arXiv subjects

Kee Hoon Kim

Publications and source records attributed to Kee Hoon Kim.

At least 55 records · Page 3Linked to original sources

arXiv2011

Determination of Intrinsic Ferroelectric Polarization in Orthorhombic Manganites with E-type Spin Order

By directly measuring electrical hysteresis loops using the Positive-Up Negative-Down (PUND) method, we accurately determined the remanent ferroelectric polarization Pr of orthorhombic RMnO3 (R = Ho, Tm, Yb, and Lu) compounds below their E-type spin ordering temperatures. We found that LuMnO3 has the largest Pr of 0.17 uC/cm^2 at 6 K in the series, indicating that its single-crystal form can produce a Pr of at least 0.6 \muuC/cm^2 at 0 K. Furthermore, at a fixed temperature, Pr decreases systematically with increasing rare earth ion radius from R = Lu to Ho, exhibiting a strong correlation with the variations in the in-plane Mn-O-Mn bond angle and Mn-O distances. Our experimental results suggest that the contribution of the Mn t2g orbitals dominates the ferroelectric polarization.

cond-mat.mtrl-sci↗

arXiv2011

Large Longitudinal Magnetoelectric Coupling in NiFe2O4-BaTiO3 Laminates

In contrast to the Pb-based magnetoelectric laminates (MELs), we find in the BaTiO3 and NiFe2O4 laminates (number of layers n = 5-25) that the longitudinal magnetoelectric (ME) voltage coefficient Alpha E33 becomes much larger than the transverse one due to preferential alignment of magnetic moments along the NiFe2O4 plane. Moreover, upon decreasing each layer thickness down to 15 um, we realize enhanced Alpha E33 up to 18 mV/ (cm Oe) and systematic increase of the ME sensitivity in proportion to n to achieve the largest in the Pb-free MELs (400*10^-6V/Oe), thereby providing pathways for tailoring ME coupling in mass-produced, environment friendly laminates.

cond-mat.mtrl-sci↗

arXiv2011

Pauli-limiting effects in the upper critical fields of a clean LiFeAs single crystal

We have investigated the temperature-dependence of the upper critical field Hc2(T) in a LiFeAs single crystal by direct measurements of resistivity under static magnetic fields up to 36 T. We find in the case of a magnetic field H along the ab-plane that Hc2ab(0) = 30 T is clearly lower than the orbital limiting field Hc2orb,ab (0) = 39.6 T estimated by the |dHc2ab / dT|Tc, suggesting the presence of both Pauli- and orbital-limiting effects in the pair breaking process. The best fit of Hc2ab(T) to the Werthamer-Helfand-Hohenberg formula results in the Maki parameter α = 0.9 and negligible spin-orbit scattering constant (λso = 0.0). On the other hand, for H along the c-axis, Hc2c(T) increases linearly down to our lowest temperature of 0.8 K, which can be explained by the multi-band effects. The anisotropy ratio Hc2ab(T) / Hc2c(T) is 3 near Tc and systematically decreases upon lowering temperature to become 1.3 at zero temperature. A comparative overview of the behavior of Hc2ab(T) in various Fe-based superconductors shows that, similar to LiFeAs, the calculated Hc2orb,ab (0) is generally much larger than the measured Hc2ab(0) and thus finite α values ranging from ~ 0.4 to 3 are necessary to describe the low temperature Hc2ab(T) behaviors. Moreover, LiFeAs is found to have the smallest |dHc2ab / dT|Tc values, indicating that LiFeAs is one of the cleanest Fe-based superconductors with a finite Maki parameter. We also discuss the implications of multi-band effects and spin-orbit scattering based on the finding that the estimated Pauli-limiting field is generally much larger than the BCS prediction in the Fe-based superconductors.

cond-mat.supr-con↗

arXiv2011

Magnetic field - dependent Labusch parameter in LiFeAs superconductor from Campbell penetration depth

A true critical current density, $j_{c}$, as opposite to commonly measured relaxed persistent (Bean) current, $j_{B}$, was extracted from the Campbell penetration depth, $λ_{C}(T,H)$ measured in single crystals of LiFeAs. The effective pinning potential is non-parabolic, which follows from the magnetic field - dependent Labusch parameter $α$. At the equilibrium (upon field - cooling), $α(H)$ is non-monotonic, but it is monotonic at a finite gradient of the vortex density. This behavior leads to a faster magnetic relaxation at the lower fields and provides a natural \emph{dynamic} explanation for the fishtail (second peak) effect. We also find the evidence for strong pinning at the lower fields. The inferred field dependence of the pinning potential is consistent with the evolution from strong pinning, through collective pinning and, eventually, to a disordered vortex lattice. The values of $j_{c}(2\text{K}) \simeq 2\times10^{6}$ A/cm$^{2}$ provide an upper estimate of the current carrying capability of LiFeAs. Overall, vortex behavior of almost isotropic, fully-gapped LiFeAs is very similar to highly anisotropic d-wave cuprate superconductors, the similarity that requires further studies in order to understand unconventional superconductivity in cuprates and pnictides.

cond-mat.supr-con↗

arXiv2011

Strong magnetoelastic effect on the magnetoelectric phenomena of TbMn$_{2}$O$_{5}$

Comparative studies of magnetoelectric susceptibility ($α$), magnetization ($M$), and magnetostriction ($u$) in TbMn$_{2}$O$_{5}$ reveal that the increment of $M$ owing to the field-induced Tb$^{3+}$ spin alignment coins a field-asymmetric line shape in the $α(H)$ curve, being conspicuous in a low temperature incommensurate phase but persistently subsisting in the entire ferroelectric phase. Correlations among electric polarization, $u$, and $M^{2}$ variation represent linear relationships, unambiguously showing the significant role of Tb magnetoelastic effects on the low field magnetoelectric phenomena of TbMn$_{2}$O$_{5}$. An effective free energy capturing the observed experimental features is also suggested.

cond-mat.str-el↗

arXiv2010

Single crystal growth and superconducting properties of LiFeAs

We report the successful growth of high quality single crystals of LiFeAs with lateral sizes up to 5 x 5 mm2 by the Sn-flux method. Electrical resistivity studies reveal that the superconducting onset temperature is 18.2 K with a transition width less than 1.1 K and the ratio of room temperature to residual resistivity is about 24. Bulk superconductivity is supported by perfect shielding in the magnetic susceptibility and a clear jump in the specific heat Cp, resulting in deltaCp/T ~ 20.0 mJ/mol*K2. Upper critical field slopes of dHc2c/dT ~ -1.39 and dHc2ab/dT ~ -2.99 T/K near Tc predict zero temperature upper critical fields of Hc2c(0) ~ 17.2 and Hc2ab(0) ~ 36.9 T and coherence lengths of Xi_ab = 4.4 and Xi_c = 2.0 nm in a single band model. This result points to a modest superconducting anisotropy about 2.3 in LiFeAs.

cond-mat.supr-con↗

arXiv2010

Quantitative determination of anisotropic magnetoelectric coupling in BiFeO$_{3}$-CoFe$_{2}$O$_{4}$ nanostructures

The transverse and longitudinal magnetoelectric susceptibilities (MES) were quantitatively determined for (001) heteroepitaxial BiFeO$_{3}$-CoFe$_{2}$O$_{4}$ nanostructures. Both of these MES values were sharply enhanced at magnetic fields below 6 kOe and revealed asymmetric lineshapes with respect to the dc magnetic field, demonstrating the strain-induced magnetoelectric effect. The maximum transverse MES, which reached as high as $\sim$60 mV/cm Oe, was about five times larger than the longitudinal MES. This observation signifies that transverse magnetostriction of the CoFe$_{2}$O$_{4}$ nanopillars is enhanced more than the bulk value due to preferred magnetic domain alignment along the [001] direction coming from compressive, heteroepitaxial strain.

cond-mat.str-el↗

arXiv2010

Evidence of a universal and isotropic 2Δ/kBTC ratio in 122-type iron pnictide superconductors over a wide doping range

We have systematically investigated the doping and the directional dependence of the gap structure in the 122-type iron pnictide superconductors by point contact Andreev reflection spectroscopy. The studies were performed on single crystals of Ba1-xKxFe2As2 (x = 0.29, 0.49, and 0.77) and SrFe1.74Co0.26As2 with a sharp tip of Pb or Au pressed along the c-axis or the ab-plane direction. The conductance spectra obtained on highly transparent contacts clearly show evidence of a robust superconducting gap. The normalized curves can be well described by the Blonder-Tinkham-Klapwijk model with a lifetime broadening. The determined gap value scales very well with the transition temperature, giving the 2Δ/kBTC value of ~ 3.1. The results suggest the presence of a universal coupling behavior in this class of iron pnictides over a broad doping range and independent of the sign of the doping. Moreover, conductance spectra obtained on c-axis junctions and ab-plane junctions indicate that the observed gap is isotropic in these superconductors.

cond-mat.supr-con↗

arXiv2010

NMR study on the stability of the magnetic ground state in MnCr${}_2$O${}_4$

The canting angles and fluctuation of the magnetic ion spins of spinel oxide MnCr${}_2$O${}_4$ were studied by nuclear magnetic resonance (NMR) at low temperatures, which has a collinear ferrimagnetic order below $T_C$ and a ferrimagnetic spiral order below $T_s < T_C$. Contrary to previous reports, only one spin canting angle of Cr ions was observed. The spin canting angles of Mn and Cr ions in the ferrimagnetic spiral obtained at a liquid-He temperature were $43\,^{\circ}$ and $110\,^{\circ}$, respectively. The nuclear spin-spin relaxation was determined by the Suhl-Nakamura interaction at low temperatures but the relaxation rate $T_2^{-1}$ increases rapidly as the temperature approaches $T_s$. This indicates that the fluctuation of the spiral component becomes faster as the temperature increases but not fast enough to leave an averaged hyperfine field to nuclei in the time scale of nuclear spin precession in the ferrimagnetic phase, which is on the order of $10^{-8}$ s. The spiral volume fraction measured for various temperatures reveals that the collinear and the spiral ferrimagnetic phases are mixed below the transition temperature of the spiral order. The temperature hysteresis in the volume fraction implies that this transition has first-order characteristics.

cond-mat.str-el↗

arXiv2010

Determination of the intrinsic ferroelectric polarization in orthorhombic HoMnO3

Whether large ferroelectric polarization P exists in the orthorhombic HoMnO3 with the E-type antiferromagnetic spin ordering or not remains as one of unresolved, challenging issues in the physics of multiferroics. The issue is closely linked to an intriguing experimental difficulty for determining P of polycrystalline specimens that conventional pyroelectric current measurements performed after a poling procedure under high dc electric fields are subject to large errors due to the problems caused by leakage currents or space charges. To overcome the difficulty, we employed the PUND method, which uses successively the two positive and two negative electrical pulses, to directly measure electrical hysteresis loops in several polycrystalline HoMnO3 specimens below their Néel temperatures. We found that all the HoMnO3 samples had similar remnant polarization Pr values at each temperature, regardless of their variations in resistivity, dielectric constant, and pyroelectric current levels. Moreover, Pr of ~0.07 μ\C/cm2 at 6 K is consistent with the P value obtained from the pyroelectric current measurement performed after a short pulse poling. Our findings suggest that intrinsic P of polycrystalline HoMnO3 can be determined through the PUND method and P at 0 K may reach ~0.24 μ\C/cm2 in a single crystalline specimen.

cond-mat.str-el↗

arXiv2010

Electron-hole asymmetry in Co- and Mn-doped SrFe2As2

Phase diagram of electron and hole-doped SrFe2As2 single crystals is investigated using Co and Mn substitution at the Fe-sites. We found that the spin-density-wave state is suppressed by both dopants, but the superconducting phase appears only for Co (electron)-doping, not for Mn (hole)-doping. Absence of the superconductivity by Mn-doping is in sharp contrast to the hole-doped system with K-substitution at the Sr sites. Distinct structural change, in particular the increase of the Fe-As distance by Mn-doping is important to have a magnetic and semiconducting ground state as confirmed by first principles calculations. The absence of electron-hole symmetry in the Fe-site-doped SrFe2As2 suggests that the occurrence of high-Tc superconductivity is sensitive to the structural modification rather than the charge doping.

cond-mat.supr-con↗

arXiv2010

Nearly isotropic upper critical fields in a SrFe$_{1.85}$Co$_{0.15}$As$_{2}$ single crystal

We study temperature dependent upper critical field $H_{\rm c2}$ of a SrFe$_{1.85}$Co$_{0.15}$As$_{2}$ single crystal (\textit{T$_c$}=20.2 K) along \textit{ab}-plane and \textit{c}-axis through resistivity measurements up to 50 T. For the both crystalline directions, $H_{\rm c2}$ becomes nearly isotropic at zero temperature limit, reaching $\sim$ 48 T. The temperature dependence of the $H_{\rm c2}$ curves is explained by interplay between orbital and Pauli limiting behaviors combined with the two band effects.

cond-mat.supr-con↗

arXiv2010

Evidence for dominant Pauli paramagnetic effect in the upper critical fields of a FeTe0.6Se0.4 superconductor

We investigate temperature-dependence of the upper critical fields Hc2(T) of a superconducting FeTe0.6Se0.4 single crystal by measuring resistivity in static magnetic fields up to 45 T. The observations of strong bending in the Hc2ab(T) curves and nearly isotropic Hc2ab(0) ~ Hc2c(0) ~ 48 T support the presence of strong Pauli paramagnetic effect. We show that the Werthamer-Helfand-Hohenberg formula considering the Pauli limiting and the spin-orbit scattering together can effectively describe both Hc2ab(T) and Hc2c(T) curves. The enhancement in quasi-particle density of states or increased scattering resulting from Te(Se) vacancy or excess Fe is discussed as a possible origin for the manifesting Pauli paramagnetic effect.

cond-mat.supr-con↗

arXiv2010

Realization of giant magnetoelectricity in helimagnets

We show that low field magnetoelectric (ME) properties of helimagnets Ba0.5Sr1.5Zn2(Fe1-xAlx)12O22 can be efficiently tailored by Al-substitution level. As x increases, the critical magnetic field for switching electric polarization is systematically reduced from ~1 T down to ~1 mT, and the ME susceptibility is greatly enhanced to reach a giant value of 2.0 x 10^4 ps/m at an optimum x = 0.08. We find that control of nontrivial orbital moment in the octahedral Fe sites through the Al-substitution is crucial for fine tuning of magnetic anisotropy and obtaining the conspicuously improved ME characteristics.

cond-mat.mtrl-sci↗

arXiv2010

Low-magnetic-field control of dielectric constant at room temperature realized in Ba0.5Sr1.5Zn2Fe12O22

We show that room temperature resistivity of Ba0.5Sr1.5Zn2Fe12O22 single crystals increases by more than three orders of magnitude upon being subjected to optimized heat treatments. The increase in the resistivity allows the determination of magnetic field (H)-induced ferroelectric phase boundaries up to 310 K through the measurements of dielectric constant at a frequency of 10 MHz. Between 280 and 310 K, the dielectric constant curve shows a peak centered at zero magnetic field and thereafter decreases monotonically up to 0.1 T, exhibiting a magnetodielectric effect of 1.1%. This effect is ascribed to the realization of magnetic field-induced ferroelectricity at an H value of less than 0.1 T near room temperature. Comparison between electric and magnetic phase diagrams in wide temperature- and field-windows suggests that the magnetic field for inducing ferroelectricity has decreased near its helical spin ordering temperature around 315 K due to the reduction of spin anisotropy in Ba0.5Sr1.5Zn2Fe12O22.

cond-mat.mtrl-sci↗

arXiv2009

Coupling of localized moments and itinerant electrons in EuFe2As2 single crystals studied by Electron Spin Resonance

Electron spin resonance measurements in EuFe2As2 single crystals revealed an absorption spectrum of a single resonance with Dysonian lineshape. Above the spin-density wave transition at T_SDW = 190 K the spectra are isotropic and the spin relaxation is strongly coupled to the CEs resulting in a Korringa-like increase of the linewidth. Below T_SDW, a distinct anisotropy develops and the relaxation behavior of the Eu spins changes drastically into one with characteristic properties of a magnetic insulating system, where dipolar and crystal-field interactions dominate. This indicates a spatial confinement of the conduction electrons to the FeAs layers in the SDW state.

cond-mat.supr-con↗

arXiv2009

Josephson effect between electron-doped and hole-doped iron pnictide single crystals

We have observed the Josephson effect in junctions formed between single crystals of SrFe1.74Co0.26As2 and Ba0.23K0.77Fe2As2. I-V curves showed resistively-shunted junction characteristics, and the ac Josephson effect was observed under microwave irradiation. By applying an in-plane magnetic field, the critical current is completely modulated and shows a relatively symmetric diffraction pattern, consistent with the intermediate junction limit. The observation of the Josephson effect in the p-n bicrystal structure not only has significant implications for designing phase-sensitive junctions to probe the pairing symmetry of iron pnictide superconductors, but also represents an important step in developing all iron pnictide devices for applications.

cond-mat.supr-con↗

arXiv2009

Observation of the Josephson effect in Pb/(Ba,K)Fe2As2 single crystal junctions

We have fabricated c-axis Josephson junctions on single crystals of (Ba,K)Fe2As2 by using Pb as the counter electrode in two geometries, planar and point contact. Junctions in both geometries show resistively shunted junction I-V curves below the Tc of the counter electrode. Microwave induced steps were observed in the I-V curves, and the critical currents are suppressed with an in-plane magnetic field in a manner consistent with the small junction limit. ICRN products of up to 0.3 mV have been observed in these junctions at 4.2 K. The observation of Josephson coupling along the c-axis between (Ba,K)Fe2As2 and a conventional superconductor suggests the existence of a s-wave superconducting order parameter in this class of iron pnictide superconductors.

cond-mat.supr-con↗