arXiv subjects

Klaus Kroy

Publications and source records attributed to Klaus Kroy.

At least 37 records · Page 2Linked to original sources

arXiv2021

Equilibrium Stochastic Delay Processes

Stochastic processes with temporal delay play an important role in science and engineering whenever finite speeds of signal transmission and processing occur. However, an exact mathematical analysis of their dynamics and thermodynamics is available for linear models only. We introduce a class of stochastic delay processes with nonlinear time-local forces and linear time-delayed forces that obey fluctuation theorems and converge to a Boltzmann equilibrium at long times. From the point of view of control theory, such ``equilibrium stochastic delay processes'' are stable and energetically passive, by construction. Computationally, they provide diverse exact constraints on general nonlinear stochastic delay problems and can, in various situations, serve as a starting point for their perturbative analysis. Physically, they admit an interpretation in terms of an underdamped Brownian particle that is either subjected to a time-local force in a non-Markovian thermal bath or to a delayed feedback force in a Markovian thermal bath. We illustrate these properties numerically for a setup familiar from feedback cooling and point out experimental implications.

cond-mat.stat-mech↗

arXiv2021

Finite-size scaling at the edge of disorder in a time-delay Vicsek model

Living many-body systems often exhibit scale-free collective behavior reminiscent of thermal critical phenomena. But their mutual interactions are inevitably retarded due to information processing and delayed actuation. We numerically investigate the consequences for the finite-size scaling in the Vicsek model of motile active matter. A growing delay time initially facilitates but ultimately impedes collective ordering and turns the dynamical scaling from diffusive to ballistic. It provides an alternative explanation of swarm traits previously attributed to inertia.

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arXiv2021

Thermotaxis of Janus Particles

The interactions of autonomous microswimmers play an important role for the formation of collective states of motile active matter. We study them in detail for the common microswimmer-design of two-faced Janus spheres with hemispheres made from different materials. Their chemical and physical surface properties may be tailored to fine-tune their mutual attractive, repulsive or aligning behavior. To investigate these effects systematically, we monitor the dynamics of a single gold-capped Janus particle in the external temperature field created by an optically heated metal nanoparticle. We quantify the orientation-dependent repulsion and alignment of the Janus particle and explain it in terms of a simple theoretical model for the induced thermoosmotic surface fluxes. The model reveals that the particle's angular velocity is solely determined by the temperature profile on the equator between the Janus particle's hemispehres and their phoretic mobility contrast. The distortion of the external temperature field by their heterogeneous heat conductivity is moreover shown to break the apparent symmetry of the problem.

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arXiv2021

Coarse Graining Nonisothermal Microswimmer Suspensions

We investigate coarse-grained models of suspended self-thermophoretic microswimmers. Upon heating, the Janus spheres, with hemispheres made of different materials, induce a heterogeneous local solvent temperature that causes the self-phoretic particle propulsion. Starting from atomistic molecular dynamics simulations, we verify the coarse-grained description of the fluid in terms of a local molecular temperature field, and its role for the particle's thermophoretic self-propulsion and hot Brownian motion. The latter is governed by effective nonequilibrium temperatures, which are measured from simulations by confining the particle position and orientation. They are theoretically shown to remain relevant for any further spatial coarse-graining towards a hydrodynamic description of the entire suspension as a homogeneous complex fluid.

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arXiv2021

Polarization-Density Patterns of Active Particles in Motility Gradients

The co-localization of density modulations and particle polarization is a characteristic emergent feature of motile active matter in activity gradients. It can therefore play the role of a smoking gun for the mesoscale detection of intrinsic microscopic activity. We employ the active-Brownian-particle (ABP) model to derive precise analytical expressions for the density and polarization profiles of a single Janus-type swimmer in the vicinity of an abrupt activity step, including situations with an orientation-dependent propulsion speed. Our results agree well with measurement data for a hot microswimmer presented in the companion paper [1] and can serve as a template for more complex applications, e.g., to motility-induced phase separation or studies of physical boundaries. The essential physics behind our formal results is robustly captured and elucidated by a schematic two-species ``run-and-tumble'' model.

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arXiv2021

Active-Particle Polarization Without Alignment Forces

Active-particle suspensions exhibit distinct polarization-density patterns in activity landscapes, even without anisotropic particle interactions. Such polarization without alignment forces is at work in motility-induced phase separation and betrays intrinsic microscopic activity to mesoscale observers. Using stable long-term confinement of a single hot microswimmer in a dedicated force-free particle trap, we examine the polarized interfacial layer at a motility step and confirm that it does not exert pressure onto the bulk. Our observations are quantitatively explained by an analytical theory that can also guide the analysis of more complex geometries and many-body effects.

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arXiv2020

Active Brownian Heat Engines

When do non-equilibrium forms of disordered energy qualify as heat? \textcolor{blue}{We address this question in the context of cyclically operating heat engines in contact with a non-equilibrium energy reservoir that defies the zeroth law of thermodynamics. To consistently address the latter as a heat bath requires the existence of a precise mapping to an equivalent cycle with an equilibrium bath at a time-dependent effective temperature. We identify the most general setup for which this can generically be ascertained and thoroughly discuss an analytically tractable, experimentally relevant scenario}: a Brownian particle confined in a \textcolor{blue}{periodically} modulated harmonic potential and coupled to some non-equilibrium bath of variable activity. We deduce formal limitations for its thermodynamic performance, including maximum efficiency, efficiency at maximum power, and maximum efficiency at fixed power. They can guide the design of new micro-machines and clarify how much these can outperform passive-bath designs, which has been a debated issue for recent experimental realizations. To illustrate the general principles for practical quasi-static and finite-rate protocols, we further analyze a specific realization of such an active heat engine based on the paradigmatic Active Brownian Particle (ABP) model. This reveals some non-intuitive features of the explicitly computed dynamical effective temperature, illustrates various conceptual and practical limitations of the effective-equilibrium mapping, and clarifies the operational relevance of various coarse-grained measures of dissipation.

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arXiv2020

Jarzynski Equality for Soret Equilibria -- Virtues of Virtual Potentials

The Jarzynski equality relates the free energy difference between two equilibrium states to the fluctuating irreversible work afforded to switch between them. The prescribed fixed temperature for the equilibrium states implicitly constrains the dissipative switching process that can take the system far from equilibrium. Here, we demonstrate theoretically and experimentally that such a relation also holds for the nonisothermal case, where the initial stationary state is not in equilibrium and the switching is effected by dynamically changing temperature gradients instead of a conservative force. Our demonstration employs a single colloidal particle trapped by optically induced thermophoretic drift currents. It relies on identifying suitable equivalents of classical work and heat and our ability to measure their distributions and express them in terms of a virtual potential.

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arXiv2019

Brownian Molecules Formed by Delayed Harmonic Interactions

A time-delayed response of individual living organisms to information exchanged within flocks or swarms leads to the emergence of complex collective behaviors. A recent experimental setup by (Khadka et al 2018 Nat. Commun. 9 3864), employing synthetic microswimmers, allows to emulate and study such behavior in a controlled way, in the lab. Motivated by these experiments, we study a system of N Brownian particles interacting via a retarded harmonic interaction. For $N \leq 3$ , we characterize its collective behavior analytically, by solving the pertinent stochastic delay-differential equations, and for $N>3$ by Brownian dynamics simulations. The particles form molecule-like non-equilibrium structures which become unstable with increasing number of particles, delay time, and interaction strength. We evaluate the entropy and information fluxes maintaining these structures and, to quantitatively characterize their stability, develop an approximate time-dependent transition-state theory to characterize transitions between different isomers of the molecules. For completeness, we include a comprehensive discussion of the analytical solution procedure for systems of linear stochastic delay differential equations in finite dimension, and new results for covariance and time-correlation matrices.

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arXiv2019

Brownian Thermometry Beyond Equilibrium

Since Albert Einstein's seminal 1905-paper on Brownian motion, the temperature of fluids and gases of known viscosity can be deduced from observations of the fluctuations of small suspended probe particles. We summarize recent generalizations of this standard technique of Brownian thermometry to situations involving spatially heterogeneous temperature fields and other non-equilibrium conditions in the solvent medium. The notion of effective temperatures is reviewed and its scope critically assessed. Our emphasis is on practically relevant real-world applications, for which effective temperatures have been explicitly computed and experimentally confirmed. We also elucidate the relation to the more general concept of (effective) temperature spectra and their measurement by Brownian thermospectrometry. Finally, we highlight the conceptual importance of non-equilibrium thermometry for active and biological matter, such as microswimmer suspensions or biological cells, which often play the role of non-thermal ('active') heat baths for embedded Brownian degrees of freedom.

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arXiv2019

Physically consistent numerical solver for time-dependent Fokker-Planck equations

We present a simple thermodynamically consistent method for solving time-dependent Fokker--Planck equations (FPE) for over-damped stochastic processes, also known as Smoluchowski equations. It yields both transition and steady-state behavior and allows for computations of moment-generating and large-deviation functions of observables defined along stochastic trajectories, such as the fluctuating particle current, heat and work. The key strategy is to approximate the FPE by a Master equation with transition rates in configuration space that obey a local detailed balance condition for arbitrary discretization. Its time-dependent solution is obtained by a direct computation of the time-ordered exponential, representing the propagator of the FPE, by summing over all possible paths in the discretized space. The method thus not only preserves positivity and normalization of the solutions, but also yields a physically reasonable total entropy production, regardless of the discretization. To demonstrate the validity of the method and to exemplify its potential for applications, we compare it against Brownian-dynamics simulations of a heat engine based on an active Brownian particle trapped in a time-dependent quartic potential.

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arXiv2018

Hot Microswimmers

Hot microswimmers are self-propelled Brownian particles that exploit local heating for their directed self-thermophoretic motion. We provide a pedagogical overview of the key physical mechanisms underlying this promising new technology. It covers the hydrodynamics of swimming, thermophoresis and -osmosis, hot Brownian motion, force-free steering, and dedicated experimental and simulation tools to analyze hot Brownian swimmers.

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arXiv2017

Analytical mesoscale modeling of aeolian sand transport

The mesoscale structure of aeolian sand transport determines a variety of natural phenomena studied in planetary and Earth science. We analyze it theoretically beyond the mean-field level, based on the grain-scale transport kinetics and splash statistics. A coarse-grained analytical model is proposed and verified by numerical simulations resolving individual grain trajectories. The predicted height-resolved sand flux and other important characteristics of the aeolian transport layer agree remarkably well with a comprehensive compilation of field and wind tunnel data, suggesting that the model robustly captures the essential mesoscale physics. By comparing the saturation length with field data for the minimum sand-dune size, we can reconcile conflicting previous models for this most enigmatic emergent aeolian scale and elucidate the importance of intermittent turbulent wind fluctuations for field measurements.

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arXiv2016

Grain-scale Modeling and Splash Parametrization for Aeolian Sand Transport

The collision of a spherical grain with a granular bed is commonly parametrized by the splash function, which provides the velocity of the rebounding grain and the velocity distribution and number of ejected grains. Starting from elementary geometric considerations and physical principles, like momentum conservation and energy dissipation in inelastic pair collisions, we derive a rebound parametrization for the collision of a spherical grain with a granular bed. Combined with a recently proposed energy-splitting model [Ho ${\it et\ al.}$, Phys. Rev. E 85, 052301 (2012)] that predicts how the impact energy is distributed among the bed grains, this yields a coarse-grained but complete characterization of the splash as a function of the impact velocity and the impactor-bed grain-size ratio. The predicted mean values of the rebound angle, total and vertical restitution, ejection speed, and number of ejected grains are in excellent agreement with experimental literature data and with our own discrete-element computer simulations. We extract a set of analytical asymptotic relations for shallow impact geometries, which can readily be used in coarse-grained analytical modeling or computer simulations of geophysical particle-laden flows.

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arXiv2016

Microscopic derivation of the hydrodynamics of active-Brownian-particle suspensions

We derive the hydrodynamic equations of motion for a fluid of active particles described by under- damped Langevin equations that reduce to the Active-Brownian-Particle model, in the overdamped limit. The contraction into the hydrodynamic description is performed by locally averaging the par- ticle dynamics with the non-equilibrium many-particle probability density, whose formal expression is found in the physically relevant limit of high-friction through a multiple-time-scale analysis. This approach permits to identify the conditions under which self-propulsion can be subsumed into the fluid stress tensor and thus to define systematically and unambiguously the local pressure of the active fluid.

cond-mat.stat-mech↗

arXiv2016

Interacting Brownian dynamics in a nonequilibrium particle bath

We set up a mesoscopic theory for interacting Brownian particles embedded in a nonequilibrium environment, starting from the microscopic interacting many-body theory. Using nonequilibrium linear response theory, we characterize the effective dynamical interactions on the mesoscopic scale and the statistics of the nonequilibrium environmental noise, arising upon integrating out the fast degrees of freedom. As hallmarks of nonequilibrium, the breakdown of the fluctuation-dissipation and action-reaction relations for Brownian degrees of freedom are exemplified with two prototypical models for the environment, namely, active Brownian particles and stirred colloids.

cond-mat.stat-mech↗

arXiv2016

Mesoscopic virial equation for nonequilibrium statistical mechanics

We derive a class of mesoscopic virial equations governing energy partition between conjugate position and momentum variables of individual degrees of freedom. They are shown to apply to a wide range of nonequilibrium steady states with stochastic (Langevin) and deterministic (Nosé--Hoover) dynamics, and to extend to collective modes for models of heat-conducting lattices. A generalised macroscopic virial theorem ensues upon summation over all degrees of freedom. This theorem allows for the derivation of nonequilibrium state equations that involve dissipative heat flows on the same footing with state variables, as exemplified for inertial Brownian motion with solid friction and overdamped active Brownian particles subject to inhomogeneous pressure.

cond-mat.stat-mech↗

arXiv2016

Exact symmetries in the velocity fluctuations of a hot Brownian swimmer

Symmetries constrain dynamics. We test this fundamental physical principle, experimentally and by molecular dynamics simulations, for a hot Janus swimmer operating far from thermal equilibrium. Our results establish scalar and vectorial steady-state fluctuation theorems and a thermodynamic uncertainty relation that link the fluctuating particle current to its entropy production at an effective temperature. A Markovian minimal model elucidates the underlying non-equilbrium physics.

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