arXiv subjects

Kenji Furuya

Publications and source records attributed to Kenji Furuya.

At least 19 recordsLinked to original sources

arXiv2026

Subarcsecond Multi-line Observations of NH$_3$ with VLA toward the Class 0 Source IRAS 16293-2422

Ammonia (NH$_3$) is one of the key volatiles that plays a central role in nitrogen chemistry and its evolution during the epoch of star and planet formation. We present subarcsecond ($\sim0.\!\!^{\prime\prime}5$) resolution observations of NH$_3$ molecular emission lines with Karl G. Jansky Very Large Array (VLA) toward the Class 0 multiple system IRAS 16293-2422 including source A and source B as major components. This comprises the most comprehensive set of NH$_3$ line observations in protostellar sources to date, which includes 17 inversion transitions with a wide range of upper state energies ($E_\mathrm{u}$) spanning from $\sim$23 K to $\sim$1,580 K. We detect spatially resolved emission of a number of transitions, and find that the high-$E_\mathrm{u}$ ($\gtrsim$1,000 K) lines show compact distributions in the vicinity of protostars while low-$E_\mathrm{u}$ ($\lesssim$150 K) lines exhibit more extended emission. Utilizing a two-component model, we constrain the rotation temperature and NH$_3$ column density for both source A and source B. The rotation temperature of the warmer component reaches $\sim$200-300 K, indicating that the high-$E_\mathrm{u}$ lines selectively trace the inner hot region. We suggest that this hot NH$_3$ gas in source A is originated from the local shock heating based on the comparison with the previous high-resolution ALMA observations, while that in source B could be explained by the mass accretion heating in the innermost hot region. We also briefly discuss the chemistry related to NH$_3$ based on the abundance ratios relative to major icy molecules derived using literature values.

astro-ph.GA↗

arXiv2026

Survival of Molecular Complexity under Recent Supernova Feedback: Detection of Hot Cores in RX J1713.7-3946

Protostellar cores located near supernova remnants are considered potential analogues of the birth environment of the solar system. However, the extent to which supernovae influence their chemical evolution remains unclear. We report the first detection of hot molecular cores in a supernova remnant using the Atacama Large Millimeter/submillimeter Array. The detected hot cores (HC1 and HC2) are located inside the X-ray shell of the young supernova remnant RX J1713.7-3946, and both sources are associated with Class I intermediate-mass protostars. This paper focuses on a detailed chemical analysis of HC1, in which a variety of carbon-, oxygen-, nitrogen-, sulfur-, and silicon-bearing species are detected. Excitation analyses indicate that HC1 harbors dense (~10^7 cm-3), compact (<500 au), and high-temperature (>100K) molecular gas. Despite being located within a supernova-feedback region, the column density ratios of complex organic molecules (HCOOCH3/CH3OH, CH3OCH3/CH3OH, and CH3CHO/CH3OH), a deuterated molecule (CH2DOH/CH3OH), and sulfur- and nitrogen-bearing species (OCS/CH3OH and C2H5CN/CH3CN) in HC1 are indistinguishable from those observed in hot cores/corinos in more typical star-forming environments. HC1 is located near the outer edge of the supernova shell, and the surrounding region has likely begun to be exposed to such a harsh environment only recently. The elapsed time since the onset of exposure to high-energy particles and photons may be too short for the chemical composition of the hot core to be significantly altered, and/or the hot-core region may be shielded by magnetic fields amplified by supernova feedback, which could suppress the penetration of enhanced cosmic rays.

astro-ph.GA↗

arXiv2026

Compact Hydrogen Sulfide Emission Indicates Sulfur-bearing Ice Sublimation in the Inner Disk of HD 163296

The sulfur chemistry in protoplanetary disks directly affects the composition and potential habitability of nascent planets, but its volatile inventory remains highly uncertain. Here, we present deep Atacama Large Millimeter/submillimeter Array (ALMA) observations of hydrogen sulfide (H$_2$S) along with SO and SO$_2$ in the disk around HD 163296 at an angular resolution of $\approx0.\!\!^{\prime\prime}3$ (or $\approx$30 au). We detect unresolved, compact emission of H$_2$S and SO (and tentatively SO$_2$) at the disk center with a broad line width of $\sim$40 km s$^{-1}$, suggesting that the emission is originating from the innermost regions. By fitting line profiles with a geometrically-thin Keplerian-rotating disk model, we constrain the emitting radii and gas temperatures of these molecules to be $\approx$3-5 au and $\gtrsim$90-120 K, respectively, consistent with sublimation of sulfur-bearing molecules along with water ice in the inner warm region. While the higher or comparable column density of H$_2$S with respect to SO and SO$_2$ indicates that H$_2$S is an important volatile sulfur reservoir in the disk, the limited constraints mean that we cannot rule out significantly depleted volatile sulfur as also commonly inferred in other planet-forming disks. Further observations are needed to better constrain disk sulfur inventory, unravel how sulfur compounds are reprocessed in disks, and shed light on the nature of less-volatile species, such as salts and sulfide minerals, which may occupy a significant portion of sulfur budget.

astro-ph.EP↗

arXiv2026

An Enriched Methane D/H Ratio in the Interstellar Object 3I/ATLAS

Interstellar objects are interlopers from other planetary systems, and their volatile compositions provide a glimpse into planet formation around their host star. We present near-infrared spectra of the coma of interstellar object 3I/ATLAS measured with the James Webb Space Telescope. Our results demonstrate an unexpectedly high D/H = $(3.33\pm0.31)\%$ for methane and represent an exceedingly rare detection of deuterated organic molecules in an interstellar object. This D/H ratio exceeds any other value for methane measured in the solar system, and is a factor of $14\pm2$ higher than that measured in comet 67P/Churyumov-Gerasimenko by the Rosetta spacecraft, the only other comet for which CH$_3$D has been detected. Both 3I/ATLAS and 67P/Churyumov-Gerasimenko show a higher degree of methane dueteration compared to water, consistent with trends seen in other solar system bodies and the nearby interstellar medium, where deuteration in organics exceeds that of water by up to an order of magnitude. The D/H ratio in methane itself is observationally unconstrained in extrasolar sources to date, but the enriched ratio in 3I/ATLAS is similar to those measured in methanol and formaldehyde toward primitive environments. The elevated D/H ratio for methane in 3I/ATLAS is consistent with the hypothesis that its ices formed in a cold, low metallicity interstellar or protostellar environment under a high cosmic ray irradiation rate (Cordiner et al. 2026).

astro-ph.EP↗

arXiv2026

Coma Physics of an Interstellar Object: JWST Spatial-Spectral Mapping of 3I/ATLAS

We report a survey of molecular emission from cometary volatiles using the James Webb Space Telescope (JWST) toward interstellar object 3I/ATLAS carried out on UT 2025 December 22 and 23 at a heliocentric distance ($r_H$) of $2.37-2.41$ au. These measurements of CO, CO$_2$, H$_2$O, CH$_3$OH, and CH$_4$ sampled molecular chemistry in 3I/ATLAS as it receded from its encounter with our Sun and entered the vicinity of the H$_2$O ice line -- the region between $r_H$ = $2-3$ au where the temperature becomes too low for H$_2$O to vigorously sublime and CO and CO$_2$ begin to control the overall activity. CO was the most abundant molecule, followed by H$_2$O and CO$_2$, whose molecular abundances with respect to CO were $(40.5\pm3.1)\%$ and ($41.6\pm0.3)\%$, respectively. This work presents spatial-spectral maps of column density and rotational temperature as a function of distance from the nucleus for all detected species. The spatial distributions of both quantities were highly anisotropic for the apolar species in the coma of 3I/ATLAS, yet were more nearly symmetric for the polar molecules. These results demonstrate how volatiles were segregated in the nucleus ices of 3I/ATLAS and reveal heating and cooling mechanisms in its coma. Derived maps of the ortho-to-para ratio (OPR) for H$_2$O were flat with increasing distance from the nucleus and consistent with a coma-averaged value $\mathrm{OPR}=2.7\pm0.2$, slightly less than the expected equilibrium value of three.

astro-ph.EP↗

arXiv2026

Isotopic Evidence for a Cold and Distant Origin of the Interstellar Object 3I/ATLAS

Interstellar objects provide the only directly observable samples of icy planetesimals formed around other stars, and can therefore provide insight into the diversity of physical and chemical conditions occurring during exoplanet formation. Here we report isotopic measurements of the interstellar comet 3I/ATLAS, which reveal an elemental composition unlike any Solar System body. The water in 3I/ATLAS is enriched in deuterium, at a level of D/H = (0.95 +- 0.06)%, which is more than an order of magnitude higher than in known comets, while its range of 12C/13C ratios (141-191 for CO2 and 123-172 for CO) exceeds typical values found in the Solar System, as well as nearby interstellar clouds and protoplanetary disks. Such extreme isotopic signatures indicate formation at temperatures $\lesssim30$ K in a relatively metal-poor environment, early in the history of the Galaxy. When interpreted with respect to models for Galactic chemical evolution, the carbon isotopic composition implies that 3I/ATLAS accreted roughly 10-12 billion years ago, following an early period of intense star formation. 3I/ATLAS thus represents a preserved fragment of an ancient planetary system, and provides direct evidence for active ice chemistry and volatile-rich planetesimal formation in the young Milky Way.

astro-ph.EP↗

arXiv2026

H$_2$ Ortho-Para Spin Conversion on Inhomogeneous Grain Surfaces. II. impact of the rotational energy difference between adsorbed ortho-H$_2$ and para-H$_2$ and implication to deuterium fractionation chemistry

We investigate how the H$_2$ ortho-to-para ratio (OPR) and dueterium fractionation in star-forming regions are affected by nuclear spin conversion (NSC) on dust grains. Particular focus is placed on the rotational energy difference between ortho-H$_2$ (o-H$_2$) and para-H$_2$ (p-H$_2$) on grain surfaces. While the ground state of o-H$_2$ has a higher rotational energy than that of p-H$_2$ by 170.5 K in the gas phase, this energy difference is expected to become smaller on solid surfaces, where interactions between the surface and adsorbed H$_2$ molecules affect their rotational motion. A previous study by Furuya et al. (2019) developed a rigorous formulation of the rate for the temporal variation of the H$_2$ OPR via the NSC on grains, assuming that adsorbed o-H$_2$ has higher rotational energy than adsorbed p-H$_2$ by 170.5 K, as in the gas phase. In this work, we relax the assumption and re-evaluate the rate, varying the rotational energy difference between their ground states. The re-evaluated rate is incorporated into a gas-ice astrochemical model to study the evolution of the H$_2$ OPR and the deuterium fractionation in prestellar cores and the outer, cold regions of protostellar envelopes. The inclusion of the NSC on grains reduces the timescale of the H2 OPR evolution and thus the deuterium fractionation, at densities of >10$^4$ cm$^{-3}$ and temperatures of <14-16 K (depending on the rotational energy difference), when the ionization rate of H$_2$ is 10$^{-17}$ s$^{-1}$.

astro-ph.GA↗

arXiv2026

Atom Addition Formation of Thionylimide (HNSO) on Interstellar Dust Grains: Chemical routes requiring oxygen and nitrogen atom surface diffusion

We investigate the formation of the recently detected HNSO molecule using quantum chemical calculations on ices and astrochemical models in tandem. Our results indicate that HNSO is efficiently produced on grain surfaces through reactions involving atomic oxygen and nitrogen atoms with the radicals NS and SO, forming NSO as a key intermediate. Subsequent hydrogenation of NSO leads to HNSO, with a clear preference for the lowest energy cis conformer, while the trans form is metastable and may be short-lived under typical interstellar conditions. The models predict that solid HNSO can reach abundances comparable to icy OCS, placing it among the major sulfur-bearing species in interstellar ices. Gas-phase abundances, in contrast, remain lower than those of OCS. The implementation of a multibinding scheme in our models clarifies the role of diffusive chemistry in the production of HNSO at early times, improving agreement with observations. These findings suggest that reactions involving diffusing O and N atoms on icy grains contribute significantly to sulfur chemistry and beyond in dense clouds and motivate further searches for molecules containing simultaneously H, N, O and S in other astronomical environments.

astro-ph.GA↗

arXiv2026

Digging into the chemical complexity in the outer Galaxy: A hot molecular core in Sharpless 2-283

The outer Galaxy (galactocentric distance $\gtrsim$13.5 kpc) serves as an excellent laboratory for investigating the chemical complexity in low-metallicity environments. Here, we present the chemical analyses for the outer Galactic hot core Sh 2-283-1a SMM1 ($D_\mathrm{GC}$ = 15.7 kpc and $Z$ $\sim$0.3 $Z_\odot$), recently detected by Ikeda et al. (2025) using ALMA. Toward this source, a variety of molecular species, including complex organic molecules (COMs: CH$_3$OH, $^{13}$CH$_3$OH, CH$_2$DOH, and CH$_3$OCH$_3$) are detected. The molecular abundances relative to CH$_3$OH are similar to those of another outer Galactic hot core, demonstrating that chemically rich hot cores exist in different regions of the outer Galaxy. We also compared molecular abundances among hot cores in the inner Galaxy, outer Galaxy, and Magellanic Clouds. This comparison revealed that the metallicity-corrected $N$(SO$_2$)/$N$(H$_2$) ratios of outer Galactic hot cores are significantly lower than those of the inner Galactic ones, while their $N$(CH$_3$OH)/$N$(H$_2$) ratios are similar. The Magellanic hot cores show different trends despite having metallicities similar to those of the outer Galaxy, indicating that the chemical complexity of hot cores is governed by environmental conditions (e.g., cosmic ray intensity and dust temperature) rather than simple metallicity scaling. These environmental differences would also affect the production efficiency of COMs derived from CH$_3$OH, as the $N$(CH$_3$OCH$_3$)/$N$(CH$_3$OH) and $N$(C$_2$H$_5$OH)/$N$(CH$_3$OH) ratios in the outer Galactic sources are moderately lower than those of inner Galactic sources. The $N$(CH$_2$DOH)/$N$(CH$_3$OH) ratio of Sh 2-283-1a SMM1 is 1.5$^{+3.9}_{-1.2}$$\%$, comparable to that of inner Galactic high-mass sources.

astro-ph.GA↗

arXiv2026

Time-dependent chemical evolution during cloud formation: H$_2$-regulated chemistry in diffuse molecular cloud

We investigate the chemical evolution of a forming molecular cloud behind an interstellar shock wave. We conduct three-dimensional magnetohydrodynamics simulations of the converging flow of atomic gas, including a simple chemical network and tracer particles that move along the local velocity field. Then we perform detailed chemical network calculations along the trajectory of each tracer particle. The diffuse part of forming molecular clouds is CO-poor; i.e., H$_2$ and CO abundances do not correlate. In diffuse regions of $n_\mathrm{H}\lesssim 10^{3}\,\mathrm{cm^{-3}}$, we find that the abundances of hydrocarbons and oxygen-bearing molecules are determined by steady-state chemistry reflecting the local H$_2$ abundance, which is determined by the gas density along the trajectory. In denser regions, the abundances are affected by water ice formation, which changes the elemental abundance of carbon and oxygen (i.e., C/O ratio) in the gas phase. Assuming quasi-steady-state chemistry given the abundances of major molecules (e.g., H$_2$) from the simple network, we derive analytic solutions for molecular abundances, which reproduce the calculation results. We also calculate the molecular column densities based on the spatial distribution of tracer particles and their molecular abundances, and compare them with observations of diffuse molecular clouds. We find that the column densities of CH, CCH, and OH are linearly correlated with those of H$_2$, which supports the empirical relation used in the observations. On the other hand, the column density of HCO$^+$ shows non-linear dependence on the H$_2$ column density, reflecting the difference in HCO$^+$ formation paths in CO-poor and CO-rich regions.

astro-ph.GA↗

arXiv2025

ALMA Observations of Cold Methanol Gas in the Large Magellanic Cloud (LMC): N79 South GMC

We report ALMA continuum and molecular line observations at 0.1 pc resolution toward the super star cluster (SSC) candidate H72.97-69.39 in the N79 region of the LMC. The continuum emission has a sharp peak around the SSC candidate but is also widely distributed. We identify two continuum sources at the northern (N79S-1) and northwestern (N79S-2) positions of the SSC continuum peak, associated with CH$_3$OH emission. In addition to CH$_3$OH, we also detect H$_2$CO, H$_2$CS, CS, SO, CO, CN, and CCH at the positions of N79S-1 and N79S-2. The rotation diagram analysis of CH$_3$OH and SO lines yields an average gas temperature of 13 $\pm$ 0.4 K for N79S-1 and 15 $\pm$ 0.9 K for N79S-2. Most emission lines exhibit line widths of less than 2.8 km s$^{-1}$, consistent with emissions from cold, dense molecular cloud cores. The abundance of cold CH$_3$OH gas is estimated to be (2.1 $\pm$ 1.1)$\times$ 10$^{-9}$ at N79S-1 and (4.5 $\pm$2.5)$\times$ 10$^{-10}$ at N79S-2. Despite the lower metallicity in the LMC, the CH$_3$OH abundance at N79S-1 is comparable to that of similar cold sources in our Galaxy. However, the formation of organic molecules is inhibited throughout the N79 regions, as can be seen in the non-detection of CH$_3$OH in most of the regions. The two positions N79S-1 and N79S-2 would be exceptional positions, where CH$_3$OH production is efficient. The possible origins of cold CH$_3$OH gas in these dense cores are discussed, along with a possible explanation for the non-detection of CH$_3$OH in the SSC candidate.

astro-ph.GA↗

arXiv2025

MAGellanic Outflow and chemistry Survey (MAGOS): Hot cores in the LMC

The Large Magellanic Cloud (LMC) provides a key laboratory for exploring the diversity of star formation and interstellar chemistry under subsolar metallicity conditions. We present the results of a hot core survey toward 30 massive protostellar objects in the LMC using the Atacama Large Millimeter/submillimeter Array (ALMA) at 350 GHz. Continuum imaging reveals 36 compact sources in total, among which line analyses identify 9 hot cores and 1 hot-core candidate, including two newly identified sources. We detect CO, HCO+, H13CO+, HC15N, HC3N, SiO, SO, SO+, NS, SO2, 34SO2, 33SO2, CH3OH, 13CH3OH, HCOOH, HCOOCH3, CH3OCH3, C2H5OH, H2CCO (tentative), and hydrogen recombination lines from hot cores. CH3OCH3, a complex organic molecule larger than CH3OH, is detected for the first time in a hot core outside the LMC bar region. All hot cores show stronger emission in the high-excitation SO line compared to non-hot-core sources, suggesting that its strong detection will be useful for identifying hot-core candidates in the LMC. Chemical analysis reveals a spread of more than two orders of magnitude in CH3OH abundances, with some sources deficient in COMs. In contrast, SO2 is detected in all hot cores, and its abundance shows a good correlation with rotational temperature. The hot cores without CH3OH detections are all located outside the LMC bar region and are characterized by either high luminosity or active star formation in their surroundings. A combination of locally low metallicity, active star formation in the vicinity, and high protostellar luminosity may jointly trigger the COM-poor hot core chemistry observed in the LMC.

astro-ph.GA↗

arXiv2025

Isotopomer-Specific Carbon Isotope Ratio of Complex Organic Molecules in Star-Forming Cores

The recent observation of complex organic molecules (COMs) in interstellar ices by the James Webb Space Telescope (JWST), along with previous gas-phase detections, underscores the importance of grain surface and ice mantle chemistry in the synthesis of COMs. In this study, we investigate the formation and carbon isotope fractionation of COMs by constructing a new astrochemical reaction network that distinguishes the position of $^{13}$C within species (e.g., H$^{13}$COOCH$_3$ and HCOO$^{13}$CH$_3$ are distinguished). We take into account the position of $^{13}$C in each species in gas and solid phase chemistry. This new model allows us to resolve isotopomer-specific $^{12}$C/$^{13}$C ratios of COMs formed in the star-forming cores. We consider thermal diffusion-driven radical-radical reactions on the ice surface and non-thermal radiolysis chemistry in the bulk (surface + mantle) ice. We find that carbon isotope fractionation of the functional groups in COMs appears through both non-thermal radiolysis in cold environments and thermal diffusion in warm environments, depending on the COMs. In particular, COMs containing methyl groups show isotopomer differences in $^{12}$C/$^{13}$C ratios that reflect their formation pathways and environments. These isotopomer-resolved fractionation patterns provide a diagnostic tool to probe the origins of COMs in star-forming cores. Our results suggest that future comparisons between high-sensitivity isotopic observations and isotopomer-specific models will be helpful for constraining the relative contributions of thermal and non-thermal formation processes of COMs.

astro-ph.GA↗

arXiv2025

CH$_3$OH and HCN in Interstellar Comet 3I/ATLAS Mapped with the ALMA Atacama Compact Array: Distinct Outgassing Behaviors and a Remarkably High CH$_3$OH/HCN Production Rate Ratio

We report the detection of methanol (CH$_3$OH) toward interstellar comet 3I/ATLAS using the Atacama Compact Array of the Atacama Large Millimeter/Submillimeter Array (ALMA) on UT 2025 August 28, September 18 and 22, and October 1, and of hydrogen cyanide (HCN) on September 12 and 15. These observations spanned pre-perihelion heliocentric distances ($r_H$) of 2.6 -- 1.7 au. The molecules showed outgassing patterns distinct from one another, with HCN production being depleted in the sunward hemisphere of the coma, whereas CH$_3$OH was enhanced in that direction. Statistical analysis of molecular scale lengths in 3I/ATLAS indicated that CH$_3$OH included production from coma sources at $L_p>258$ km at 99% confidence. However low signal-to-noise on long baselines, which sample emission on small spatial scales closest to the nucleus, prevented definitively ruling out CH$_3$OH as purely a parent species. In contrast, HCN production was indistinguishable from direct nucleus sublimation. The CH$_3$OH production rate increased sharply from August through October, including an uptick near the inner edge of the H$_2$O sublimation zone at $r_H$ = 2 au. Compared to comets measured to date at radio wavelengths, the derived CH$_3$OH/HCN ratios in 3I/ATLAS of $124^{+30}_{-34}$ and $79^{+11}_{-14}$ on September 12 and 15, respectively, are among the most enriched values measured in any comet, surpassed only by anomalous solar system comet C/2016 R2 (PanSTARRS).

astro-ph.EP↗

arXiv2025

Pristine ices in a planet-forming disk revealed by heavy water

Water is essential to our understanding of the planet-formation process and habitability on Earth. Although trace amounts of water are seen across all phases of star and planet formation, the bulk of the water reservoir often goes undetected, hiding crucial parts of its journey from giant molecular clouds to planets. This raises the question of whether water molecules in comets and (exo-)planets is largely inherited from the interstellar medium or if the water molecules are destroyed and then reformed in the disk. Water isotopologue ratios involving doubly deuterated water (D$_2$O) are a sensitive tracer to answer this question. We present strong evidence of inheritance through an enhancement of D$_2$O in the outbursting V883 Ori disk. The high D$_2$O/H$_2$O ratio of $(3.2 \pm 1.2) \times 10^{-5}$ is consistent with values seen in protostellar envelopes and a comet and is two orders of magnitude higher than expected if water is reprocessed. The high deuteration of the heaviest isotopologues D$_2$O/HDO = $(2.3 \pm 1.0) \times $HDO/H$_2$O further establishes the inheritance of water. We conclude that water ice in disks originates from the earliest phases of star formation, providing the missing link between cold dark clouds and (exo-)comets.

astro-ph.EP↗

arXiv2025

Winding Motion of Spirals in a Gravitationally Unstable Protoplanetary Disk

The discovery of wide-orbit giant exoplanets has posed a challenge to our conventional understanding of planet formation by coagulation of dust grains and planetesimals, and subsequent accretion of protoplanetary disk gas. As an alternative mechanism, the direct in-situ formation of planets or planetary cores by gravitational instability (GI) in protoplanetary disks has been proposed. However, observational evidence for GI in regions where wide-orbit planets are formed is still lacking. Theoretical studies predict that GI induces spiral arms moving at the local Keplerian speed in a disk. Here, with multiple high angular resolution observations over a seven-year time baseline using the Atacama Large Millimeter/submillimeter Array (ALMA), we report the evidence for spiral arms following the Keplerian rotation in the dust continuum disk around the young star IM Lup. This demonstrates that GI can operate in wide-orbit planet-formation regions, establishing it as a plausible formation mechanism for such planets.

astro-ph.EP↗

arXiv2025

Formation of unsaturated carbon chains through carbon chemisorption on solid CO

The interaction of carbon atoms with solid carbon monoxide (CO) is a fundamental process in astrochemistry, influencing the formation of complex organic molecules in interstellar environments. This study investigates the adsorption and reaction mechanisms of carbon atoms on solid CO under cryogenic conditions, employing a combination of experimental techniques, including photostimulated desorption and resonance-enhanced multiphoton ionization (PSD-REMPI) and infrared spectroscopy, alongside quantum chemical calculations. The results reveal the formation of oxygenated carbon chains, such as CCO, C$_3$O$_2$, and C$_5$O$_2$, as well as CO$_2$. The findings highlight the role of chemisorption and subsequent reactions in driving molecular complexity on solid CO, with implications for the chemical evolution of interstellar ices and the potential formation of prebiotic molecules.

astro-ph.GA↗

arXiv2025

Extended and Compact Ortho-H$_2$D$^+$ Structures Close to the Moment of Star-Formation: Evidence from ALMA-ACA Observations in Taurus

Observing and characterizing pre- and protostellar cores in the earliest and densest stages of star formation is challenging due to their short timescales and high densities, limiting the suitable tracers and targets. We conducted ALMA-Atacama Compact Array (ACA) stand-alone observations of ortho-H$_2$D$^+$ (1$_{\rm 1,0}$-1$_{\rm 1,1}$) emission, which is believed to trace cold high-density regions, toward three dense cores in the Taurus molecular cloud: (1) L1544, likely in the densest prestellar phase; (2) MC 35-mm, a candidate for the first hydrostatic core; and (3) MC 27/L1521F, which hosts a Class 0 very-low luminosity object. These observations provide high angular resolution data for the line across a set of cores selected to represent consecutive stages around the onset of star formation, offering a unique opportunity to trace the time evolution of $\sim$10$^4$ years. With the single-dish total-power array, we detected ortho-H$_2$D$^+$ emission in all three cores, revealing its presence over scales of $\sim$10,000 au. In the interferometric 7 m array data with a beam size of 3.$''$5 ($\sim$500\,au), emission was detected only toward the central continuum source of MC 35-mm, with a significance of $\sim$3$\sigma$. No significant detections were found in the other targets, placing an upper limit on the H$_2$D$^{+}$ abundance of $\sim$10$^{-11}$ in the dense components traced by the interferometric continuum emission. These results suggest that ortho-H$_2$D$^+$ predominantly exhibits an extended distribution over several thousand au in the early stages of star formation. Detection in compact, dense central structures may only be achieved within a few $\times$ 10$^{4}$ years immediately before or after protostar formation.

astro-ph.GA↗