arXiv subjects

Krishna Balasubramanian

Publications and source records attributed to Krishna Balasubramanian.

5 recordsLinked to original sources

arXiv2026

Dominant Role of Sulphur divacancy in Charge Trapping Dynamics in MoS$_2$

Intrinsic defects govern carrier trapping and recombination in two-dimensional semiconductors, yet the microscopic origin of defect-dependent capture dynamics remains unclear. Here, we compute carrier capture coefficients of vacancy defects, treating monolayer MoS$_2$ as a prototype, from first principles. We find that the single Sulphur vacancy forms a shallow defect with a small capture coefficient of $\sim 10^{-16}\ \mathrm{cm}^3/\mathrm{s}$, whereas the Sulphur divacancy exhibits a capture coefficient larger by seven orders of magnitude, $\sim 10^{-9}\ \mathrm{cm}^3/\mathrm{s}$, despite being only moderately deeper in energy. This enhancement originates from strong lattice relaxation enabling efficient multiphonon capture. Consequently, single vacancies contribute weakly to trapping, while Sulphur divacancies dominate nonradiative recombination and reduce quantum yield. In contrast, molybdenum vacancies and Sulphur antisites, although deep, show much smaller capture coefficients, indicating a limited role in carrier trapping in n-type devices.

cond-mat.str-el↗

arXiv2025

Restricted Spectral Gap Decomposition for Simulated Tempering Targeting Mixture Distributions

Simulated tempering is a widely used strategy for sampling from multimodal distributions. In this paper, we consider simulated tempering combined with an arbitrary local Markov chain Monte Carlo sampler and present a new decomposition theorem that provides a lower bound on the restricted spectral gap of the algorithm for sampling from mixture distributions. By working with the restricted spectral gap, the applicability of our results is extended to broader settings such as when the usual spectral gap is difficult to bound or becomes degenerate. We demonstrate the application of our theoretical results by analyzing simulated tempering combined with random walk Metropolis--Hastings for sampling from mixtures of Gaussian distributions. Our complexity bound scales polynomially with the separation between modes, logarithmically with $1/\varepsilon$, where $\varepsilon$ denotes the target accuracy in total variation distance, and exponentially with the dimension $d$.

math.ST↗

arXiv2025

Online Covariance Estimation in Nonsmooth Stochastic Approximation

We consider applying stochastic approximation (SA) methods to solve nonsmooth variational inclusion problems. Existing studies have shown that the averaged iterates of SA methods exhibit asymptotic normality, with an optimal limiting covariance matrix in the local minimax sense of Hájek and Le Cam. However, no methods have been proposed to estimate this covariance matrix in a nonsmooth and potentially non-monotone (nonconvex) setting. In this paper, we study an online batch-means covariance matrix estimator introduced in Zhu et al.(2023). The estimator groups the SA iterates appropriately and computes the sample covariance among batches as an estimate of the limiting covariance. Its construction does not require prior knowledge of the total sample size, and updates can be performed recursively as new data arrives. We establish that, as long as the batch size sequence is properly specified (depending on the stepsize sequence), the estimator achieves a convergence rate of order $O(\sqrt{d}n^{-1/8+\varepsilon})$ for any $\varepsilon>0$, where $d$ and $n$ denote the problem dimensionality and the number of iterations (or samples) used. Although the problem is nonsmooth and potentially non-monotone (nonconvex), our convergence rate matches the best-known rate for covariance estimation methods using only first-order information in smooth and strongly-convex settings. The consistency of this covariance estimator enables asymptotically valid statistical inference, including constructing confidence intervals and performing hypothesis testing.

stat.ML↗

arXiv2022

Winding Through: Crowd Navigation via Topological Invariance

We focus on robot navigation in crowded environments. The challenge of predicting the motion of a crowd around a robot makes it hard to ensure human safety and comfort. Recent approaches often employ end-to-end techniques for robot control or deep architectures for high-fidelity human motion prediction. While these methods achieve important performance benchmarks in simulated domains, dataset limitations and high sample complexity tend to prevent them from transferring to real-world environments. Our key insight is that a low-dimensional representation that captures critical features of crowd-robot dynamics could be sufficient to enable a robot to wind through a crowd smoothly. To this end, we mathematically formalize the act of passing between two agents as a rotation, using a notion of topological invariance. Based on this formalism, we design a cost functional that favors robot trajectories contributing higher passing progress and penalizes switching between different sides of a human. We incorporate this functional into a model predictive controller that employs a simple constant-velocity model of human motion prediction. This results in robot motion that accomplishes statistically significantly higher clearances from the crowd compared to state-of-the-art baselines while maintaining competitive levels of efficiency, across extensive simulations and challenging real-world experiments on a self-balancing robot.

cs.RO↗

arXiv2019

Low-Rank Principal Eigenmatrix Analysis

Sparse PCA is a widely used technique for high-dimensional data analysis. In this paper, we propose a new method called low-rank principal eigenmatrix analysis. Different from sparse PCA, the dominant eigenvectors are allowed to be dense but are assumed to have a low-rank structure when matricized appropriately. Such a structure arises naturally in several practical cases: Indeed the top eigenvector of a circulant matrix, when matricized appropriately is a rank-1 matrix. We propose a matricized rank-truncated power method that could be efficiently implemented and establish its computational and statistical properties. Extensive experiments on several synthetic data sets demonstrate the competitive empirical performance of our method.

stat.ML↗