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Kyle D. Gilroy

Publications and source records attributed to Kyle D. Gilroy.

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A high-speed anamorphic pupil-conjugate slit spectrograph for rapid, self-luminous sources

We present a slit imaging spectrograph whose wavelength registration is a property of the instrument rather than of the pointing of the fore-optic or the position of the source. An internal telecentric 4f relay places the system stop within the instrument while a cylindrical lens places the slit aperture at a plane where transverse position encodes source angle only (an $A = 0$ conjugate in the ABCD matrix formulation). As a result, the lateral motion of the source or the pointing of the fore-optic does not cause the spectral image illuminating the sensor to wander, thus eliminating any non-physical registration of chemical species not present in the event and the need for on-the-fly recalibration. Additionally, the use of a high-speed CMOS camera eliminates temporally averaged spectral lines and aliasing noise. We characterize wavelength calibration (He discharge lamp, quadratic fit, RMS residual 0.12 nm, verified with Ne discharge lamp, same calibration, RMS residual 0.13 nm), spectral resolution (R $\approx$ 639, FWHM 0.92 nm at the optimal slit width setting, R $\approx$ 783, FWHM 0.75 nm at the instrument profile floor), and pointing invariance (He 587.6 nm line wander 0.29 nm RMS, 1.03 nm peak-to-peak, a nearly 100x reduction relative to the same instrument with the aperture stop at the fore-optic pupil). We perform combustion spectroscopy on ignited nitrocellulose at 10 kHz, 99 $μ$s exposure time, identifying Na, K, Ca, CaOH, and Rb chemical species using the unchanged wavelength calibration transferred from the helium discharge lamp.

physics.ins-det

Intermetallic Nanocrystals: Syntheses and Catalytic Applications

At the forefront of nanochemistry, there exists a research endeavor centered around intermetallic nanocrystals, which are unique in terms of long-range atomic ordering, well-defined stoichiometry, and controlled crystal structure. In contrast to alloy nanocrystals with no atomic ordering, it has been challenging to synthesize intermetallic nanocrystals with a tight control over their size and shape. This review article highlights recent progress in the synthesis of intermetallic nanocrystals with controllable sizes and well-defined shapes. We begin with a simple analysis and some insights key to the selection of experimental conditions for generating intermetallic nanocrystals. We then present examples to highlight the viable use of intermetallic nanocrystals as electrocatalysts or catalysts for various reactions, with a focus on the enhanced performance relative to their alloy counterparts that lack atomic ordering. We conclude with perspectives on future developments in the context of synthetic control, structure-property relationship, and application.

physics.chem-ph