arXiv subjects

L. Balicas

Publications and source records attributed to L. Balicas.

At least 37 records · Page 2Linked to original sources

arXiv2017

Bulk Fermi-surface of the Weyl type-II semi-metallic candidate MoTe2

The electronic structure of WTe$_2$ and orthorhombic $γ-$MoTe$_2$, are claimed to contain pairs of Weyl type-II points. A series of ARPES experiments claim a broad agreement with these predictions. We synthesized single-crystals of MoTe$_2$ through a Te flux method to validate these predictions through measurements of its bulk Fermi surface (FS) \emph{via} quantum oscillatory phenomena. We find that the superconducting transition temperature of $γ-$MoTe$_2$ depends on disorder as quantified by the ratio between the room- and low-temperature resistivities, suggesting the possibility of an unconventional superconducting pairing symmetry. Similarly to WTe$_2$, the magnetoresistivity of $γ-$MoTe$_2$ does not saturate at high magnetic fields and can easily surpass $10^{6}$ \%. Remarkably, the analysis of the de Haas-van Alphen (dHvA) signal superimposed onto the magnetic torque, indicates that the geometry of its FS is markedly distinct from the calculated one. The dHvA signal also reveals that the FS is affected by the Zeeman-effect precluding the extraction of the Berry-phase. A direct comparison between the previous ARPES studies and density-functional-theory (DFT) calculations reveals a disagreement in the position of the valence bands relative to the Fermi level $\varepsilon_F$. Here, we show that a shift of the DFT valence bands relative to $\varepsilon_F$, in order to match the ARPES observations, and of the DFT electron bands to explain some of the observed dHvA frequencies, leads to a good agreement between the calculations and the angular dependence of the FS cross-sectional areas observed experimentally. However, this relative displacement between electron- and hole-bands eliminates their crossings and, therefore, the Weyl type-II points predicted for $γ-$MoTe$_2$.

cond-mat.mes-hall↗

arXiv2017

Fermi surface of the Weyl type-II metallic candidate WP2

Weyl type-II fermions are massless quasiparticles that obey the Weyl equation and which are predicted to occur at the boundary between electron- and hole-pockets in certain semi-metals, i.e. the (W,Mo)(Te,P)$_2$ compounds. Here, we present a study of the Fermi-surface of WP$_2$ \emph{via} the Shubnikov-de Haas (SdH) effect. Compared to other semi-metals WP$_2$ exhibits a very low residual resistivity, i.e. $ρ_0 \simeq 10$ n$Ω$cm, which leads to perhaps the largest non-saturating magneto-resistivity $(ρ(H))$ reported for any compound. For the samples displaying the smallest $ρ_0$, $ρ(H)$ is observed to increase by a factor of $2.5 \times 10^{7}$ $\%$ under $μ_{0}H = 35$ T at $T = 0.35$ K. The angular dependence of the SdH frequencies is found to be in very good agreement with the first-principle calculations when the electron- and hole-bands are slightly shifted with respect to the Fermi level, thus supporting the existence of underlying Weyl type-II points in WP$_2$.

cond-mat.mes-hall↗

arXiv2017

Possible devil's staircase in the Kondo lattice CeSbSe

The temperature ($T$) - magnetic field ($H$) phase diagram for the tetragonal layered compound CeSbSe, is determined from magnetization, specific heat, and electrical resistivity measurements. This system exhibits complex magnetic ordering at $T_{\rm{M}}$ $=$ 3 K and the application of a magnetic field results in a cascade of magnetically ordered states for $H$ $\lesssim$ 1.8 T which are characterized by fractional integer size steps: i.e., a possible Devil's staircase is observed. Electrical transport measurements show a weak temperature dependence and large residual resistivity which suggest a small charge carrier density and strong scattering from the $f$-moments. These features reveal Kondo lattice behavior where the $f$-moments are incompletely screened, resulting in a fine balanced magnetic interaction between different Ce neighbors that is mediated by the RKKY interaction. This produces the nearly degenerate magnetically ordered states that are accessed under an applied magnetic field.

cond-mat.str-el↗

arXiv2017

Electronic in-plane symmetry breaking at field-tuned quantum criticality in CeRhIn5

Electronic nematics are exotic states of matter where electronic interactions break a rotational symmetry of the underlying lattice, in analogy to the directional alignment without translational order in nematic liquid crystals. Intriguingly such phases appear in the copper- and iron-based superconductors, and their role in establishing high-temperature superconductivity remains an open question. Nematicity may take an active part, cooperating or competing with superconductivity, or may appear accidentally in such systems. Here we present experimental evidence for a phase of nematic character in the heavy fermion superconductor CeRhIn5. We observe a field-induced breaking of the electronic tetragonal symmetry of in the vicinity of an antiferromagnetic (AFM) quantum phase transition at Hc~50T. This phase appears in out-of-plane fields of H*~28T and is characterized by substantial in-plane resistivity anisotropy. The anisotropy can be aligned by a small in-plane field component, with no apparent connection to the underlying crystal structure. Furthermore no anomalies are observed in the magnetic torque, suggesting the absence of metamagnetic transitions in this field range. These observations are indicative of an electronic nematic character of the high field state in CeRhIn5. The appearance of nematic behavior in a phenotypical heavy fermion superconductor highlights the interrelation of nematicity and unconventional superconductivity, suggesting nematicity to be a commonality in such materials.

cond-mat.str-el↗

arXiv2016

Thermodynamic Anomaly Above the Superconducting Critical Temperature in the Quasi One-Dimensional Superconductor Ta$_4$Pd$_3$Te$_{16}$

We study the intrinsic transport anisotropy and fermiology of the quasi one-dimensional superconductor Ta$_4$Pd$_3$Te$_{16}$. Below $T^*=20$ K we detect a thermodynamic phase transition that predominantly affects the conductivity perpendicular to the quasi one-dimensional chains, consistent with a thermodynamic transition related to the presence of charge order that precedes superconductivity. Remarkably the Fermi surface pockets detected by de Haas-van Alphen (dHvA) oscillations are unaffected by this transition, suggesting that the ordered state does not break any translational symmetries but rather alters the scattering of the quasiparticles themselves.

cond-mat.supr-con↗

arXiv2016

Engineering the structural and electronic phases of MoTe2 through W substitution

MoTe$_2$ is an exfoliable transition metal dichalcogenide (TMD) which crystallizes in three symmetries, the semiconducting trigonal-prismatic $2H-$phase, the semimetallic $1T^{\prime}$ monoclinic phase, and the semimetallic orthorhombic $T_d$ structure. The $2H-$phase displays a band gap of $\sim 1$ eV making it appealing for flexible and transparent optoelectronics. The $T_d-$phase is predicted to possess unique topological properties which might lead to topologically protected non-dissipative transport channels. Recently, it was argued that it is possible to locally induce phase-transformations in TMDs, through chemical doping, local heating, or electric-field to achieve ohmic contacts or to induce useful functionalities such as electronic phase-change memory elements. The combination of semiconducting and topological elements based upon the same compound, might produce a new generation of high performance, low dissipation optoelectronic elements. Here, we show that it is possible to engineer the phases of MoTe$_2$ through W substitution by unveiling the phase-diagram of the Mo$_{1-x}$W$_x$Te$_2$ solid solution which displays a semiconducting to semimetallic transition as a function of $x$. We find that only $\sim 8$ \% of W stabilizes the $T_d-$phase at room temperature. Photoemission spectroscopy, indicates that this phase possesses a Fermi surface akin to that of WTe$_2$.

cond-mat.mes-hall↗

arXiv2016

Hall-effect within the colossal magnetoresistive semi-metallic state of MoTe2

Here, we report a systematic study on the Hall-effect of the semi-metallic state of bulk MoTe$_2$, which was recently claimed to be a candidate for a novel type of Weyl semi-metallic state. The temperature ($T$) dependence of the carrier densities and of their mobilities, as estimated from a numerical analysis based on the isotropic two-carrier model, indicates that its exceedingly large and non-saturating magnetoresistance may be attributed to a near perfect compensation between the densities of electrons and holes at low temperatures. A sudden increase in hole density, with a concomitant rapid increase in the electron mobility below $T \sim 40$ K, leads to comparable densities of electrons and holes at low temperatures suggesting a possible electronic phase-transition around this temperature.

cond-mat.supr-con↗

arXiv2016

Two-dimensional superconductivity in a bulk single-crystal

Both Nb$_3$Pd$_x$Se$_7$ and Ta$_4$Pd$_3$Te$_{16}$ crystallize in a monoclinic point group while exhibiting superconducting transition temperatures as high as $T_c\sim 3.5$ and $\sim 4.7 $ K, respectively. Disorder was claimed to lead to the extremely large upper critical fields ($H_{c2}$) observed in related compounds. Despite the presence of disorder and heavier elements, $H_{c2}$s in Ta$_4$Pd$_3$Te$_{16}$ are found to be considerably smaller than those of Nb$_3$Pd$_x$Se$_7$ while displaying an anomalous, non-saturating linear dependence on temperature $T$ for fields along all three crystallographic axes. In contrast, crystals of the latter compound displaying the highest $T_c$s display $H_{c2}\propto (1-T/T_c)^{1/2}$, which in monolayers of transition metal dichalcogenides is claimed to be evidence for an Ising paired superconducting state resulting from strong spin-orbit coupling. This anomalous $T$-dependence indicates that the superconducting state of Nb$_3$Pd$_x$Se$_7$ is quasi-two-dimensional in nature. This is further supported by a nearly divergent anisotropy in upper-critical fields, i.e. $γ= H_{c2}^{b}/H_{c2}^{a^{\prime}}$, upon approaching $T_c$. Hence, in Nb$_3$Pd$_x$Se$_7$ the increase of $T_c$ correlates with a marked reduction in electronic dimensionality as observed, for example, in intercalated FeSe. For the Nb compound, Density functional theory (DFT) calculations indicate that an increase in the external field produces an anisotropic orbital response, with especially strong polarization at the Pd sites when the field is perpendicular to their square planar environment. Therefore, DFT suggests the field-induced pinning of the spin to the lattice as a possible mechanism for decoupling the superconducting planes. Overall, our observations represent further evidence for unconventional superconductivity in the Pd chalcogenides.

cond-mat.supr-con↗

arXiv2016

Uncovering the behavior of Hf2Te2P and the candidate Dirac metal Zr2Te2P

Results are reported for single crystal specimens of Hf$_2$Te$_2$P and compared to its structural analogue Zr$_2$Te$_2$P, which was recently proposed to be a potential reservoir for Dirac physics.[1] Both materials are produced using the iodine vapor transport method and the resulting crystals are exfoliable. The bulk electrical transport and thermodynamic properties indicate Fermi liquid behavior at low temperature for both compounds. Quantum oscillations are observed in magnetization measurements for fields applied parallel but not perpendicular to the $c$-axis, suggesting that the Fermi surfaces are quasi-two dimensional. Frequencies are determined from quantum oscillations for several parts of the Fermi surfaces. Lifshitz-Kosevich fits to the temperature dependent amplitudes of the oscillations reveal small effective masses, with a particularly small value $m^*$ $=$ 0.046$m_0$ for the α branch of Zr$_2$Te$_2$P. Electronic structure calculations are in good agreement with quantum oscillation results and illustrate the effect of a stronger spin-orbit interaction going from Zr to Hf. These results suggest that by using appropriate tuning parameters this class of materials may deepen the pool of novel Dirac phenomena.

cond-mat.mtrl-sci↗

arXiv2016

Inter-planar coupling dependent magnetoresistivity in high purity layered metals

The magnetic field-induced changes in the conductivity of metals are the subject of intense interest, both for revealing new phenomena and as a valuable tool for determining their Fermi surface. Here, we report a hitherto unobserved magnetoresistive effect in ultra-clean layered metals, namely a negative longitudinal magnetoresistance that is capable of overcoming their very pronounced orbital one. This effect is correlated with the inter-layer coupling disappearing for fields applied along the so-called Yamaji angles where the inter-layer coupling vanishes. Therefore, it is intrinsically associated with the Fermi points in the field-induced quasi-one-dimensional electronic dispersion, implying that it results from the axial anomaly among these Fermi points. In its original formulation, the anomaly is predicted to violate separate number conservation laws for left- and right-handed chiral- (e.g. Weyl) fermions. Its observation in PdCoO$_2$, PtCoO$_2$ and Sr$_2$RuO$_4$ suggests that the anomaly affects the transport of clean conductors, particularly near the quantum limit.

cond-mat.mes-hall↗

arXiv2015

Temperature - Pressure phase diagram of the cubic Laves phase Au$_2$Pb

The temperature ($T$) as a function of pressure ($P$) phase diagram is reported for the cubic Laves phase compound Au$_2$Pb, which was recently proposed to support linearly dispersing "topological" bands, together with conventional quadratic bands. At ambient pressure, Au$_2$Pb exhibits several structural phase transitions at $T_1$ $=$ 97 K, $T_2$ $=$ 51 K, and $T_3$ $=$ 40 K with superconductivity below $T_{\rm{c}}$ $=$ 1.2 K. Applied pressure results in a rich phase diagram where $T_1$, $T_2$, and $T_3$ evolve strongly with $P$ and a new phase is stabilized for $P$ $>$ 0.64 GPa that also supports superconductivity below 1.1 K. These observations suggest that Au$_2$Pb is an ideal system in which to investigate the relationship between structural degrees of freedom, band topology, and resulting anomalous behaviors.

cond-mat.mtrl-sci↗

arXiv2015

Role of spin-orbit coupling and evolution of the electronic structure of WTe$_2$ under an external magnetic field

Here, we present a detailed study on the temperature and angular dependence of the Shubnikov-de-Haas (SdH) effect in the semi-metal WTe$_2$. This compound was recently shown to display a very large non-saturating magnetoresistance which was attributed to nearly perfectly compensated densities of electrons and holes. We observe four fundamental SdH frequencies and attribute them to spin-orbit split, electron- and hole-like, Fermi surface (FS) cross-sectional areas. Their angular dependence seems consistent with ellipsoidal FSs with volumes suggesting a modest excess in the density of electrons with respect to that of the holes. We show that density functional theory (DFT) calculations fail to correctly describe the FSs of WTe$_2$. When their cross-sectional areas are adjusted to reflect the experimental data, the resulting volumes of the electron/hole FSs obtained from the DFT calculations would imply a pronounced imbalance between the densities of electrons and holes. We find evidence for field-dependent Fermi surface cross-sectional areas by fitting the oscillatory component superimposed onto the magnetoresistivity signal to several Lifshitz-Kosevich components. We also observe a pronounced field-induced renormalization of the effective masses. Taken together, our observations suggest that the electronic structure of WTe$_2$ evolves with the magnetic field. This evolution might be a factor contributing to its pronounced magnetoresistivity.

cond-mat.mtrl-sci↗

arXiv2015

Unconventional Fermi surface in an insulating state

Insulators occur in more than one guise, a recent finding was a class of topological insulators, which host a conducting surface juxtaposed with an insulating bulk. Here we report the observation of an unusual insulating state with an electrically insulating bulk that simultaneously yields bulk quantum oscillations with characteristics of an unconventional Fermi liquid. We present quantum oscillation measurements of magnetic torque in high purity single crystals of the Kondo insulator SmB6, which reveal quantum oscillation frequencies characteristic of a large three-dimensional conduction electron Fermi surface similar to the metallic rare earth hexaborides such as PrB6 and LaB6. The quantum oscillation amplitude strongly increases at low temperatures, appearing strikingly at variance with conventional metallic behaviour.

cond-mat.str-el↗

arXiv2015

Spectroscopic evidence for two-gap superconductivity in the quasi-one dimensional chalcogenide Nb$_{2}$Pd$_{0.81}$S$_{5}$

We present the first direct evidence for two-band superconductivity in the quasi-one dimensional chalcogenide Nb$_{2}$Pd$_{0.81}$S$_{5}$. Soft point contact spectroscopic measurements reveal Andreev reflection in the differential conductance $G$ in the zero-resistance superconducting (SC) state below $T_c$(=6.6~K). Multiple peaks in $G$ were clearly observed at 1.8~K and were successfully explained by the two-band Blonder-Tinkham-Klapwijk model with two gaps $Δ_{1}=0.48$~meV and $Δ_{2}=1.05$~meV. Their evolution in temperature and magnetic field is consistent with the conventional BCS theory. The SC gap to $T_c$ ratio for $Δ_1$ and $Δ_2$ is 1.7 and 3.7, which is similar to the weak coupling BCS prediction of 3.5. These results demonstrate that the newly discovered niobium chalcogenide is a two-gap superconductor in the weak coupling limit.

cond-mat.supr-con↗

arXiv2015

Hall and field-effect mobilities in few layered $p$-WSe$_2$ field-effect transistors

Here, we present a temperature ($T$) dependent comparison between field-effect and Hall mobilities in field-effect transistors based on few-layered WSe$_2$ exfoliated onto SiO$_2$. Without dielectric engineering and beyond a $T$-dependent threshold gate-voltage, we observe maximum hole mobilities approaching 350 cm$^2$/Vs at $T$=300 K. The hole Hall mobility reaches a maximum value of 650 cm$^2$/Vs as $T$ is lowered below $\sim$ 150 K, indicating that insofar WSe$_2$-based field-effect transistors (FETs) display the largest Hall mobilities among the transition metal dichalcogenides. The gate capacitance, as extracted from the Hall-effect, reveals the presence of spurious charges in the channel, while the two-terminal sheet resistivity displays two-dimensional variable-range hopping behavior, indicating carrier localization induced by disorder at the interface between WSe$_2$ and SiO$_2$. We argue that improvements in the fabrication protocols as, for example, the use of a substrate free of dangling bonds are likely to produce WSe$_2$-based FETs displaying higher room temperature mobilities, i.e. approaching those of $p$-doped Si, which would make it a suitable candidate for high performance opto-electronics.

cond-mat.mes-hall↗

arXiv2014

Composite Fermions and Broken Symmetries in Graphene

The electronic properties of graphene are described by a Dirac Hamiltonian with a fourfold symmetry of spin and valley. This symmetry may yield novel fractional quantum Hall (FQH) states at high magnetic field depending on the relative strength of symmetry breaking interactions. However, observing such states in transport remains challenging in graphene, as they are easily destroyed by disorder. In this work, we observe in the first two Landau levels (v<6) the composite-fermion sequences of FQH states at p/(2p+1) between each integer filling factor. In particular, odd numerator fractions appear between v=1 and v=2, suggesting a broken valley symmetry, consistent with our observation of a gap at charge neutrality and zero field. Contrary to our expectations, the evolution of gaps in a parallel magnetic field suggests that states in the first Landau level are not spin-polarized even up to very large out of plane fields.

cond-mat.mes-hall↗

arXiv2014

CeCu_2Ge_2: Challenging our Understanding of Quantum Criticality

Here, we unveil evidence for a quantum phase-transition in CeCu_2Ge_2 which displays both an incommensurate spin-density wave (SDW) ground-state, and a strong renormalization of the quasiparticle effective masses (mu) due to the Kondo-effect. For all angles theta between an external magnetic field (H) and the crystallographic c-axis, the application of H leads to the suppression of the SDW-state through a 2^nd-order phase-transition at a theta-dependent critical-field H_p(theta) leading to the observation of small Fermi surfaces (FSs) in the paramagnetic (PM) state. For H || c-axis, these FSs are characterized by light mu's pointing also to the suppression of the Kondo-effect at H_p with surprisingly, no experimental evidence for quantum-criticality (QC). But as $H$ is rotated towards the a-axis, these mu's increase considerably becoming undetectable for θ> 56^0 between H and the c-axis. Around H_p^a~ 30 T the resistivity becomes proportional T which, coupled to the divergence of mu, indicates the existence of a field-induced QC-point at H_p^a(T=0 K). This observation, suggesting FS hot-spots associated with the SDW nesting-vector, is at odds with current QC scenarios for which the continuous suppression of all relevant energy scales at H_p(theta,T) should lead to a line of quantum-critical points in the H-theta plane. Finally, we show that the complexity of its magnetic phase-diagram(s) makes CeCu_2Ge_2 an ideal system to explore field-induced quantum tricritical and QC end-points.

cond-mat.str-el↗

arXiv2014

Quantum Oscillations in EuFe2As2 single crystals

Quantum oscillation measurements can provide important information about the Fermi surface (FS) properties of strongly correlated metals. Here, we report a Shubnikov-de Haas (SdH) effect study on the pnictide parent compounds EuFe$_{2}$As$_{2}$ (Eu122) and BaFe$_{2}$As$_{2}$ (Ba122) grown by In-flux. Although both members are isovalent compounds with approximately the same density of states at the Fermi level, our results reveal subtle changes in their fermiology. Eu122 displays a complex pattern in the Fourier spectrum, with band splitting, magnetic breakdown orbits, and effective masses sistematically larger when compared to Ba122, indicating that the former is a more correlated metal. Moreover, the observed pockets in Eu122 are more isotropic and 3D-like, suggesting an equal contribution from the Fe $3d$ orbitals to the FS. We speculate that these FS changes may be responsible for the higher spin-density wave ordering temperature in Eu122.

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