic metal) and MnF2 (an altermagnetic insulator) as concrete examples, we show nonzero third-order nonlinear THE from electrons and magnons, respectively, both exhibiting a pi-periodic dependence on the direction of temperature gradient. These symmetry-guaranteed Berry curvature phenomena provide a diagnostic for altermagnetism in candidate materials and enable determination of the Neel vector orientation.

cond-mat.mtrl-sci

DiagChain: A Diagnostic Benchmark for Evaluating LLM Agents on Evidence-Grounded Attack Chain Reconstruction

Large Language Model (LLM) agents offer a promising approach to attack chain reconstruction by retrieving and interpreting heterogeneous telemetry to infer ordered attacker actions. However, existing benchmarks mainly evaluate final outputs or aggregate accuracy, providing limited insight into how errors arise and propagate across intermediate reasoning stages. We present DiagChain, a diagnostic benchmark for evidence-grounded attack chain reconstruction that enables stage-wise evaluation of LLM agents. DiagChain includes MAIN-69, a suite of 69 scenarios spanning multiple operating systems, evidence noise levels, and chain lengths. It further introduces Evidence-Centric Retrieval-Augmented Generation (ECRAG), which couples evidence retrieval with an evolving structured representation of the reconstructed chain. Five complementary metrics are introduced to assess distinct stages of the reconstruction process and support systematic failure diagnosis. Based on evaluations using 6 LLMs, DiagChain reveals that even the strongest configuration succeeds on only 39.6% of the 849 reference steps in MAIN-69. Our analysis further shows that smaller models struggle with the more basic task of incorporating retrieved evidence into their outputs, whereas larger models can proceed to later steps, where correctly ordering that evidence becomes the main bottleneck. These results validate the importance of diagnostic evaluation beyond end-to-end accuracy and provide actionable insights for improving evidence-grounded cybersecurity agents.

cs.CR

LingShu: A Large-Scale Symptom-Centric Contextualized Knowledge Graph Bridging Traditional Chinese Medicine and Modern Biomedicine

Biomedical knowledge graphs (KGs) are pivotal for knowledge organization, yet traditional binary relations often struggle to represent the conditional nature of biomedical knowledge. Symptoms provide a shared phenotypic layer for linking Traditional Chinese Medicine (TCM), which relies on symptom patterns for syndrome differentiation and treatment selection, with modern biomedicine, which connects clinical manifestations to diseases and molecular mechanisms. We present LingShu, a large-scale symptom-centric contextualized knowledge graph designed to bridge TCM and modern biomedicine. The exported version of LingShu analyzed in this study comprises 17.33 million atom-level entity records and 39.47 million relation records, including 17.19 million semantic triples and 22.29 million contextualized quadruples. LingShu integrates multi-source data, including clinical electronic medical records, authoritative TCM texts, biomedical ontologies, and curated knowledge bases, through a pipeline combining natural language processing, terminology normalization, and human-in-the-loop verification. A key innovation of LingShu is its hybrid data model: it maintains 64 typed triple relation patterns to ensure broad connectivity, while incorporating 35 contextual quadruple relation patterns to capture conditional medical associations. This dual-structure approach explicitly encodes conditional knowledge, providing a granular representation of the contexts associated with medical relations. These contextualized relations cover syndrome-dependent herb efficacy, disease-contextualized drug effects, population-specific clinical associations, and mechanism-related therapeutic responses. Furthermore, we developed a web platform (http://www.tcmkg.com/) that integrates graph visualization, graph-based reasoning, and an evidence-grounded knowledge question-answering agent.

cs.CL

Imaging the N\'eel Vector in Two-Dimensional Antiferromagnets using Antisymmetric Compton Scattering

We demonstrate that antisymmetric Compton scattering can detect both the switching and the continuous rotation of the N\'eel vector in two-dimensional (2D) antiferromagnets. By probing magnetoelectric (ME) multipoles, which couple electric and magnetic dipoles, this approach overcomes the limitations of conventional techniques that rely on a finite net magnetization. Using a group-theoretical decomposition of the staggered moments in 2D MnPS$_3$ into irreducible representations, combined with first-principles calculations, we show that the antisymmetric Compton profile (ACP) is highly sensitive to the N\'eel vector orientation: it reverses sign under N\'eel vector reversal and exhibits distinct anisotropies under in-plane rotation. These results establish the ACP as a versatile probe of antiferromagnetic (AFM) order and magnetoelectric phenomena in van der Waals materials.

cond-mat.mtrl-sci

Antiferromagnetic pseudospintronics without spin splitting

Antiferromagnets (AFMs) are promising for high-density spintronics due to their zero net magnetization, yet conventional AFM spintronics relies on spin splitting-a requirement that excludes many collinear AFMs with compensated spin sublattices. Here we exploit the sublattice degree of freedom in a honeycomb AFM with zero spin splitting. We uncover a coupling between spin and sublattice: the out-of-plane pseudospin polarization is spin-dependent, a mechanism we term partial pseudospin-spin coupling. This allows switching of the pseudospin polarization by reversing the N\'eel vector. Introducing an impurity into a specific sublattice induces Friedel oscillations with a sublattice-resolved amplitude ratio dictated solely by the pseudospin polarization, which is directly measurable by spin-polarized scanning tunneling microscopy. Furthermore, we demonstrate N\'eel-vector-controlled transmission and a large nonvolatile tunneling magnetoresistance in an all-in-one AFM junction, with pronounced resonant enhancement in gate-tunable two-dimensional devices. Our work establishes a new paradigm-AFM pseudospintronics-that utilizes the sublattice pseudospin in zero-spin-splitting AFMs, extending spintronics beyond the conventional spin-splitting paradigm.

cond-mat.mes-hall

Selective stabilization of antiferromagnetic orders in FeTe films via local strain engineering

The parent compound FeTe hosts a complex magnetic landscape that is highly susceptible to lattice distortions. Although theoretical models have predicted a bicollinear to dimer antiferromagnetic (AFM) phase transition under tensile strain, its experimental realization and deterministic control has remained elusive owing to severe magnetic frustration. Here, combining high-resolution scanning tunneling microscopy (STM) and density functional theory (DFT) calculations, we demonstrate the selective stabilization of bicollinear and dimer AFM orders in few-layer FeTe films via local uniaxial strain engineering. By mapping the strain fields near dislocation areas in FeTe films and FeTe/FeSe heterostructures, we establish a direct correspondence between specific strain components and the resulting magnetic ground states. We find that uniaxial compression along the Fe-Fe next-nearest-neighbor direction stabilizes the bicollinear AFM order, with the stripe orientation aligning parallel to the compression axis. Crucially, we report the experimental realization of the long-range dimer AFM order, which emerges under anisotropic strain along the Fe-Fe nearest-neighbor direction. This phase manifests as a distinct $\sqrt{2} \times \sqrt{2}$ electronic reconstruction and shares a common Neel temperature with the bicollinear phase. Our findings reveal that anisotropic strain effectively lifts the magnetic degeneracy among competing states. This work provides a robust strategy for the manipulation of elusive magnetic orders and offers insights into the interplay between lattice, spin, and electronic degrees of freedom in iron-based superconductors.

cond-mat.str-el

Tailoring pure valley-Zeeman spin-orbit coupling in WSe$_2$-encapsulated monolayer graphene

Engineering proximity effects in twisted van der Waals heterostructures offers a powerful platform for designing electronic properties. While theoretical predictions of quantum interference in transition metal dichalcogenide-encapsulated graphene can selectively control the spin-orbit coupling component, experimental realizations have remained elusive. Here, we report pure valley-Zeeman spin-orbit coupling in monolayer graphene, achieved by encapsulation between two parallel twisted WSe$_2$ monolayers. We observed a symmetry-enforced reordering of Landau levels, which is driven by the competition between the fixed valley-Zeeman energy and the magnetic-field-dependent cyclotron energy. This reordering is characterized by a transition from symmetry-broken states in the quantum Hall effect to a restored fourfold degeneracy with integer or half-integer quantum Hall sequences. We also demonstrate the ability to completely quench the proximity spin-orbit coupling by tuning the encapsulated geometry.

cond-mat.mes-hall

Artificial-atom arrays in moire superlattices for quantum optics

Solid-state platforms are particularly attractive for quantum optics because they facilitate on-chip integration and are compatible with established semiconductor and photonic technologies. However, a major challenge in solid-state quantum optics is the fabrication of arrays of identical emitters, such as quantum dots. In this work, we propose moire superlattices as a novel solid-state platform for manipulating light at the single-photon level. Moire superlattices form arrays of artificial-atom states characterized by nearly identical optical transition energies, tunable spacing, and highly adjustable electronic structures. They naturally operate as atomically thin, scalable, periodic emitters, making them ideal for quantum applications. Additionally, the extensive materials database of moire superlattices offers spectral coverage spanning a broad range of optical wavelengths.

physics.optics

Joule heating and electronic Gurzhi effect in hydrodynamic differential transport in an electron liquid

We perform a differential resistance study in the hydrodynamic regime of electron liquid in GaAs/AlGaAs quantum wells. At zero magnetic field ($B$) a Lorentzian profile occurs in the nonlinear transport driven by a U-turn (ac) current loop, in (ac + dc) measurements a minimum deepens with the external dc current bias ($j_{dc}$). Our analysis shows that the observed electronic transport valley induced by $j_{dc}$ is attributed to Joule heating effect on the electron temperature ($T_{e}$) of electron liquid. Quantitatively, we demonstrate that the viscosity resistivity ($\Delta \rho$) is proportional to $T^{-2}$ and is consistent with the dc-current induced electronic Gurzhi effect in various configurations of measurement.

cond-mat.mes-hall

Reversible tuning of magnetic order and intrinsic superconductivity in strained FeTe films via stoichiometry control

FeTe is a prototypical parent compound of iron-based superconductors. While bulk FeTe is non-superconducting with a long-range bicollinear antiferromagnetic order, superconductivity has been achieved in thin films. However, the approaches usually involve complex oxygen incorporation or interfacial effects, the microscopic mechanisms of which remain elusive. Here, we prepare high-purity, bare FeTe thin films on SrTiO3 and investigate their magnetic and superconducting states combining both microscopic and macroscopic characterizations. By reducing the interstitial Fe impurities, we successfully suppress the long-range antiferromagnetic order, enhance the quasiparticle coherence and induce superconductivity at ~10 K. Moreover, this process is readily reversible by tuning the Fe concentration. Our findings reveal that precise stoichiometric control is sufficient to induce intrinsic superconductivity in strained FeTe thin films. This work provides insights into the competition between magnetism and superconductivity in iron chalcogenides, and supplies methods for developing stable, high-purity superconducting FeTe films.

cond-mat.supr-con

LingLanMiDian: Systematic Evaluation of LLMs on TCM Knowledge and Clinical Reasoning

Large language models (LLMs) are advancing rapidly in medical NLP, yet Traditional Chinese Medicine (TCM) with its distinctive ontology, terminology, and reasoning patterns requires domain-faithful evaluation. Existing TCM benchmarks are fragmented in coverage and scale and rely on non-unified or generation-heavy scoring that hinders fair comparison. We present the LingLanMiDian (LingLan) benchmark, a large-scale, expert-curated, multi-task suite that unifies evaluation across knowledge recall, multi-hop reasoning, information extraction, and real-world clinical decision-making. LingLan introduces a consistent metric design, a synonym-tolerant protocol for clinical labels, a per-dataset 400-item Hard subset, and a reframing of diagnosis and treatment recommendation into single-choice decision recognition. We conduct comprehensive, zero-shot evaluations on 14 leading open-source and proprietary LLMs, providing a unified perspective on their strengths and limitations in TCM commonsense knowledge understanding, reasoning, and clinical decision support; critically, the evaluation on Hard subset reveals a substantial gap between current models and human experts in TCM-specialized reasoning. By bridging fundamental knowledge and applied reasoning through standardized evaluation, LingLan establishes a unified, quantitative, and extensible foundation for advancing TCM LLMs and domain-specific medical AI research. All evaluation data and code are available at https://github.com/TCMAI-BJTU/LingLan and http://tcmnlp.com.

cs.AI

Bosonic phases across the superconductor-insulator transition in infinite-layer samarium nickelate

Superconductivity arises from the global phase coherence of Cooper pairs. Modulation of phase coherence leads to quantum phase transitions, serving as an important tool for studying unconventional superconductivity. Here, we demonstrate bosonic phases across the superconductor-insulator transition in infinite-layer nickelate superconducting films by the control of spatially periodic network patterns. Magnetoresistance oscillations with a periodicity of h/2e provide direct evidence of 2e Cooper pairing in nickelates. The phase transition is predominantly driven by enhanced superconducting fluctuations, and Cooper pairs are involved in charge transport across the transition. Notably, we observe two types of anomalous metallic phases, emerging respectively at finite magnetic fields and down to zero magnetic field. They can be characterized by bosonic excitations, suggesting the dynamic roles of vortices in the ground states. Our work establishes nickelates as a key platform for investigating the rich landscape of bosonic phases controlled via the phase coherence of Cooper pairs.

cond-mat.supr-con

A Generalizable Framework for Building Executable Domain-Specific LLMs under Data Scarcity: Demonstration on Semiconductor TCAD Simulation

Scientific and engineering verticals often suffer from data scarcity and strict executability requirements: models must generate not only fluent text, but also syntactically valid, tool-compilable scripts. We present a schema-first alignment framework for building compact, executable domain-specific LLMs in low-resource settings. The framework integrates three core components: (i) large-scale synthetic QA data generation from expert documentation to instill foundational domain knowledge; (ii) a code-centric IR->DPO workflow that converts verified tool decks into interpretable intermediate representations (IR), performs equivalence-preserving diversification, and constructs preference pairs to directly optimize instruction compliance and code executability; and (iii) a controlled evaluation of Retrieval-Augmented Generation (RAG), showing that while RAG benefits general LLMs, it can marginally degrade the performance of already domain-aligned models. We demonstrate the framework by instantiating TcadGPT for semiconductor Technology Computer-Aided Design (TCAD). Using 1.5M synthetic QA pairs and an IR-driven DPO dataset, TcadGPT attains 85.6% semantic accuracy and an 80.0% syntax pass rate on SDE executability tests, substantially outperforming state-of-the-art general LLMs such as GPT-4o. To probe portability beyond TCAD, we apply the same recipe to the open-source FEM solver Elmer, observing consistent improvements in script-level success rates over general-purpose baselines. All datasets, benchmarks, and code (including P1, P2, and IR->DPO) are released for reproducibility. Together, these results suggest that the proposed framework provides a robust and reproducible path toward executable LLMs in specialized, data-scarce professional domains.

cs.CE

Non-Abelian gauge field optics in the time domain

Artificial gauge fields open up burgeoning opportunities for wave engineering in different disciplines. So far,previous works have mostly focused on synthesizing spatial gauge fields, where the pseudo-magnetic fields lie at the heart of these phenomena. In this Letter, we generalize the paradigm of gauge field optics to the time domain by using time-varying media with rotating anisotropy. Dual to its spatial counterpart, the temporal gauge field induces a pseudo-electric field for optical pulses, leading to the spin-dependent longitudinal shift and Zitterbewegung for both trajectory and frequency. In addition, we analyze the temporal non-Abelian interference effect induced by temporally bounded non-Abelian gauge field media, which results in the temporal spin-precession and the temporal analogy of the non-Abelian Aharonov-Bohm effect. Our work not only fills the gap between synthetic gauge fields and time-varying physical systems, but also provides a fundamentally new approach for manipulating light with time-varying media.

physics.optics

Quantized Quadrupole Superconductors

We introduce a class of superconductors termed "quantized quadrupole superconductors" that support Majorana corner modes according to the bulk-corner correspondence, distinct from previous works on the second-order topological superconductors. An intrinsic physical quantity for superconductors, i.e., the quadrupole moment serves as the topological invariant, which is always half-quantized due to the particle-hole symmetry. As examples, two types of mixed pairings, $d_{x^{2}-y^{2}}\pm id_{xy}$ and $d_{x^{2}-y^{2}}\pm is$, induced in the bilayer two-dimensional electron gases with Rashba spin-orbit coupling give the quadrupole phase. Extended discussions indicate that the nontrivial phase is robust against relative phase fluctuations in the mixed pairings and the disorders. Our schemes provide realistic platforms to implement Majorana zero modes, paving the way for studying the Majorana physics.

cond-mat.supr-con

Incommensurate-Stabilized Fractional Chern Insulator in Alternating Twisted Trilayer Graphene

Fractional Chern insulators (FCIs) typically emerge in topological flat bands and are regarded as lattice analogs of fractional quantum Hall states. Conventionally, the flat-band wavefunctions that support FCIs are expected to mimic the lowest Landau level, a condition that can be quantified by the quantum-geometric indicators. In realistic systems, however, FCIs often compete with lattice symmetry-breaking orders, especially when the hosting flat bands not ideal. In this work, we propose stabilizing FCIs by exploiting the intrinsic incommensurability of alternating twisted trilayer graphene, which naturally suppresses competing charge-density-wave (CDW) phase while FCIs are less effected. Within an adiabatic approximation at the supermoir\'e scale, the effect of incommensuration on local physics can be quantified as phase shifts of interlayer coupling. Using exact diagonalization, we compute ground states in different local patches and uncover a strikingly counterintuitive result: the FCI gap increases as the quantum-geometric indicators worsen. Within certain parameter ranges, we further identify mixed phases where FCIs coexist with CDWs, but with CDWs confined only to patches of weak incommensurability. Finally, we provide experimental protocols and discuss how incommensuration enrich the system's topology and quantum geometry. Not only do our results establish incommensuration as a robust stabilizer of FCIs, but also provide a general paradigm for exploring strong-correlation physics in incommensurate systems.

cond-mat.mes-hall

Giant Nonlinear Photon-Drag Currents in Moir\'e Bilayers

The bulk photovoltaic effect provides a fundamental pathway for direct light-to-current conversion in quantum materials. However, these nonlinear currents are often strictly constrained or forbidden by crystal symmetries, hindering their exploration in a broader range of materials. While the nonlinear photon-drag effect leverages finite photon momentum to circumvent these constraints, its investigation has been largely confined to toy models, lacking a robust numerical framework for realistic materials. Here, we develop a unified microscopic theory of nonlinear photon-drag currents formulated within a geometric-loop framework, providing both a transparent quantum-geometric interpretation and numerical tractability. Applying this formalism to twisted bilayer graphene (TBG), we demonstrate that a finite, in-plane photon momentum can trigger massive nonlinear responses, rivaling the giant photovoltaic currents reported in typical 2D materials. These currents exhibit high tunability via photon wavevector, twist angle, and light polarization. Our work not only provides a generalized framework for momentum-dependent light-matter interactions but also establishes the nonlinear photon-drag effect as a potent mechanism for unlocking unprecedented optoelectronic functionalities beyond the limitations of the conventional bulk photovoltaic effect.

cond-mat.mes-hall

Unconventional Geometric Phase in Twisted Junction of Cuprates

Originally introduced in optics, the Pancharatnam-Berry phase is a general concept of geometric phase defined for any two interfering polarization states. In electronic systems, however, its counterpart has long been overlooked due to the absence of electron polarization. Here, using large-scale first-principles calculations, we investigate the electronic structure of twisted bilayer Bi2Sr2CaCu2O8. We find spontaneous spin polarization and the emergence of hidden flat bands at the interface between atomic layers. Most notably, we discover an unconventional geometric phase analogous to the Pancharatnam-Berry phase in optics. This electronic geometric phase exerts opposite effects on superconducting currents of opposite chirality, enabling twisted cuprates to act as a filter for chiral superconducting current-even if the ground state itself is non-chiral.

cond-mat.supr-con