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Kohei Aso

Publications and source records attributed to Kohei Aso.

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One-Dimensional Electronic States in a Moir\'e Superlattice of Twisted Bilayer WTe2

One-dimensional (1D) moir\'e superlattices provide a new route to engineering reduced-dimensional electronic states in van der Waals materials, yet their electronic structure and microscopic origin remain largely unexplored. Here, we investigate the structural relaxation and electronic properties of a 1D moir\'e superlattice formed in twisted bilayer 1T$'$-WTe$_2$ using density functional theory calculations, complemented by high-angle annular dark-field scanning transmission electron microscopy. We show that lattice relaxation strongly reconstructs the moir\'e stripes, leading to stacking-dependent stripe widths that are in excellent agreement with experimental observations. The relaxed structure hosts quasi-one-dimensional electronic bands near the Fermi level, characterized by strong dispersion along the stripe direction and nearly flat dispersion in the perpendicular direction. By comparing the full bilayer with isolated relaxed layers, we establish that these 1D electronic states are governed predominantly by an intralayer moir\'e potential induced by in-plane lattice relaxation, rather than by interlayer hybridization. We extract this position-dependent moir\'e potential directly from DFT calculations and construct an effective tight-binding model that reproduces both the band dispersion and the real-space localization of the electronic wave functions. Our results identify lattice relaxation as the key mechanism underlying 1D electronic states in 1D moir\'e superlattices. %and establish twisted bilayer WTe$_2$ as a promising platform for exploring emergent one-dimensional moir\'e physics. The framework developed here provides a unified theoretical basis for realizing and exploring one-dimensional moir\'e physics in a broad class of anisotropic two-dimensional materials.

cond-mat.mes-hall

Atomic-scale observation of ordered structure induced by surface segregation in annealed Pt@Co core-shell nanoparticles

The ordered structure of binary alloy nanoparticles determines their magnetic and catalytic characteristics. In the alloys after annealing, one of the components preferentially segregates on the surface to reduce surface energy. This surface segregation has been known as a factor in the construction of an ordered phase near the surface. However, the segregation-induced ordering has not been observed for nanoparticles. Here, platinum@cobalt (Pt@Co) core-shell nanoparticles were synthesized, and their structural changes after annealing at 600°C, 700°C, and 800°C for 3 hours were observed by a scanning transmission electron microscope. We discovered an L10-PtCo structure near the surface at 700°C, which was unexpected given the initial Pt:Co ratio of about 4:1. The L10-PtCo structure was considered to form due to surface segregation of Pt atoms and diffusion insufficient to mix Pt and Co atoms in the particle overall because the structure did not form at 600°C and 800°C.

cond-mat.mtrl-sci

Shape-dependent local strain in gold nanorods: data-driven atomic-resolution electron microscopy analysis

The local variation in inter-atomic distances, or local lattice strain often influences significantly material properties of nanoparticles. Strain measurement with ~1% precision is provided by recent atomic-resolution electron microscopy. However, the precision has been limited by noises in the experimental data. Here, we have applied one of the data-driven analyses, Gaussian process regression to predict true form of strain. The precision has been improved to be sub-percent of 0.2 % and more for detection of local strain. Rod-shaped nanoparticles have been revealed to contain characteristic lattice expansion ~+0.6 % around the subsurface cap tip area. The experimental results are reproduced by molecular dynamics simulations of the corresponding shaped atomic models. The strain peculiar to nanorods are explained in terms of curvature-dependent non-uniform surface stress due to shape anisotropy. The present results bring a hint to nanoscale engineering to optimize the strain in nanoparticles by shape control.

cond-mat.mtrl-sci