arXiv subjects

L. B. F. M. Waters

Publications and source records attributed to L. B. F. M. Waters.

At least 19 recordsLinked to original sources

arXiv2026

Impact of accretion variability on the CO emission of a disk around a very-low-mass star with JWST

Studying the structure of very-low-mass stars ($M_\star<0.2M_\odot$) protoplanetary disk is crucial to understand the formation of Earth-like planets. In this paper, we characterize the innermost regions of the disk around a known very-low-mass star, 2MASS J16053215-1933159 (J1605 hereafter), by analyzing new JWST/NIRSpec observations taken in 2024, 2 years after a first observation with JWST/MIRI. We find that between the two epochs (2022 \& 2024), the CO flux is reduced by a factor $\sim 3$, the flux of the HI 10-6 line seen by both NIRSpec and MIRI is reduced by a factor $\sim13$, and the total continuum density flux is reduced by $\sim 15 \%$. The accretion rate derived from individual HI lines is consistent with a decrease of a factor $\sim13$ in 2 years. After correcting the spectrum from the CO absorption present in J1605 stellar photosphere, we find that the decrease of the disk's CO emission is consistent with a CO gas of same column density and temperature at each epoch, but originating from a smaller emitting area when the accretion rate is low. While warm hydrocarbons ($\simeq 500~$K) are detected with MIRI-MRS with extremely high column densities of $\rm C_2H_2$, no hydrocarbons features are seen with NIRSpec. We propose that non-LTE effects quench the near-IR emission of hydrocarbons in the warm reservoir. The variation of the accretion luminosity of J1605 correlates with the variation of its fundamental CO luminosity in a similar way as in T-Tauri stars, supporting the idea that very-low-mass stars could be seen as scaled-down versions of T-Tauri stars. The detection of the emission of the fundamental band of CO in disks around cold objects is challenging because of the presence of CO absorption in their photosphere. Future observations (e.g., with ELT/METIS) looking for such emission will require robust ways to constrain the photosphere emission.

astro-ph.EP↗

arXiv2026

MINDS survey of silicates in T Tauri disks: Correlation between dust and gas

Context. Silicates are key constituents of planet-forming disks and major building blocks of rocky planets. Mid-infrared spectral features of micron-sized silicate grains trace grain growth, mineralogy, and disk chemistry. Aims. We characterized the dust mineralogy in T Tauri disks using James Webb Space Telescope (JWST)/Mid-Infrared Instrument (MIRI) observations and investigated the connections between the dust and molecular gas compositions. Methods. We analyzed JWST/MIRI spectra of 26 disks from the MIRI mid-Infrared Disk Survey (MINDS). Using our DustComp spectral decomposition tool, we inferred the mass fractions of individual dust species. The fits included Mg$_2$SiO$_4$ (forsterite), MgSiO$_3$ (enstatite), and SiO$_2$ (silica), together with amorphous silicates of corresponding stoichiometry. Results. Mg-rich (and Fe-poor) silicates reproduce the data well, with residuals typically within $\pm3\%$. Grain size distributions are skewed toward sizes larger than $2μ$m, indicating significant growth. The average dust composition is dominated by Mg$_2$SiO$_4$-stoichiometry grains ($\sim60\%$), followed by MgSiO$_3$ ($\sim30\%$) and SiO$_2$ ($\sim10\%$). Crystalline mass fractions are typically in the $5$-$24\%$ range, with a mean of $14\%$. Annealed silica is robustly detected in nine objects, with cristobalite as the main polymorph. We found a correlation between dust and molecular gas composition: disks with strong annealed silica features show stronger CO$_2$ emission, while forsterite-rich disks display stronger H$_2$O emission. Disks with annealed silica features may also have elevated gas-phase C/O ratios. Conclusions. The observed dust-gas correlation may provide the first indication that the molecular gas composition regulates the availability of dust species in the inner disk.

astro-ph.SR↗

arXiv2026

Reflections on future problems in cluster science

This article is a collection of contributions from speakers at the 2025 DEAMN [Dynamics of Electrons in Atomic and Molecular Nanoclusters] workshop at the Majorana Centre in Erice. Not ordinary contributions to a conference proceeding, this gives a new and different perspective on the work done by the workshop participants.

physics.atm-clus↗

arXiv2026

The asymmetric structure of the inner disc around HD 142527 A with VLTI/MATISSE

Circumstellar discs, and especially their inner regions, covering ranges from <1 au to a few astronomical units, are the birthplaces of terrestrial planets. The inner regions are thought to be similarly diverse in structure as the well-observed outer regions probed by ALMA. Combining data and results from previous studies of the VLTI/PIONIER and VLTI/GRAVITY instruments with new, multi-epoch VLTI/MATISSE observations, we aim to provide a comprehensive picture of the structure of the inner regions of the circumstellar disc around the F-type Herbig Ae/Be star HD 142527 A, the primary of a binary star system. We model the multi-wavelength interferometric data using a parametrised, geometrically thin disc model, allowing for azimuthal asymmetry, exploring a first-order disc modulation and an off-centre Gaussian component. We find time-variable structures in the N-band observables, which we reproduce with time-dependent models. This variability manifests as azimuthally asymmetric emission, evidenced by strong, non-zero closure phases in the N-band data. Fits to individual epochs of the N-band observations yield better $χ^2_\text{r}$ values than fits to all epochs simultaneously. This suggests substantial changes in the geometry of the inner disc emission from ~1 au up to a few astronomical-unit scales from one year to the next. Moreover, our models produce a very close-in inner disc rim $R_\text{rim}\approx0.1$ au. All together, we find a very complex, substantially non-point symmetric and temporally-variable disc ($r_\text{out}\lesssim6$ au) around the primary. The very close-in inner rim indicates the presence of material inside the typical wall-like sublimation radius $R_\text{rim,literature}\approx0.3$ au. The complex, temporally variable inner-disc geometry is likely affected or even caused by the close passing (~5 au) and short orbit ($P\approx24$ yr) of the companion HD 142527 B.

astro-ph.EP↗

arXiv2026

Information content of JWST transmission spectroscopy of the exoplanet HAT-P-12b from the optical to the mid-infrared

The James Webb Space Telescope (JWST) provides low- to medium-resolution spectra with unprecedented precision and broad near- to mid-infrared wavelength coverage, enabling detailed characterization of exoplanet atmospheres. We present a new JWST NIRISS SOSS transit observation of the warm sub-Saturn HAT-P-12b. Combined with NIRSpec G395M and MIRI LRS data, this enables an assessment of the information content across JWST instruments over the full accessible wavelength range. The NIRISS data were reduced and the impact of reduction choices on the transmission spectrum evaluated. Atmospheric retrievals were performed for all JWST combinations, with selected cases including archival HST data. Four molecules are significantly detected: H2O, CO2, CO, and H2S. Except for H2O, detections require NIRSpec coverage, while H2S is only detected in multi-instrument retrievals. NIRISS SOSS is essential to establish robust evidence for non-gray cloud behavior. A moderate scattering slope (p < 4) is consistently retrieved. Single-instrument retrievals tend to overestimate abundances, whereas combined JWST datasets yield more consistent constraints. The C/O ratio remains sensitive to differences between NIRSpec reductions. Results broadly agree with studies of WASP-39b, but highlight variations in information content across exoplanet types.

astro-ph.EP↗

arXiv2026

JWST MIRI-MRS observations of the Red Rectangle: AIB class transformation in the outer nebula

Aims: We characterize the mid-infrared spectrum of the outer regions of the Red Rectangle nebula to probe the carbonaceous dust and molecular content beyond the circumbinary disk. Methods: We present JWST MIRI-MRS observations of the SW whisker, extracted from three distinct environments: the biconical outflow, the whisker itself, and the shadow region outside the outflow. We compare these with an archival ISO-SWS observation of the inner nebula. Results: The JWST spectra display only classical AIB emission on a weak dust continuum, with no signatures of the oxygen-rich circumbinary disk mineralogy nor of the rich molecular emission seen at optical wavelengths. The AIBs are predominantly Class A - in marked contrast to the exclusively Class B profiles previously reported for the inner regions - with systematic differences between the outflow and shadow regions pointing to environmentally driven PAH processing.

astro-ph.GA↗

arXiv2026

Detection of CO$_2$ ice in the planetary nebula NGC 6302

Using JWST/MIRI observations, we report the detection of CO$_2$ ice in the dusty torus of the planetary nebula NGC 6302, an environment generally considered hostile to fragile molecular species and ices due to intense UV irradiation. This detection accompanies cold (20-50 K) gas-phase CO$_2$ along the same sightlines. The ice absorption profile exhibits a double-peak profile, a characteristic of pure, crystalline CO$_2$ ice. The CO$_2$ gas-to-ice ratio is more than an order of magnitude higher than in young stellar objects, pointing to distinct ice formation or processing mechanisms in evolved stellar environments. This discovery demonstrates that the dusty torus provides sufficient shielding to harbour ice chemistry, and that ice-mediated surface reactions must be incorporated into chemical models of planetary nebulae.

astro-ph.GA↗

arXiv2025

Detection of CO$_2$, CO, and H$_2$O in the atmosphere of the warm sub-Saturn HAT-P-12b

The chemical composition of warm gas giant exoplanet atmospheres (with Teq < 1000 K) is not well known due to the lack of observational constraints. HAT-P-12 b is a warm, sub-Saturn-mass transiting exoplanet that is ideal for transmission spectroscopy. One transit of HAT-P-12 b was observed with JWST NIRSpec in the 2.87--5.10 $μ$m range with a resolving power of $\sim$1000. The JWST data are combined with archival observations from HST WFC3 covering the 1.1--1.7 $μ$m range. The data were analysed using two data reduction pipelines and two atmospheric retrieval tools. Atmospheric simulations using chemical forward models were performed. CO2, CO, and H2O are detected at 12.2, 4.1, and 6.0 $σ$ confidence, respectively. Their volume mixing ratios are consistent with an atmosphere of $\sim10\times$ solar metallicity and production of CO2 by photochemistry. CH4 is not detected and seems to be lacking, which could be due to a high intrinsic temperature with strong vertical mixing or other phenomena. SO2 is also not detected and its production seems limited by low upper atmosphere temperatures ($\sim$500 K at $P<10^{-3}$ bar derived from one-dimensional retrievals), insufficient to produce it in detectable quantities ($\gtrsim$ 800 K required according to photochemical models). Retrievals indicate the presence of clouds between 2 and 269 mbar. This study points towards an atmosphere for HAT-P-12 b that could be enriched in carbon and oxygen with respect to its host star. When including the production of CO2 via photochemistry, an atmospheric metallicity that is close to Saturn's can explain the observations. Metallicities inferred for other gas giant exoplanets based on their CO2 mixing ratios may need to account for its photochemical production pathways. This may impact studies on mass-metallicity trends and links between exoplanet atmospheres, interiors, and formation history.

astro-ph.EP↗

arXiv2025

Multi-band infrared imaging reveals dusty spiral arcs around the binary B[e] star 3 Puppis

3 Puppis is the brightest known B[e] star. Recent work classifies this A-type object as a supergiant, yet the impact of its binarity on the circumstellar environment (CE) remains hard to characterize. To resolve its dusty region at 5-10 mas, we obtained mid-IR interferometric observations with VLTI/MATISSE over 3-12 μm. Because the (u,v) coverage supports imaging, we introduce a statistical interferometric-imaging workflow based on MiRA to generate averaged images: this systematic approach enables the selection of an optimal set of reconstructions, improving the robustness and fidelity of the recovered features. We also use SPARCO, an independent tool well suited to bright central objects embedded in fainter extended emission. Images from both tools in the L, M, and N bands agree and reveal an asymmetric, elongated feature ~17 mas (~10 au at 631 pc) southeast of the star with ~20% density contrast. A second northwest asymmetry and a skewed inner rim are detected. Simple geometric modelling, guided by the MATISSE images, constrains the morphology, location, and flux of the CE and its asymmetries. The images are consistent with earlier VLTI measurements but expose a more complex CE with large-scale clumps in the southeast and northwest parts of the disc. Hydrodynamic modelling indicates that tidal spiral-wake perturbations from the central binary, dynamically excited at Lindblad resonances in the circumbinary disc, best explain the radial extent and curvature of the elongated structures seen in all bands.

astro-ph.SR↗

arXiv2025

Detection of CH3+ in the O-rich planetary nebula NGC 6302

Planetary nebulae are sites where ejected stellar material evolves into complex molecules, but the precise physical conditions and chemical routes that govern these processes are unclear. The presence of abundant carbon-rich molecules in O-rich environments poses particular challenges. Here we report the first detection of methyl cation (CH3+) in any planetary nebula, observed in the O-rich nebula NGC 6302 using JWST MIRI/MRS observations. CH3+ is a key driver of organic chemistry in UV-irradiated environments. Spatially resolved observations reveal that CH3+ is co-located with 12CO, H2, H II, HCO+, and Polycyclic aromatic hydrocarbons (PAHs). LTE modelling of the CH3+ emission yields excitation temperatures of 500-800K in the inner bubble and torus, rising to 1000-2000K in the outer bubble of NGC 6302, with column densities ranging from ~10^11 to 10^13 cm^-2. This detection demonstrates that hydrocarbon radical chemistry must be incorporated into planetary nebulae chemical models. Further near-IR observations are crucial to map different chemical networks operating in these environments.

astro-ph.GA↗

arXiv2025

The JWST/MIRI view of the planetary nebula NGC 6302 I.: a UV irradiated torus and a hot bubble triggering PAH formation

NGC 6302 is a spectacular bipolar planetary nebula (PN) whose spectrum exhibits fast outflows and highly ionized emission lines, indicating the presence of a very hot central star (~220,000 K). Its infrared spectrum reveals a mixed oxygen and carbon dust chemistry, displaying both silicate and polycyclic aromatic hydrocarbon (PAH) features. Using the JWST Mid-Infrared Instrument (MIRI) and Medium Resolution Spectrometer, a mosaic map was obtained over the core of NGC 6302, covering the wavelength range of 5--28 micron and spanning an area of ~18.5 arcsec x15 arcsec. The spatially resolved spectrum reveals ~200 molecular and ionized lines from species requiring ionisation potentials of up to 205 eV. The spatial distributions highlight a complex structure at the nebula's centre. Highly ionized species such as Mg VII and Si VII show compact structures, while lower-ionization species such as H^+ extend much farther outwards, forming filament-defined rims that delineate a bubble. Within the bubble, the H^+ and H_2 emission coincide, while the PAH emission appears farther out, indicating an ionization structure distinct from typical photodissociation regions, such as the Orion Bar. This may be the first identification of a PAH formation site in a PN. This PN appears to be shaped not by a steady, continuous outflow, but by a series of dynamic, impulsive bubble ejections, creating local conditions conducive to PAH formation. A dusty torus surrounds the core, primarily composed of large (micron-sized) silicate grains with crystalline components. The long-lived torus contains a substantial mass of material, which could support an equilibrium chemistry and a slow dust-formation process.

astro-ph.SR↗

arXiv2025

MINDS. Cha Hα 1, a brown dwarf with a hydrocarbon-rich disk

Context. Recent JWST observations have shown that brown dwarfs (BD) are chemically rich, offering valuable insights into giant planet formation. Aims. As part of the MIRI mid-INfrared Disk Survey (MINDS) JWST guaranteed time program, we aim to characterize the gas and dust composition of the disk around the brown dwarf [NC98] Cha HA 1, hereafter Cha H$α$ 1, in the mid-infrared. Methods. We obtain data from the MIRI Medium Resolution Spectrometer (MRS) from 4.9 to 28$μ$m. We use the dust fitting tool DuCK to investigate the dust composition and grain sizes while we identify and fit molecular emission using slab models. Results. Compared with disks around very low mass stars, clear silicate emission features are seen in this BD disk. In addition, JWST reveals a plethora of hydrocarbons, including C$_2$H$_2$, $^{13}$CCH$_2$, CH$_3$, CH$_4$, C$_2$H$_4$, C$_4$H$_2$, C$_3$H$_4$, C$_2$H$_6$, and C$_6$H$_6$ which suggest a disk with a gas C/O > 1. Additionally, we detect CO$_2$, $^{13}$CO$_2$, HCN, H$_2$, and H$_2$O. CO and OH are absent from the spectrum. The dust is dominated by large $\sim$4 $μ$m size amorphous silicates (MgSiO$_3$). We infer a small dust mass fraction ($>$10$\%$) of 5 $μ$m size crystalline forsterite. We do not detect polycyclic aromatic hydrocarbons. Conclusions. Cha H$α$ 1 shows the most diverse chemistry seen to date in a BD protoplanetary disk, consisting of a strong dust feature, 12 carbon-bearing molecules plus H$_2$, and water. The diverse molecular environment offers a unique opportunity to test our understanding of BD disks chemistry and how it affects the possible planets forming in them.

astro-ph.SR↗

arXiv2025

A transition from H$_2$O to C$_2$H$_2$ dominated spectra with decreasing stellar luminosity

The chemical composition of the inner regions of disks around young stars will determine the properties of planets forming there. Many disk physical processes drive the chemical evolution, some of which depend on/correlate with the stellar properties. We aim to explore the connection between stellar properties and inner disk chemistry, using mid-infrared spectroscopy. We use JWST-MIRI observations of a large, diverse sample of sources to explore trends between C$_2$H$_2$ and H$_2$O. Additionally, we calculate the average spectrum for the T Tauri ($M_{*}$$>$0.2 $M_{\odot}$) and very low-mass star (VLMS, $M_{*}$$\leq$0.2 $M_{\odot}$) samples and use slab models to determine the properties. We find a significant anti-correlation between the flux ratio of C$_2$H$_2$/H$_2$O and the stellar luminosity. Disks around VLMS have significantly higher $F_{\rm{C_2H_2}}$/$F_{\rm{H_2O}}$ flux ratios than their higher-mass counterparts. We also explore trends with the strength of the 10 $μ$m silicate feature, stellar accretion rate, and disk dust mass, all of which show correlations with the flux ratio, which may be related to processes driving the carbon-enrichment in disks around VLMS, but also have degeneracies with system properties. Slab model fits to the average spectra show that the VLMS H$_2$O emission is quite similar in temperature and column density to a warm ($\sim$600 K) H$_2$O component in the T Tauri spectrum, indicating that the high C/O gas phase ratio in these disks is not due to oxygen depletion alone. Instead, the presence of many hydrocarbons, including some with high column densities, points to carbon enhancement in the disks around VLMS. The observed differences in the inner disk chemistry as a function of host properties are likely to be accounted for by differences in the disk temperatures, stellar radiation field, and the evolution of dust grains.

astro-ph.EP↗

arXiv2025

Evidence for SiO cloud nucleation in the rogue planet PSO J318

Silicate clouds are known to significantly impact the spectra of late L-type brown dwarfs, with observable absorption features at ~ 10 micron. JWST has reopened our window to the mid-infrared with unprecedented sensitivity, bringing the characterization of silicates into focus again. Using JWST, we characterize the planetary-mass brown dwarf PSO J318.5338-22.8603, concentrating on any silicate cloud absorption the object may exhibit. PSO J318's spectrum is extremely red, and its flux is variable, both of which are likely hallmarks of cloud absorption. We present JWST NIRSpec PRISM, G395H, and MIRI MRS observations from 1-18 micron. We introduce a method based on PSO J318's brightness temperature to generate a list of cloud species that are likely present in its atmosphere. We then test for their presence with petitRADTRANS retrievals. Using retrievals and grids from various climate models, we derive bulk parameters from PSO J318's spectra, which are mutually compatible. Our retrieval results point to a solar to slightly super-solar atmospheric C/O, a slightly super-solar metallicity, and a 12C/13C below ISM values. The atmospheric gravity proves difficult to constrain for both retrievals and grid models. Retrievals describing the flux of PSO J318 by mixing two 1-D models (``two-column models'') appear favored over single-column models; this is consistent with PSO J318's variability. The JWST spectra also reveal a pronounced absorption feature at 10 micron. This absorption is best reproduced by introducing a high-altitude cloud layer of small (<0.1 micron), amorphous SiO grains. The retrieved particle size and location of the cloud is consistent with SiO condensing as cloud seeding nuclei. High-altitude clouds comprised of small SiO particles have been suggested in previous studies, therefore the SiO nucleation we potentially observe in PSO J318 could be a more wide-spread phenomenon.

astro-ph.EP↗

arXiv2025

MINDS: Detection of an inner gas disk caused by evaporating bodies around HD 172555

Mechanisms such as collisions of rocky bodies or cometary activity give rise to dusty debris disks. Debris disks trace the leftover building blocks of planets, and thus also planetary composition. HD 172555, a stellar twin of beta Pic, hosts a debris disk thought to have resulted from a giant collision. It is known for its extreme mid-infrared silica dust feature, indicating a warm population of silica-rich grains in the asteroid belt (~5 au), cold CO observed by ALMA, and small bodies evaporating as they approach close to the star. Our JWST MIRI/MRS observations now reveal emission from an inner gaseous disk (<0.5 au) that arises from the evaporation of close-in material. For the first time in a debris disk, we detect neutral atomic chlorine and sulfur, as well as ionized nickel. We recovered the neutral sulfur line in ~20-year-old Spitzer data, showing it is long-lived and stable. Ionized iron, previously seen only in beta Pic, is also detected. All lines are broadened by Keplerian rotation, pinpointing the gas location. The HD 172555 system serves as a unique laboratory to study the composition of planetesimals, asteroids, and comets beyond the Solar System. The comparison to beta Pic reveals, that the gas in HD 172555 is hotter, closer to the star, and poor in argon -- suggesting it originates from evaporating rocky bodies near the star, while beta Pic's gas may trace volatile-rich bodies from larger separations.

astro-ph.EP↗

arXiv2025

Direct imaging discovery of a young giant planet orbiting on Solar System scales

HD 135344 AB is a young visual binary system that is best known for the protoplanetary disk around the secondary star. The circumstellar environment of the A0-type primary star, on the other hand, is already depleted. HD 135344 A is therefore an ideal target for the exploration of recently formed giant planets because it is not obscured by dust. We searched for and characterized substellar companions to HD 135344 A down to separations of about 10 au. We observed HD 135344 A with VLT/SPHERE in the $H23$ and $K12$ bands and obtained $YJ$ and $YJH$ spectroscopy. In addition, we carried out VLTI/GRAVITY observations for the further astrometric and spectroscopic confirmation of a detected companion. We discovered a close-in young giant planet, HD 135344 Ab, with a mass of about 10 $M_\mathrm{J}$. The multi-epoch astrometry confirms the bound nature based on common parallax and common proper motion. This firmly rules out the scenario of a non-stationary background star. The semi-major axis of the planetary orbit is approximately 15-20 au, and the photometry is consistent with that of a mid L-type object. The inferred atmospheric and bulk parameters further confirm the young and planetary nature of the companion. HD 135344 Ab is one of the youngest directly imaged planets that has fully formed and orbits on Solar System scales. It is a valuable target for studying the early evolution and atmosphere of a giant planet that could have formed in the vicinity of the snowline.

astro-ph.EP↗

arXiv2025

Investigating silicate, carbon, and water in the diffuse interstellar medium: the first shots from WISCI

The dusty interstellar medium (ISM) of the Milky Way is distributed in a complex, cloudy structure. It is fundamental to the radiation balance within the Milky Way, provides a reaction surface to form complex molecules, and is the feedstock for future generations of stars and planets. The life cycle of interstellar dust is not completely understood, and neither are its structure nor composition. The abundance, composition, and structure of dust in the diffuse ISM can be determined by combining infrared, optical and ultraviolet spectroscopy. JWST enables measurement of the faint absorption of ISM dust grains against bright stars at kiloparsec distances across the infrared spectrum. Here we present an overview of the project `Webb Investigation of Silicates, Carbons, and Ices' (WISCI) along with interpretation of two targets, GSC 08152-02121 and CPD-59 5831. Observations of 12 WISCI target stars were taken by JWST, the Hubble Space Telescope, Himalayan Chandra Telescope, and the Very Large Telescope. We use these to characterize the targets' spectral types and calculate their line-of-sight extinction parameters, $A_{\rm V}$ and $R_{\rm V}$. We find absorption in the JWST spectra of GSC 08152-02121, and CPD-59 5831 associated with carbonaceous dust around 3.4 and 6.2 micron and amorphous silicates at 9.7 micron. In GSC 08152-02121 we also find indications of absorption by trapped water around 3 micron. This first look from WISCI demonstrates the line-of-sight variability within the sample, and the program's potential to identify and correlate features across ultraviolet to mid-infrared wavelengths.

astro-ph.GA↗

arXiv2025

MINDS: The very low-mass star and brown dwarf sample. Detections and trends in the inner disk gas

Planet-forming disks around brown dwarfs and very low-mass stars (VLMS) are on average less massive and are expected to undergo faster radial solid transport than their higher mass counterparts. Spitzer had detected C$_2$H$_2$, CO$_2$ and HCN around these objects. With better sensitivity and spectral resolving power, JWST recently revealed incredibly carbon-rich spectra from such disks. A study of a larger sample of objects is necessary to understand how common such carbon-rich inner disk regions are and to put constraints on their evolution. We present and analyze MIRI observations of 10 disks around VLMS from the MIRI GTO program. This sample is diverse, with the central object ranging in mass from 0.02 to 0.14 $M_{\odot}$. They are located in three star-forming regions and a moving group (1-10 Myr). We identify molecular emission in all sources and report detection rates. We compare the molecular flux ratios between different species and to dust emission strengths. We also compare the flux ratios with the stellar and disk properties. The spectra of these VLMS disks are extremely molecular rich, and we detect the 10 $μ$m silicate dust emission feature in 70% of the sample. We detect C$_2$H$_2$ and HCN in all of the sources and find larger hydrocarbons such as C$_4$H$_2$ and C$_6$H$_6$ in nearly all sources. Among O-bearing molecules, we find firm detections of CO$_2$, H$_2$O, and CO in 90%, 50%, and 20% of the sample, respectively. We find that the detection rates of organic molecules correlate with other organic molecules and anti-correlate with inorganic molecules. Hydrocarbon-rich sources show a weaker 10$μ$m dust strength as well as lower disk dust mass than the oxygen-rich sources. We find potential evidence for C/O enhancement with disk age. The observed trends are consistent with models that suggest rapid inward solid material transport and grain growth.

astro-ph.EP↗