arXiv subjects

L. Harnagea

Publications and source records attributed to L. Harnagea.

At least 19 recordsLinked to original sources

arXiv2025

Point-contact enhanced superconductivity in trigonal PtBi2: quest for the origin of high-Tc

We studied enhanced superconductivity in point contacts (PCs) based on a type-I Weyl semimetal trigonal t-PtBi2 using both normal metal (Ag, Cu, Pt) and ferromagnetic (Fe, Co, Ni) tips by measuring the differential resistance dV/dI(V) curves. In most cases, the value of the superconducting critical temperature Tc ranges between 3 and 5 K, which is several times higher than the maximum bulk Tc. Notably, among the various PCs we examined, a few achieved Tc values as high as 8 K, including those with both normal and ferromagnetic tips. Additionally, the critical magnetic field is also highly enhanced in these PCs and reaches up to several Tesla. The common reason for the Tc increase may be related to pressure/strain caused during the PC's formation. It is worth noting that a greater increase in Tc is observed in PCs formed at the edge of the sample flake, compared to those formed on the plane of the platelet. The results also reveal that the enhancement of Tc in PCs based on t-PtBi2 is compatible with ferromagnetic tip, which may suggest a potentially complex nature of enhanced superconductivity. Our findings besides suggest that t-PtBi2 is a promising candidate for realizing topological superconductivity at more accessible temperatures.

cond-mat.supr-con↗

arXiv2025

Observation of resistive switching and diode effect in the conductivity of TiTe2 point contacts

We measured the I(V) and dV/dI(V) characteristics of TiTe2-based point contacts (PCs) from room to helium temperatures. Features indicating the emergence of a charge density wave (CDW) were detected. They represent symmetrical relatively V=0 maxima in dV/dI(V) around 150 mV at liquid helium temperatures, which disappear above 150 K, similar to the case of sister CDW compound TiSe2. Applying higher voltages above 200 mV, we observed resistive switching in TiTe2 PCs from a metallic-like low-resistance state to non-metallic type high-resistance state with a change of resistance by an order of magnitude. A unique diode-like effect was registered in "soft" TiTe2 PCs with hysteretic I(V) at negative voltage on TiTe2. Discovering the resistive switching and diode effect adds TiTe2 to the transition-metal dichalcogenides, which could be useful in developing non-volatile ReRAM and other upcoming nanotechnologies.

cond-mat.mes-hall↗

arXiv2024

Electron-phonon interaction, magnetic phase transition, charge density waves and resistive switching in VS2 and VSe2 revealed by Yanson point contact spectroscopy

VS2 and VSe2 have attracted particular attention among the transition metals dichalcogenides because of their promising physical properties concerning magnetic ordering, charge density wave (CDW), emergent superconductivity, etc., which are very sensitive to stoichiometry and dimensionality reduction. Yanson point contact (PC) spectroscopic study reveals metallic and nonmetallic states in VS2 PCs, as well as a magnetic phase transition was detected below 25 K. Analysis of PC spectra of VS2 testifies the realization of the thermal regime in PCs. At the same time, rare PC spectra, where the magnetic phase transition was not visible, shows a broad maximum of around 20 mV, likely connected with electron-phonon interaction (EPI). On the other hand, PC spectra of VSe2 demonstrate metallic behavior, which allowed us to detect features associated with EPI and CDW transition. The Kondo effect appeared for both compounds, apparently due to interlayer vanadium ions. Besides, the resistive switching was observed in PCs on VSe2 between a low resistive, mainly metallic-type state, and a high resistive nonmetallic-type state by applying bias voltage (about 0.4V). In contrast, reverse switching occurs by applying a voltage of opposite polarity (about 0.4V). The reason may be the alteration of stoichiometry in the PC core due to the displacement of V ions to interlayer under a high electric field. The observed resistive switching characterize VSe2 as a potential material, e.g., for non-volatile resistive RAM, neuromorphic engineering, and for other nanoelectronic applications. At the same time, VSe2 attracts attention as a rare layered van der Waals compound with magnetic transition.

cond-mat.mes-hall↗

arXiv2019

Pressure-induced suppression of charge density wave and emergence of Superconductivity in 1T-VSe2

We report pressure evolution of charge density wave (CDW) order and emergence of superconductivity (SC) in 1T-VSe2 single crystal by studying resistance and magnetoresistance behavior under high pressure. With increasing quasi-hydrostatic pressure the CDW order enhances with increase ofthe ordering temperature up to 240K at 12 GPa. Upon further increase of pressure, the resistance anomaly due to CDW order gets suppressed drastically and superconductivity emerges at ~15 GPa, with the onset critical temperature (Tc) ~ 4K. The pressure dependence of Tc is found negligible, different from the significant increase or a dome-shape seen in iso-structural layered diselenide superconductors. The high pressure magnetoresistance and Hall measurements suggest successive electronic structural changes with Fermi surface modifications at 6 GPa and 12GPa. From the observed negative magnetoresistance in this pressure range and absence of coexisting CDW and SC phases, we propose that intra-layer spin-fluctuation can play a role in the emergence of superconductivity in the high pressure phase.

cond-mat.str-el↗

arXiv2018

Superconductivity-induced nematicity

The role of nematic order for the mechanism of high-temperature superconductivity is highly debated. In most iron-based superconductors (IBS) the tetragonal symmetry is broken already in the normal state, resulting in orthorhombic lattice distortions, static stripe magnetic order, or both. Superconductivity then emerges, at least at weak doping, already from the state with broken $C_4$ rotational symmetry. One of the few stoichiometric IBS, lithium iron arsenide, superconducts below 18 K and does not display either structural or magnetic transition in the normal state. Here we demonstrate, using angle-resolved photoemission, that even superconducting state in LiFeAs is also a nematic one. We observe spontaneous breaking of the rotational symmetry in the gap amplitude on all Fermi surfaces, as well as unidirectional distortion of the Fermi pockets. Remarkably, these deformations disappear above superconducting $T_c$. Our results demonstrate the realization of a novel phenomenon of superconductivity-induced nematicity in IBS, emphasizing the intimate relation between them. We suggest a theoretical explanation based on the emergence of a secondary instability inside the superconducting state, which leads to the nematic order and s-d mixing in the gap function.

cond-mat.supr-con↗

arXiv2014

Lower critical field and SNS-Andreev spectroscopy of 122-arsenides: Evidence of nodeless superconducting gap

Using two experimental techniques, we studied single crystals of the 122-FeAs family with almost the same critical temperature, Tc. We investigated the temperature dependence of the lower critical field of a single crystal under static magnetic fields parallel to the axis. The temperature dependence of the London penetration depth can be described equally well either by a single anisotropic -wave-like gap or by a two-gap model, while a d-wave approach cannot be used to fit the London penetration depth data. Intrinsic multiple Andreev reflection effect spectroscopy was used to detect bulk gap values in single crystals of the intimate compound, with the same Tc. We estimated the range of the large gap value 6-8 meV (depending on small variation of and its a space anisotropy of about 30%, and the small gap 1.7 meV. This clearly indicates that the gap structure of our investigated systems more likely corresponds to a nodeless s-wave two gaps.

cond-mat.supr-con↗

arXiv2014

Incommensurate antiferromagnetic fluctuations in single-crystalline LiFeAs studied by inelastic neutron scattering

We present an inelastic neutron scattering study on single-crystalline LiFeAs devoted to the characterization of the incommensurate antiferromagnetic fluctuations at $\mathbf{Q}=(0.5\pmδ, 0.5\mpδ, q_l)$. Time-of-flight measurements show the presence of these magnetic fluctuations up to an energy transfer of 60 meV, while polarized neutrons in combination with longitudinal polarization analysis on a triple-axis spectrometer prove the pure magnetic origin of this signal. The normalization of the magnetic scattering to an absolute scale yields that magnetic fluctuations in LiFeAs are by a factor eight weaker than the resonance signal in nearly optimally Co-doped BaFe$_2$As$_2$, although a factor two is recovered due to the split peaks owing to the incommensurability. The longitudinal polarization analysis indicates weak spin space anisotropy with slightly stronger out-of-plane component between 6 and 12 meV. Furthermore, our data suggest a fine structure of the magnetic signal most likely arising from superposing nesting vectors.

cond-mat.supr-con↗

arXiv2014

Phonon Anomalies, Orbital-Ordering and Electronic Raman Scattering in iron-pnictide Ca(Fe0.97Co0.03)2As2: Temperature-dependent Raman Study

We report inelastic light scattering studies on Ca(Fe0.97Co0.03)2As2 in a wide spectral range of 120-5200 cm-1 from 5K to 300K, covering the tetragonal to orthorhombic structural transition as well as magnetic transition at Tsm ~ 160K. The mode frequencies of two first-order Raman modes B1g and Eg, both involving displacement of Fe atoms, show sharp increase below Tsm. Concomitantly, the linewidths of all the first-order Raman modes show anomalous broadening below Tsm, attributed to strong spin-phonon coupling. The high frequency modes observed between 400-1200 cm-1 are attributed to the electronic Raman scattering involving the crystal field levels of d-orbitals of Fe2+. The splitting between xz and yz d-orbital levels is shown to be ~ 25 meV which increases as temperature decreases below Tsm. A broad Raman band observed at ~ 3200 cm-1 is assigned to two-magnon excitation of the itinerant Fe 3d antiferromagnet.

cond-mat.supr-con↗

arXiv2014

Signatures of superconducting and pseudogap phases in ultrafast transient reflectivity of Ca(Fe0.927Co0.073)2As2

We present femtosecond time-resolved pump-probe spectroscopic studies of a pseudogap (PG) along with the superconducting (SC) gap in an overdoped iron pnictide Ca(Fe0.927Co0.073)2As2. It is seen that the temperature evolution of the photoexcited quasiparticle (QP) relaxation dynamics, coherently excited A1g-symmetric optical phonon and two acoustic phonon dynamics behave anomalously in the vicinity of the superconducting transition temperature Tc. A continuous change in the sign of the experimentally measured transient differential reflectivity Delta_R/R signal at the zero time-delay between the pump and probe pulses at a temperature of ~200 K is inferred as an evidence of the emergence of the PG phase around that temperature. This behavior is independent of the pump photon energy and occurs for crystals without the spin density wave phase transition.

cond-mat.supr-con↗

arXiv2013

Specific heat of Ca$_{0.32}$Na$_{0.68}$Fe$_2$As$_2$ single crystals: unconventional s$_\pm$ multi-band superconductivity with intermediate repulsive interband coupling and sizable attractive intraband couplings

We report a low-temperature specific heat study of high-quality single crystals of the heavily hole doped superconductor Ca$_{0.32}$Na$_{0.68}$Fe$_2$As$_2$. This compound exhibits bulk superconductivity with a transition temperature $T_c \approx 34$\,K, which is evident from the magnetization, transport, and specific heat measurements. The zero field data manifests a significant electronic specific heat in the normal state with a Sommerfeld coefficient $γ\approx 53$ mJ/mol K$^{2}$. Using a multi-band Eliashberg analysis, we demonstrate that the dependence of the zero field specific heat in the superconducting state is well described by a three-band model with an unconventional s$_\pm$ pairing symmetry and gap magnitudes $Δ_i$ of approximately 2.35, 7.48, and -7.50 meV. Our analysis indicates a non-negligible attractive intraband coupling,which contributes significantly to the relatively high value of $T_c$. The Fermi surface averaged repulsive and attractive coupling strengths are of comparable size and outside the strong coupling limit frequently adopted for describing high-$T_c$ iron pnictide superconductors. We further infer a total mass renormalization of the order of five, including the effects of correlations and electron-boson interactions.

cond-mat.supr-con↗

arXiv2013

Unusual band renormalization in the simplest iron based superconductor

The electronic structure of the iron chalcogenide superconductor FeSe_{1-x} was investigated by high- resolution angle-resolved photoemission spectroscopy (ARPES). The results were compared to DFT calculations showing some significant differences between the experimental electronic structure of FeSe_{1-x}, DFT calculations and existing data on FeSe_{x}Te_{1-x}. The bands undergo a pronounced orbital dependent renormalization, different from what was observed for FeSe_{x}Te_{1-x} and any other pnictides.

cond-mat.supr-con↗

arXiv2013

Anomalous superconducting state in LiFeAs implied by the $^{75}$As Knight shift measurement

$^{75}$As NMR investigation of a single crystal of superconducting LiFeAs is presented. The Knight shift and the \textit{in situ} ac susceptibility measurements as a function of temperature and external field are indicative of two superconducting (SC) transition temperatures, each of which is associated with its own upper critical field. Strikingly, the Knight shift maintains its normal state value over a temperature range in the SC state before it drops abruptly being consistent with spin-singlet pairing. Together with our previous NMR study, the anomalous SC state featured by the constant Knight shift is attributed to the extremely sensitive SC properties of LiFeAs, probably stemming from its proximity to a critical instability.

cond-mat.supr-con↗

arXiv2013

Ultrafast quasiparticle dynamics in superconducting iron pnictide CaFe1.89Co0.11As2

Nonequilibrium quasiparticle relaxation dynamics is reported in superconducting CaFe1.89Co0.11As2 single crystal using femtosecond time-resolved pump-probe spectroscopy. The carrier dynamics reflects a three-channel decay of laser deposited energy with characteristic time scales varying from few hundreds of femtoseconds to order of few nanoseconds where the amplitudes and time-constants of the individual electronic relaxation components show significant changes in the vicinity of the spin density wave (T_SDW ~ 85 K) and superconducting (T_SC ~ 20 K) phase transition temperatures. The quasiparticles dynamics in the superconducting state reveals a charge gap with reduced gap value of 2$Δ$_0/k_BT_SC ~ 1.8. We have determined the electron-phonon coupling constant $\lemda$ to be ~ 0.14 from the temperature dependent relaxation time in the normal state, a value close to those reported for other types of pnictides. From the peculiar temperature-dependence of the carrier dynamics in the intermediate temperature region between the superconducting and spin density wave phase transitions, we infer a temperature scale where the charge gap associated with the spin ordered phase is maximum and closes on either side while approaching the two phase transition temperatures.

cond-mat.str-el↗

arXiv2013

Gap-dependent quasiparticle dynamics and coherent acoustic phonons in parent iron pnictide CaFe2As2 across the spin density wave phase transition

We report ultrafast quasiparticle (QP) dynamics and coherent acoustic phonons in undoped CaFe_2As_2 iron pnictide single crystals exhibiting spin-density wave (SDW) and concurrent structural phase transition at temperature TSDW ~ 165 K using femtosecond time-resolved pump-probe spectroscopy. The contributions in transient differential reflectivity arising from exponentially decaying QP relaxation and oscillatory coherent acoustic phonon mode show large variations in the vicinity of T_SDW. From the temperature-dependence of the QP recombination dynamics in the SDW phase, we evaluate a BCS-like temperature dependent charge gap with its zero-temperature value of ~(1.6+/-0.2)k_BT_SDW, whereas, much above T_SDW, an electron-phonon coupling constant of ~0.13 has been estimated from the linear temperature-dependence of the QP relaxation time. The long-wavelength coherent acoustic phonons with typical time-period of ~100 ps have been analyzed in the light of propagating strain pulse model providing important results for the optical constants, sounds velocity and the elastic modulus of the crystal in the whole temperature range of 3 K to 300 K.

cond-mat.str-el↗

arXiv2012

Electronic band structure and momentum dependence of the superconducting gap in (Ca, Na)Fe2As2 from angle-resolved photoemission spectroscopy

Electronic structure of newly synthesized single crystals of calcium iron arsenide doped with sodium with Tc ranging from 33 to 14 K has been determined by angle-resolved photoemission spectroscopy (ARPES). The measured band dispersion is in general agreement with theoretical calculations, nonetheless implies absence of Fermi surface nesting at antiferromagnetic vector. A clearly developing below Tc strongly band-dependant superconducting gap has been revealed for samples with various doping levels. BCS ratio for optimal doping, $2Δ/k_{\rm B}T_{\rm c}=5.5$, is substantially smaller than the numbers reported for related compounds, implying a non-trivial relation between electronic dispersion and superconducting gap in iron arsenides.

cond-mat.supr-con↗

arXiv2012

Observation of charge accumulation and onsite Coulomb repulsion at transition metal impurities in the iron pnictides

We report a combined valence band photoemission and Auger spectroscopy study of single crystalline Ca(Fe,Co)2As2 and Ba(Fe,TM)2As2 with TM=Ni or Cu. The valence band photoemission data show directly that the TM-states move to higher binding energies with increasing atomic number, contributing less and less to the states close to the Fermi level. Furthermore, the 3d8 final state of the LVV Auger decay, which is observed for Ni and Cu, unambiguously reveals the accumulation of charge at these impurities. We also show that the onsite Coulomb interaction on the impurity strongly increases when moving from Co over Ni to Cu. Our results quantify the impurity potentials and imply that the superconducting state is robust against impurity scattering.

cond-mat.supr-con↗

arXiv2012

Acoustic and optical phonon dynamics from femtosecond time-resolved optical spectroscopy of superconducting iron pnictide Ca(Fe_0.944Co_0.056)_2As_2

We report temperature evolution of coherently excited acoustic and optical phonon dynamics in superconducting iron pnictide single crystal Ca(Fe_0.944Co_0.056)_2As_2 across the spin density wave transition at T_SDW ~ 85 K and superconducting transition at T_SC ~20 K. Strain pulse propagation model applied to the generation of the acoustic phonons yields the temperature dependence of the optical constants, and longitudinal and transverse sound velocities in the temperature range of 3.1 K to 300 K. The frequency and dephasing times of the phonons show anomalous temperature dependence below T_SC indicating a coupling of these low energy excitations with the Cooper-pair quasiparticles. A maximum in the amplitude of the acoustic modes at T ~ 170 is seen, attributed to spin fluctuations and strong spin-lattice coupling before T_SDW.

cond-mat.str-el↗

arXiv2012

Probing the role of Co substitution in the electronic structure of iron-pnictides

The role of Co substitution in the low-energy electronic structure of Ca(Fe$_{0.944}$Co$_{0.056}$)$_2$As$_2$ is investigated by resonant photoemission spectroscopy and density functional theory. The Co 3d-state center-of-mass is observed at 250 meV higher binding energy than Fe's, indicating that Co posses one extra valence electron, and that Fe and Co are in the same 2+ oxidation state. Yet, significant Co character is detected for the Bloch wavefunctions at the chemical potential, revealing that the Co 3d electrons are part of the Fermi sea determining the Fermi surface. This establishes the complex role of Co substitution in CaFe2As2, and the inadequacy of a rigid-band shift description.

cond-mat.supr-con↗