Bridgman method grown $Cs_2Li_3I_5$: an inter-alkali metal scintillator with high lithium content
In this study, we report on the growth of ternary caesium lithium iodide ($Cs_2Li_3I_5$, CLI) bulk crystals, both undoped and doped with thallium (Tl) and indium (In), using the miniaturised vertical Bridgman method (mVB). X-ray Powder Diffraction (XRPD) confirmed the presence of the ternary CLI phase in all three crystals, with CLI : In appearing homogeneous structure-wise throughout the entire ingot. Measurements of radioluminescence (RL), photoluminescence emission (PL), photoluminescence excitation (PLE) spectra, and photoluminescence decay kinetics (PL decay) demonstrated that the primary luminescence centers originate from the matrix itself. When doped with thallium, the efficiency of the luminescence was significantly increased. Furthermore, CLI : Tl and CLI : In crystals exhibited emission spectra similar to those of their doped caesium iodide counterparts, CsI : Tl and CsI : In, respectively. The main component of the PL decay was 523 ns, 557 ns, and 554 ns for the undoped, Tl+-doped, and In+-doped crystals, respectively. It is worthy of note that only CLI : Tl exhibited a single exponential decay. Differential Scanning Calorimetry (DSC) measurements revealed two endothermic peaks corresponding to the eutectic and liquidus temperature for CLI and CLI : In, indicating that this ternary compound has a congruent melting behaviour. Finally, the melting point of CLI was estimated to be approximately 220 °C.