arXiv subjects

Kevin B. Stevenson

Publications and source records attributed to Kevin B. Stevenson.

At least 109 records · Page 6Linked to original sources

arXiv2021

Retrieving Exoplanet Atmospheres using Planetary Infrared Excess: Prospects for the Nightside of WASP-43 b and other Hot Jupiters

To increase the sample size of future atmospheric characterization efforts, we build on the planetary infrared excess (PIE) technique that has been proposed as a means to detect and characterize the thermal spectra of transiting and non-transiting exoplanets using sufficiently broad wavelength coverage to uniquely constrain the stellar and planetary spectral components from spatially unresolved observations. We performed simultaneous retrievals of stellar and planetary spectra for the archetypal planet WASP-43b in its original configuration and a non-transiting configuration to determine the efficacy of the PIE technique for characterizing the planet's nightside atmospheric thermal structure and composition using typical out-of-transit JWST observations. We found that using PIE with JWST should enable the stellar and planetary spectra to be disentangled with no degeneracies seen between the two flux sources, thus allowing robust constraints on the planet's nightside thermal structure and water abundance to be retrieved. The broad wavelength coverage achieved by combining spectra from NIRISS, NIRSpec, and MIRI enables PIE retrievals that are within 10% of the precision attained using traditional secondary eclipse measurements, although mid-IR observations with MIRI alone may face up to 3.5 times lower precision on the planet's irradiation temperature. For non-transiting planets with unconstrained radius priors, we were able to identify and break the degeneracy between planet radius and irradiation temperature using data that resolved the peak of both the stellar and planetary spectra, thus potentially increasing the number of planets amenable to atmospheric characterization with JWST and other future mission concepts.

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arXiv2021

On the Utility of Transmission Color Analysis I: Differentiating Super-Earths and Sub-Neptunes

The majority of exoplanets found to date have been discovered via the transit method, and transmission spectroscopy represents the primary method of studying these distant worlds. Currently, in-depth atmospheric characterization of transiting exoplanets entails the use of spectrographs on large telescopes, requiring significant observing time to study each planet. Previous studies have demonstrated trends for solar system worlds using color-color photometry of reflectance spectra, as well as trends within transmission spectra for hot Jupiters. Building on these concepts, we have investigated the use of transmission color photometric analysis for efficient, coarse categorization of exoplanets and for assessing the nature of these worlds, with a focus on resolving the bulk composition degeneracy to aid in discriminating super-Earths and sub-Neptunes. We present our methodology and first results, including spectrum models, model comparison frameworks, and wave band selection criteria. We present our results for different transmission "color" metrics, filter selection methods, and numbers of filters. Assuming noise-free spectra of isothermal atmospheres in chemical equilibrium, with our pipeline, we are able to constrain atmospheric mean molecular weight in order to distinguish between super-Earth and sub-Neptune atmospheres with >90$\%$ overall accuracy using as few as two specific low-resolution filter combinations. We also found that increasing the number of filters does not substantially impact this performance. This method could allow for broad characterization of large numbers of planets much more efficiently than current methods permit, enabling population and system-level studies. Additionally, data collected via this method could inform follow-up observing time by large telescopes for more detailed studies of worlds of interest.

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arXiv2021

Spitzer phase curve observations and circulation models of the inflated ultra-hot Jupiter WASP-76b

The large radii of many hot Jupiters can only be matched by models that have hot interior adiabats, and recent theoretical work has shown that the interior evolution of hot Jupiters has a significant impact on their atmospheric structure. Due to its inflated radius, low gravity, and ultra-hot equilibrium temperature, WASP-76b is an ideal case study for the impact of internal evolution on observable properties. Hot interiors should most strongly affect the non-irradiated side of the planet, and thus full phase curve observations are critical to ascertain the effect of the interior on the atmospheres of hot Jupiters. In this work, we present the first Spitzer phase curve observations of WASP-76b. We find that WASP-76b has an ultra-hot day side and relatively cold nightside with brightness temperatures of $2471 \pm 27~\mathrm{K}$/$1518 \pm 61~\mathrm{K}$ at $3.6~\micron$ and $2699 \pm 32~\mathrm{K}$/$1259 \pm 44~\mathrm{K}$ at $4.5~\micron$, respectively. These results provide evidence for a dayside thermal inversion. Both channels exhibit small phase offsets of $0.68 \pm 0.48^{\circ}$ at $3.6~\micron$ and $0.67 \pm 0.2^{\circ}$ at $4.5~μ\mathrm{m}$. We compare our observations to a suite of general circulation models that consider two end-members of interior temperature along with a broad range of frictional drag strengths. Strong frictional drag is necessary to match the small phase offsets and cold nightside temperatures observed. From our suite of cloud-free GCMs, we find that only cases with a cold interior can reproduce the cold nightsides and large phase curve amplitude at $4.5~\micron$, hinting that the hot interior adiabat of WASP-76b does not significantly impact its atmospheric dynamics or that clouds blanket its nightside.

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arXiv2021

Variable Irradiation on 1D Cloudless Eccentric Exoplanet Atmospheres

Exoplanets on eccentric orbits experience an incident stellar flux that can be markedly larger at periastron versus apoastron. This variation in instellation can lead to dramatic changes in atmospheric structure in regions of the atmosphere where the radiative and advective heating/cooling timescales are shorter than the orbital timescale. To explore this phenomenon, we develop a sophisticated one-dimensional (vertical) time-stepping atmospheric structure code, EGP+, capable of simulating the dynamic response of atmospheric thermal and chemical structure to time-dependent perturbations. Critically, EGP+ can efficiently simulate multiple orbits of a planet, thereby providing new opportunities for exoplanet modeling without the need for more computationally-expensive models. We make the simplifying assumption of cloud-free atmospheres, and apply our model to HAT-P-2b, HD~17156b, and HD~80606b, which are known to be on higher-eccentricity orbits. We find that for those planets which have Spitzer observations, our planet-to-star ratio predictions are roughly consistent with observations. However, we are unable to reproduce the observed peak offsets from periastron passage. Finally, we discuss promising pathways forward for adding new model complexity that would enable more detailed studies of clear and cloudy eccentric planets as well as worlds orbiting active host stars.

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arXiv2021

The Dark World: A Tale of WASP-43b in Reflected Light with HST WFC3/UVIS

Optical, reflected light eclipse observations provide a direct probe of the exoplanet scattering properties, such as from aerosols. We present here the photometric, reflected light observations of WASP-43b using the HST WFC3/UVIS instrument with the F350LP filter (346-822nm) encompassing the entire optical band. This is the first reflected light, photometric eclipse using UVIS in scanning mode; as such we further detail our scanning extraction and analysis pipeline Arctor. Our HST WFC3/UVIS eclipse light curve for WASP-43 b derived a 3-σ upper limit of 67 ppm on the eclipse depth, which implies that WASP-43b has a very dark dayside atmosphere. With our atmospheric modeling campaign, we compared our reflected light constraints with predictions from global circulation and cloud models, benchmarked with HST and Spitzer observations of WASP-43b. We infer that we do not detect clouds on the dayside within the pressure levels probed by HST WFC3/UVIS with the F350LP filter (P > 1 bar). This is consistent with the GCM predictions based on previous WASP-43b observations. Dayside emission spectroscopy results from WASP-43b with HST and Spitzer observations are likely to not be significantly affected by contributions from cloud particles.

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arXiv2021

A Comprehensive Reanalysis of $\textit{Spitzer}$'s 4.5 $μ$m Phase Curves, and the Phase Variations of the Ultra-hot Jupiters MASCARA-1b and KELT-16b

We have developed an open-source pipeline for the analysis of \textit{Spitzer}/IRAC channel 1 and 2 time-series photometry, incorporating some of the most popular decorrelation methods. We applied this pipeline to new phase curve observations of ultra-hot Jupiters MASCARA-1b and KELT-16b, and we performed the first comprehensive reanalysis of 15 phase curves. We find that MASCARA-1b and KELT-16b have phase offsets of $6^{+11}_{-11}~^{\circ}$W and $38^{+16}_{-15}~^{\circ}$W, dayside temperatures of $2952^{+100}_{-97}$ K and $3070^{+160}_{-150}$ K, and nightside temperatures of $1300^{+340}_{-340}$ K and $1900^{+430}_{-440}$ K, respectively. We confirm a strong correlation between dayside and irradiation temperatures with a shallower dependency for nightside temperature. We also find evidence that the normalized phase curve amplitude (peak-to-trough divided by eclipse depth) is correlated with stellar effective temperature. In addition, while our different models often retrieve similar parameters, significant differences occasionally arise between them, as well as between our preferred model and the literature values. Nevertheless, our preferred models are consistent with published phase offsets to within $-8\pm21$ degrees ($-1.6\pm3.2$ sigma), and normalized phase curve amplitudes are on average reproduced to within $-0.01\pm0.24$ ($-0.1\pm1.6$ sigma). Finally, we find that BLISS performs best in most cases, but not all; we therefore recommend future analyses consider numerous detector models to ensure an optimal fit and to assess model dependencies.

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arXiv2020

Clouds in Three-Dimensional Models of Hot Jupiters Over a Wide Range of Temperatures I: Thermal Structures and Broadband Phase Curve Predictions

Using a general circulation model (GCM), we investigate trends in simulated hot Jupiter atmospheres for a range of irradiation temperatures (1,500 - 4,000 K), surface gravities (10 and 40 m s-2), and cloud conditions. Our models include simplified temperature-dependent clouds with radiative feedback and show how different cloud compositions, vertical thicknesses, and opacities shape hot Jupiters atmospheres by potentially increasing planetary albedos, decreasing photospheric pressures and nightside temperatures, and in some cases producing strong dayside thermal inversions. With decreasing irradiation, clouds progressively form on the nightside and cooler western limb followed by the eastern limb and central dayside. We find that clouds significantly modify the radiative transport and affect the observable properties of planets colder than T_irr ~ 3,000~K (T_eq~2,100 K) depending on the clouds' vertical extent. The precise strength of expected effects depends on the assumed parameters, but trends in predicted phase curves emerge from an ensemble of simulations. Clouds lead to larger phase curve amplitudes and smaller phase curve offsets at IR wavelengths, compared to cloud-free models. At optical wavelengths, we predict mostly westward phase curve offsets at intermediate temperatures (T_irr ~ 2,000 - 3,500 K) with clouds confined to the nightside and western limb. If clouds are vertically compact (i.e. on order of a pressure scale height in thickness), their distributions and effects become more complicated as different condensates form at different heights -- some too deep to significantly affect the observable atmosphere. Our results have implications for interpreting the diversity of phase curve observations of planets with T_irr <~3,000~K.

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arXiv2020

Keys of a Mission to Uranus or Neptune, the Closest Ice Giants

Uranus and Neptune are the archetypes of "ice giants", a class of planets that may be among the most common in the Galaxy. They hold the keys to understand the atmospheric dynamics and structure of planets with hydrogen atmospheres inside and outside the solar system; however, they are also the last unexplored planets of the Solar System. Their atmospheres are active and storms are believed to be fueled by methane condensation which is both extremely abundant and occurs at low optical depth. This means that mapping temperature and methane abundance as a function of position and depth will inform us on how convection organizes in an atmosphere with no surface and condensates that are heavier than the surrounding air, a general feature of giant planets. Owing to the spatial and temporal variability of these atmospheres, an orbiter is required. A probe would provide a reference atmospheric profile to lift ambiguities inherent to remote observations. It would also measure the abundances of noble gases which can be used to reconstruct the history of planet formation in the Solar System. Finally, mapping the planets' gravity and magnetic fields will be essential to constrain their global composition, atmospheric dynamics, structure and evolution. An exploration of Uranus or Neptune will be essential to understand these planets and will also be key to constrain and analyze data obtained at Jupiter, Saturn, and for numerous exoplanets with hydrogen atmospheres.

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arXiv2020

An Unusual Transmission Spectrum for the Sub-Saturn KELT-11b Suggestive of a Sub-Solar Water Abundance

We present an optical-to-infrared transmission spectrum of the inflated sub-Saturn KELT-11b measured with the Transiting Exoplanet Survey Satellite (TESS), the Hubble Space Telescope (HST) Wide Field Camera 3 G141 spectroscopic grism, and the Spitzer Space Telescope (Spitzer) at 3.6 $μ$m, in addition to a Spitzer 4.5 $μ$m secondary eclipse. The precise HST transmission spectrum notably reveals a low-amplitude water feature with an unusual shape. Based on free retrieval analyses with varying molecular abundances, we find strong evidence for water absorption. Depending on model assumptions, we also find tentative evidence for other absorbers (HCN, TiO, and AlO). The retrieved water abundance is generally $\lesssim 0.1\times$ solar (0.001--0.7$\times$ solar over a range of model assumptions), several orders of magnitude lower than expected from planet formation models based on the solar system metallicity trend. We also consider chemical equilibrium and self-consistent 1D radiative-convective equilibrium model fits and find they too prefer low metallicities ($[M/H] \lesssim -2$, consistent with the free retrieval results). However, all the retrievals should be interpreted with some caution since they either require additional absorbers that are far out of chemical equilibrium to explain the shape of the spectrum or are simply poor fits to the data. Finally, we find the Spitzer secondary eclipse is indicative of full heat redistribution from KELT-11b's dayside to nightside, assuming a clear dayside. These potentially unusual results for KELT-11b's composition are suggestive of new challenges on the horizon for atmosphere and formation models in the face of increasingly precise measurements of exoplanet spectra.

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arXiv2020

Into the UV: The Atmosphere of the Hot Jupiter HAT-P-41b Revealed

For solar-system objects, ultraviolet spectroscopy has been critical in identifying sources for stratospheric heating and measuring the abundances of a variety of hydrocarbon and sulfur-bearing species, produced via photochemical mechanisms, as well as oxygen and ozone. To date, less than 20 exoplanets have been probed in this critical wavelength range (0.2-0.4 um). Here we use data from Hubble's newly implemented WFC3 UVIS G280 grism to probe the atmosphere of the hot Jupiter HAT-P-41b in the ultraviolet through optical in combination with observations at infrared wavelengths. We analyze and interpret HAT-P-41b's 0.2-5.0 um transmission spectrum using a broad range of methodologies including multiple treatments of data systematics as well as comparisons with atmospheric forward, cloud microphysical, and multiple atmospheric retrieval models. Although some analysis and interpretation methods favor the presence of clouds or potentially a combination of Na, VO, AlO, and CrH to explain the ultraviolet through optical portions of HAT-P-41b's transmission spectrum, we find that the presence of a significant H- opacity provides the most robust explanation. We obtain a constraint for the abundance of H-, log(H-) = -8.65 +/- 0.62 in HAT-P-41b's atmosphere, which is several orders of magnitude larger than predictions from equilibrium chemistry for a 1700 - 1950 K hot Jupiter. We show that a combination of photochemical and collisional processes on hot hydrogen-dominated exoplanets can readily supply the necessary amount of H- and suggest that such processes are at work in HAT-P-41b and many other hot Jupiter atmospheres.

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arXiv2020

Eigenspectra: A Framework for Identifying Spectra from 3D Eclipse Mapping

Planetary atmospheres are inherently 3D objects that can have strong gradients in latitude, longitude, and altitude. Secondary eclipse mapping is a powerful way to map the 3D distribution of the atmosphere, but the data can have large correlations and errors in the presence of photon and instrument noise. We develop a technique to mitigate the large uncertainties of eclipse maps by identifying a small number of dominant spectra to make them more tractable for individual analysis via atmospheric retrieval. We use the eigencurves method to infer a multi-wavelength map of a planet from spectroscopic secondary eclipse light curves. We then apply a clustering algorithm to the planet map to identify several regions with similar emergent spectra. We combine the similar spectra together to construct an "eigenspectrum" for each distinct region on the planetary map. We demonstrate how this approach could be used to isolate hot from cold regions and/or regions with different chemical compositions in observations of hot Jupiters with the James Webb Space Telescope (JWST). We find that our method struggles to identify sharp edges in maps with sudden discontinuities, but generally can be used as a first step before a more physically motivated modeling approach to determine the primary features observed on the planet.

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arXiv2020

A New Method For Studying Exoplanet Atmospheres Using Planetary Infrared Excess

To date, the ability for observers to reveal the composition or thermal structure of an exoplanet's atmosphere has rested on two techniques: high-contrast direct imaging and time-series observations of transiting exoplanets. The former is currently limited to characterizing young, massive objects while the latter requires near 90 degree orbital inclinations, thus limiting atmospheric studies to a small fraction of the total exoplanet population. Here we present an observational and analysis technique for studying the atmospheres of non-transiting exoplanets that relies on acquiring simultaneous, broad-wavelength spectra and resolving planetary infrared emission from the stellar spectrum. This method could provide an efficient means to study exoplanet atmospheric dynamics using sparsely-sampled phase curve observations or a mechanism to search for signs of life on non-transiting exoplanets orbiting the nearest M-dwarf stars (such as Proxima Centauri). If shown to be effective with James Webb Space Telescope (JWST) observations, the method of measuring planetary infrared excess (PIE) would open up the large population of nearby, non-transiting exoplanets for atmospheric characterization.

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arXiv2020

Introducing a New Spitzer Master BLISS Map to Remove the Instrument-Systematic -- Phase-Curve-Parameter Degeneracy, as Demonstrated by a Reanalysis of the 4.5$μm$ WASP-43b Phase Curve

While Spitzer IRAC systematics are generally well understood, each data set can provide its own challenges that continue to teach us about the underlying functional form of these systematics. Multiple groups have analyzed the phase curves of WASP-43b with varying detrending techniques, each obtaining different results. In this work, we take another look at WASP-43b while exploring the degenerate relation between Bilinearly-Interpolated Subpixel Sensitivity (BLISS) mapping, point response function full width at half-maximum (PRF-FWHM) detrending, and phase curve parameters. We find that there is a strong correlation between the detrending parameters in the two models, and best fit phase curve amplitudes vary strongly when the data are temporally binned. To remove this degeneracy, we present a new Gaussian centroided intrapixel sensitivity map (hereafter fixed sensitivity map), generated using 3,712,830 exposures spanning 5 years, for a variety of aperture sizes at 4.5$μm$. We find evidence for time variability in the sensitivity at 3.6$μm$ and do not generate a visit-independent map for this channel. With the fixed 4.5 $μm$ intrapixel sensitivity map, the best fits for WASP-43b no longer vary strongly with bin size and PRF-FWHM detrending is no longer required to remove correlated noise. For data sets that do not fall completely within the sweet spot, temporal binning should not be used in the analysis of Spitzer phase curves. We confirm night side emission for WASP-43b with a disk integrated nightside temperature of 806 $\pm$ 48 K at 4.5$μm$. The 4.5$μm$ maps are available at \url{github.com/kevin218/POET}

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arXiv2020

Aerosol Composition of Hot Giant Exoplanets Dominated by Silicates and Hydrocarbon Hazes

Aerosols are common in the atmospheres of exoplanets across a wide swath of temperatures, masses, and ages. These aerosols strongly impact observations of transmitted, reflected, and emitted light from exoplanets, obfuscating our understanding of exoplanet thermal structure and composition. Knowing the dominant aerosol composition would facilitate interpretations of exoplanet observations and theoretical understanding of their atmospheres. A variety of compositions have been proposed, including metal oxides and sulphides, iron, chromium, sulphur, and hydrocarbons. However, the relative contributions of these species to exoplanet aerosol opacity is unknown. Here we show that the aerosol composition of giant exoplanets observed in transmission is dominated by silicates and hydrocarbons. By constraining an aerosol microphysics model with trends in giant exoplanet transmission spectra, we find that silicates dominate aerosol opacity above planetary equilibrium temperatures of 950 K due to low nucleation energy barriers and high elemental abundances, while hydrocarbon aerosols dominate below 950 K due to an increase in methane abundance. Our results are robust to variations in planet gravity and atmospheric metallicity within the range of most giant transiting exoplanets. We predict that spectral signatures of condensed silicates in the mid-infrared are most prominent for hot (>1600 K), low-gravity (<10 m s$^{-2}$) objects.

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arXiv2020

Smaller than expected bright-spot offsets in Spitzer phase curves of the hot Jupiter Qatar-1b

We present \textit{Spitzer} full-orbit thermal phase curves of the hot Jupiter Qatar-1b, a planet with the same equilibrium temperature---and intermediate surface gravity and orbital period---as the well-studied planets HD 209458b and WASP-43b. We measure secondary eclipse of $0.21 \pm 0.02 \%$ at $3.6~μ$m and $0.30 \pm 0.02 \%$ at $4.5~μ$m, corresponding to dayside brightness temperatures of $1542^{+32}_{-31}$~K and $1557^{+35}_{-36}$~K, respectively, consistent with a vertically isothermal dayside. The respective nightside brightness temperatures are $1117^{+76}_{-71}$~K and $1167^{+69}_{-74}$~K, in line with a trend that hot Jupiters all have similar nightside temperatures. We infer a Bond albedo of $0.12_{-0.16}^{+0.14}$ and a moderate day-night heat recirculation efficiency, similar to HD 209458b. General circulation models for HD 209458b and WASP-43b predict that their bright-spots should be shifted east of the substellar point by tens of degrees, and these predictions were previously confirmed with \textit{Spitzer} full-orbit phase curve observations. The phase curves of Qatar-1b are likewise expected to exhibit eastward offsets. Instead, the observed phase curves are consistent with no offset: $11^{\circ}\pm 7^{\circ}$ at $3.6~μ$m and $-4^{\circ}\pm 7^{\circ}$ at $4.5~μ$m. The discrepancy in circulation patterns between these three otherwise similar planets points to the importance of secondary parameters like rotation rate and surface gravity, and the presence or absence of clouds, in determining atmospheric conditions on hot Jupiters.

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arXiv2020

Statistical Characterization of Hot Jupiter Atmospheres using Spitzer's Secondary Eclipses

We report 78 secondary eclipse depths for a sample of 36 transiting hot Jupiters observed at 3.6- and 4.5 microns using the Spitzer Space Telescope. Our eclipse results for 27 of these planets are new, and include highly irradiated worlds such as KELT-7b, WASP-87b, WASP-76b, and WASP-64b, and important targets for JWST such as WASP-62b. We find that WASP-62b has a slightly eccentric orbit e cos(omega) = 0.00614+/- 0.00064, and we confirm the eccentricity of HAT-P-13b and WASP-14b. The remainder are individually consistent with circular orbits, but we find statistical evidence for eccentricity increasing with orbital period in our range from 1 to 5 days. Our day-side brightness temperatures for the planets yield information on albedo and heat redistribution, following Cowan and Agol (2011). Planets having maximum day side temperatures exceeding ~ 2200K are consistent with zero albedo and distribution of stellar irradiance uniformly over the day-side hemisphere. Our most intriguing result is that we detect a systematic difference between the emergent spectra of these hot Jupiters as compared to blackbodies. The ratio of observed brightness temperatures, Tb(4.5)/Tb(3.6), increases with equilibrium temperature by 100 +/- 24 parts-per-million per Kelvin, over the entire temperature range in our sample (800K to 2500K). No existing model predicts this trend over such a large range of temperature. We suggest that this may be due to a structural difference in the atmospheric temperature profile between the real planetary atmospheres as compared to models.

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arXiv2020

Global Chemistry and Thermal Structure Models for the Hot Jupiter WASP-43b and Predictions for JWST

The James Webb Space Telescope (JWST) is expected to revolutionize the field of exoplanets. The broad wavelength coverage and the high sensitivity of its instruments will allow characterization of exoplanetary atmospheres with unprecedented precision. Following the Call for the Cycle 1 Early Release Science Program, the Transiting Exoplanet Community was awarded time to observe several targets, including WASP-43b. The atmosphere of this hot Jupiter has been intensively observed but still harbors some mysteries, especially concerning the day-night temperature gradient, the efficiency of the atmospheric circulation, and the presence of nightside clouds. We will constrain these properties by observing a full orbit of the planet and extracting its spectroscopic phase curve in the 5--12 $μ$m range with JWST/MIRI. To prepare for these observations, we performed an extensive modeling work with various codes: radiative transfer, chemical kinetics, cloud microphysics, global circulation models, JWST simulators, and spectral retrieval. Our JWST simulations show that we should achieve a precision of 210 ppm per 0.1 $μ$m spectral bin on average, which will allow us to measure the variations of the spectrum in longitude and measure the night-side emission spectrum for the first time. If the atmosphere of WASP-43b is clear, our observations will permit us to determine if its atmosphere has an equilibrium or disequilibrium chemical composition, providing eventually the first conclusive evidence of chemical quenching in a hot Jupiter atmosphere. If the atmosphere is cloudy, a careful retrieval analysis will allow us to identify the cloud composition.

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arXiv2020

Evidence for H$_{2}$ Dissociation and Recombination Heat Transport in the Atmosphere of KELT-9b

Phase curve observations provide an opportunity to study the full energy budgets of exoplanets by quantifying the amount of heat redistributed from their daysides to their nightsides. Theories explaining the properties of phase curves for hot Jupiters have focused on the balance between radiation and dynamics as the primary parameter controlling heat redistribution. However, recent phase curves have shown deviations from the trends that emerge from this theory, which has led to work on additional processes that may affect hot Jupiter energy budgets. One such process, molecular hydrogen dissociation and recombination, can enhance energy redistribution on ultra-hot Jupiters with temperatures above $\sim2000$ K. In order to study the impact of H$_{2}$ dissociation on ultra-hot Jupiters, we present a phase curve of KELT-9b observed with the Spitzer Space Telescope at 4.5 $μ$m. KELT-9b is the hottest known transiting planet, with a 4.5-$μ$m dayside brightness temperature of $4566^{+140}_{-136}$ K and a nightside temperature of $2556^{+101}_{-97}$ K. We observe a phase curve amplitude of $0.609 \pm 0.020$ and a hot spot offset of $18.7^{+2.1}_{-2.3}$ degrees. The observed amplitude is too small to be explained by a simple balance between radiation and advection. General circulation models (GCMs) and an energy balance model that include the effects of H$_{2}$ dissociation and recombination provide a better match to the data. The GCMs, however, predict a maximum hot spot offset of $5$ degrees, which disagrees with our observations at $>5σ$ confidence. This discrepancy may be due to magnetic effects in the planet's highly ionized atmosphere.

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