arXiv subjects

Klaus Weber

Publications and source records attributed to Klaus Weber.

4 recordsLinked to original sources

arXiv2024

Physics-based material parameters extraction from perovskite experiments via Bayesian optimization

The ability to extract material parameters of perovskite from quantitative experimental analysis is essential for rational design of photovoltaic and optoelectronic applications. However, the difficulty of this analysis increases significantly with the complexity of the theoretical model and the number of material parameters for perovskite. Here we use Bayesian optimization to develop an analysis platform that can extract up to 8 fundamental material parameters of an organometallic perovskite semiconductor from a transient photoluminescence experiment, based on a complex full physics model that includes drift-diffusion of carriers and dynamic defect occupation. An example study of thermal degradation reveals that the carrier mobility and trap-assisted recombination coefficient are reduced noticeably, while the defect energy level remains nearly unchanged. The reduced carrier mobility can dominate the overall effect on thermal degradation of perovskite solar cells by reducing the fill factor, despite the opposite effect of the reduced trap-assisted recombination coefficient on increasing the fill factor. In future, this platform can be conveniently applied to other experiments or to combinations of experiments, accelerating materials discovery and optimization of semiconductor materials for photovoltaics and other applications.

cond-mat.mtrl-sci↗

arXiv2023

Fostering User Engagement in the Critical Reflection of Arguments

A natural way to resolve different points of view and form opinions is through exchanging arguments and knowledge. Facing the vast amount of available information on the internet, people tend to focus on information consistent with their beliefs. Especially when the issue is controversial, information is often selected that does not challenge one's beliefs. To support a fair and unbiased opinion-building process, we propose a chatbot system that engages in a deliberative dialogue with a human. In contrast to persuasive systems, the envisioned chatbot aims to provide a diverse and representative overview - embedded in a conversation with the user. To account for a reflective and unbiased exploration of the topic, we enable the system to intervene if the user is too focused on their pre-existing opinion. Therefore we propose a model to estimate the users' reflective engagement (RUE), defined as their critical thinking and open-mindedness. We report on a user study with 58 participants to test our model and the effect of the intervention mechanism, discuss the implications of the results, and present perspectives for future work. The results show a significant effect on both user reflection and total user focus, proving our proposed approach's validity.

cs.HC↗

arXiv2022

Evaluation of histological findings with severity grade, to analyze toxicology in-vivo studies

In-vivo toxicological studies are characterized by multiple primary endpoints with quite different scales. Whereas guidelines and publications provide various statistical tests for normally distributed endpoints (such as organ weights) and proportions (such as tumor rates), few approaches are available for graded histopathological findings, such as 0, +, ++, +++. This represents a basic contradiction of the statistical analysis because these graded findings sometimes show a high predictive value for potential toxic effects. Here we discuss different methods comparatively, especially from the viewpoints of i) designs for very small sample sizes and ii) interpretability by toxicologists. A new approach is recommended where a simultaneous test is performed over all class combinations of score levels, such as (0, +) vs (++, +++). Corresponding R code is provided by way of a data example.

stat.AP↗

arXiv1993

Study of High Energy Heavy-Ion Collisions in a Relativistic BUU-Approach with Momentum-Dependent Mean-Fields

We introduce momentum-dependent scalar and vector fields into the Lorentz covariant relativistic BUU- (RBUU-) approach employing a polynomial ansatz for the relativistic nucleon-nucleon interaction. The momentum-dependent parametrizations are shown to be valid up to about 1 GeV/u for the empirical proton-nucleus optical potential. We perform numerical simulations for heavy-ion collisions within the RBUU-approach adopting momentum-dependent and momentum-independent mean-fields and calculate the transverse flow in and perpendicular to the reaction plane, the directivity distribution as well as subthreshold K+-production. By means of these observables we discuss the particular role of the momentum-dependent forces and their implications on the nuclear equation of state. We find that only a momentum-dependent parameter-set can explain the experimental data on the transverse flow in the reaction plane from 150 - 1000 MeV/u and the differential K+-production cross sections at 1 GeV/u at the same time.

nucl-th↗