arXiv subjects

Kenji Nakajima

Publications and source records attributed to Kenji Nakajima.

23 records · Page 2Linked to original sources

arXiv2016

Rotor-phonon coupling in perovskite CH3NH3PbI3: the origin of exceptional transport properties

Atomic dynamics takes a fundamental part in numbers of physical properties of solids like high-Tc superconductivity, semiconducting transports, and thermoelectricity. Perovskite CH3NH3PbI3 exhibits outstanding photovoltaic performances, but the exact physical scenario has not been established yet, due to the inadequate understanding of the atomic dynamics and exceptional transport properties. We present a complete atomic dynamic picture consisting of phonons, rotational modes of protons and molecular vibrational modes, which is constructed by carrying out high-resolution time-of-flight inelastic neutron scattering measurements in a wide energy window ranging from 0.0036 to 54 meV on a large single crystal sample. A three-fold rotational mode of protons activated around 80 K reduces the lifetimes of acoustic and optical phonons down to about 4.5 ps and below 1 ps at 150 K, respectively. The orthorhombic to tetragonal phase transition takes place with a slower four-fold rotational mode of the C-N axis concomitantly setting in at ~ 165 K, above which the optical phonons are too broadened to be distinguished whereas the acoustic ones are still robust. The significantly reduced lifetimes of optical phonons are linked to the smaller mobility of charge carriers while the ultralow lattice thermal conductivity is attributed to nanoscale mean free paths of acoustic phonons. These microscopic insights provide a solid standing point, on which perovskite solar cells can be understood more accurately and their performances are perhaps further optimized. The revealed rotor-phonon coupling opens up an emergent opportunity to create unprecedented functionalities of materials.

cond-mat.mtrl-sci↗

arXiv2016

Spontaneous decays of magneto-elastic excitations in noncollinear antiferromagnet (Y,Lu)MnO3

When magnons and phonons, the fundamental quasiparticles of the solid, are coupled to one another, they form a new hybrid quasi-particle, leading to novel phenomena and interesting applications. Despite its wide-ranging importance, however, detailed experimental studies on the underlying Hamiltonian is rare for actual materials. Moreover, the anharmonicity of such magnetoelastic excitations remains largely unexplored although it is essential for a proper understanding of their diverse thermodynamic behaviour as well as intrinsic zero-temperature decay. Here we show that in noncollinear antiferromagnets, a strong magnon-phonon coupling can significantly enhance the anharmonicity, resulting in the creation of magnetoelastic excitations and their spontaneous decay. By measuring the spin waves over the full Brillouin zone and carrying out anharmonic spin wave calculations using a Hamiltonian with an explicit magnon-phonon coupling, we have identified a hybrid magnetoelastic mode in (Y,Lu)MnO3 and quantified its decay rate and the exchange-striction coupling term required to produce it. Our work has wide implications for understanding of the spin-phonon coupling and the resulting excitations of the broad classes of noncollinear magnets.

cond-mat.mtrl-sci↗

arXiv2015

Spinon, soliton and breather in the spin-1/2 antiferromagnetic chain KCuGaF$_6$

Elementary excitations of the S=1/2 one-dimensional antiferromagnet KCuGaF_6 were investigated by inelastic neutron scattering in zero and finite magnetic fields perpendicular to the (1, 1, 0) plane combined with specific heat measurements. KCuGaF$_6$ exhibits no long-range magnetic ordering down to 50 mK despite the large exchange interaction J/k_B=103 K. At zero magnetic field, well-defined spinon excitations were observed. The energy of the des Cloizeaux and Pearson mode of the spinon excitations is somewhat larger than that calculated with the above exchange constant. This discrepancy is mostly ascribed to the effective XY anisotropy arising from the large Dzyaloshinsky-Moriya interaction with an alternating D vector. KCuGaF_6 in a magnetic field is represented by the quantum sine-Gordon model, for which low-energy elementary excitations are composed of solitons, antisolitons and their bound states called breathers. Unlike the theoretical prediction, it was found that the energy of a soliton is smaller than that of the first breather, although the energy of the first breather coincides with that observed in a previous ESR measurement.

cond-mat.str-el↗

arXiv2015

Magnetic excitations of the spin-1/2 tetramer substance Cu$_2$$^{114}$Cd$^{11}$B$_2$O$_6$ obtained by inelastic neutron scattering experiments

We performed inelastic neutron scattering experiments on Cu$_2$$^{114}$Cd$^{11}$B$_2$O$_6$ powder. The magnetic excitations at low temperatures are similar to those of the interacting spin-1/2 tetramers in the ordered state. The weak excitations existing above 3 meV suggest that the Higgs mode appears in Cu$_2$CdB$_2$O$_6$ at ambient pressure and zero magnetic field. We evaluated $J_1 = 27.3 \pm 1.0$ and $J_2 = -14.0 \pm 1.4$ meV for the intra-tetramer interactions and $J_3 = -0.4 \pm 0.2$ and $J_4 = 1.4 \pm 0.2$ meV for the inter-tetramer interactions. The spin gap in the isolated spin tetramer was calculated to be 1.6 meV, which is less than the effective inter-tetramer interaction value ($3.6 \pm 0.8$ meV). Therefore, antiferromagnetic long-range order is possible, although the ground state of the isolated spin tetramer is the spin-singlet state. We discuss the temperature dependence of the magnetic excitations.

cond-mat.str-el↗

arXiv2004

Study of Field-Induced Magnetic Order in Singlet-Ground-State Magnet CsFeCl$_3$

The field-induced magnetic order in the singlet-ground-state system CsFeCl$_3$ has been studied by measuring magnetization and neutron diffraction. The field dependence of intensity for the neutron magnetic reflection has clearly demonstrated that the field-induced ordered phase is described by the order parameter $ $. A condensate growth of magnons is investigated through the temperature dependence of $M_z$ and $M_{\perp}$, and this ordering is discussed in the context of a magnon Bose-Einstein condensation. Development of the coherent state and the static correlation length has been observed in the incommensurate phase in the field region of $5 < H < 6$ T at 1.8 K. At $H > H_{\rm c}$, a satellite peak was found in coexistence with the commensurate peak at the phase boundary around 10 T, which indicates that the tilt of the c-axis would be less than $\sim 0.5^{\circ}$ in the whole experiments.

cond-mat.mtrl-sci↗