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Kenneth J. Domanik

Publications and source records attributed to Kenneth J. Domanik.

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OSIRIS-REx Returned a Pristine Sample of Asteroid Bennu: Takeaways from the Mission's Contamination Control and Knowledge Program

NASA's OSIRIS-REx mission had the objective of delivering a pristine sample from asteroid (101955) Bennu to Earth for scientific analysis--where "pristine" signifies the absence of foreign materials that could affect sample measurements. OSIRIS-REx returned 121.6 g of regolith in September 2023; this study documents the systematic investigation of suspected contaminants encountered during the mission's sample analysis phase. Most suspected contaminants did not originate from the spacecraft or sample curation. Some were introduced during laboratory analyses, reinforcing the importance of procedural blanks and a strategic approach to sharing samples across laboratories with different analytical targets. Several suspected contaminants, such as phosphate and sodium fluoride particles, were ultimately identified as indigenous to Bennu, highlighting the critical role of contamination knowledge in preventing the dismissal of valuable scientific data. We find that the returned sample meets the definition of pristine, except for an isolated 1.24% (by mass) that escaped the sample container and was thereby contaminated with spacecraft particulates. These findings demonstrate the effectiveness of systematically applied contamination science and engineering practices and provide lessons and approaches to help maximize the scientific integrity of future planetary sample return missions.

astro-ph.EP

Ecosystem-bedrock interaction changes nutrient compartmentalization during early oxidative weathering

Ecosystem-bedrock interactions power the biogeochemical cycles of Earth's shallow crust, supporting life, stimulating substrate transformation, and spurring evolutionary innovation. While oxidative processes have dominated half of terrestrial history, the relative contribution of the biosphere and its chemical fingerprints on Earth's developing regolith are still poorly constrained. Here, we report results from a two-year incipient weathering experiment. We found that the mass release and compartmentalization of major elements during weathering of granite, rhyolite, schist and basalt was rock-specific and regulated by ecosystem components. A tight interplay between physiological needs of different biota, mineral dissolution rates, and substrate nutrient availability resulted in intricate elemental distribution patterns. Biota accelerated CO2 mineralization over abiotic controls as ecosystem complexity increased, and significantly modified stoichiometry of mobilized elements. Microbial and fungal components inhibited element leaching (23.4% and 7%), while plants increased leaching and biomass retention by 63.4%. All biota left comparable biosignatures in the dissolved weathering products. Nevertheless, the magnitude and allocation of weathered fractions under abiotic and biotic treatments provide quantitative evidence for the role of major biosphere components in the evolution of upper continental crust, presenting critical information for large-scale biogeochemical models and for the search for stable in situ biosignatures beyond Earth.

astro-ph.EP