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Ken-ichi Uchida

Publications and source records attributed to Ken-ichi Uchida.

At least 73 records · Page 4Linked to original sources

Above-room-temperature giant thermal conductivity switching in spintronic multilayer

Thermal switching provides an effective way for active heat flow control, which has recently attracted increasing attention in terms of nanoscale thermal management technologies. In magnetic and spintronic materials, the thermal conductivity depends on the magnetization configuration: this is the magneto-thermal resistance effect. Here we show that an epitaxial Cu/Co$_{50}$Fe$_{50}$ multilayer film exhibits giant magnetic-field-induced modulation of the cross-plane thermal conductivity. The magneto-thermal resistance ratio for the Cu/Co$_{50}$Fe$_{50}$ multilayer reaches 150% at room temperature, which is much larger than the previous record high. Although the ratio decreases with increasing the temperature, the giant magneto-thermal resistance effect of ~100% still appears up to 400 K. The magnetic field dependence of the thermal conductivity of the Cu/Co$_{50}$Fe$_{50}$ multilayer was observed to be about twice greater than that of the cross-plane electrical conductivity. The observation of the giant magneto-thermal resistance effect clarifies a potential of spintronic multilayers as thermal switching devices.

cond-mat.mtrl-sci↗

Thickness dependence of spin Peltier effect visualized by thermal imaging technique

Magnon propagation length in a ferrimagnetic insulator yttrium iron garnet (YIG) has been investigated by measuring and analyzing the YIG-thickness t_YIG dependence of the spin Peltier effect (SPE) in a Pt/YIG junction system. By means of the lock-in thermography technique, we measured the spatial distribution of the SPE-induced temperature modulation in the Pt/YIG system with the t_YIG gradation, allowing us to obtain the accurate t_YIG dependence of SPE with high t_YIG resolution. Based on the t_YIG dependence of SPE, we verified the applicability of several phenomenological models to estimate the magnon diffusion length in YIG.

cond-mat.mtrl-sci↗

High-temperature dependence of anomalous Ettingshausen effect in SmCo$_5$-type permanent magnets

The anomalous Ettingshausen effect (AEE) in SmCo$_5$-type permanent magnets has been investigated in the high-temperature range from room temperature to around 600 K. The anomalous Ettingshausen coefficient of the SmCo$_5$ and (SmGd)Co$_5$ magnets monotonically increases with increasing the temperature and shows the similar temperature dependence, while the coefficient of SmCo$_5$ is slightly larger than that of (SmGd)Co$_5$ at high temperatures. The dimensionless figure of merit for AEE in SmCo$_5$ at high temperatures is much greater than the previous record obtained for the anomalous Nernst effect. The observed high-temperature behavior of AEE is discussed based on the first-principles calculations of transverse transport coefficients.

cond-mat.mtrl-sci↗

Strain-induced enhancement of the Seebeck effect in magnetic tunneling junctions via interface resonant tunneling: Ab-initio study

We investigate the thermoelectric properties of Fe/MgO/Fe(001) magnetic tunnel junctions (MTJs) by means of the linear-response theory combined with a first-principles-based Landauer-Büttiker approach. We find that the Seebeck coefficient of Fe/MgO/Fe(001) MTJs strongly depends on the barrier thickness and the tetragonal distortion. A compressive tetragonal distortion of the in-plane lattice parameter in the MTJs provides interface resonant states just above the Fermi energy. This causes resonant tunneling in the MTJs and significantly enhances the Seebeck coefficient when the thickness of the MgO barrier is around 1 nm (four or five atomic layers of MgO). Moreover, an extensive tetragonal distortion of the in-plane lattice parameter pushes the interface states away from the Fermi energy, leading to a reduction of the Seebeck coefficient. Furthermore, we find that the interface resonant tunneling enhances the power factor of the MTJs for the compressive distortion. These results indicate that control of the barrier thickness and the tetragonal distortion will be effective for maximizing the thermoelectric properties of MTJs.

cond-mat.mtrl-sci↗

Spin-mediated charge-to-heat current conversion phenomena in ferromagnetic binary alloys

Spin-mediated charge-to-heat current conversion phenomena, i.e., the anomalous Ettingshausen effect (AEE) and the anisotropic magneto-Peltier effect (AMPE), have been investigated in various ferromagnetic Ni-Fe, Ni-Pt, Ni-Pd, and Fe-Pt binary alloys at room temperature. When a charge current is applied to a ferromagnetic conductor, the AMPE modulates the Peltier coefficient depending on the angle between the directions of the charge current and magnetization, while the AEE generates a heat current in the direction perpendicular to both the charge current and magnetization. We observed the strong material dependence of the thermoelectric conversion coefficients and figures of merit of these phenomena. Among the ferromagnetic alloys used in this study, Ni$_{95}$Pt$_{5}$ exhibits the largest AMPE of which the anisotropy of the Peltier coefficient is $\sim 12\%$. In contrast, the magnitude of the AEE signals is moderate in Ni$_{95}$Pt$_{5}$ but largest in Ni$_{75}$Pt$_{25}$ and Ni$_{50}$Fe$_{50}$. We discuss these behaviors by exploring the relations between these charge-to-heat current conversion phenomena and other transport as well as magnetic properties. This systematic study will provide a clue for clarifying the mechanisms of the AMPE and AEE and for enhancing the thermoelectric conversion efficiency of these phenomena.

cond-mat.mtrl-sci↗

Machine learning analysis of tunnel magnetoresistance of magnetic tunnel junctions with disordered MgAl2O4

Through Bayesian optimization and the least absolute shrinkage and selection operator (LASSO) technique combined with first-principles calculations, we investigated the tunnel magnetoresistance (TMR) effect of Fe/disordered-MgAl2O4(MAO)/Fe(001) magnetic tunnel junctions (MTJs) to determine structures of disordered-MAO that give large TMR ratios. The optimal structure with the largest TMR ratio was obtained by Bayesian optimization with 1728 structural candidates, where the convergence was reached within 300 structure calculations. Characterization of the obtained structures suggested that the in-plane distance between two Al atoms plays an important role in determining the TMR ratio. Since the Al-Al distance of disordered MAO significantly affects the imaginary part of complex band structures, the majority-spin conductance of the Δ1 state in Fe/disordered-MAO/Fe MTJs increases with increasing in-plane Al-Al distance, leading to larger TMR ratios. Furthermore, we found that the TMR ratio tended to be large when the ratio of the number of Al, Mg, and vacancies in the [001] plane was 2:1:1, indicating that the control of Al atomic positions is essential to enhancing the TMR ratio in MTJs with disordered MAO. The present work reveals the effectiveness and advantage of material informatics combined with first-principles transport calculations in designing high-performance spintronic devices based on MTJs.

cond-mat.mtrl-sci↗

Transient response of spin Peltier effect revealed by lock-in thermoreflectance measurement

Transient response of the spin Peltier effect (SPE) in a Pt/yttrium iron garnet junction system has been investigated by means of a lock-in thermoreflectance method. We applied an alternating charge current to the Pt layer to drive SPE through the spin Hall effect, and measured the AC response of the resultant SPE-induced temperature modulation at frequencies ranging from 10 Hz to 1 MHz. We found that the SPE-induced temperature modulation decreases with increasing the frequency when the frequency is >1 kHz. This is a characteristic feature of SPE revealed by the high frequency measurements based on the lock-in thermoreflectance, while previous low frequency measurements showed that the SPE signal is independent of the frequency. We attribute the decrease of the temperature modulation to the length scale of the SPE-induced heat current; by comparing the experimental results with one-dimensional heat conduction calculations, the length scale of SPE is estimated to be 0.94 μm.

cond-mat.mtrl-sci↗

Observation of anomalous Ettingshausen effect and large transverse thermoelectric conductivity in permanent magnets

This study focuses on the potential of permanent magnets as thermoelectric converters. It is found that a SmCo$_5$-type magnet exhibits the large anomalous Ettingshausen effect (AEE) at room temperature and that its charge-to-heat current conversion coefficient is more than one order of magnitude greater than that of typical ferromagnetic metals. The large AEE is an exclusive feature of the SmCo$_5$-type magnet among various permanent magnets in practical use, which is independent of the conventional performance of magnets based on static magnetic properties. The experimental results show that the large AEE originates from the intrinsic transverse thermoelectric conductivity of SmCo$_5$. This finding makes a connection between permanent magnets and thermal energy engineering, providing the basis for creating "thermoelectric permanent magnets."

cond-mat.mtrl-sci↗

Thermoelectric microscopy of magnetic skyrmions

The magnetic skyrmion is a nanoscale topological object characterized by the winding of the magnetic moments, appearing in magnetic materials with broken inversion symmetry. Because of its low current threshold for driving, the skyrmions have been intensely studied toward novel storage applications by using electron-beam, X-ray, and visible light microscopies. Here, we show that the skyrmions can be imaged via thermoelectric signals of spin-caloritronic phenomena in combination with focused heating. We applied a local temperature gradient to a CoFeB/Ta/W multilayer film with scanning a heating position and, by exploiting a Hall bar structure, mapped the magnitude as well as the direction of the resultant thermoelectric current distributions, which link to skyrmions' inner magnetic textures. This method also enables the observation of skyrmion dynamics under driving current pulses, being a useful imaging technique for the development of skyrmion devices.

cond-mat.mes-hall↗

Systematic Investigation of Anisotropic Magneto-Peltier Effect and Anomalous Ettingshausen Effect in Ni Thin Films

The anisotropic magneto-Peltier effect (AMPE) and anomalous Ettingshausen effect (AEE) have been investigated in U-shaped Ni thin films of varying thickness and substrate by means of the lock-in thermography (LIT) method. We have established a procedure to extract pure AMPE and AEE contributions, separated from other thermoelectric effects, for ferromagnetic thin films. The measurements of the magnetic-field-angle $θ_{\rm H}$ dependence of the LIT images clearly show that the temperature modulation induced by the AMPE (AEE) in the Ni films varies with the $\cos 2θ_{\rm H}$ ($\cos θ_{\rm H}$) pattern, confirming the symmetry of the AMPE (AEE). The systematic LIT measurements using various substrates show that the AMPE-induced temperature modulation decreases with the increase in thermal conductivity of the substrates, whereas the AEE-induced temperature modulation is almost independent of the thermal conductivity, indicating that the heat loss into the substrates plays an important role in determining the magnitude of the AMPE-induced temperature modulation in thin films. Our experimental results were reproduced by numerical calculations based on a two-dimensional finite element method. These findings provide a platform for investigating the AMPE and AEE in thin film devices.

cond-mat.mtrl-sci↗

First-principles study of the anisotropic magneto-Peltier effect

We study theoretically the anisotropic magneto-Peltier effect, which was recently demonstrated experimentally. A first-principles-based Boltzmann transport approach including the spin-orbit interaction shows that Ni has a larger anisotropy of the Peltier coefficient ($ΔΠ$) than Fe, consistent with experiments. It is clarified that spin-flip electron transitions due to the spin-orbit interaction are the key in the mechanism of the large anisotropic magneto-Peltier effect. Using our method, we further predict several ferromagnetic metals with much larger $ΔΠ$ than that of Ni.

cond-mat.mtrl-sci↗

Thermopile based on anisotropic magneto-Peltier effect

We propose conceptually novel thermopile structures for the anisotropic magneto-Peltier effect (AMPE) to enhance its heating/cooling power. The cross-shaped thermopile, one of the representative AMPE-based thermopile structures, consists of four L-shaped ferromagnetic metals arranged in a cross-shaped configuration, which allows concentration of the AMPE-induced temperature modulation at the center of the cross structure. The AMPE-based thermopile does not require the use of any complicated junctions comprising different materials, enabling the design of compact and versatile temperature controllers for nanoscale devices.

cond-mat.mtrl-sci↗

Machine-learning guided discovery of a high-performance spin-driven thermoelectric material

Thermoelectric conversion using Seebeck effect for generation of electricity is becoming an indispensable technology for energy harvesting and smart thermal management. Recently, the spin-driven thermoelectric effects (STEs), which employ emerging phenomena such as the spin-Seebeck effect (SSE) and the anomalous Nernst effect (ANE), have garnered much attention as a promising path towards low cost and versatile thermoelectric technology with easily scalable manufacturing. However, progress in development of STE devices is hindered by the lack of understanding of the mechanism and materials parameters that govern the STEs. To address this problem, we enlist machine learning modeling to establish the key physical parameters controlling SSE. Guided by these models, we have carried out a high-throughput experiment which led to the identification of a novel STE material with a thermopower an order of magnitude larger than that of the current generation STE devices.

cond-mat.mtrl-sci↗

High-throughput direct measurement of magnetocaloric effect based on lock-in thermography technique

We demonstrate a high-throughput direct measurement method for the magnetocaloric effect (MCE) by means of a lock-in thermography (LIT) technique. This method enables systematic measurements of the magnetic-field and operation-frequency dependences of the temperature change induced by the MCE. This is accomplished in a shorter time compared with conventional adiabatic temperature measurement methods. The direct measurement based on LIT is free from any possible miscalculations and errors arising from indirect measurements using thermodynamic relations. Importantly, the LIT technique makes simultaneous MCE measurements of multiple materials possible without increasing measurement time, realizing high-throughput investigations of the MCE. By applying this method to Gd, we obtain the MCE-induced temperature change of 1.84 $\pm$ 0.11 K under a modulation field of 1.0 T and modulation frequency of 0.5 Hz at a temperature of 300.5 $\pm$ 0.5 K, offering evidence that the LIT method gives quantitative results.

cond-mat.mtrl-sci↗

Magnetic-field-induced suppression of spin Peltier effect in Pt/${\rm Y_{3}Fe_{5}O_{12}}$ system at room temperature

We report the observation of magnetic-field-induced suppression of the spin Peltier effect (SPE) in a junction of a paramagnetic metal Pt and a ferrimagnetic insulator ${\rm Y_{3}Fe_{5}O_{12}}$ (YIG) at room temperature. For driving the SPE, spin currents are generated via the spin Hall effect from applied charge currents in the Pt layer, and injected into the adjacent thick YIG film. The resultant temperature modulation is detected by a commonly-used thermocouple attached to the Pt/YIG junction. The output of the thermocouple shows sign reversal when the magnetization is reversed and linearly increases with the applied current, demonstrating the detection of the SPE signal. We found that the SPE signal decreases with the magnetic field. The observed suppression rate was found to be comparable to that of the spin Seebeck effect (SSE), suggesting the dominant and similar contribution of the low-energy magnons in the SPE as in the SSE.

cond-mat.mtrl-sci↗

Detection of induced paramagnetic moments in Pt on Y$_3$Fe$_5$O$_{12}$ via x-ray magnetic circular dichroism

Magnetic moments in an ultra-thin Pt film on a ferrimagnetic insulator Y$_3$Fe$_5$O$_{12}$ (YIG) have been investigated at high magnetic fields and low temperatures by means of X-ray magnetic circular dichroism (XMCD). We observed an XMCD signal due to the magnetic moments in a Pt film at the Pt $L_{3}$- and $L_{2}$-edges. By means of the element-specific magnetometry, we found that the XMCD signal at the Pt $L_{3}$-edge gradually increases with increasing the magnetic field even when the field is much greater than the saturation field of YIG. Importantly, the observed XMCD intensity was found to be much greater than the intensity expected from the Pauli paramagnetism of Pt when the Pt film is attached to YIG. These results imply the emergence of induced paramagnetic moments in Pt on YIG and explain the characteristics of the unconventional Hall effect in Pt/YIG systems.

cond-mat.mtrl-sci↗

Thermographic measurements of the spin Peltier effect in metal/yttrium-iron-garnet junction systems

The spin Peltier effect (SPE), heat-current generation due to spin-current injection, in various metal (Pt, W, and Au single layers and Pt/Cu bilayer)/ferrimagnetic insulator (yttrium iron garnet: YIG) junction systems has been investigated by means of a lock-in thermography (LIT) method. The SPE is excited by a spin current across the metal/YIG interface, which is generated by applying a charge current to the metallic layer via the spin Hall effect. The LIT method enables the thermal imaging of the SPE free from the Joule-heating contribution. Importantly, we observed spin-current-induced temperature modulation not only in the Pt/YIG and W/YIG systems but also in the Au/YIG and Pt/Cu/YIG systems, excluding the possible contamination by anomalous Ettingshausen effects due to proximity-induced ferromagnetism near the metal/YIG interface. As demonstrated in our previous study, the SPE signals are confined only in the vicinity of the metal/YIG interface; we buttress this conclusion by reducing a spatial blur due to thermal diffusion in an infrared emission layer on the sample surface used for the LIT measurements. We also found that the YIG-thickness dependence of the SPE is similar to that of the spin Seebeck effect measured in the same Pt/YIG sample, implying the reciprocal relation between them.

cond-mat.mtrl-sci↗

Probing length-scale separation of thermal and spin currents by nanostructuring YIG

We have fabricated bulk nanostructured ferrimagnetic materials with different grain sizes by sintering ball-milled Y3Fe5O12 (YIG) nanoparticles and measured the grain-size dependence of the thermal conductivity and spin Seebeck thermopower. The nanostructuring reduces both thermal conductivity and thermopower, but the reduction of the latter was found to be considerably stronger despite the moderate difference in magnetization, which suggests that the length scales of transport of magnons and phonons contributing to the spin Seebeck effect are significantly larger than that of phonons carrying thermal current. This is consistent with the measurements of high-magnetic-field response of the spin Seebeck thermopower and low-temperature thermal conductivity, where the quenching of magnons seen in single-crystalline YIG was not observed in nanostructured YIG due to scattering of long-range low frequency magnons.

cond-mat.mtrl-sci↗