arXiv subjects

Karthik Peddireddy

Publications and source records attributed to Karthik Peddireddy.

3 recordsLinked to original sources

arXiv2026

Molecular chirality controls droplet division and helical fiber formation in liquid crystal emulsions

Molecular chirality is a source of broken mirror symmetry, but using it to control mesoscale structures with a tunable length scale remains challenging. Here, we demonstrate that adding a chiral dopant to nematic liquid crystal droplets bounded by a deformable two-surfactant interface controls their morphogenesis: the ratio of droplet diameter to cholesteric pitch determines whether droplets divide asymmetrically or symmetrically upon cooling, and whether they transform into single- or double-strand helical fibers. The fiber periodicity and thickness both scale linearly with the cholesteric pitch, which varies by less than 2% with temperature across the self-shaping window. Numerical simulations reveal that chirality-driven elastic stresses at the interface destabilize the droplets and trigger cusp-mediated shape transformations. These results establish cholesteric pitch as a design variable to precisely control droplet division and decouple the dimensions of spontaneously formed mesoscale structures from temperature dependence.

cond-mat.soft↗

arXiv2022

Active restructuring of cytoskeleton composites leads to increased mechanical stiffness, memory, and heterogeneity

The composite cytoskeleton, comprising interacting networks of semiflexible actin and rigid microtubules, actively generates forces and restructures using motor proteins such as myosins to enable key mechanical processes including cell motility and mitosis. Yet, how motor-driven activity alters the mechanics of cytoskeleton composites remains an open challenge. Here, we perform optical tweezers microrheology on actin-microtubule composites driven by myosin II motors to show that motor activity increases the linear viscoelasticity and elastic storage of the composite by active restructuring to a network of tightly-packed filament clusters and bundles. Our nonlinear microrheology measurements performed hours after cessation of activity show that the motor-contracted structure is stable and robust to nonlinear forcing. Unique features of the nonlinear response include increased mechanical stiffness, memory and heterogeneity, coupled with suppressed filament bending following motor-driven restructuring. Our results shed important new light onto the interplay between viscoelasticity and non-equilibrium dynamics in active polymer composites such as the cytoskeleton.

cond-mat.soft↗

arXiv2022

Cellulose-Based Reflective Liquid Crystal Films as Optical Filters and Solar Gain Regulators

Many promising approaches for designing interactions of synthetic materials with light involve solid optical monocrystals and nanofabricated photonic crystal structures with spatially periodic variations of refractive index. Although their high costs limit current technological applications, remarkably, such photonic and optically anisotropic materials have also evolved throughout nature and enable narrow or broad-band spectral reflection of light. Here we use self-assembly of biomaterial cellulose nanocrystals to obtain three-layer films with helicoidal and nematic-like organization of the cellulose nanoparticles, which mimics naturally occurring polarization-insensitive reflectors found in the wings of Plusiotis resplendens beetles. These films were characterized with polarized optical microscopy and circular dichroism spectrometry, as well as scanning and transmission electron microscopies. These films exhibit high reflectivity tunable within the visible and near-infrared regions of the optical spectrum and may find applications ranging from color filters to smart cloth designs and in solar-gain-regulating building technologies.

cond-mat.mtrl-sci↗