arXiv subjects

Kyle Buznitsky

Publications and source records attributed to Kyle Buznitsky.

5 recordsLinked to original sources

arXiv2025

Thermophotovoltaic performance metrics and techno-economics: efficiency vs. power density

Thermophotovoltaics (TPV) are a promising new approach for converting heat to electricity. Their performance is primarily characterized by two metrics: efficiency and power density. While recent works have shown high efficiency, it is important to understand how both of these metrics impact the techno-economics of a TPV system as efforts to commercialize the technology advance. In this work, we develop the first unification of efficiency and power density into a single techno-economic metric based on the levelized cost of electricity (LCOE). We find that the LCOE can be broken into two parts: heating cost, including infrastructure and inputs for providing heat to the TPV cells, and cell cost, the capital cost of the TPV cells. We show that systems with high heating costs should prioritize TPV efficiency, while systems with high cell costs should prioritize power density. We then develop a model to identify the most impactful cell properties in improving the important performance metric and reducing system LCOE. Namely, improving spectral control with increased back-surface reflectance is the most effective to reduce LCOE in systems with high infrastructural costs, while increasing the view factor and reducing front-surface reflectance are most critical in systems with high TPV cell cost. Improving just one or two of these properties can reduce the LCOE by 25-75%, reaching competitive values ~ 8 cents/kWh-e, less than the average cost of electricity in the US. This study thus elucidates which TPV performance metric is more important for system technoeconomics and how to maximize it.

physics.app-ph↗

arXiv2024

Designing for effective heat transfer in a solid thermal energy storage system

Thermal energy storage using sensible heating of a solid storage medium is a potential low-cost technology for long-duration energy storage. To effectively get heat in and out of the solid material, channels of heat transfer fluid can be embedded within the storage material. Here we present design principles to improve performance of channel-embedded thermal energy storage systems, and we apply these principles to a high-temperature system using graphite as the storage material and liquid tin as the heat transfer fluid. We first analyze the impact of geometry and material properties on the performance of the system, determining the ideal channel spacing and length to achieve high (dis)charge temperature uniformity. We then analyze how controlling the fluid flowrate, heating infrastructure, and heat engine can increase discharge power uniformity and accelerate charging. Finally, we model 100 high-temperature graphite storage blocks using a porous media approximation and implement the developed design principles to demonstrate significant improvement in performance for both discharging (constant discharge power for >90% of rated duration) and charging (>90% charged within 4 hours). Overall, the hierarchical design procedure presented here enables the design of cheap yet high-performing solid thermal energy storage systems.

physics.app-ph↗

arXiv2023

Power Availability of PV plus Thermal Batteries in real-world electric power grids

As variable renewable energy sources comprise a growing share of total electricity generation, energy storage technologies are becoming increasingly critical for balancing energy generation and demand. In this study, we modeled an existing thermal energy storage unit with estimated capital costs that are sufficiently low to enable large-scale deployment in the electric power system. Our analysis emphasizes the value of using such units to cost-effectively improve renewable energy dispatchability. This study modeled an existing real-world grid rather than simulating hypothetical future electric power systems. The storage unit coupled with a photovoltaic (PV) system was modeled with different storage capacities, whereas each storage unit size had various discharge capacities. The modeling was performed under a baseline case with no emission constraints and under hypothetical scenarios in which CO$_2$ emissions were reduced. The results show that power availability increases with increasing storage size and vastly increases in the hypothetical CO$_2$ reduction scenarios, as the storage unit is utilized differently. When CO$_2$ emissions are reduced, the power system must be less dependent on fossil fuel technologies that currently serve the grid, and thus rely more on the power that is served from the PV + storage unit. The proposed approach can provide increased knowledge to power system planners regarding how adding PV + storage systems to existing grids can contribute to the efficient stepwise decarbonization of electric power systems.

math.DS↗

arXiv2021

Thermophotovoltaic Efficiency of 40%

We report the fabrication and measurement of thermophotovoltaic (TPV) cells with efficiencies of >40%, which is a record high TPV efficiency and the first experimental demonstration of the efficiency of high-bandgap tandem TPV cells. TPV efficiency was determined by simultaneous measurement of electric power output and heat dissipation from the device via calorimetry. The TPV cells are two-junction devices comprising high-quality III-V materials with band gaps between 1.0 and 1.4 eV that are optimized for high emitter temperatures of 1900-2400°C. The cells exploit the concept of band-edge spectral filtering to obtain high efficiency, using high-reflectivity back surface reflectors to reject unusable sub-bandgap radiation back to the emitter. A 1.4/1.2 eV device reached a maximum efficiency of (41.1 +/- 1)% operating at a power density of 2.39 W/cm2 under an irradiance of 30.4 W/cm2 and emitter temperature of 2400°C. A 1.2/1.0 device reached a maximum efficiency of (39.3 +/- 1)% operating at a power density of 1.8 W/cm2 under an irradiance of 20.1 W/cm2 and emitter temperature of 2127°C. These cells can be integrated into a TPV system for thermal energy grid storage (TEGS) to enable dispatchable renewable energy. These new TPV cells enable a pathway for TEGS to reach sufficiently high efficiency and sufficiently low cost to enable full decarbonization of the grid. Furthermore, the high demonstrated efficiency also gives TPV the potential to compete with turbine-based heat engines for large-scale power production with respect to both cost and performance, thereby enabling possible usage in natural gas or hydrogen-fueled electricity production.

physics.app-ph↗

arXiv2021

Technoeconomic Analysis of Thermal Energy Grid Storage Using Graphite and Tin

Energy storage is needed to enable dispatchable renewable energy supply and thereby full decarbonization of the grid. However, this can only occur with drastic cost reductions compared to current battery technology, with predicted targets for the cost per unit energy (CPE) below $20/kWh. Notably, for full decarbonization, long duration storage up to 100 hrs will be needed at such low costs, and prior analyses have shown that in such high renewable penetration scenarios, CPE is more critical than other parameters such as round trip efficiency or cost per unit power when comparing the costs of different technologies. Here, we introduce an electricity storage concept that stores electricity as sensible heat in graphite storage blocks and uses multi-junction thermophotovoltaics (TPV) as a heat engine to convert it back to electricity on demand. This design is an outgrowth of the system proposed by Amy et al. in 2019, which has been modified here to use a solid graphite medium and molten tin as a heat transfer fluid rather than silicon as both. The reason for this is two-fold: (1) the CPE of graphite is almost 10X lower than that of silicon, which derives from the lower cost per unit mass (i.e., $0.5/kg vs. $1.5/kg) and the higher heat capacity per unit mass (2000 J/kg-K vs. 950 J/kg-K); and (2) the melting point tin and solubility of tin in graphite are much lower than that of silicon, which lessens the number of issues that have to overcome along the research and development pathway. The usage of graphite also eliminates the need for a second tank, but the main disadvantage of using a solid medium is that one cannot easily provide a steady discharge rate, as the power output from the storage will change with time, as the graphite cools during discharge. Thus, the objective of this work is to examine how these changes in the system design effect the overall technoeconomics.

physics.app-ph↗