arXiv subjects

L. H. Coudert

Publications and source records attributed to L. H. Coudert.

4 recordsLinked to original sources

arXiv2026

Searching for the elusive CH2+ with the James Webb Space Telescope. Another carbocation to constrain astrochemical networks

Carbocations are key species in interstellar chemistry, providing entry points for building larger hydrocarbons. CH+, and more recently, CH3+, have been detected. Other carbocations await detection to provide a comprehensive view of the astrochemical network that is at work in the interstellar medium. We search for CH2+ in objects in which CH3+ was detected and evaluate the most favorable conditions for detecting the elusive CH2+ reactive cation. We calculated the CH2+ rotational and rovibrational transitions expected to contribute in the mid- to far-infrared, focusing on the lower-energy rovibrational levels. We then calculated CH2+ infrared emission spectra at different excitation temperatures and compared them to JWST spectra of the externally irradiated disk d203-506 in Orion, where CH+ and CH3+ have already been detected. We used thermochemical models to predict the abundance and spatial morphology of CH2+ to better understand its nondetection. The comparison to JWST spectra allowed us to provide excitation-temperature-dependent upper limits to the excited column density. These are several times lower than those detected for CH+ and CH3+ in their excited states. Based on model calculations for photodissociation regions and assuming similar excitation temperatures, the upper limit derived from observations and CH2+ model spectrum is either slightly above or below the column density expected from models of photodissociation regions. We provide a list of tabulated transitions to allow the community to search for this carbocation in future observations as CH2+ is key in providing observational constraints on astrochemical models.

astro-ph.GA↗

arXiv2025

High deuteration of methanol in L1544

Isotopic fractionation is a very powerful tool to follow the evolution of material from one stage to the next in the star-formation process. Pre-stellar cores exhibit some of the highest levels of deuteration because their physical conditions greatly favor deuteration processes. Deuteration maps are a measure of the effectiveness of the deuteration across the core, and they are useful to study both the deuteration as well as the formation mechanism of the main species. Methanol is the simplest O-bearing complex organic molecule (COM) detected in the interstellar medium (ISM). It represents the beginning of molecular complexity in star-forming regions, thus a complete understanding of its formation and deuteration is a necessary step to understand the development of further chemical complexity. In this paper, we use single-dish observations with the IRAM 30 m telescope and state-of-the-art chemical models to investigate the deuteration of methanol towards the prototypical pre-stellar core L1544. We also compare the results of the chemical models with previous observations of deuterated methanol towards the pre-stellar cores HMM1 and L694-2. The spectra extracted from the CHD$_2$OH map show that the emission is concentrated in the center and towards the north-west of the core. Using deep observations towards the dust and the methanol peaks of the core, we derive a very large deuterium fraction for methanol ($\sim20\%$) towards both peaks. The comparison of our observational results with chemical models has highlighted the importance of H-abstraction processes in the formation and deuteration of methanol. Deep observations combined with state-of-the-art chemical models are of fundamental importance in understanding the development of molecular complexity in the ISM. Our analysis also shows the importance of non-LTE effects when measuring the D/H ratios in methanol.

astro-ph.GA↗

arXiv2023

Millimetre and sub-millimetre spectroscopy of doubly deuterated acetaldehyde (CHD2CHO) and first detection towards IRAS 16293-2422

The abundances of deuterated molecules with respect to their main isotopologue counterparts have been determined to be orders of magnitude higher than expected from the cosmic abundance of deuterium relative to hydrogen. The increasing number of singly and multi-deuterated species detections helps us to constrain the interplay between gas-phase and solid-state chemistry and to understand better deuterium fractionation in the early stages of star formation. Acetaldehyde is one of the most abundant complex organic molecules (COMs) in star-forming regions and its singly deuterated isotopologues have already been observed towards protostars. A spectroscopic catalogue for astrophysical purposes is built for doubly deuterated acetaldehyde CHD2CHO from measurements in the laboratory. Submillimetre wave transitions were measured for the non-rigid doubly deuterated acetaldehyde CHD2CHO displaying hindered internal rotation of its asymmetrical CHD2 methyl group. A line position analysis is carried out allowing us to reproduce 853 transition frequencies with a weighted root mean square standard deviation of 1.7, varying 40 spectroscopic constants. A spectroscopic catalogue for astrophysical purposes is built from the analysis results. Using this catalogue we were able to detect for the first time CHD2CHO towards the low-mass protostellar system IRAS 16293-2422 utilizing data from the ALMA Protostellar Interferometric Line Survey. The first detection of the CHD2CHO species allows for the derivation of its column density with a value of 1.3x10^15 cm^-2 and an uncertainty of 10-20%. The resulting D2/D ratio of ~20% is found to be coincident with D2/D ratios derived for other complex organic molecules towards IRAS~16293-2422, pointing at a common formation environment with enhanced deuterium fractionation.

astro-ph.GA↗

arXiv2016

The NH$_2$D hyperfine structure revealed by astrophysical observations

The 1$_{11}$-1$_{01}$ lines of ortho and para--NH$_2$D (o/p-NH$_2$D), respectively at 86 and 110 GHz, are commonly observed to provide constraints on the deuterium fractionation in the interstellar medium. In cold regions, the hyperfine structure due to the nitrogen ($^{14}$N) nucleus is resolved. To date, this splitting is the only one which is taken into account in the NH$_2$D column density estimates. We investigate how the inclusion of the hyperfine splitting caused by the deuterium (D) nucleus affects the analysis of the rotational lines of NH$_2$D. We present 30m IRAM observations of the above mentioned lines, as well as APEX o/p-NH$_2$D observations of the 1$_{01}$-0$_{00}$ lines at 333 GHz. The hyperfine spectra are first analyzed with a line list that only includes the hyperfine splitting due to the $^{14}$N nucleus. We find inconsistencies between the line widths of the 1$_{01}$-0$_{00}$ and 1$_{11}$-1$_{01}$ lines, the latter being larger by a factor of $\sim$1.6$\pm0.3$. Such a large difference is unexpected given the two sets of lines are likely to originate from the same region. We next employ a newly computed line list for the o/p-NH$_2$D transitions, where the hyperfine structure induced by both nitrogen and deuterium nuclei is included. With this new line list, the analysis of the previous spectra leads to linewidths which are compatible. Neglecting the hyperfine structure owing to D leads to overestimate the linewidths of the o/p-NH$_2$D lines at 3 mm. The error for a cold molecular core is about 50\%. This error propagates directly to the column density estimate. It is therefore recommended to take into account the hyperfine splittings caused by both the $^{14}$N and D nuclei in any analysis relying on these lines.

astro-ph.GA↗