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Ken Takahashi

Publications and source records attributed to Ken Takahashi.

4 recordsLinked to original sources

Setting the Standard: Recommended Practices for Data Preprocessing in Data-Driven Climate Prediction

Artificial intelligence (AI) - and specifically machine learning (ML) - applications for climate prediction across timescales are proliferating quickly. The emergence of these methods prompts a revisit to the impact of data preprocessing, a topic familiar to the climate community, as more traditional statistical models work with relatively small sample sizes. Indeed, the skill and confidence in the forecasts produced by data-driven models are directly influenced by the quality of the datasets and how they are treated during model development, thus yielding the colloquialism, "garbage in, garbage out." As such, this article establishes protocols for the proper preprocessing of input data for AI/ML models designed for climate prediction (i.e., subseasonal to decadal and longer). The three aims are to: (1) educate researchers, developers, and end users on the effects that preprocessing has on climate predictions; (2) provide recommended practices for data preprocessing for such applications; and (3) empower end users to decipher whether the models they are using are properly designed for their objectives. Specific topics covered in this article include the creation of (standardized) anomalies, dealing with non-stationarity and the spatiotemporally correlated nature of climate data, and handling of extreme values and variables with potentially complex distributions. Case studies will illustrate how using different preprocessing techniques can produce different predictions from the same model, which can create confusion and decrease confidence in the overall process. Ultimately, implementing the recommended practices set forth in this article will enhance the robustness and transparency of AI/ML in climate prediction studies.

physics.data-an

Origin of Aggregation-Induced Enhanced Emission: A Role of Pseudo-Degenerate Electronic States of Excimers Formed in Aggregation Phases

Origin of aggregation-induced enhanced emission (AIEE) is investigated considering cyano-substituted 1,2-bis(pyridylphenyl)ethene (CNPPE) as an example. On the basis of ONIOM calculations using the time-dependent density functional theory (TD-DFT), we found that pseudo-degeneracy of excimers formed in solid phase plays an important role in the appearance of AIEE. The electron density difference delocalized over molecules gives rise to small diagonal vibronic coupling constants (VCCs), which suggests that the internal conversion is more suppressed in solid phase than in solution phase. The reduction of the off-diagonal VCCs owing to the packing effect is elucidated by vibronic coupling density (VCD) analysis. The pseudo-degeneracy enables fluorescence from the high singlet excited states against Kasha's rule because the electron density difference and the overlap density between the excited states vanish. A Hubbard model of a pseudo-degenerate electronic system is constructed to explain the vanishing mechanism. We propose the following design principle for AIEE: a candidate molecule for AIEE should have pseudo-degenerate adiabatic electronic states in the aggregation phases originating from the excimer formation.

cond-mat.mtrl-sci

The First VERA Astrometry Catalog

We present the first astrometry catalog from the Japanese VLBI (very long baseline interferometer) project VERA (VLBI Exploration of Radio Astrometry). We have compiled all the astrometry results from VERA, providing accurate trigonometric annual parallax and proper motion measurements. In total, 99 maser sources are listed in the VERA catalog. Among them, 21 maser sources are newly reported while the rest of 78 sources are referred to previously published results or those in preparation for forthcoming papers. The accuracy in the VERA astrometry are revisited and compared with those from the other VLBI astrometry projects such as BeSSeL (The Bar and Spiral Structure Legacy) Survey and GOBELINS (the Gould's Belt Distances Survey) with the VLBA (Very Long Baseline Array). We have confirmed that most of the astrometry results are consistent with each other, and the largest error sources are due to source structure of the maser features and their rapid variation, along with the systematic calibration errors and different analysis methods. Combined with the BeSSeL results, we estimate the up-to-date fundamental Galactic parameter of $R_{0}=7.92\pm0.16_{\rm{stat.}}\pm0.3_{\rm{sys.}}$~kpc and $Ω_{\odot}=30.17\pm0.27_{\rm{stat.}}\pm0.3_{\rm{sys.}}$~km~s$^{-1}$~kpc$^{-1}$, where $R_{0}$ and $Ω_{\odot}$ are the distance from the Sun to the Galactic center and the Sun's angular velocity of the Galactic circular rotation, respectively.

astro-ph.GA

Noetherian properties of rings of differential operators of affine semigroup algebras

We consider the Noetherian properties of the ring of differential operators of an affine semigroup algebra. First we show that it is always right Noetherian. Next we give a condition, based on the data of the difference between the semigroup and its scored closure, for the ring of differential operators being anti-isomorphic to another ring of differential operators. Using this, we prove that the ring of differential operators is left Noetherian if the condition is satisfied. Moreover we give some other conditions for the ring of differential operators being left Noetherian. Finally we conjecture necessary and sufficient conditions for the ring of differential operators being left Noetherian.

math.RA