arXiv subjects

Katarina Karlova

Publications and source records attributed to Katarina Karlova.

At least 19 recordsLinked to original sources

arXiv2026

Approaching Kasteleyn transition in frustrated quantum Heisenberg antiferromagnets

We show that the Kasteleyn transition, the abrupt proliferation of infinite strings of defects in classical dimer and related models, can also be relevant for frustrated 2d quantum magnets. This is explicitly demonstrated in a phase of the spin-1/2 Heisenberg diamond-decorated honeycomb lattice where a family of exact eigenstates built as products of dimer and plaquette singlets can be mapped onto the dimer coverings of the honeycomb lattice. The low-temperature properties of this phase are accurately described by an effective dimer model with anisotropic activities and a small, tunable density of monomers, leading to an arbitrarily sharp crossover version of the Kasteleyn transition. The generalization to other geometries and the possibility to realize this model in organo-metallic compounds are briefly discussed.

cond-mat.stat-mech↗

arXiv2026

Thermal phase transitions in a mixed-spin Ising model on the Lieb lattice: Exact results beyond zero magnetic field

We investigate the ground-state and finite-temperature properties of a mixed spin-1/2 and spin-1 Ising model on a decorated square (Lieb) lattice incorporating a uniaxial single-ion anisotropy and magnetic field. By employing the generalized decoration-iteration transformation, the model is mapped exactly onto an effective spin-1/2 Ising model on the square lattice characterized by an effective nearest-neighbor interaction and an effective field. The studied model consequently becomes exactly solvable even for finite values of the applied magnetic field whenever the effective field vanishes. The ground-state analysis reveals three distinct phases: ferrimagnetic phase (FRI), disordered phase (DP), and ferromagnetic (FM) phase. The ground-state boundary between FRI and DP phases gives rise to a dome-shaped surface of discontinuous thermal phase transitions, which is terminated by a line of Ising-type critical points associated with continuous thermal phase transitions. Both continuous and discontinuous thermal phase transitions belong to the exactly solvable parameter regime defined by a vanishing effective field in spite of the fact that the applied magnetic field is finite. Two consecutive discontinuous thermally-induced reentrant phase transitions DP-FRI-DP are identified in a narrow parameter region. The exact analytical predictions including reentrance, field- and thermally-driven phase transitions are independently verified by classical Monte Carlo simulations.

cond-mat.stat-mech↗

arXiv2026

Magnetization plateaus, spin-canted orders and field-induced transitions in a spin-1/2 Heisenberg antiferromagnet on a distorted diamond-decorated honeycomb lattice

We investigate the spin-1/2 Heisenberg antiferromagnet on a distorted diamond-decorated honeycomb lattice in an external magnetic field. By combining density-matrix renormalization group, sign-problem-free quantum Monte Carlo in a mixed dimer-monomer basis, exact diagonalization, and an effective lattice-gas approach, we determine the ground-state phase diagram and analyze the finite-temperature magnetization process. The model hosts a rich variety of frustration-induced quantum phases including a quantum ferrimagnetic phase of Lieb-Mattis type, a quantum ferromagnetic phase, a spin-canted phase, a monomer-dimer phase, a dimer-tetramer liquid, a dimer-tetramer solid, and two distinct one-dimensional-crossover phases of ferromagnetic and ferrimagnetic character. Depending on the lattice distortion, we identify robust magnetization plateaus at 0, 1/4, 1/2, and 3/4 of the saturation magnetization originating from competing local dimer and tetramer singlets. Finite-temperature QMC data reveal how thermal fluctuations progressively smear the plateau structure, while the effective lattice-gas description reliably captures the corresponding low-temperature behavior.

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arXiv2025

Fingerprints of cluster-based Haldane and bound-magnon states in a spin-1 Heisenberg diamond chain

We investigate magnetic and thermodynamic properties of a spin-1 Heisenberg diamond chain in a magnetic field using a combination of analytical and numerical methods including the variational approach, exact diagonalization, density-matrix renormalization group, localized-magnon theory, and quantum Monte Carlo simulations. In the unfrustrated regime, the model exhibits a quantum ferrimagnetic phase that captures key magnetic features of the nickel-based polymeric compound [Ni3(OH)2(C4H2O4)(H2O)4].2H2O such as a at minimum in the temperature dependence of the susceptibility times temperature product and an intermediate one-third magnetization plateau. In the frustrated regime, we uncover a rich variety of unconventional quantum phases including uniform and cluster-based Haldane states, fragmented monomer-dimer phase, and bound-magnon crystals. Analysis of the adiabatic temperature change and magnetic Gruneisen parameter reveals an enhanced magnetocaloric effect near field-induced transitions between these exotic quantum phases. Additionally, we demonstrate that the frustrated spin-1 diamond chain can operate as an efficient working medium of a quantum Stirling engine, which approaches near-optimal efficiency when driven into these unconventional quantum states.

cond-mat.stat-mech↗

arXiv2025

Thermodynamic properties of the macroscopically degenerate tetramer-dimer phase of the spin-1/2 Heisenberg model on the diamond-decorated square lattice

The spin-1/2 Heisenberg antiferromagnet on the diamond-decorated square lattice in the presence of a magnetic field displays various quantum phases including the Lieb-Mattis ferrimagnetic, dimer-tetramer, monomer-dimer, and spin-canted phases, in addition to the trivial fully saturated state. Thermodynamic properties of this model are investigated using several complementary analytical and numerical methods such as exact diagonalization up to the systems of 40 spins, an effective monomer-dimer description, sign-problem-free quantum Monte Carlo simulations for up to 180 spins, and a decoupling approximation. Our particular attention is focused on the parameter region favoring the dimer-tetramer phase. This ground state can be represented by a classical hard-dimer model on the square lattice and retains a macroscopic degeneracy even under a magnetic field. However, the description of the low-temperature thermodynamics close to the boundary between the macroscopically degenerate dimer-tetramer and the non-degenerate monomer-dimer phases requires an extended classical monomer-dimer lattice-gas model. Anomalous thermodynamic properties emerging in the vicinity of the dimer-tetramer phase are studied in detail. Under the adiabatic demagnetization we detect an enhanced magnetocaloric effect promoting an efficient cooling to absolute zero temperature, provided that the system reaches the dimer-tetramer ground state at zero field.

cond-mat.str-el↗

arXiv2024

Pseudo-transition between antiferromagnetic and charge orders in a minimal spin-pseudospin model of one-dimensional cuprates

This study rigorously investigates the phenomenon of a pseudo-transition in a minimal spinpseudospin model, serving as a simplified model of one-dimensional cuprate chains [CuO]n, by making use of the transfer-matrix method. The studied spin-pseudospin model of one-dimensional cuprate chains [CuO]n reveals a peculiar pseudo-transition between a charged-ordered phase and an antiferromagnetic phase, which is accompanied with anomalous behavior of magnetic and thermodynamic quantities. While the entropy and short-range correlations undergo near the pseudo-transition steep continuous changes reminiscent of a discontinuous phase transition, the specific heat displays a sizable sharp peak akin to a continuous phase transition.

cond-mat.stat-mech↗

arXiv2024

Quantum Magnetism in Fe2Cu2 Polymeric Branched Chains: Insights from Exactly Solved Ising-Heisenberg Model

The spin-1/2 Ising-Heisenberg branched chain, inspired by the magnetic structure of three isostructural polymeric coordination compounds [(Tp)2Fe2(CN)6X(bdmap)Cu2(H2O)].H2O to be further denoted as Fe2Cu2 (Tp = tris(pyrazolyl)hydroborate, bdmapH = 1,3-bis(dimethylamino)-2-propanol, HX = acetic acid, propionic acid or trifluoroacetic acid), is rigorously studied using the transfer-matrix method. The overall ground-state phase diagram reveals three distinct phases: a quantum antiferromagnetic phase, a quantum ferrimagnetic phase and a classical ferromagnetic phase. In the zero-temperature magnetization curve, two quantum ground states are manifested as intermediate plateaus at zero and half of the saturation magnetization, while the magnetization reaches its saturated value within the classical ferromagnetic phase. The bipartite entanglement between nearest-neighbor Heisenberg spins is more pronounced in the quantum ferrimagnetic phase compared to the quantum antiferromagnetic phase due to a fully polarized nature of the Ising spins. A reasonable agreement between theoretical predictions for the spin-1/2 Ising-Heisenberg branched chain and experimental data measured for a temperature dependence of the magnetic susceptibility and a low-temperature magnetization curve suggests strong antiferromagnetic coupling between nearest-neighbor CuII-CuII magnetic ions and moderately strong ferromagnetic coupling between nearest-neighbor CuII-FeIII magnetic ions in the polymeric compounds Fe2Cu2. A thermal entanglement between nearest-neighbor CuII-CuII magnetic ions persists up to a relatively high threshold temperature T = 224 K and undergoes a transient magnetic-field-driven strengthening.

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arXiv2023

Magnetic analogue of liquid-gas phase transition of water: case study of a spin-1/2 Ising-Heisenberg model on a diamond-decorated square lattice

The spin-1/2 Ising-Heisenberg model on a diamond-decorated square lattice exhibits an intriguing temperature-driven phase transition in a magnetic field between a classical ferrimagnetic phase and a quantum monomer-dimer phase. A generalized decoration-iteration transformation accurately maps the considered model to an effective spin-1/2 Ising model on a square lattice with temperature-dependent effective interactions and field, whereby the effective field vanishes at the phase boundary separating the classical ferrimagnetic phase from the quantum monomer-dimer phase. Typical features of the magnetization, magnetic susceptibility and specific heat in the vicinity of discontinuous and continuous thermal phase transitions between the classical ferrimagnetic phase and the quantum monomer-dimer phase are elucidated.

cond-mat.stat-mech↗

arXiv2023

Thermal first-order phase transitions, Ising critical points, and reentrance in the Ising-Heisenberg model on the diamond-decorated square lattice in a magnetic field

The thermal phase transitions of a spin-1/2 Ising-Heisenberg model on the diamond-decorated square lattice in a magnetic field are investigated using a decoration-iteration transformation and classical Monte Carlo simulations. A generalized decoration-iteration transformation maps this model exactly onto an effective classical Ising model on the square lattice with temperature-dependent effective nearest-neighbor interactions and magnetic field strength. The effective field vanishes along a ground-state phase boundary of the original model, separating a ferrimagnetic and a quantum monomer-dimer phase. At finite temperatures this phase boundary gives rise to an exactly solvable surface of discontinuous (first-order) phase transitions, which terminates in a line of Ising critical points. The existence of discontinuous reentrant phase transitions within a narrow parameter regime is reported and explained in terms of the low-energy excitations from both phases. These exact results, obtained from the mapping to the zero-field effective Ising model are corroborated by classical Monte Carlo simulations of the effective model.

cond-mat.stat-mech↗

arXiv2023

Phases of the spin-1/2 Heisenberg antiferromagnet on the diamond-decorated square lattice in a magnetic field

The spin-1/2 Heisenberg antiferromagnet on the frustrated diamond-decorated square lattice is known to feature various zero-field ground-state phases, consisting of extended monomer-dimer and dimer-tetramer ground states as well as a ferrimagnetic regime. Using a combination of analytical arguments, density matrix renormalization group (DMRG), exact diagonalization, as well as sign-problem-free quantum Monte Carlo (QMC) calculations, we investigate the properties of this system and the related Lieb lattice in the presence of a finite magnetic field, addressing both the ground-state phase diagram as well as several thermodynamic properties. In addition to the zero-field ground states, we find at high magnetic field a spin-canted phase with a continuously rising magnetization for increasing magnetic field strength, as well as the fully polarized paramagnetic phase. At intermediate field strength, we identify a first-order quantum phase transition line between the ferrimagnetic and the monomer-dimer regime. This first-order line extends to finite temperatures, terminating in a line of critical points that belong to the universality class of the two-dimensional Ising model.

cond-mat.str-el↗

arXiv2023

Thermal entanglement of a geometrically frustrated spin-1 Heisenberg diamond cluster

Thermal entanglement of a geometrically frustrated spin-1 Heisenberg diamond cluster is examined within the framework of the exact diagonalization method by computing the measure of entanglement negativity. The calculated exact analytical results are applied in order to obtain theoretical prediction of the robustness of bipartite thermal entanglement of the tetranuclear nickel complex [Ni4(CO3)2(aetpy)8](ClO4)4 (aetpy = 2-aminoethyl-pyridine) against rising temperature and magnetic field.

cond-mat.stat-mech↗

arXiv2022

Towards lattice-gas description of low-temperature properties above the Haldane and cluster-based Haldane ground states of a mixed spin-(1,1/2) Heisenberg octahedral chain

The rich ground-state phase diagram of the mixed spin-(1,1/2) Heisenberg octahedral chain was previously elaborated from effective mixed-spin Heisenberg chains, which were derived by employing a local conservation of a total spin on square plaquettes of an octahedral chain. Here we present a comprehensive analysis of the thermodynamic properties of this model. In the highly frustrated parameter region the lowest-energy eigenstates of the mixed-spin Heisenberg octahedral chain belong to flat bands, which allow a precise description of low-temperature magnetic properties within the localized-magnon approach exploiting a classical lattice-gas model of hard-core monomers. The present article provides a more comprehensive version of the localized-magnon approach, which extends the range of its validity down to a less frustrated parameter region involving the Haldane and cluster-based Haldane ground states. A comparison between results of the developed localized-magnon theory and accurate numerical methods such as full exact diagonalization and finite-temperature Lanczos technique convincingly evidence that the low-temperature magnetic properties above the Haldane and the cluster-based Haldane ground states can be extracted from a classical lattice-gas model of hard-core monomers and dimers, which is additionally supplemented by a hard-core particle spanned over the whole lattice representing the gapped Haldane phase.

cond-mat.stat-mech↗

arXiv2021

Influence of a spatial anisotropy on presence of the intermediate one-half magnetization plateau of a spin-1/2 Ising-Heisenberg branched chain

A spin-1/2 Ising-Heisenberg branched chain constituted by regularly alternating Ising spins and Heisenberg dimers involving an additional side branching is exactly solved in a magnetic field by the transfer-matrix method. The spin-1/2 Ising-Heisenberg branched chain involves two different Ising and one Heisenberg coupling constants. The overall ground-state phase diagram is formed by three different ground states emergent depending on a mutual interplay between the magnetic field and three considered coupling constants: the modulated quantum antiferromagnetic phase, the quantum ferrimagnetic phase, and the classical ferromagnetic phase. It is shown that the interaction anisotropy connected to two different Ising coupling constants substantially influences a breakdown of the intermediate one-half magnetization plateau, which represents a macroscopic manifestation of the quantum ferrimagnetic phase.

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arXiv2021

Effect of uniaxial single-ion anisotropy on a stability of intermediate magnetization plateaus of a spin-1 Heisenberg diamond cluster

Ground-state phase diagrams and magnetization curves of a spin-1 Heisenberg diamond cluster with two different coupling constants and uniaxial single-ion anisotropy are investigated in a presence of the external magnetic field with the help of exact diagonalization methods. It is shown that the spin-1 Heisenberg diamond cluster exhibits several remarkable quantum ground states, which are manifested in zero- and low-temperature magnetization curves as intermediate plateaus at one-quarter, one-half and three-quarters of the saturation magnetization. It is found that the width of the fractional magnetization plateaus depends basically on a relative strength of the coupling constants as well as uniaxial single-ion anisotropy, which may substantially shrink or even cause full breakdown of some intermediate magnetization plateaus. It is evidenced that a relatively weak uniaxial single-ion anisotropy of the easy-axis type considerably improves a theoretical fit of low-temperature magnetization curves of the tetranuclear nickel complex [Ni4(CO3)2(aetpy)8](ClO4)4 in a low-field region without spoiling the previous fit based on the fully isotropic Heisenberg model in a high-field region.

cond-mat.str-el↗

arXiv2021

On the failure of effective-field theory in predicting a spurious spontaneous ordering and phase transition of Ising nanoparticles, nanoislands, nanotubes and nanowires

The present work clarifies a failure of the effective-field theory in predicting a false spontaneous long-range order and phase transition of Ising nanoparticles, nanoislands, nanotubes and nanowires with either zero- or one-dimensional magnetic dimensionality. It is conjectured that the standard formulation of the effective-field theory due to Honmura and Kaneyoshi generally predicts for the Ising spin systems a spurious spontaneous long-range order with nonzero critical temperature regardless of their magnetic dimensionality whenever at least one Ising spin has coordination number greater than two. The failure of the effective-field theory is exemplified on a few paradigmatic exactly solved examples of zero- and one-dimensional Ising nanosystems: star, cube, decorated hexagon, star of David, branched chain, sawtooth chain, two-leg and hexagonal ladders. The presented exact solutions illustrate eligibility of a few rigorous analytical methods for exact treatment of the Ising nanosystems: exact enumeration, graph-theoretical approach, transfer-matrix method and decoration-iteration transformation. The paper also provides a substantial survey of the scientific literature, in which the effective-field theory led to a false prediction of the spontaneous long-range ordering and phase transition.

cond-mat.stat-mech↗

arXiv2020

Insights into nature of magnetization plateaus of a nickel complex [Ni4(CO3)2(aetpy)8](ClO4)4 from a spin-1 Heisenberg diamond cluster

Magnetic and magnetocaloric properties of a spin-1 Heisenberg diamond cluster with two different coupling constants are investigated with the help of an exact diagonalization based on the Kambe's method, which employs a local conservation of composite spins formed by spin-1 entities located in opposite corners of a diamond spin cluster. It is shown that the spin-1 Heisenberg diamond cluster exhibits several intriguing quantum ground states, which are manifested in low-temperature magnetization curves as intermediate plateaus at 1/4, 1/2 and 3/4 of the saturation magnetization. Besides, the spin-1 Heisenberg diamond cluster may also exhibit an enhanced magnetocaloric effect, which may be relevant for a low-temperature refrigeration achieved through the adiabatic demagnetization. It is evidenced that the spin-1 Heisenberg diamond cluster with the antiferromagnetic coupling constants J1/kB = 41.4 K and J2/kB = 9.2 K satisfactorily reproduces a low-temperature magnetization curve recorded for the tetranuclear nickel complex [Ni4(CO3)2(aetpy)8](ClO4)4 (aetpy = 2-aminoethyl-pyridine) including a size and position of intermediate plateaus detected at 1/2 and 3/4 of the saturation magnetization. A microscopic nature of fractional magnetization plateaus observed experimentally is clarified and interpreted in terms of valence-bond crystal with either a single or double valence bond. It is suggested that this frustrated magnetic molecule can provide a prospective cryogenic coolant with the maximal isothermal entropy change - Delta S = 10.6 J/(K.kg) in a temperature range below 2.3 K.

cond-mat.stat-mech↗

arXiv2019

Breakdown of intermediate one-half magnetization plateau of spin-1/2 Ising-Heisenberg and Heisenberg branched chains at triple and Kosterlitz-Thouless critical points

The spin-1/2 Ising-Heisenberg branched chain composed of regularly alternating Ising spins and Heisenberg dimers involving an additional side branching is rigorously solved in a magnetic field by the transfer-matrix approach. The ground-state phase diagram, the magnetization process and the concurrence measuring a degree of bipartite entanglement within the Heisenberg dimers are examined in detail. Three different ground states were found depending on a mutual interplay between the magnetic field and two different coupling constants: the modulated quantum antiferromagnetic phase, the quantum ferrimagnetic phase and the classical ferromagnetic phase. Two former quantum ground states are manifested in zero-temperature magnetization curves as intermediate plateaus at zero and one-half of the saturation magnetization, whereas the one-half plateau disappears at a triple point induced by a strong enough ferromagnetic Ising coupling. The ground-state phase diagram and zero-temperature magnetization curves of the analogous spin-1/2 Heisenberg branched chain were investigated using DMRG calculations. The latter fully quantum Heisenberg model involves, besides two gapful phases manifested as zero and one-half magnetization plateaus, gapless quantum spin-liquid phase. The intermediate one-half plateau of the spin-1/2 Heisenberg branched chain vanishes at Kosterlitz-Thouless quantum critical point between gapful and gapless quantum ground states unlike the triple point of the spin-1/2 Ising-Heisenberg branched chain.

cond-mat.stat-mech↗

arXiv2019

Cluster-based Haldane phases, bound magnon crystals and quantum spin liquids of a mixed spin-1 and spin-1/2 Heisenberg octahedral chain

The mixed spin-1 and spin-1/2 Heisenberg octahedral chain with regularly alternating monomeric spin-1 sites and square-plaquette spin-1/2 sites is investigated using variational technique, localized-magnon approach, exact diagonalization (ED) and density-matrix renormalization group (DMRG) method. The investigated model has in a magnetic field an extraordinarily rich ground-state phase diagram, which includes the uniform and cluster-based Haldane phases, two ferrimagnetic phases of Lieb-Mattis type, two quantum spin liquids and two bound magnon crystals in addition to the fully polarized ferromagnetic phase. The lowest-energy eigenstates in a highly-frustrated parameter region belong to flat bands and hence, low-temperature thermodynamics above the bound magnon-crystal ground states can be satisfactorily described within the localized-magnon approach. The variational method provides an exact evidence for the magnon-crystal phase with a character of the monomer-tetramer ground state at zero field, while another magnon-crystal phase with a single bound magnon at each square plaquette is found in a high-field region. A diversity of quantum ground states gives rise to manifold zero-temperature magnetization curves, which may involve up to four wide intermediate plateaus at zero, one-sixth, one-third and two-thirds of the saturation magnetization, two quantum spin-liquid regions and two tiny plateaus at one-ninth and one-twelfth of the saturation magnetization corresponding to the fragmentized cluster-based Haldane phases.

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