arXiv subjects

Korenobu Matsuzaki

Publications and source records attributed to Korenobu Matsuzaki.

3 recordsLinked to original sources

arXiv2026

Electron confinement within a fluctuation "box" in liquid water

Electron confinement within a small volume is intriguing as a realization of the particle-in-a-box system, which appears in every quantum mechanics textbook. While the electron confinement is readily imaginable in solid-state systems, it also occurs in liquids, where the local voids in the liquid serve as confining "boxes." Confinement within these flexible cavities in liquids is expected to differ fundamentally from that in solids. Here, we experimentally investigate the electrons confined in liquid water, which are called hydrated electrons, using transient two-dimensional electronic spectroscopy. Our experiment reveals the large nonuniformity of the shape and the size of hydrated electrons with significant fluctuation at the timescale shorter than 30 fs.

physics.optics↗

arXiv2022

A robust tip-less positioning device for near-field investigations: Press and Roll Scan (PROscan)

Scanning probe microscopes scan and manipulate a sharp tip in the immediate vicinity of a sample surface. The limited bandwidth of the feedback mechanism used for stabilizing the separation between the tip and the sample makes the fragile nanoscopic tip very susceptible to mechanical instabilities. We propose, demonstrate and characterize a new alternative device based on bulging a thin substrate against a second substrate and rolling them with respect each other. We showcase the power of this method by placing gold nanoparticles and semiconductor quantum dots on the two opposite substrates and positioning them with nanometer precision to enhance the fluorescence intensity and emission rate. We exhibit the passive mechanical stability of the system over more than one hour. The design concept presented in this work holds promise in a variety of other contexts, where nanoscopic features have to be positioned and kept near contact with each other.

quant-ph↗

arXiv2016

Strong plasmonic enhancement of biexciton emission: controlled coupling of a single quantum dot to a gold nanocone antenna

Multiexcitonic transitions and emission of several photons per excitation comprise a very attractive feature of semiconductor quantum dots for optoelectronics applications. However, these higher-order radiative processes are usually quenched in colloidal quantum dots by Auger and other non-radiative decay channels. To increase the multiexcitonic quantum efficiency, several groups have explored plasmonic enhancement, so far with moderate results. By controlled positioning of individual quantum dots in the near field of gold nanocone antennas, we enhance the radiative decay rates of monoexcitons and biexcitons by 109 and 100 folds at quantum efficiencies of 60% and 70%, respectively, in very good agreement with the outcome of numerical calculations. We discuss the implications of our work for future fundamental and applied research in nano-optics.

physics.optics↗