arXiv subjects
Publications and source records attributed to Keita Iba.
The structural evolution and superconductivity of a 122-type solid solution Sr1-xBaxNi2P2 were studied. We found that an orthorhombic-tetragonal structural phase transition takes place at x = 0.5, and is characterized by the P-P dimers breaking. The superconducting transition temperature exhibited its highest value of 2.85 K at x = 0.4.
The effects of isovalent doping on the superconducting transition temperature Tc in novel 112-type iron arsenide Ca1-xLaxFeAs2 were studied by conducting measurements of electrical resistivity rho and magnetization M. P or Sb doping strongly enhances Tc: P-doped Ca0.84La0.16FeAs2 and Sb-doped Ca0.85La0.15FeAs2 exhibited Tc of 41 and 43 K, respectively, while Ca0.85La0.15FeAs2 without P/Sb exhibited Tc = 35 K. These observations will give a hint for further enhancing Tc of rare-earth doped Ca-Fe-As systems.
We report superconductivity in the novel 112-type iron-based compound Ca1-xLaxFeAs2. Single-crystal X-ray diffraction analysis revealed that the compound crystallizes in a monoclinic structure (space group P21), in which Fe2As2 layers alternate with Ca2As2 spacer layers such that monovalent arsenic forms zigzag chains. Superconductivity with a transition temperature (Tc) of 34 K was observed for the x = 0.1 sample, while the x = 0.21 sample exhibited trace superconductivity at 45 K. First-principles band calculations demonstrated the presence of almost cylindrical Fermi surfaces, favorable for the high Tc in La-doped CaFeAs2.
Mineral calaverite AuTe2 is a layered compound with an incommensurately modulated structure. The modulation is characterized by the formation of molecular-like Te2 dimers. We have found that the breaking of Te2 dimers that occurs in Au1-xPtxTe2 results in the emergence of superconductivity at Tc = 4.0 K.
Co-doping of lanthanum and phosphorus in CaFe2As2 induces superconductivity at 45 K. This superconducting transition temperature is higher than the 38 K transition in Ba1-xKxFe2As2, which is the maximum found thus far among the 122 phases. Superconductivity with a substantial shielding volume fraction was observed at 0.12 $\leq$ x $\leq$ 0.18 and y = 0.06 in Ca1-xLaxFe2(As1-yPy)2. The superconducting phase of the present system seems to be not adjacent to an antiferromagnetic phase.