arXiv subjects

Karin I. Öberg

Publications and source records attributed to Karin I. Öberg.

At least 19 recordsLinked to original sources

arXiv2026

SMA Observations Reveal Abundant HNC Chemistry in Transition Disks

The physical and chemical conditions of protoplanetary disks shape the properties of nascent planetary systems. The line ratios and relative abundances of the HCN-HNC isomer pair are well-suited for tracing these gas conditions, since isomer chemistry is linked to the underlying temperature, elemental abundances, and irradiation environment of the emitting gas. While HCN emits bright lines regularly observed in disks, the fainter HNC lines are targeted significantly less often, precluding our ability to calibrate the HNC-to-HCN ratio as a tracer of disk properties. Here, we present new Submillimeter Array observations of five transition disks around the T Tauri stars GM Aur, J1604, LkCa 15, GG Tau, and V4046 Sgr, covering the J=3-2 and J=4-3 lines of HCN and HNC. We detected at least one line of both HCN and HNC in each source and measured disk-integrated HNC-to-HCN flux and column density ratios of $\approx$0.1-0.7 and 0.1-0.4, respectively. For all sources, measured HNC fluxes exceed predictions from models of full (non-transition) disks by $\approx$3-10x, while HCN fluxes appear typical. The relative brightness of HNC vs. HCN in transition disks strongly suggests a link between the presence of a cavity and efficient HNC production. We corroborate this trend using chemical models of the DM Tau transition disk, showing HNC production and destruction are connected to the radiation environment. In our sample, disk-integrated HNC-to-HCN column density ratio shows no trend with disk gas temperature but positively correlates with disk mass due to increased HNC abundance in the larger reservoirs of cooler gas in more massive disks.

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arXiv2026

JWST Edge-on Disk Ice (JEDIce): Vibrationally hot, rotationally cold H$_2$ in the outer disk of Oph 163131 non-thermally excited by UV and cosmic rays

Constraining ionization and excitation processes in protoplanetary disks is essential for understanding the chemical structure and evolution of disk material, shaping planet formation pathways. We present JWST/NIRSpec IFU observations of the edge-on disk Oph 163131, which reveal a unusual ro-vibrational H$_2$ spectrum dominated by the 1--0 O(2) line (2.627 $μ$m), with suppressed higher-$J$ emission despite excitation to $v=2$ and $3$. This vibrationally hot, rotationally cold H$_2$ emission is spatially extended, broadly following the molecular disk traced by CO($J{=}2$--1), with emission increasing above and below a thin midplane dark lane and extending radially beyond $\sim$200 au, where near-IR scattered-light emission is no longer dominant. We interpret the observed H$_2$ emission as arising from non-thermal excitation in cold, dense outer-disk gas, where collisions depopulate higher-$J$ rotational levels within each vibrational manifold prior to emission, producing the characteristic ``$v$-hot, $J$-cold" spectrum. We consider both ultraviolet irradiation and cosmic-ray excitation as contributors to the H$_2$ emission and find that their combined action, together with collisional de-excitation of high-$J$ level populations, broadly reproduces the observed line ratios and morphology. Within this framework, we infer a rather high effective cosmic-ray ionization rate of $\sim(1$-$10)\times10^{-15}$ s$^{-1}$ in the presence of a moderate UV field ($χ_{UV}=100-1000$, in Draine units). These results for disks, together with the recent findings by Bialy et al. 2025 for the lower-density starless core B68, highlight the potential of ro-vibrational H$_2$ emission as a novel probe of cosmic-ray ionization.

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arXiv2026

An SMA Molecular Inventory of the Edge-on Protoplanetary Disk Gomez's Hamburger

Gomez's Hamburger (IRAS 18059-3211, GoHam) is a massive, edge-on protoplanetary disk that is potentially gravitationally unstable and hosts an overdensity that may be the site of a forming giant planet, making it a particularly interesting source for the study of planet formation in the direct collapse scenario. In this study, we present a molecular inventory of GoHam's disk combining several Submillimeter Array observations for a wideband survey at an angular resolution on the order of ~1 arcsecond. We detect 11 different molecules, including 15 individual lines, and measure their disk-integrated fluxes. We also infer column densities for several species over a range of fixed excitation temperatures. We find that the molecular inventory of GoHam and the inferred column densities for select molecules are broadly consistent with the general population of large protoplanetary disks. We explore the putative gravitational instability (GI) in GoHam's disk via possible enhancements in the gas-phase H$_2$CO abundance, but find no definitive evidence of GI. The results of this study can guide future, higher-resolution studies of GoHam, as well as efforts to characterize the giant protoplanet candidate GoHam b.

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arXiv2026

Compact Hydrogen Sulfide Emission Indicates Sulfur-bearing Ice Sublimation in the Inner Disk of HD 163296

The sulfur chemistry in protoplanetary disks directly affects the composition and potential habitability of nascent planets, but its volatile inventory remains highly uncertain. Here, we present deep Atacama Large Millimeter/submillimeter Array (ALMA) observations of hydrogen sulfide (H$_2$S) along with SO and SO$_2$ in the disk around HD 163296 at an angular resolution of $\approx0.\!\!^{\prime\prime}3$ (or $\approx$30 au). We detect unresolved, compact emission of H$_2$S and SO (and tentatively SO$_2$) at the disk center with a broad line width of $\sim$40 km s$^{-1}$, suggesting that the emission is originating from the innermost regions. By fitting line profiles with a geometrically-thin Keplerian-rotating disk model, we constrain the emitting radii and gas temperatures of these molecules to be $\approx$3-5 au and $\gtrsim$90-120 K, respectively, consistent with sublimation of sulfur-bearing molecules along with water ice in the inner warm region. While the higher or comparable column density of H$_2$S with respect to SO and SO$_2$ indicates that H$_2$S is an important volatile sulfur reservoir in the disk, the limited constraints mean that we cannot rule out significantly depleted volatile sulfur as also commonly inferred in other planet-forming disks. Further observations are needed to better constrain disk sulfur inventory, unravel how sulfur compounds are reprocessed in disks, and shed light on the nature of less-volatile species, such as salts and sulfide minerals, which may occupy a significant portion of sulfur budget.

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arXiv2026

JWST Edge-on Disk Ice (JEDIce): Program overview and ice survey results

The icy material within protoplanetary disks plays a central role in planet formation, yet remains poorly characterized by observations. We present 1.6-28$μ$m spectra of five disks obtained as part of the JWST Edge-on Disk Ice (JEDIce) program, representing the largest survey of disk ices to date. The major ice species H$_2$O, CO$_2$, and CO are detected towards all disks, and exhibit a wide range of absolute optical depths and optical depth ratios across the sample. This is suggestive of a range of ice abundances and compositions, but quantitative constraints will require radiative transfer modeling. All disks exhibit ice features across the entire spatial region where the IR continuum is detected; vertically elevated ice grains therefore seem to be ubiquitous in disks. The CO ice is consistently dominated by apolar CO:CO$_2$ mixtures, implying that the disk ice compositions are neither completely reset nor pristinely inherited from the protostellar stage. The presence of these mixtures also suggests that entrapment may be important in shaping the spatial distribution of CO within the disks. Small molecules commonly seen in protostellar ices (CH$_4$, CH$_3$OH, NH$_3$) are generally not detected in our sample, though tracers of ammonium salts (OCN$^-$ and the 6.85 $μ$m band) are common, potentially reflecting an evolution towards comet-like ice compositions. The spectra also contain a wealth of information about the micron-sized dust, atomic and molecular gas, and PAH content, which together with the ice constraints will provide a comprehensive picture of the chemical, physical, and dynamical state of these systems.

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arXiv2026

Physical and Chemical Characterization of GY 91's Multi-ringed Protostellar Disk with ALMA

GY 91, commonly categorized as a Class I young stellar object, is notable for disk dust substructures that have been hypothesized to trace early planet formation. Using the ALMA 12-m and ACA arrays, we present new Band 7 dust continuum and molecular line observations of GY 91 at an angular resolution of (~40 au). We report detections of CS $J=6-5$, N$_2$H$^+$ $J=3-2$, C$^{18}$O $J=3-2$, H$_2$CS $J_{K_a, K_c} = 8_{1,7}-7_{1,6}$, H$_2$CO $J_{K_a, K_c} = 4_{0,4}-3_{0,3}$, and H$_2$CO $J_{K_a, K_c} = 4_{2,3}-3_{2,2}$, as well as a tentative detection of $^{13}$C$^{18}$O $J=3-2$. We observe azimuthal asymmetry in CS and H$_2$CS emission, as well as radially structured H$_2$CO $4_{0,4}-3_{0,3}$ emission outside the dust continuum. C$^{18}$O and H$_2$CO 4$_{0,4}-3_{0,3}$ show significant cloud contamination, while CS and N$_2$H$^+$ are good tracers of Keplerian rotation originating from the disk. Envelope emission does not appear to contribute significantly either to the continuum or molecular line observations. GY 91's chemical properties appear in large part to resemble those of Class II disks, although observations of additional molecular probes should be obtained for a fuller comparison. With CS, we estimated a dynamical stellar mass of 0.58 $M_\odot$, which is higher than previous estimates from stellar evolutionary models (0.25 $M_\odot$). Using both radiative transfer modeling of the dust continuum and comparison of the C$^{18}$O and N$_2$H$^+$ fluxes to literature thermochemical models, we estimate a disk mass of $\sim0.01$ $M_\odot$.

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arXiv2026

Functionalization of Benzene Ices by Atomic Oxygen

Small aromatic molecules, including functionalized derivatives of benzene, are known to be present throughout the different stages of star and planet formation. In particular, oxygen-bearing monosubstituted aromatics, likely including phenol, have been identified in the coma of comet 67P. This suggests that, earlier in the star and planet formation evolution, icy grains may act as both reservoirs and sites of functionalization for these small aromatics. We investigate the ice-phase reactivity of singlet oxygen atoms (O($^1$D)) with benzene, using ozone as a precursor that is readily photodissociated by relatively low-energy. Our experiments show that O($^1$D) efficiently reacts with benzene, forming phenol, benzene oxide, and oxepine as the main products. Phenol formation is temperature-independent, consistent with a barrierless insertion mechanism. In contrast, the formation of benzene oxide/oxepine shows a slight temperature dependence, suggesting that additional reaction pathways involving either ground-state or excited-state oxygen atoms may contribute. In H$_2$O and \COO ice matrices we find that dilution does not suppress formation of phenol. We extrapolate an experimental upper limit for the benzene-to-phenol conversion fraction of 27-44$\%$ during the lifetime of an interstellar cloud, assuming O($^1$D) production rates based on CO$_2$ ice abundances and a cosmic-ray induced UV field. We compare these estimates with a new analysis of data from the comet 67P, where the C$_6$H$_6$O/C$_6$H$_6$ ratio is 20$\pm$6$\%$. This value lies within our estimated range, suggesting that O($^1$D)-mediated chemistry is a viable pathway for producing oxygenated aromatics in cold astrophysical ices, potentially enriching icy planetesimals with phenol and other biorelevant compounds.

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arXiv2026

Tracing Pebble Drift History in Two Protoplanetary Disks with CO Enhancement

Pebble drift is an important mechanism for supplying the materials needed to build planets in the inner region of protoplanetary disks. Thus, constraining pebble drift's timescales and mass flux is essential to understanding planet formation history. Current pebble drift models suggest pebble fluxes can be constrained from the enhancement of gaseous volatile abundances when icy pebbles sublimate after drifting across key snowlines. In this work, we present ALMA observations of spatially resolved $^{13}$C$^{18}$O J=2-1 line emission inside the midplane CO snowline of the HD 163296 and MWC 480 protoplanetary disks. We use radiative transfer and thermochemical models to constrain the spatial distribution of CO gas column density. We find that both disks display centrally peaked CO abundance enhancement of up to ten times of ISM abundance levels. For HD 163296 and MWC 480, the inferred enhancements require 250-350 and 480-660 Earth Masses of pebbles to have drifted across their CO snowlines, respectively. These ranges fall within cumulative pebble mass flux ranges to grow gas giants in the interior to the CO snowline. The centrally peaked CO enhancement is unexpected in current pebble drift models, which predict CO enhancement peaks at the CO snowline or is uniform inside the snowline. We propose two hypotheses to explain the centrally-peaked CO enhancement, including a large CO desorption distance and CO trapped in water ice. By testing both hypotheses with the 1D gas and dust evolution code chemcomp, we find that volatile trapping (about 30\%) best reproduces the centrally peaked CO enhancement observed.

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arXiv2025

A Submillimeter Survey of CS Excitation in Protoplanetary Disks: Evidence of X-ray-Driven Sulfur Chemistry

The sulfur chemistry in protoplanetary disks influences the properties of nascent planets, including potential habitability. Although the inventory of sulfur molecules in disks has gradually increased over the last decade, CS is still the most commonly-observed sulfur-bearing species and it is expected to be the dominant gas-phase sulfur carrier beyond the water snowline. Despite this, few dedicated multi-line observations exist, and thus the typical disk CS chemistry is not well constrained. Moreover, it is unclear how that chemistry - and in turn, the bulk volatile sulfur reservoir - varies with stellar and disk properties. Here, we present the largest survey of CS to date, combining both new and archival observations from ALMA, SMA, and NOEMA of 12 planet-forming disks, covering a range of stellar spectral types and dust morphologies. Using these data, we derived disk-integrated CS gas excitation conditions in each source. Overall, CS chemistry appears similar across our sample with rotational temperatures of ${\approx}$10-40 K and column densities between 10$^{12}$-10$^{13}$ cm$^{-2}$. CS column densities do not show strong trends with most source properties, which broadly suggests that CS chemistry is not highly sensitive to disk structure or stellar characteristics. We do, however, identify a positive correlation between stellar X-ray luminosity and CS column density, which indicates that the dominant CS formation pathway is likely via ion-neutral reactions in the upper disk layers, where X-ray-enhanced S$^+$ and C$^+$ drive abundant CS production. Thus, using CS as a tracer of gas-phase sulfur abundance requires a nuanced approach that accounts for its emitting region and dependence on X-ray luminosity.

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arXiv2025

Methyl Isocyanate Formation from Oxygen Insertion in Methyl Cyanide Ices

In cold molecular clouds, UV photolysis of icy grain mantles generates radicals that lead to new molecule formation. When radical diffusion is limited by low temperatures, oxygen atom addition and insertion reactions, enabled by photolysis of common ice components such as H$_2$O, CO$_2$, CO, and O$_3$, offer an alternative route to chemical complexity through the production of metastable, highly reactive O($^{1}D$) atoms. We examine the reactivity of these oxygen atoms generated by UV photolysis of O$_3$ with methyl cyanide (CH$_3$CN). These studies are conducted in an ultrahigh vacuum chamber at cryogenic and low-pressure conditions equipped with in situ infrared spectroscopy to monitor destruction and product formation in real time. We conclude that oxygen atoms rapidly insert into CH$_3$CN to produce primarily methyl isocyanate (CH$_3$NCO) in matrix free ices. Over the range from 10 K to 40 K, we observe no temperature dependence to either CH$_3$CN destruction or CH$_3$NCO production. When placing CH$_3$CN:O$_3$ in H$_2$O and CO$_2$ ice matrices, we find that CH$_3$NCO formation remains robust, but that the yield likely decreases due to competing reaction pathways. In the case of the H$_2$O ice we also observe a shift in product branching ratios towards alternative pathways such as the formation of hydroxyacetonitrile (HOCH$_2$CN). Overall, our results demonstrate that oxygen atom reactivity provides an important channel for generating chemical complexity from nitriles on cold grains where radical mobility is limited.

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arXiv2025

H2S ice sublimation dynamics: experimentally constrained binding energies, entrapment efficiencies, and snowlines

Hydrogen sulfide (H2S) is thought to be an important sulfur reservoir in interstellar ices. It serves as a key precursor to complex sulfur-bearing organics, and has been proposed to play a significant role in the origin of life. Although models and observations both suggest H2S to be present in ices in non-negligible amounts, its sublimation dynamics remain poorly constrained. In this work, we present a comprehensive experimental characterization of the sublimation behavior of H2S ice under astrophysically-relevant conditions. The sublimation behavior of H2S was monitored with a quadrupole mass spectrometer (QMS) during temperature-programmed desorption (TPD) experiments. These experiments are used to determine binding energies and entrapment efficiencies of H2S, which are then employed to estimate its snowline positions in a protoplanetary disk midplane. We derive mean binding energies of 3159\pm46 K for pure H2S ice and 3392\pm56 K for submonolayer H2S desorbing from a compact amorphous solid water (cASW) surface. These values correspond to sublimation temperatures of around 64 K and 69 K in the disk midplane, placing its sublimation fronts at radii just interior to the CO2 snowline. We also investigate the entrapment of H2S in water ice and find it to be highly efficient, with ~75-85% of H2S remaining trapped past its sublimation temperature for H2O:H2S mixing ratios of ~5-17:1. We discuss potential mechanisms behind this efficient entrapment. Our findings imply that, in protoplanetary disks, H2S will mostly be retained in the ice phase until water crystallizes, at radii near the water snowline, if it forms mixed into water ice. This has significant implications for the possibility of H2S being incorporated into icy planetesimals and its potential delivery to terrestrial planets, which we discuss in detail.

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arXiv2025

Thermal Desorption Kinetics, Binding Energies, and Entrapment of Methyl Mercaptan Ices

Organosulfur species are potential major carriers of sulfur in the interstellar medium, as well as interesting ingredients in prebiotic chemistry. The most fundamental question regarding these species is under which conditions they reside in the gas versus solid phase. Here, we characterize the thermal desorption kinetics, binding energies, and entrapment of the organosulfur methyl mercaptan (CH$_3$SH, or MeSH) in different ice environments, comparing them with those of methanol (CH$_3$OH, or MeOH) ices. The derived multi-layer (pure MeSH-MeSH) and sub-monolayer (layered MeSH-H$_2$O) binding energies are surprisingly similar, corresponding to snow line locations where the disk midplane temperature is ~105 K. In both H$_2$O-dominated and more realistic H$_2$O:CO$_2$-dominated ices, 100% of the MeSH is entrapped, almost exclusively desorbing at the molecular volcano desorption peak, indicating that MeSH is retained at the water snow line if initially mixed with water ice during formation. Additionally, the presence of MeSH in an ice mixture enhances the entrapment of CO$_2$ and MeOH (up to 100%) until the onset of volcano desorption; without MeSH, both desorb at their respective pure desorption temperatures and also co-desorb with water. Compared to MeOH, MeSH binds less well to water, explaining why MeSH escapes during water ice crystallization rather than co-desorbing with water. These results show the larger relative size of MeSH compared to MeOH significantly impacts its ability to bind to water and its entrapment efficiency. Therefore, molecular size plays an important role in the adsorption and retention of S-bearing organics and, in turn, other volatiles in ices.

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arXiv2024

A Wideband Chemical Survey of Massive Star-forming Regions at Subarcsecond Resolution with the Submillimeter Array

Massive star-forming regions exhibit a rich chemistry with complex gas distributions, especially on small scales. While surveys have yielded constraints on typical gas conditions, they often have coarse spatial resolution and limited bandwidths. Thus, to establish an interpretative framework for these efforts, detailed observations that simultaneously provide high sensitivity, spatial resolution, and large bandwidths for a subset of diverse sources are needed. Here, we present wideband (32 GHz) Submillimeter Array observations of four high-mass star-forming regions (G28.20-0.05, G20.08-0.14 N, G35.58-0.03, W33 Main) at subarcsecond resolution, where we detect and spatially-resolve 100s of lines from over 60 molecules, including many complex organic molecules (COMs). The chemical richness of our sample is consistent with an evolutionary sequence from the line-rich hot cores and HC HII regions of G28.20-0.05 and G20.08-0.14 N to the more chemically-modest UC HII regions in G35.58-0.03, followed by the molecule-poor HII region W33 Main. We detect lines across a range of excitation conditions (Eu=20 to >800 K) and from numerous isotopologues, which enables robust estimates of gas properties. We derive nearly constant COM column density ratios that agree with literature values in other low- and high-mass protostellar cores, supporting the idea that COM abundances are set during the pre-stellar phase. In all regions, we identify spatial offsets among different molecular families, due to a combination of source physical structure and chemistry. In particular, we find potential evidence of carbon grain sublimation in G28.20-0.05 and identify an elemental oxygen gradient and rich sulfur-chemistry in G35.58-0.03. Overall, these results demonstrate that the SMA's wide bandwidth is a powerful tool to untangle the complex molecular gas structures associated with massive star formation.

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arXiv2024

Ice origins of OCS and chemistry of CS2-bearing ice mantles

Understanding the formation of carbonyl sulfide (OCS) in interstellar ices is key to constrain the sulfur chemistry in the interstellar medium (ISM), since it is the only ice S-bearing molecule securely detected thus far. Two general pathways for OCS formation have been proposed: sulfurization of CO (CO+S) and oxidation of CS (CS+O), but their relative contribution in interstellar ices remains unconstrained. We have evaluated the contribution of both pathways to OCS formation upon energetic processing in isotopically-labeled CO2:CS2 and CO:CS2 ice samples at 7-50 K. Our results indicated that formation of OCS through the CS+O pathway was more favorable than through the CO+S pathway, as previously suggested by theoretical calculations. In addition, its relative contribution increased at higher temperatures. Therefore, this pathway could play a role in the ice formation of OCS, especially in warm regions where CO is expected to be preferentially in the gas phase. At the same time, we have explored the chemistry of CS2-bearing, CO2-, CO-, and also H2O-rich ices, that could be relevant to the sulfur interstellar chemistry. We observed formation of a variety of S-bearing products in addition to OCS, including SO2, C3S2, and S2. However, a significant fraction of sulfur was not detected at the end of the experiments, and could be locked in long, undetectable sulfur allotropes, one of the potential carriers of the missing sulfur in the dense ISM.

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arXiv2024

Retrieval of Thermally-Resolved Water Vapor Distributions in Disks Observed with JWST-MIRI

The mid-infrared water vapor emission spectrum provides a novel way to characterize the delivery of icy pebbles towards the innermost ($<5$ au) regions of planet-forming disks. Recently, JWST MIRI-MRS showed that compact disks exhibit an excess of low-energy water vapor emission relative to extended multi-gapped disks, suggesting that icy pebble drift is more efficient in the former. We carry out detailed emission line modeling to retrieve the excitation conditions of rotational water vapor emission in a sample of four compact and three extended disks within the JDISC Survey. We present two-temperature H$_2$O slab model retrievals and, for the first time, constrain the spatial distribution of water vapor by fitting parametric radial temperature and column density profiles. Such models statistically outperform the two-temperature slab fits. We find a correlation between the observable hot water vapor mass and stellar mass accretion rate, as well as an anti-correlation between cold water vapor mass and sub-mm dust disk radius, confirming previously reported water line flux trends. We find that the mid-IR spectrum traces H$_2$O with temperatures down to 180-300 K, but the coldest 150-170 K gas remains undetected. Furthermore the H$_2$O temperature profiles are generally steeper and cooler than the expected `super-heated' dust temperature in passive irradiated disks. The column density profiles are used to estimate icy pebble mass fluxes, which suggest that compact and extended disks may produce markedly distinct inner-disk exoplanet populations if local feeding mechanisms dominate their assembly.

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arXiv2024

Detection of Dimethyl Ether in the Central Region of the MWC 480 Protoplanetary Disk

Characterizing the chemistry of complex organic molecules (COMs) at the epoch of planet formation provides insights into the chemical evolution of the interstellar medium (ISM) and the origin of organic materials in our Solar System. We report a detection of dimethyl ether (CH$_3$OCH$_3$) in the disk around the Herbig Ae star MWC 480 with the sensitive Atacama Large Millimeter/submillimeter Array observations. This is the first detection of CH$_3$OCH$_3$ in a non-transitional Class II disk. The spatially unresolved, compact (${\lesssim}$25 au in radius) nature, the broad line width ($\sim$30 km s$^{-1}$), and the high excitation temperature (${\sim}$200 K) indicate sublimation of COMs in the warm inner disk. Despite the detection of CH$_3$OCH$_3$, methanol (CH$_3$OH), the most abundant COM in the ISM, has not been detected, from which we constrain the column density ratio of CH$_3$OCH$_3$/CH$_3$OH ${\gtrsim}$7. This high ratio may indicate the reprocessing of COMs during the disk phase, as well as the effect of the physical structure in the inner disk. We also find that this ratio is higher than in COM-rich transition disks recently discovered. This may indicate that, in the full disk of MWC 480, COMs have experienced substantial chemical reprocessing in the innermost region, while the COM emission in the transition disks predominantly traces the inherited ice sublimating at the dust cavity edge located at larger radii (${\gtrsim}$20 au).

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arXiv2024

Radial and vertical constraints on the icy origin of H$_{2}$CO in the HD 163296 Protoplanetary Disk

H$_2$CO is a small organic molecule widely detected in protoplanetary disks. As a precursor to grain-surface formation of CH$_3$OH, H$_2$CO is considered an important precursor of O-bearing organic molecules that are locked in ices. Still, since gas-phase reactions can also form H$_2$CO, there remains an open question on the channels by which organics form in disks, and how much the grain versus the gas pathways impact the overall organic reservoir. We present spectrally and spatially resolved Atacama Large Millimeter/submillimeter Array observations of several ortho- and para-H$_2$CO transitions toward the bright protoplanetary disk around the Herbig Ae star HD 163296. We derive column density, excitation temperature, and ortho-to-para ratio (OPR) radial profiles for H$_2$CO, as well as disk-averaged values of $N_{\mathrm{T}}\sim4\times 10^{12}$ cm$^{-2}$, $T_{\mathrm{ex}}\sim20$ K, and $\mathrm{OPR}\sim2.7$, respectively. We empirically determine the vertical structure of the emission, finding vertical heights of $z/r\sim0.1$. From the profiles, we find a relatively constant $\mathrm{OPR}\sim2.7$ with radius, but still consistent with $3.0$ among the uncertainties, a secondary increase of $N_{\mathrm{T}}$ in the outer disk, and low $T_{\mathrm{ex}}$ values that decrease with disk radius. Our resulting radial, vertical, and OPR constraints suggest an increased UV penetration beyond the dust millimeter edge, consistent with an icy origin but also with cold gas-phase chemistry. This Herbig disk contrasts previous results for the T Tauri disk, TW Hya, which had a larger contribution from cold gas-phase chemistry. More observations of other sources are needed to disentangle the dominant formation pathway of H$_2$CO in protoplanetary disks.

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arXiv2024

Chemistry in externally FUV irradiated disks in the outskirts of the Orion Nebula

Most stars are born in stellar clusters and their protoplanetary disks, which are the birthplaces of planets, can therefore be affected by the radiation of nearby massive stars. However, little is known about the chemistry of externally irradiated disks, including whether or not their properties are similar to the so-far better-studied isolated disks. Motivated by this question, we present ALMA Band 6 observations of two irradiated Class II protoplanetary disks in the outskirts of the Orion Nebula Cluster (ONC) to explore the chemical composition of disks exposed to (external) FUV radiation fields: the 216-0939 disk and the binary system 253-1536A/B, which are exposed to radiation fields of $10^2-10^3$ times the average interstellar radiation field. We detect lines from CO isotopologues, HCN, H$_2$CO, and C$_2$H toward both protoplanetary disks. Based on the observed disk-integrated line fluxes and flux ratios, we do not find significant differences between isolated and irradiated disks. The observed differences seem to be more closely related to the different stellar masses than to the external radiation field. This suggests that these disks are far enough away from the massive Trapezium stars, that their chemistry is no longer affected by external FUV radiation. Additional observations towards lower-mass disks and disks closer to the massive Trapezium stars are required to elucidate the level of external radiation required to make an impact on the chemistry of planet formation in different kinds of disks.

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