arXiv subjects

Katharina Kaiser

Publications and source records attributed to Katharina Kaiser.

8 recordsLinked to original sources

arXiv2026

Dataset on residential electricity load profiles in Switzerland

Residential electricity profiles are undergoing significant changes due to the increasing adoption of distributed renewable generation, heat pumps, and electric vehicles. Up-to-date real-world measurements are essential for characterizing these evolving consumption patterns and providing a timely empirical foundation for research. This paper presents a dataset of 15-minute smart meter measurements from 2,447 residential installations in Switzerland, covering the years 2023 and 2024. The dataset encompasses both active and reactive energy (withdrawal and injection) of diverse installation types, including apartments, single-family houses, heat pumps, and common building areas. A subset of the associated customers participated in a pilot project featuring novel grid tariffs and automated load control. The corresponding price profiles and metadata are also included. The dataset aims to support research focusing on distribution grid modeling, load forecasting, and the assessment of time-varying tariffs.

eess.SY↗

arXiv2026

Residential Peak Load Reduction via Direct Load Control under Limited Information

Thermostatically controlled loads and electric vehicles offer flexibility to reduce power peaks in low-voltage distribution networks. This flexibility can be maximized if the devices are coordinated centrally, given some level of information about the controlled devices. In this paper, we propose novel optimization-based control schemes with prediction capabilities that utilize limited information from heat pumps, electric water heaters, and electric vehicles. The objective is to flatten the total load curve seen by the distribution transformer by restricting the times at which the available flexible loads are allowed to operate, subject to the flexibility constraints of the loads to preserve customers' comfort. The original scheme was tested in a real-world setup, considering both winter and summer days. The pilot results confirmed the technical feasibility but also informed the design of an improved version of the controller. Computer simulations using the adjusted controller show that, compared to the original formulation, the improved scheme achieves greater peak reductions in summer. Additionally, comparisons were made with an ideal controller, which assumes perfect knowledge of the inflexible load profile, the models of the controlled devices, the hot water and space heating demand, and future electric vehicle charging sessions. The proposed scheme with limited information achieves almost half of the potential average daily peak reduction that the ideal controller with perfect knowledge would achieve.

eess.SY↗

arXiv2024

Gating single-molecule fluorescence with electrons

Tip-enhanced photoluminescence (TEPL) measurements are performed with sub-nanometer spatial resolution on individual molecules decoupled from a metallic substrate by a thin NaCl layer. TEPL spectra reveal progressive fluorescence quenching with decreasing tip-molecule distance when electrons tunneling from the tip of a scanning tunneling microscope are injected at resonance with the molecular states. Rate equations based on a many-body model reveal that the luminescence quenching is due to a progressive population inversion between the ground neutral (S$_0$) and the ground charge ($D_0^-$) states of the molecule occurring when the current is raised. We demonstrate that both the bias voltage and the atomic-scale lateral position of the tip can be used to gate the molecular emission. Our approach can in principle be applied to any molecular system, providing unprecedented control over the fluorescence of a single molecule.

cond-mat.mes-hall↗

arXiv2024

Electrically driven cascaded photon-emission in a single molecule

Controlling electrically-stimulated quantum light sources (QLS) is key for developing integrated and low-scale quantum devices. The mechanisms leading to quantum emission are complex, as a large number of electronic states of the system impacts the emission dynamics. Here, we use a scanning tunneling microscope (STM) to excite a model QLS, namely a single molecule. The luminescence spectra reveal two lines, associated to the emission of the neutral and positively charged molecule, both exhibiting single-photon source behavior. In addition, we find a correlation between the charged and neutral molecule's emission, the signature of a photon cascade. By adjusting the charging/discharging rate, we can control these emission statistics. This generic strategy is further established by a rate equation model revealing the complex internal dynamics of the molecular junction.

cond-mat.mes-hall↗

arXiv2023

Charge-state lifetimes of single molecules on ultrathin insulating films

In scanning tunneling microscopy (STM) experiments of molecules on insulating films, tunneling through molecular resonances implies transiently charging the molecule. The transition back to the charge ground state by tunneling through the insulating film is crucial, for example, for understanding STM-induced electroluminescence. Here, using STM, we report on the charge-state lifetimes of individual molecules adsorbed on NaCl films of different thicknesses on Cu(111) and Au(111). To that end, we approached the tip to the molecule at resonant tunnel conditions up to a regime where charge transport was limited by tunneling through the NaCl film. The resulting saturation of tunnel current is a direct measure of the molecule's charge-state lifetime, thus providing a means to study charge dynamics and, thereby, exciton dynamics. Comparison of anion and cation lifetimes on different substrates reveals the critical role of the level alignment with the insulator's conduction and valence band, and the metal-insulator interface state.

cond-mat.mes-hall↗

arXiv2023

Submolecular-scale control of phototautomerization

Many natural and artificial reactions including photosynthesis or photopolymerization are initiated by stimulating organic molecules into an excited state, which enables new reaction paths. Controlling light-matter interaction can influence this key concept of photochemistry, however, it remained a challenge to apply this strategy to control photochemical reactions at the atomic scale. Here, we profit from the extreme confinement of the electromagnetic field at the apex of a scanning tunneling microscope (STM) tip to drive and control the rate of a free-base phthalocyanine phototautomerization with submolecular precision. By tuning the laser excitation wavelength and choosing the STM tip position, we control the phototautomerization rate and the relative tautomer population. This sub-molecular optical control can be used to study any other photochemical processes.

cond-mat.mes-hall↗

arXiv2022

Non-benzenoid high-spin polycyclic hydrocarbons generated by atom manipulation

We report the on-surface synthesis of a non-benzenoid triradical through dehydrogenation of truxene (C27H18) on coinage metal and insulator surfaces. Voltage pulses applied via the tip of a combined scanning tunneling microscope/atomic force microscope were used to cleave individual C-H bonds in truxene. The resultant final product truxene-5,10,15-triyl (1) was characterized at the single-molecule scale using a combination of atomic force microscopy, scanning tunneling microscopy and scanning tunneling spectroscopy. Our analyses show that 1 retains its open-shell quartet ground state, predicted by density functional theory, on a two monolayer-thick NaCl layer on a Cu(111) surface. We image the frontier orbital densities of 1 and confirm that they correspond to spin-split singly occupied molecular orbitals. Through our synthetic strategy, we also isolate two reactive intermediates toward the synthesis of 1 - derivatives of fluorenyl radical and indeno[1,2-a]fluorene, with predicted spin-doublet and spin-triplet ground states, respectively. Our results should have bearings on the synthesis of non-benzenoid high-spin polycyclic frameworks with magnetism beyond Lieb's theorem.

cond-mat.mes-hall↗

arXiv2019

An sp-hybridized molecular carbon allotrope, cyclo[18]carbon

Carbon allotropes built from rings of two-coordinate atoms, known as cyclo[n]carbons, have fascinated chemists for many years, but until now they could not be isolated or structurally characterized, due to their high reactivity. We generated cyclo[18]carbon (C18) using atom manipulation on bilayer NaCl on Cu(111) at 5 Kelvin by eliminating carbon monoxide from a cyclocarbon oxide molecule C24O6. Characterization of cyclo[18]carbon by high-resolution atomic force microscopy revealed a polyynic structure with defined positions of alternating triple and single bonds. The high reactivity of cyclocarbon and cyclocarbon oxides allows covalent coupling between molecules to be induced by atom manipulation, opening an avenue for the synthesis of other carbon allotropes and carbon-rich materials from the coalescence of cyclocarbon molecules.

physics.chem-ph↗