arXiv subjects

Karel Netočný

Publications and source records attributed to Karel Netočný.

At least 19 recordsLinked to original sources

arXiv2026

Relaxation to nonequilibrium

We describe the structure of relaxation for a steadily driven macroscopic body. The time-evolution is characterized as the zero-cost flow for a nonequilibrium and nonlinear extension of the Onsager-Machlup action governing the dynamical fluctuations. The approach hinges on two main elements: the principle of local detailed balance, which identifies the relevant thermodynamic forces, and the canonical decomposition of the frenesy into a Legendre pair. Notably, it is the time-symmetric component of the Lagrangian, the frenesy, that shapes the structure of the macroscopic evolution for given forcing. We add a simple argument for why the nonequilibrium entropy, which governs the static macroscopic fluctuations of the system, is monotone in time. The results can be interpreted as the steady nonequilibrium extension of GENERIC where relaxation to equilibrium is governed by a dissipative gradient flow superimposed on a Hamiltonian flow.

cond-mat.stat-mech↗

arXiv2024

Affine relationships between steady currents

Perturbing transition rates in a steady nonequilibrium system, e.g. modelled by a Markov jump process, causes a change in the local currents. Their susceptibility is usually expressed via Green-Kubo relations or their nonequilibrium extensions. However, we may also wish to directly express the mutual relation between currents. Such a nonperturbative interrelation was discovered by P.E. Harunari et al. in [1] by applying algebraic graph theory showing the mutual linearity of currents over different edges in a graph. We give a novel and shorter derivation of that current relationship where we express the current-current susceptibility as a difference in mean first-passage times. It allows an extension to multiple currents, which remains affine but the relation is not additive.

cond-mat.stat-mech↗

arXiv2023

On the Poisson equation for nonreversible Markov jump processes

We study the solution $V$ of the Poisson equation $LV + f=0$ where $L$ is the backward generator of an irreducible (finite) Markov jump process and $f$ is a given centered state function. Bounds on $V$ are obtained using a graphical representation derived from the Matrix Forest Theorem and using a relation with mean first-passage times. Applications include estimating time-accumulated differences during relaxation toward a steady nonequilibrium regime.

math.PR↗

arXiv2023

A Nernst heat theorem for nonequilibrium jump processes

We discuss via general arguments and examples when and why the steady nonequilibrium heat capacity vanishes with temperature. The framework is the one of Markov jump processes on finite connected graphs where the condition of local detailed balance allows to identify the heat fluxes, and where the discreteness more easily enables sufficient nondegeneracy of the stationary distribution at absolute zero, as under equilibrium. However, for the nonequilibrium extension of the Third Law, a dynamic condition is needed as well: the low-temperature dynamical activity and accessibility of the dominant state must remain sufficiently high so that relaxation times do not start to dramatically differ between different initial states. It suffices in fact that the relaxation times do not exceed the dissipation time.

cond-mat.stat-mech↗

arXiv2023

The vanishing of excess heat for nonequilibrium processes reaching zero ambient temperature

We present the mathematical ingredients for an extension of the Third Law of Thermodynamics (Nernst heat postulate) to nonequilibrium processes. The central quantity is the excess heat which measures the quasistatic addition to the steady dissipative power when a parameter in the dynamics is changed slowly. We prove for a class of driven Markov jump processes that it vanishes at zero environment temperature. Furthermore, the nonequilibrium heat capacity goes to zero with temperature as well. Main ingredients in the proof are the matrix-forest theorem for the relaxation behavior of the heat flux, and the matrix-tree theorem giving the low-temperature asymptotics of the stationary probability. The main new condition for the extended Third Law requires the absence of major (low-temperature induced) delays in the relaxation to the steady dissipative structure.

cond-mat.stat-mech↗

arXiv2023

Calorimetry for active systems

We provide the theoretical basis of calorimetry for a class of active particles subject to thermal noise. Simulating AC-calorimetry, we numerically evaluate the heat capacity of run-and-tumble particles in double-well and in periodic potentials, and of systems with a flashing potential. Low-temperature Schottky-like peaks show the role of activity and indicate shape transitions, while regimes of negative heat capacity appear at higher propulsion speeds. From there, a significant increase in heat capacities of active systems may be inferred at low temperatures, as well as the possibility of diagnostic tools for the activity of self-motile artificial or biomimetic systems based on heat capacity measurements.

cond-mat.stat-mech↗

arXiv2022

Trees and forests for nonequilibrium purposes: an introduction to graphical representations

Using local detailed balance we rewrite the Kirchhoff formula for stationary distribution of Markov jump processes in terms of a physically interpretable tree-ensemble. We use that arborification of path-space integration to derive a McLennan-tree characterization close to equilibrium, as well as to obtain response formula for the stationary distribution in the asymptotic regime of large driving. Graphical expressions of currents and of traffic are obtained, allowing the study of various asymptotic regimes. Finally, we present how the matrix-forest theorem gives a representation of quasi-potentials, as used e.g. for computing excess work and heat in nonequilibrium thermal physics. A variety of examples illustrate and explain the graph elements and constructions.

cond-mat.stat-mech↗

arXiv2019

Nonequilibrium corrections to gradient flow

The force on a probe induced by a nonequilibrium medium is in general nongradient. We detail the mechanism of that feature via nonequilibrium response theory. The emergence of nongradient forces is due to a systematic "twist" of the excess frenesy with respect to the entropy flux, in response to changes in the coupling or in the position of the probe in the nonequilibrium medium.

cond-mat.stat-mech↗

arXiv2017

Stabilization in the eye of a cyclone

We consider the systematic force on a heavy probe induced by interaction with an overdamped diffusive medium where particles undergo a rotating force around a fixed center. The stiffness matrix summarizes the stability of the probe around that center, where the induced force vanishes. We prove that the introduction of the rotational force in general enhances the stability of that point (and may turn it from unstable to stable!), starting at second-order in the nonequilibrium amplitude. When the driving is further enhanced the stabilization occurs for a wide range of rotation profiles and the induced stiffness converges to a universal expression proportional to the average mechanical stiffness. The model thus provides a rigorous example of stabilization of a fixed point due to contact with a nonequilibrium medium and beyond linear order around equilibrium.

cond-mat.stat-mech↗

arXiv2016

Driving-induced stability with long-range effects

We give a sufficient condition under which an applied rotation on medium particles stabilizes a slow probe in the rotation center. The symmetric part of the stiffness matrix thus gets a positive Lamb shift with respect to equilibrium. For illustration we take diffusive medium particles with a self-potential in the shape of a Mexican hat, high around the origin. There is a short-range attraction between the medium particles and the heavier probe, all immersed in an equilibrium thermal bath. For no or small rotation force on the medium particles, the origin is an unstable fixed point for the probe and the precise shape of the self-potential at large distances from the origin is irrelevant for the statistical force there. Above a certain rotation threshold, while the medium particles are still repelled from the origin, the probe stabilizes there and more details of the medium-density at large distance start to matter. The effect is robust around the quasi-static limit with rotation threshold only weakly depending on the temperature but the stabilization gets stronger at lower temperatures.

cond-mat.stat-mech↗

arXiv2015

Statistical forces from close--to--equilibrium media

We discuss the physical meaning and significance of statistical forces on quasi-static probes in first order around detailed balance for driven media. Exploiting the quasi-static energetics and the structure of (McLennan) steady nonequilibrium ensembles, we find that the statistical force obtains a nonequilibrium correction deriving from the excess work of driving forces on the medium in its relaxation after probe displacement. This reformulates, within a more general context, the recent result by N. Nakagawa (Phys. Rev. E 90, 022108 (2014)) on thermodynamic aspects of weakly nonequilibrium adiabatic pumping. It also proposes a possible operational tool for accessing some excess quantities in steady state thermodynamics. Furthermore, we show that the point attractors of a (macroscopic) probe coupled to a weakly driven medium realize the predictions of the minimum entropy production principle. Finally, we suggest a method to measure the relative dynamical activity through different transition channels, via the measurement of the statistical force induced by a suitable driving.

cond-mat.stat-mech↗

arXiv2015

Locality and nonlocality of classical restrictions of quantum spin systems with applications to quantum large deviations and entanglement

We study the projection on classical spins starting from quantum equilibria. We show Gibbsianness or quasi-locality of the resulting classical spin system for a class of gapped quantum systems at low temperatures including quantum ground states. A consequence of Gibbsianness is the validity of a large deviation principle in the quantum system which is known and here recovered in regimes of high temperature or for thermal states in one dimension. On the other hand we give an example of a quantum ground state with strong nonlocality in the classical restriction, giving rise to what we call measurement induced entanglement, and still satisfying a large deviation principle.

math-ph↗

arXiv2013

Low temperature behavior of nonequilibrium multilevel systems

We give a low temperature formula for the stationary occupations in Markovian systems away from detailed balance. Two applications are discussed, one to determine the direction of the ratchet current and one on population inversion. Both can take advantage of low temperature to improve the gain and typical nonequilibrium features. The new formula brings to the foreground the importance of kinetic aspects in terms of reactivities for deciding the levels with highest occupation and thus gives a detailed quantitative meaning to Landauer's blowtorch theorem at low temperature.

cond-mat.stat-mech↗

arXiv2009

Dynamical fluctuations for semi-Markov processes

We develop an Onsager-Machlup-type theory for nonequilibrium semi-Markov processes. Our main result is an exact large time asymptotics for the joint probability of the occupation times and the currents in the system, establishing some generic large deviation structures. We discuss in detail how the nonequilibrium driving and the non-exponential waiting time distribution influence the occupation-current statistics. The violation of the Markov condition is reflected in the emergence of a new type of nonlocality in the fluctuations. Explicit solutions are obtained for some examples of driven random walks on the ring.

cond-mat.stat-mech↗

arXiv2008

Exact computation of current cumulants in small Markovian systems

We describe an algorithm computing the exact value of the mean current, its variance, and higher order cumulants for stochastic driven systems. The method uses a Rayleigh-Schrodinger perturbation expansion of the generating function of the current, and can be extended to compute covariances of multiple currents. As an example of application of the method, we give numerical evidence for a simple relation [Eq.(5)] between the second and the fourth cumulants of the current in a symmetric exclusion process.

cond-mat.stat-mech↗

arXiv2008

Computation of current cumulants for small nonequilibrium systems

We analyze a systematic algorithm for the exact computation of the current cumulants in stochastic nonequilibrium systems, recently discussed in the framework of full counting statistics for mesoscopic systems. This method is based on identifying the current cumulants from a Rayleigh-Schrodinger perturbation expansion for the generating function. Here it is derived from a simple path-distribution identity and extended to the joint statistics of multiple currents. For a possible thermodynamical interpretation, we compare this approach to a generalized Onsager-Machlup formalism. We present calculations for a boundary driven Kawasaki dynamics on a one-dimensional chain, both for attractive and repulsive particle interactions.

cond-mat.stat-mech↗

arXiv2007

On and beyond entropy production: the case of Markov jump processes

How is it that entropy derivatives almost in their own are characterizing the state of a system close to equilibrium, and what happens further away from it? We explain within the framework of Markov jump processes why fluctuation theory can be based on considerations involving entropy production alone when perturbing around the detailed balance condition. Variational principles such as that of minimum entropy production are understood in that way. Yet, further away from equilibrium, dynamical fluctuations reveal a structure where the time-symmetric sector crucially enters. The fluctuations of densities and currents get coupled and a time-symmetric notion of dynamical activity becomes the counterpart and equal player to the entropy production. The results are summarized in an extended Onsager-Machlup Lagrangian, which in its quadratic approximation is expected to be quite general in governing the small fluctuations of nonequilibrium systems whose macroscopic behavior can be written in terms of a Master equation autonomously describing the time-dependence of densities and currents.

cond-mat.stat-mech↗

arXiv2007

Canonical structure of dynamical fluctuations in mesoscopic nonequilibrium steady states

We give the explicit structure of the functional governing the dynamical density and current fluctuations for a mesoscopic system in a nonequilibrium steady state. Its canonical form determines a generalised Onsager-Machlup theory. We assume that the system is described as a Markov jump process satisfying a local detailed balance condition such as typical for stochastic lattice gases and for chemical networks. We identify the entropy current and the traffic between the mesoscopic states as extra terms in the fluctuation functional with respect to the equilibrium dynamics. The density and current fluctuations are coupled in general, except close to equilibrium where their decoupling explains the validity of entropy production principles.

cond-mat.stat-mech↗