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Katherine de Kleer

Publications and source records attributed to Katherine de Kleer.

At least 37 records · Page 2Linked to original sources

Comparing NASA Discovery and New Frontiers Class Mission Concepts for the Io Volcano Observer (IVO)

Jupiter's moon Io is a highly compelling target for future exploration that offers critical insight into tidal dissipation processes and the geology of high heat flux worlds, including primitive planetary bodies, such as the early Earth, that are shaped by enhanced rates of volcanism. Io is also important for understanding the development of volcanogenic atmospheres and mass-exchange within the Jupiter System. However, fundamental questions remain about the state of Io's interior, surface, and atmosphere, as well as its role in the evolution of the Galilean satellites. The Io Volcano Observer (IVO) would address these questions by achieving the following three key goals: (A) Determine how and where tidal heat is generated inside Io; (B) Understand how tidal heat is transported to the surface of Io; and (C) Understand how Io is evolving. IVO was selected for Phase A study through the NASA Discovery program in 2020 and, in anticipation of a New Frontiers 5 opportunity, an enhanced IVO-NF mission concept was advanced that would increase the Baseline mission from 10 flybys to 20, with an improved radiation design; employ a Ka-band communications to double IVO's total data downlink; add a wide angle camera for color and stereo mapping; add a dust mass spectrometer; and lower the altitude of later flybys to enable new science. This study compares and contrasts the mission architecture, instrument suite, and science objectives for Discovery (IVO) and New Frontiers (IVO-NF) missions to Io, and advocates for continued prioritization of Io as an exploration target for New Frontiers.

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LBT SHARK-VIS Observes a Major Resurfacing Event on Io

Since volcanic activity was first discovered on Io from Voyager images in 1979, changes on Io's surface have been monitored from both spacecraft and ground-based telescopes. Here, we present the highest spatial resolution images of Io ever obtained from a ground-based telescope. These images, acquired by the SHARK-VIS instrument on the Large Binocular Telescope, show evidence of a major resurfacing event on Io's trailing hemisphere. When compared to the most recent spacecraft images, the SHARK-VIS images show that a plume deposit from a powerful eruption at Pillan Patera has covered part of the long-lived Pele plume deposit. Although this type of resurfacing event may be common on Io, few have been detected due to the rarity of spacecraft visits and the previously low spatial resolution available from Earth-based telescopes. The SHARK-VIS instrument ushers in a new era of high resolution imaging of Io's surface using adaptive optics at visible wavelengths.

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Isotopic evidence of long-lived volcanism on Io

Jupiter's moon Io hosts extensive volcanism driven by tidal heating. The isotopic composition of Io's inventory of volatile elements, including sulfur and chlorine, reflects its outgassing and mass loss history and provides an avenue for exploring its evolution. We used millimeter observations of Io's atmosphere to measure sulfur isotopes in gaseous SO2 and SO, and chlorine isotopes in gaseous NaCl and KCl. We find $^{34}$S/$^{32}$S=0.0595$\pm$0.0038 ($δ^{34}$S=+347$\pm$86 per mille), which is highly enriched compared to average Solar System values and indicates that Io has lost 94 to 99% of its available sulfur. Our measurement of $^{37}$Cl/$^{35}$Cl=0.403$\pm$0.028 ($δ^{37}$Cl=+263$\pm$88 per mille) shows chlorine is similarly enriched. These measurements indicate that Io has been volcanically active for most or all of its history, with potentially higher outgassing and mass-loss rates at earlier times.

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Detection of a 2.85 micrometer Feature on 5 Spinel-rich Asteroids from JWST

Ground-based observations of `Barbarian' L-type asteroids at 1 to 2.5-$μ$m indicate that their near-infrared spectra are dominated by the mineral spinel, which has been attributed to a high abundance of calcium-aluminum inclusions (CAIs) -- the first solids to condense out of the protoplanetary disk during the formation of the Solar System. However, the spectral properties of these asteroids from 2.5 to 5-$μ$m, a wavelength region that covers signatures of hydrated minerals, water, and organics, have not yet been explored. Here, we present 2 to 5-$μ$m reflectance spectra of five spinel-rich asteroids obtained with the NIRSpec instrument on the James Webb Space Telescope. All five targets exhibit a $\sim$ 2.85-$μ$m absorption feature with a band depth of 3-6$\%$ that appears correlated in strength with that of the 2-$μ$m spinel absorption feature. The shape and position of the 2.85-$μ$m feature are not a good match to the 2.7-$μ$m feature commonly seen in carbonaceous CM meteorites or C-type asteroids. The closest spectral matches are to the Moon and Vesta, suggesting commonalities in aqueous alteration across silicate bodies, infall of hydrated material, and/or space weathering by solar wind H implantation. Lab spectra of CO/CV chondrites, CAIs, as well as the minerals cronstedtite and spinel, also show a similar feature, providing clues into the origin of the 2.85-$μ$m feature.

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Observations of Titan's Stratosphere During Northern Summer: Temperatures, CH3CN and CH3D Abundances

Titan's atmospheric composition and dynamical state have previously been studied over numerous epochs by both ground- and space-based facilities. However, stratospheric measurements remain sparse during Titan's northern summer and fall. The lack of seasonal symmetry in observations of Titan's temperature field and chemical abundances raises questions about the nature of the middle atmosphere's meridional circulation and evolution over Titan's 29-yr seasonal cycle that can only be answered through long-term monitoring campaigns. Here, we present maps of Titan's stratospheric temperature, acetonitrile (or methyl cyanide; CH$_3$CN), and monodeuterated methane (CH$_3$D) abundances following Titan's northern summer solstice obtained with Band 9 ($\sim0.43$ mm) ALMA observations. We find that increasing temperatures towards high-southern latitudes, currently in winter, resemble those observed during Titan's northern winter by the Cassini mission. Acetonitrile abundances have changed significantly since previous (sub)millimeter observations, and we find that the species is now highly concentrated at high-southern latitudes. The stratospheric CH$_3$D content is found to range between 4-8 ppm in these observations, and we infer the CH$_4$ abundance to vary between $\sim0.9-1.6\%$ through conversion with previously measured D/H values. A global value of CH$_4=1.15\%$ was retrieved, lending further evidence to the temporal and spatial variability of Titan's stratospheric methane when compared with previous measurements. Additional observations are required to determine the cause and magnitude of stratospheric enhancements in methane during these poorly understood seasons on Titan.

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Atacama Large Aperture Submillimeter Telescope (AtLAST) Science: Planetary and Cometary Atmospheres

The study of planets and small bodies within our Solar System is fundamental for understanding the formation and evolution the Earth and other planets. Compositional and meteorological studies of the giant planets provide a foundation for understanding the nature of the most commonly observed exoplanets, while spectroscopic observations of the atmospheres of terrestrial planets, moons, and comets provide insights into the past and present-day habitability of planetary environments, and the availability of the chemical ingredients for life. While prior and existing (sub)millimeter observations have led to major advances in these areas, progress is hindered by limitations in the dynamic range, spatial and temporal coverage, as well as sensitivity of existing telescopes and interferometers. Here, we summarize some of the key planetary science use cases that factor into the design of the Atacama Large Aperture Submillimeter Telescope (AtLAST), a proposed 50-m class single dish facility: (1) to more fully characterize planetary wind fields and atmospheric thermal structures, (2) to measure the compositions of icy moon atmospheres and plumes, (3) to obtain detections of new, astrobiologically relevant gases and perform isotopic surveys of comets, and (4) to perform synergistic, temporally-resolved measurements in support of dedicated interplanetary space missions. The improved spatial coverage (several arcminutes), resolution ($\sim1.2''-12''$), bandwidth (several tens of GHz), dynamic range ($\sim10^5$) and sensitivity ($\sim1$ mK km s$^{-1}$) required by these science cases would enable new insights into the chemistry and physics of planetary environments, the origins of prebiotic molecules and the habitability of planetary systems in general.

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The Heterogeneous Surface of Asteroid (16) Psyche

Main-belt asteroid (16) Psyche is the largest M-type asteroid, a class of object classically thought to be the metal cores of differentiated planetesimals and the parent bodies of the iron meteorites. de Kleer, Cambioni, and Shepard (2021, https://doi.org/10.3847/psj/ac01ec) presented new data from the Atacama Large Millimeter Array (ALMA), from which they derived a global best-fit thermal inertia and dielectric constant for Psyche, proxies for regolith particle size, porosity, and/or metal content, and observed thermal anomalies that could not be explained by surface albedo variations only. Motivated by this, here we fit a model to the same ALMA data set that allows dielectric constant and thermal inertia to vary across the surface. We find that Psyche has a heterogeneous surface in both dielectric constant and thermal inertia but, intriguingly, we do not observe a direct correlation between these two properties over the surface. We explain the heterogeneity in dielectric constant as being due to variations in the relative abundance of metal and silicates. Furthermore, we observe that the lowlands of a large depression in Psyche's shape have distinctly lower thermal inertia than the surrounding highlands. We propose that the latter could be explained by a thin mantle of fine regolith, fractured bedrock, and/or implanted silicate-rich materials covering an otherwise metal-rich surface. All these scenarios are indicative of a collisionally evolved world.

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Revealing Callisto's carbon-rich surface and CO2 atmosphere with JWST

We analyzed spectral cubes of Callisto's leading and trailing hemispheres, collected with the NIRSpec Integrated Field Unit (G395H) on the James Webb Space Telescope. These spatially resolved data show strong 4.25-micron absorption bands resulting from solid-state 12CO2, with the strongest spectral features at low latitudes near the center of its trailing hemisphere, consistent with radiolytic production spurred by magnetospheric plasma interacting with native H2O mixed with carbonaceous compounds. We detected CO2 rovibrational emission lines between 4.2 and 4.3 microns over both hemispheres, confirming the global presence of CO2 gas in Callisto's tenuous atmosphere. These results represent the first detection of CO2 gas over Callisto's trailing side. The distribution of CO2 gas is offset from the subsolar region on either hemisphere, suggesting that sputtering, radiolysis, and geologic processes help sustain Callisto's atmosphere. We detected a 4.38-micron absorption band that likely results from solid-state 13CO2. A prominent 4.57-micron absorption band that might result from CN-bearing organics is present and significantly stronger on Callisto's leading hemisphere, unlike 12CO2, suggesting these two spectral features are spatially anti-associated. The distribution of the 4.57-micron band is more consistent with a native origin and/or accumulation of dust from Jupiter's irregular satellites. Other, more subtle absorption features could result from CH-bearing organics, CO, carbonyl sulfide (OCS), and Na-bearing minerals. These results highlight the need for preparatory laboratory work and improved surface-atmosphere interaction models to better understand carbon chemistry on the icy Galilean moons before the arrival of NASA's Europa Clipper and ESA's JUICE spacecraft.

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Recovering simulated planet and disk signals using SCALES aperture masking

The Slicer Combined with Array of Lenslets for Exoplanet Spectroscopy (SCALES) instrument is a lenslet-based integral field spectrograph that will operate at 2 to 5 microns, imaging and characterizing colder (and thus older) planets than current high-contrast instruments. Its spatial resolution for distant science targets and/or close-in disks and companions could be improved via interferometric techniques such as sparse aperture masking. We introduce a nascent Python package, NRM-artist, that we use to design several SCALES masks to be non-redundant and to have uniform coverage in Fourier space. We generate high-fidelity mock SCALES data using the scalessim package for SCALES' low spectral resolution modes across its 2 to 5 micron bandpass. We include realistic noise from astrophysical and instrument sources, including Keck adaptive optics and Poisson noise. We inject planet and disk signals into the mock datasets and subsequently recover them to test the performance of SCALES sparse aperture masking and to determine the sensitivity of various mask designs to different science signals.

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Simulating medium-spectral-resolution exoplanet characterization with SCALES angular/reference differential imaging

SCALES (Slicer Combined with Array of Lenslets for Exoplanet Spectroscopy) is a 2 - 5 micron high-contrast lenslet-based integral field spectrograph (IFS) designed to characterize exoplanets and their atmospheres. The SCALES medium-spectral-resolution mode uses a lenslet subarray with a 0.34 x 0.36 arcsecond field of view which allows for exoplanet characterization at increased spectral resolution. We explore the sensitivity limitations of this mode by simulating planet detections in the presence of realistic noise sources. We use the SCALES simulator scalessim to generate high-fidelity mock observations of planets that include speckle noise from their host stars, as well as other atmospheric and instrumental noise effects. We employ both angular and reference differential imaging as methods of disentangling speckle noise from the injected planet signals. These simulations allow us to assess the feasibility of speckle deconvolution for SCALES medium resolution data, and to test whether one approach outperforms another based on planet angular separations and contrasts.

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The Slicer Combined with Array of Lenslets for Exoplanet Spectroscopy (SCALES): driving science cases and expected outcomes

The Slicer Combined with Array of Lenslets for Exoplanet Spectroscopy (SCALES) is a $2-5~μ$m, high-contrast integral field spectrograph (IFS) currently being built for Keck Observatory. With both low ($R\lesssim250$) and medium ($R\sim3500-7000$) spectral resolution IFS modes, SCALES will detect and characterize significantly colder exoplanets than those accessible with near-infrared ($\sim1-2~μ$m) high-contrast spectrographs. This will lead to new progress in exoplanet atmospheric studies, including detailed characterization of benchmark systems that will advance the state of the art of atmospheric modeling. SCALES' unique modes, while designed specifically for direct exoplanet characterization, will enable a broader range of novel (exo)planetary observations as well as galactic and extragalactic studies. Here we present the science cases that drive the design of SCALES. We describe an end-to-end instrument simulator that we use to track requirements, and show simulations of expected science yields for each driving science case. We conclude with a discussion of preparations for early science when the instrument sees first light in $\sim2025$.

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Thermal properties of the leading hemisphere of Callisto inferred from ALMA observations

We present a thermal observation of Callisto's leading hemisphere obtained using the Atacama Large Millimeter/submillimeter Array (ALMA) at 0.87 mm (343 GHz). The angular resolution achieved for this observation was $\sim$$0.16^{\prime\prime}$, which for Callisto at the time of this observation ($D\sim 1.05^{\prime\prime}$) was equivalent to $\sim$6 elements across the surface. Our disk-integrated brightness temperature of 116 $\pm$ 5 K (8.03 $\pm$ 0.40 Jy) is consistent with prior disk-integrated observations. Global surface properties were derived from the observation using a thermophysical model (de Kleer et al. 2021) constrained by spacecraft data. We find that models parameterized by two thermal inertia components more accurately fit the data than single thermal inertia models. Our best-fit global parameters adopt a lower thermal inertia of 15-50 $\text{J}\:\text{m}^{-2}\:\text{K}^{-1}\:\text{s}^{-1/2}$ and a higher thermal inertia component of 1200-2000 $\text{J}\:\text{m}^{-2}\:\text{K}^{-1}\:\text{s}^{-1/2}$, with retrieved millimeter emissivities of 0.89-0.91. We identify several thermally anomalous regions, including spots $\sim$3 K colder than model predictions co-located with the Valhalla impact basin and a complex of craters in the southern hemisphere; this indicates the presence of materials possessing either a higher thermal inertia or a lower emissivity. A warm region confined to the mid-latitudes in these leading hemisphere data may be indicative of regolith property changes due to exogenic sculpting.

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Evolution of Neptune at Near-Infrared Wavelengths from 1994 through 2022

Using archival near-infrared observations from the Keck and Lick Observatories and the Hubble Space Telescope, we document the evolution of Neptune's cloud activity from 1994 to 2022. We calculate the fraction of Neptune's disk that contained clouds, as well as the average brightness of both cloud features and cloud-free background over the planet's disk. We observe cloud activity and brightness maxima during 2002 and 2015, and minima during 2007 and 2020, the latter of which is particularly deep. Neptune's lack of cloud activity in 2020 is characterized by a near-total loss of clouds at mid-latitudes and continued activity at the South Pole. We find that the periodic variations in Neptune's disk-averaged brightness in the near-infrared H (1.6 $μ$m), K (2.1 $μ$m), FWCH4P15 (893 nm), F953N (955 nm), FWCH4P15 (965 nm), and F845M (845 nm) bands are dominated by discrete cloud activity, rather than changes in the background haze. The clear positive correlation we find between cloud activity and Solar Lyman-Alpha (121.56 nm) irradiance lends support to the theory that the periodicity in Neptune's cloud activity results from photochemical cloud/haze production triggered by Solar ultraviolet emissions.

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Drift Rates of Major Neptunian Features between 2018 and 2021

Using near-infrared observations of Neptune from the Keck and Lick Observatories, and the Hubble Space Telescope in combination with amateur datasets, we calculated the drift rates of prominent infrared-bright cloud features on Neptune between 2018 and 2021. These features had lifespans of $\sim 1$ day to $\geq$1 month and were located at mid-latitudes and near the south pole. Our observations permitted determination of drift rates via feature tracking. These drift rates were compared to three zonal wind profiles describing Neptune's atmosphere determined from features tracked in H band (1.6 $μm$), K' band (2.1 $μm$), and Voyager 2 data at visible wavelengths. Features near $-70 °$ measured in the F845M filter (845nm) were particularly consistent with the K' wind profile. The southern mid-latitudes hosted multiple features whose lifespans were $\geq$1 month, providing evidence that these latitudes are a region of high stability in Neptune's atmosphere. We also used HST F467M (467nm) data to analyze a dark, circumpolar wave at $- 60 °$ latitude observed on Neptune since the Voyager 2 era. Its drift rate in recent years (2019-2021) is $4.866 \pm 0.009 °$/day. This is consistent with previous measurements by Karkoschka (2011), which predict a $4.858 \pm 0.022 °$/day drift rate during these years. It also gained a complementary bright band just to the north.

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Io's Optical Aurorae in Jupiter's Shadow

Decline and recovery timescales surrounding eclipse are indicative of the controlling physical processes in Io's atmosphere. Recent studies have established that the majority of Io's molecular atmosphere, SO2 and SO, condenses during its passage through Jupiter's shadow. The eclipse response of Io's atomic atmosphere is less certain, having been characterized solely by ultraviolet aurorae. Here we explore the response of optical aurorae for the first time. We find oxygen to be indifferent to the changing illumination, with [O I] brightness merely tracking the plasma density at Io's position in the torus. In shadow, line ratios confirm sparse SO2 coverage relative to O, since their collisions would otherwise quench the emission. Io's sodium aurora mostly disappears in eclipse and e-folding timescales, for decline and recovery differ sharply: ~10 minutes at ingress and nearly 2 hr at egress. Only ion chemistry can produce such a disparity; Io's molecular ionosphere is weaker at egress due to rapid recombination. Interruption of a NaCl+ photochemical pathway best explains Na behavior surrounding eclipse, implying that the role of electron impact ionization is minor relative to photons. Auroral emission is also evident from potassium, confirming K as the major source of far red emissions seen with spacecraft imaging at Jupiter. In all cases, direct electron impact on atomic gas is sufficient to explain the brightness without invoking significant dissociative excitation of molecules. Surprisingly, the nonresponse of O and rapid depletion of Na is opposite the temporal behavior of their SO2 and NaCl parent molecules during Io's eclipse phase.

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The Optical Aurorae of Europa, Ganymede and Callisto

The tenuous atmospheres of the Galilean satellites are sourced from their surfaces and produced by a combination of plasma-surface interactions and thermal processes. Though thin, these atmospheres can be studied via their auroral emissions, and most work to date has focused on their aurora at UV wavelengths. Here we present the first detections of Ganymede's and Callisto's optical aurorae, as well detections of new optical auroral lines at Europa, based on observations of the targets over ten Jupiter eclipses from 1998 to 2021 with Keck/HIRES. We present measurements of OI emission at 6300/6364, 5577, 7774, and 8446 A and place upper limits on hydrogen at 6563 A. These constitute the first detections of emissions at 7774 and 8446 A at a planetary body other than Earth. The simultaneous measurement of multiple emission lines provides robust constraints on atmospheric composition. We find that the eclipse atmospheres of Europa and Ganymede are composed predominantly of O2 with average column densities of (4.1 \pm 0.1) x 10^{14} cm^{-2} and (4.7 \pm 0.1) x 10^{14} cm^{-2}, respectively. We find weak evidence for H2O in Europa's bulk atmosphere at an H2O/O2 ratio of $\sim$0.25, and place only an upper limit on H2O in Ganymede's bulk atmosphere, corresponding to H2O/O2 < 0.6. The column density of O2 derived for Callisto is (4.0 \pm 0.9 x 10^{15} cm^{-2} for an assumed electron density of 0.15 cm^{-3}, but electron properties at Callisto's orbit are very poorly constrained.

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NaCl & KCl in Io's Atmosphere

We present the first comprehensive study of NaCl and KCl gases in Io's atmosphere in order to investigate their characteristics, and to infer properties of Io's volcanoes and subsurface magma chambers. In this work, we compile all past spectral line observations of NaCl and KCl in Io's atmosphere from the Atacama Large Millimeter/submillimeter Array (ALMA) and use atmospheric models to constrain the physical properties of the gases on several dates between 2012 and 2018. NaCl and KCl appear to be largely spatially confined and for observations with high spectral resolution, the temperatures are high (~500-1000 K), implying a volcanic origin. The ratio of NaCl:KCl was found to be ~5-6 in June 2015 and ~3.5-10 in June 2016, which is consistent with predictions based on observations of Io's extended atmosphere, and less than half the Na:K ratio in chondrites. Assuming these gases are volcanic in origin, these ratios imply a magma temperature of ~1300 K, such that the magma will preferentially outgas KCl over NaCl.

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Design of SCALES: A 2-5 Micron Coronagraphic Integral Field Spectrograph for Keck Observatory

We present the design of SCALES (Slicer Combined with Array of Lenslets for Exoplanet Spectroscopy) a new 2-5 micron coronagraphic integral field spectrograph under construction for Keck Observatory. SCALES enables low-resolution (R~50) spectroscopy, as well as medium-resolution (R~4,000) spectroscopy with the goal of discovering and characterizing cold exoplanets that are brightest in the thermal infrared. Additionally, SCALES has a 12x12" field-of-view imager that will be used for general adaptive optics science at Keck. We present SCALES's specifications, its science case, its overall design, and simulations of its expected performance. Additionally, we present progress on procuring, fabricating and testing long lead-time components.

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