arXiv subjects

Karin I. Oberg

Publications and source records attributed to Karin I. Oberg.

90 records · Page 5Linked to original sources

arXiv2011

Laboratory H2O:CO2 ice desorption data: entrapment dependencies and its parameterization with an extended three-phase model

Ice desorption affects the evolution of the gas-phase chemistry during the protostellar stage, and also determines the chemical composition of comets forming in circumstellar disks. From observations, most volatile species are found in H2O-dominated ices. The aim of this study is first to experimentally determine how entrapment of volatiles in H2O ice depends on ice thickness, mixture ratio and heating rate, and second, to introduce an extended three-phase model (gas, ice surface and ice mantle) to describe ice mixture desorption with a minimum number of free parameters. Thermal H2O:CO2 ice desorption is investigated in temperature programmed desorption experiments of thin (10 - 40 ML) ice mixtures under ultra-high vacuum conditions. Desorption is simultaneously monitored by mass spectrometry and reflection-absorption infrared spectroscopy. The H2O:CO2 experiments are complemented with selected H2O:CO, and H2O:CO2:CO experiments. The results are modeled with rate equations that connect the gas, ice surface and ice mantle phases through surface desorption and mantle-surface diffusion. The fraction of trapped CO2 increases with ice thickness (10 - 32 ML) and H2O:CO2 mixing ratio (5:1 - 10:1), but not with one order of magnitude different heating rates. The fraction of trapped CO2 is 44 - 84 % with respect to the initial CO2 content for the investigated experimental conditions. This is reproduced quantitatively by the extended three-phase model that is introduced here. The H2O:CO and H2O:CO2:CO experiments are consistent with the H2O:CO2 desorption trends, suggesting that the model can be used for other ice species found in the interstellar medium to significantly improve the parameterization of ice desorption.

astro-ph.EP↗

arXiv2011

Ices in starless and starforming cores

Icy grain mantles are commonly observed through infrared spectroscopy toward dense clouds, cloud cores, protostellar envelopes and protoplanetary disks. Up to 80% of the available oxygen, carbon and nitrogen are found in such ices; the most common ice constituents - H2O, CO2 and CO - are second in abundance only to H2 in many star forming regions. In addition to being a molecular reservoir, ice chemistry is responsible for much of the chemical evolution from H2O to complex, prebiotic molecules. Combining the existing ISO, Spitzer, VLT and Keck ice data results in a large sample of ice sources (\sime80) that span all stages of star formation and a large range of protostellar luminosities (<0.1-105 L\odot). Here we summarize the different techniques that have been applied to mine this ice data set on information on typical ice compositions in different environments and what this implies about how ices form and evolve during star and planet formation. The focus is on how to maximize the use of empirical constraints from ice observations, followed by the application of information from experiments and models. This strategy is used to identify ice bands and to constrain which ices form early during cloud formation, which form later in the prestellar core and which require protostellar heat and/or UV radiation to form. The utility of statistical tests, survival analysis and ice maps is highlighted; the latter directly reveals that the prestellar ice formation takes place in two phases, associated with H2O and CO ice formation, respectively, and that most protostellar ice variation can be explained by differences in the prestellar CO ice formation stage. Finally, special attention is paid to the difficulty of observing complex ices directly and how gas observations, experiments and models help in constraining this ice chemistry stage.

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arXiv2011

Complex molecules toward low-mass protostars: the Serpens core

Gas-phase complex organic molecules are commonly detected toward high-mass protostellar hot cores. Detections toward low-mass protostars and outflows are comparatively rare, and a larger sample is key to investigate how the chemistry responds to its environment. Guided by the prediction that complex organic molecules form in CH3OH-rich ices and thermally or non-thermally evaporate with CH3OH, we have identified three sight-lines in the Serpens core - SMM1, SMM4 and SMM4-W - which are likely to be rich in complex organics. Using the IRAM 30m telescope, narrow lines (FWHM of 1-2 km s-1) of CH3CHO and CH3OCH3 are detected toward all sources, HCOOCH3 toward SMM1 and SMM4-W, and C2H5OH not at all. Beam-averaged abundances of individual complex organics range between 0.6 and 10% with respect to CH3OH when the CH3OH rotational temperature is applied. The summed complex organic abundances also vary by an order of magnitude, with the richest chemistry toward the most luminous protostar SMM1. The range of abundances compare well with other beam-averaged observations of low-mass sources. Complex organic abundances are of the same order of magnitude toward low-mass protostars and high-mass hot cores, but HCOOCH3 is relatively more important toward low-mass protostars. This is consistent with a sequential ice photochemistry, dominated by CHO-containing products at low temperatures and early times.

astro-ph.GA↗

arXiv2011

The Spitzer ice legacy: Ice evolution from cores to protostars

Ices regulate much of the chemistry during star formation and account for up to 80% of the available oxygen and carbon. In this paper, we use the Spitzer c2d ice survey, complimented with data sets on ices in cloud cores and high-mass protostars, to determine standard ice abundances and to present a coherent picture of the evolution of ices during low- and high-mass star formation. The median ice composition H2O:CO:CO2:CH3OH:NH3:CH4:XCN is 100:29:29:3:5:5:0.3 and 100:13:13:4:5:2:0.6 toward low- and high-mass protostars, respectively, and 100:31:38:4:-:-:- in cloud cores. In the low-mass sample, the ice abundances with respect to H2O of CH4, NH3, and the component of CO2 mixed with H2O typically vary by <25%, indicative of co-formation with H2O. In contrast, some CO and CO2 ice components, XCN and CH3OH vary by factors 2-10 between the lower and upper quartile. The XCN band correlates with CO, consistent with its OCN- identification. The origin(s) of the different levels of ice abundance variations are constrained by comparing ice inventories toward different types of protostars and background stars, through ice mapping, analysis of cloud-to-cloud variations, and ice (anti-)correlations. Based on the analysis, the first ice formation phase is driven by hydrogenation of atoms, which results in a H2O-dominated ice. At later prestellar times, CO freezes out and variations in CO freeze-out levels and the subsequent CO-based chemistry can explain most of the observed ice abundance variations. The last important ice evolution stage is thermal and UV processing around protostars, resulting in CO desorption, ice segregation and formation of complex organic molecules. The distribution of cometary ice abundances are consistent with with the idea that most cometary ices have a protostellar origin.

astro-ph.GA↗

arXiv2011

Resolving the CO Snow Line in the Disk around HD 163296

We report Submillimeter Array (SMA) observations of CO (J=2--1, 3--2 and 6--5) and its isotopologues (13CO J=2--1, C18O J=2--1 and C17O J=3--2) in the disk around the Herbig Ae star HD 163296 at ~2" (250 AU) resolution, and interpret these data in the framework of a model that constrains the radial and vertical location of the line emission regions. First, we develop a physically self-consistent accretion disk model with an exponentially tapered edge that matches the spectral energy distribution and spatially resolved millimeter dust continuum emission. Then, we refine the vertical structure of the model using wide range of excitation conditions sampled by the CO lines, in particular the rarely observed J=6--5 transition. By fitting 13CO data in this structure, we further constrain the vertical distribution of CO to lie between a lower boundary below which CO freezes out onto dust grains (T ~ 19 K) and an upper boundary above which CO can be photodissociated (the hydrogen column density from the disk surface is ~ 10^{21} cm-2). The freeze-out at 19 K leads to a significant drop in the gas-phase CO column density beyond a radius of ~155 AU, a "CO snow line" that we directly resolve. By fitting the abundances of all CO isotopologues, we derive isotopic ratios of 12C/13C, 16O/18O and 18O/17O that are consistent with quiescent interstellar gas-phase values. This detailed model of the HD 163296 disk demonstrates the potential of a staged, parametric technique for constructing unified gas and dust structure models and constraining the distribution of molecular abundances using resolved multi-transition, multi-isotope observations.

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arXiv2011

Disk Imaging Survey of Chemistry with SMA: II. Southern Sky Protoplanetary Disk Data and Full Sample Statistics

This is the second in a series of papers based on data from DISCS, a Submillimeter Array observing program aimed at spatially and spectrally resolving the chemical composition of 12 protoplanetary disks. We present data on six Southern sky sources - IM Lup, SAO 206462 (HD 135344b), HD 142527, AS 209, AS 205 and V4046 Sgr - which complement the six sources in the Taurus star forming region reported previously. CO 2-1 and HCO+ 3-2 emission are detected and resolved in all disks and show velocity patterns consistent with Keplerian rotation. Where detected, the emission from DCO+ 3-2, N2H+ 3-2, H2CO 3-2 and 4-3,HCN 3-2 and CN 2-1 are also generally spatially resolved. The detection rates are highest toward the M and K stars, while the F star SAO 206462 has only weak CN and HCN emission, and H2CO alone is detected toward HD 142527. These findings together with the statistics from the previous Taurus disks, support the hypothesis that high detection rates of many small molecules depend on the presence of a cold and protected disk midplane, which is less common around F and A stars compared to M and K stars. Disk-averaged variations in the proposed radiation tracer CN/HCN are found to be small, despite two orders of magnitude range of spectral types and accretion rates. In contrast, the resolved images suggest that the CN/HCN emission ratio varies with disk radius in at least two of the systems. There are no clear observational differences in the disk chemistry between the classical/full T Tauri disks and transitional disks. Furthermore, the observed line emission does not depend on measured accretion luminosities or the number of infrared lines detected, which suggests that the chemistry outside of 100 AU is not coupled to the physical processes that drive the chemistry in the innermost few AU.

astro-ph.GA↗

arXiv2010

Disk Imaging Survey of Chemistry with SMA (DISCS): I. Taurus Protoplanetary Disk Data

Chemistry plays an important role in the structure and evolution of protoplanetary disks, with implications for the composition of comets and planets. This is the first of a series of papers based on data from DISCS, a Submillimeter Array survey of the chemical composition of protoplanetary disks. The six Taurus sources in the program (DM Tau, AA Tau, LkCa 15, GM Aur, CQ Tau and MWC 480) range in stellar spectral type from M1 to A4 and offer an opportunity to test the effects of stellar luminosity on the disk chemistry. The disks were observed in 10 different lines at ~3" resolution and an rms of ~100 mJy beam-1 at ~0.5 km s-1. The four brightest lines are CO 2-1, HCO+ 3-2, CN 2_3-1_2 and HCN 3-2 and these are detected toward all sources (except for HCN toward CQ Tau). The weaker lines of CN 2_2-1_1, DCO+ 3-2, N2H+ 3-2, H2CO 3_03-2_02 and 4_14-3_13 are detected toward two to three disks each, and DCN 3-2 only toward LkCa 15. CH3OH 4_21-3_12 and c-C3H2 are not detected. There is no obvious difference between the T Tauri and Herbig Ae sources with regard to CN and HCN intensities. In contrast, DCO+, DCN, N2H+ and H2CO are detected only toward the T Tauri stars, suggesting that the disks around Herbig Ae stars lack cold regions for long enough timescales to allow for efficient deuterium chemistry, CO freeze-out, and grain chemistry.

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arXiv2010

The effect of H2O on ice photochemistry

UV irradiation of simple ices is proposed to efficiently produce complex organic species during star- and planet-formation. Through a series of laboratory experiments, we investigate the effects of the H2O concentration, the dominant ice constituent in space, on the photochemistry of more volatile species, especially CH4, in ice mixtures. In the experiments, thin (~40 ML) ice mixtures, kept at 20-60 K, are irradiated under ultra-high vacuum conditions with a broad-band UV hydrogen discharge lamp. Photodestruction cross sections of volatile species (CH4 and NH3) and production efficiencies of new species (C2H6, C2H4, CO, H2CO, CH3OH, CH3CHO and CH3CH2OH) in water-containing ice mixtures are determined using reflection-absorption infrared spectroscopy during irradiation and during a subsequent slow warm-up. The four major effects of increasing the H2O concentration are 1) an increase of the destruction efficiency of the volatile mixture constituent by up to an order of magnitude due to a reduction of back reactions following photodissociation, 2) a shift to products rich in oxygen e.g. CH3OH and H2CO, 3) trapping of up to a factor of five more of the formed radicals in the ice and 4) a disproportional increase in the diffusion barrier for the OH radical compared to the CH3 and HCO radicals. The radical diffusion temperature dependencies are consistent with calculated H2O-radical bond strengths. All the listed effects are potentially important for the production of complex organics in H2O-rich icy grain mantles around protostars and should thus be taken into account when modeling ice chemistry.

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arXiv2010

The c2d Spitzer Spectroscopic Survey of Ices Around Low-Mass Young Stellar Objects. IV. NH3 and CH3OH

NH3 and CH3OH are key molecules in astrochemical networks leading to the formation of more complex N- and O-bearing molecules, such as CH3CN and HCOOCH3. Despite a number of recent studies, little is known about their abundances in the solid state. (...) In this work, we investigate the ~ 8-10 micron region in the Spitzer IRS (InfraRed Spectrograph) spectra of 41 low-mass young stellar objects (YSOs). These data are part of a survey of interstellar ices in a sample of low-mass YSOs studied in earlier papers in this series. We used both an empirical and a local continuum method to correct for the contribution from the 10 micron silicate absorption in the recorded spectra. In addition, we conducted a systematic laboratory study of NH3- and CH3OH-containing ices to help interpret the astronomical spectra. We clearly detect a feature at ~9 micron in 24 low-mass YSOs. Within the uncertainty in continuum determination, we identify this feature with the NH3 nu_2 umbrella mode, and derive abundances with respect to water between ~2 and 15%. Simultaneously, we also revisited the case of CH3OH ice by studying the nu_4 C-O stretch mode of this molecule at ~9.7 micron in 16 objects, yielding abundances consistent with those derived by Boogert et al. 2008 (hereafter paper I) based on a simultaneous 9.75 and 3.53 micron data analysis. Our study indicates that NH3 is present primarily in H2O-rich ices, but that in some cases, such ices are insufficient to explain the observed narrow FWHM. The laboratory data point to CH3OH being in an almost pure methanol ice, or mixed mainly with CO or CO2, consistent with its formation through hydrogenation on grains. Finally, we use our derived NH3 abundances in combination with previously published abundances of other solid N-bearing species to find that up to 10-20 % of nitrogen is locked up in known ices.

astro-ph.GA↗

arXiv2010

A cold complex chemistry toward the low-mass protostar B1-b: evidence for complex molecule production in ices

Gas-phase complex organic molecules have been detected toward a range of high- and low-mass star-forming regions at abundances which cannot be explained by any known gas-phase chemistry. Recent laboratory experiments show that UV irradiation of CH3OH-rich ices may be an important mechanism for producing complex molecules and releasing them into the gas-phase. To test this ice formation scenario we mapped the B1-b dust core and nearby protostar in CH3OH gas using the IRAM 30m telescope to identify locations of efficient non-thermal ice desorption. We find three CH3OH abundance peaks tracing two outflows and a quiescent region on the side of the core facing the protostar. The CH3OH gas has a rotational temperature of ~10 K at all locations. The quiescent CH3OH abundance peak and one outflow position were searched for complex molecules. Narrow, 0.6-0.8 km s-1 wide, HCOOCH3 and CH3CHO lines originating in cold gas are clearly detected, CH3OCH3 is tentatively detected and C2H5OH and HOCH2CHO are undetected toward the quiescent core, while no complex molecular lines were found toward the outflow. The core abundances with respect to CH3OH are ~2.3% and 1.1% for HCOOCH3 and CH3CHO, respectively, and the upper limits are 0.7-1.1%, which is similar to most other low-mass sources. The observed complex molecule characteristics toward B1-b and the pre-dominance of HCO-bearing species suggest a cold ice (below 25 K, the sublimation temperature of CO) formation pathway followed by non-thermal desorption through e.g. UV photons traveling through outflow cavities. The observed complex gas composition together with the lack of any evidence of warm gas-phase chemistry provide clear evidence of efficient complex molecule formation in cold interstellar ices.

astro-ph.GA↗

arXiv2009

Photodesorption of ices I: CO, N2 and CO2

A longstanding problem in astrochemistry is how molecules can be maintained in the gas phase in dense inter- and circumstellar regions. Photodesorption is a non-thermal desorption mechanism, which may explain the small amounts of observed cold gas in cloud cores and disk mid-planes. This paper aims to determine the UV photodesorption yields and to constrain the photodesorption mechanisms of three astrochemically relevant ices: CO, N2 and CO2. In addition, the possibility of co-desorption in mixed and layered CO:N2 ices is explored. The ice photodesorption is studied experimentally under ultra high vacuum conditions and at 15-60 K using a hydrogen discharge lamp (7-10.5 eV). The ice desorption during irradiation is monitored by reflection absorption infrared spectroscopy of the ice and simultaneous mass spectrometry of the desorbed molecules. Both the UV photodesorption yields per incident photon and the photodesorption mechanisms are molecule specific. CO photodesorbs without dissociation from the surface layer of the ice. N2, which lacks an electronic transition in this wavelength range, has a photodesorption yield that is more than an order of magnitude lower. This yield increases significantly due to co-desorption when N2 is mixed in with or layered on top of CO ice. CO2 photodesorbs through dissociation and subsequent recombination from the top 10 layers of the ice. At low temperatures (15-18 K) the derived photodesorption yields are 2.7x10^-3 and <2x10^-4 molecules photon-1 for pure CO and N2, respectively. The CO2 photodesorption yield is 1.2x10^-3x(1-e^(-X/2.9)) + 1.1x10^-3x(1-e^(-X/4.6)) molecules photon-1, where X is the ice thickness in monolayers and the two parts of the expression represent a CO2 and CO photodesorption pathway.

astro-ph↗

arXiv2009

Cold gas as an ice diagnostic toward low mass protostars

Up to 90% of the chemical reactions during star formation occurs on ice surfaces, probably including the formation of complex organics. Only the most abundant ice species are however observed directly by infrared spectroscopy. This study aims to develop an indirect observational method of ices based on non-thermal ice desorption in the colder part of protostellar envelopes. For that purpose the IRAM 30m telescope was employed to observe two molecules that can be detected both in the gas and the ice, CH3 OH and HNCO, toward 4 low mass embedded protostars. Their respective gas-phase column densities are determined using rotational diagrams. The relationship between ice and gas phase abundances is subsequently determined. The observed gas and ice abundances span several orders of magnitude. Most of the CH3OH and HNCO gas along the lines of sight is inferred to be quiescent from the measured line widths and the derived excitation temperatures, and hence not affected by thermal desorption close to the protostar or in outflow shocks. The measured gas to ice ratio of ~10-4 agrees well with model predictions for non-thermal desorption under cold envelope conditions and there is a tentative correlation between ice and gas phase abundances. This indicates that non-thermal desorption products can serve as a signature of the ice composition. A larger sample is however necessary to provide a conclusive proof of concept.

astro-ph.SR↗

arXiv2008

Photodesorption of Ices II: H2O and D2O

Gaseous H2O has been detected in several cold astrophysical environments, where the observed abundances cannot be explained by thermal desorption of H2O ice or by H2O gas phase formation. These observations hence suggest an efficient non-thermal ice desorption mechanism. Here, we present experimentally determined UV photodesorption yields of H2O and D2O ice and deduce their photodesorption mechanism. The ice photodesorption is studied under ultra high vacuum conditions and at astrochemically relevant temperatures (18-100 K) using a hydrogen discharge lamp (7-10.5 eV), which simulates the interstellar UV field. The ice desorption during irradiation is monitored using reflection absorption infrared spectroscopy of the ice and simultaneous mass spectrometry of the desorbed species. The photodesorption yield per incident photon is identical for H2O and D2O and depends on both ice thickness and temperature. For ices thicker than 8 monolayers the photodesorption yield Y is linearly dependent on temperature due to increased diffusion of ice species such that Y(T) = 1E-3(1.3+0.032*T) UV photon-1, with a 60% uncertainty for the absolute yield. The increased diffusion also results in an increasing H2O:OH desorption product ratio with temperature. The yield does not depend on the substrate, the UV photon flux or the UV fluence. The yield is also independent on the initial ice structure since UV photons efficiently amorphize H2O ice. The results are consistent with theoretical predictions of H2O photodesorption and partly in agreement with a previous experimental study. Applying the experimentally determined yield to a Herbig Ae/Be star+disk model shows that UV photodesorption of ices increases the H2O content by orders of magnitude in the disk surface region compared to models where non-thermal desorption is ignored.

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arXiv2008

The c2d Spitzer spectroscopy survey of ices around low-mass young stellar objects, III: CH4

CH4 is proposed to be the starting point of a rich organic chemistry. Solid CH4 abundances have previously been determined mostly toward high mass star forming regions. Spitzer/IRS now provides a unique opportunity to probe solid CH4 toward low mass star forming regions as well. Infrared spectra from the Spitzer Space Telescope are presented to determine the solid CH4 abundance toward a large sample of low mass young stellar objects. 25 out of 52 ice sources in the $c2d$ (cores to disks) legacy have an absorption feature at 7.7 um, attributed to the bending mode of solid CH4. The solid CH4 / H2O abundances are 2-8%, except for three sources with abundances as high as 11-13%. These latter sources have relatively large uncertainties due to small total ice column densities. Toward sources with H2O column densities above 2E18 cm-2, the CH4 abundances (20 out of 25) are nearly constant at 4.7+/-1.6%. Correlation plots with solid H2O, CH3OH, CO2 and CO column densities and abundances relative to H2O reveal a closer relationship of solid CH4 with CO2 and H2O than with solid CO and CH3OH. The inferred solid CH4 abundances are consistent with models where CH4 is formed through sequential hydrogenation of C on grain surfaces. Finally the equal or higher abundances toward low mass young stellar objects compared with high mass objects and the correlation studies support this formation pathway as well, but not the two competing theories: formation from CH3OH and formation in gas phase with subsequent freeze-out.

astro-ph↗

arXiv2007

Band profiles and band strengths in mixed H2O:CO ices

A laboratory study on the band profiles and band strengths of H2O in CO ice, and vice versa, is presented and interpreted in terms of two models. The results show that a mutual interaction takes place between the two species in the solid, which alters the band positions and band strengths. It is found that the band strengths of the H2O bulk stretch, bending and libration vibrational bands decrease linearly by a factor of up to 2 when the CO concentration is increased from 0 to 80%. By contrast, the band strength of the free OH stretch increases linearly. The results are compared to a recently performed quantitative study on H2O:CO2 ice mixtures. It is shown that for mixing ratios of 1:0.5 H2O:X and higher, the H2O bending mode offers a good tracer to distinguish between CO2 or CO in H2O ice. Additionally, it is found that the band strength of the CO fundamental remains constant when the water concentration is increased in the ice. The integrated absorbance of the 2152 cm-1 CO feature, with respect to the total integrated CO absorption feature, is found to be a good indicator of the degree of mixing of CO in the H2O:CO laboratory ice system. From the change in the H2O absorption band strength in laboratory ices upon mixing we conclude that astronomical water ice column densities on various lines of sight can be underestimated by up to 25% if significant amounts of CO and CO2 are mixed in.

astro-ph↗

arXiv2007

The c2d Spitzer spectroscopic survey of ices around low-mass young stellar objects II: CO2

This paper presents Spitzer-IRS spectroscopy of the CO2 15.2 micron bending mode toward a sample of 50 embedded low-mass stars in nearby star-forming clouds, taken mostly from the ``Cores to Disks (c2d)'' Legacy program. The average abundance of solid CO2 relative to water in low-mass protostellar envelopes is 0.32 +/- 0.02, significantly higher than that found in quiescent molecular clouds and in massive star forming regions. It is found that a decomposition of all the observed CO2 bending mode profiles requires a minimum of five unique components. Roughly 2/3 of the CO2 ice is found in a water-rich environment, while most of the remaining 1/3 is found in a CO environment. Ground-based observations of solid CO toward a large subset of the c2d sample are used to further constrain the CO2:CO component and suggest a model in which low-density clouds form the CO2:H2O component and higher density clouds form the CO2:CO ice during and after the freeze-out of gas-phase CO. It is suggested that the subsequent evolution of the CO2 and CO profiles toward low-mass protostars, in particular the appearance of the splitting of the CO2 bending mode due to pure, crystalline CO2, is first caused by distillation of the CO2:CO component through evaporation of CO due to thermal processing to ~20-30 K in the inner regions of infalling envelopes. The formation of pure CO2 via segregation from the H2O rich mantle may contribute to the band splitting at higher levels of thermal processing (>50 K), but is harder to reconcile with the physical structure of protostellar envelopes around low-luminosity objects.

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arXiv2007

Photodesorption of CO ice

At the high densities and low temperatures found in star forming regions, all molecules other than H2 should stick on dust grains on timescales shorter than the cloud lifetimes. Yet these clouds are detected in the millimeter lines of gaseous CO. At these temperatures, thermal desorption is negligible and hence a non-thermal desorption mechanism is necessary to maintain molecules in the gas phase. Here, the first laboratory study of the photodesorption of pure CO ice under ultra high vacuum is presented, which gives a desorption rate of 3E-3 CO molecules per UV (7-10.5 eV) photon at 15 K. This rate is factors of 1E2-1E5 larger than previously estimated and is comparable to estimates of other non-thermal desorption rates. The experiments constrains the mechanism to a single photon desorption process of ice surface molecules. The measured efficiency of this process shows that the role of CO photodesorption in preventing total removal of molecules in the gas has been underestimated.

astro-ph↗

arXiv2006

Effects of CO2 on H2O band profiles and band strengths in mixed H2O:CO2 ices

H2O is the most abundant component of astrophysical ices. In most lines of sight it is not possible to fit both the H2O 3 um stretching, the 6 um bending and the 13 um libration band intensities with a single pure H2O spectrum. Recent Spitzer observations have revealed CO2 ice in high abundances and it has been suggested that CO2 mixed into H2O ice can affect relative strengths of the 3 um and 6 um bands. We used laboratory infrared transmission spectroscopy of H2O:CO2 ice mixtures to investigate the effects of CO2 on H2O ice spectral features at 15-135 K. We find that the H2O peak profiles and band strengths are significantly different in H2O:CO2 ice mixtures compared to pure H2O ice. In all H2O:CO2 mixtures, a strong free-OH stretching band appears around 2.73 um, which can be used to put an upper limit on the CO2 concentration in the H2O ice. The H2O bending mode profile also changes drastically with CO2 concentration; the broad pure H2O band gives way to two narrow bands as the CO2 concentration is increased. This makes it crucial to constrain the environment of H2O ice to enable correct assignments of other species contributing to the interstellar 6 um absorption band. The amount of CO2 present in the H2O ice of B5:IRS1 is estimated by simultaneously comparing the H2O stretching and bending regions and the CO2 bending mode to laboratory spectra of H2O, CO2, H2O:CO2 and HCOOH.

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