arXiv subjects

L. Ilsedore Cleeves

Publications and source records attributed to L. Ilsedore Cleeves.

At least 37 records · Page 2Linked to original sources

arXiv2025

The Multiband Imaging Survey for High-Alpha PlanetS (MISHAPS) I: Preliminary Constraints on the Occurrence Rate of Hot Jupiters in 47 Tucanae

The first generation of transiting planet searches in globular clusters yielded no detections, and in hindsight, only placed occurrence rate limits slightly higher than the measured occurrence rate in the higher-metallicity Galactic thick disk. To improve these limits, we present the first results of a new wide field search for transiting hot Jupiters in the globular cluster 47~Tucanae. We have observed 47~Tuc as part of the Multiband Imaging Survey for High-Alpha Planets (MISHAPS). Using 24 partial and full nights of observations taken with the Dark Energy Camera on the 4-m Blanco telescope at CTIO, we perform a search on 19,930 stars in the outer regions of the cluster. Though we find no clear planet detections, by combining our result with the upper limit enabled by Gilliland et al.'s 2000 Hubble search for planets around an independent sample of 34,091 stars in the inner cluster, we place the strongest limit to date on hot Jupiters with periods of $0.8 \leq P \leq 8.3$ days and $0.5~R_{\rm Jup} \leq R_{\rm P} \leq 2.0~R_{\rm Jup}$ of $f_{\rm HJ} < 0.11\%$, a factor of ${\sim}$4 below the occurrence rate in the \textit{Kepler} field. Our search found 35 transiting planet candidates, though we are ultimately able to rule out each without follow-up observations. We also found 4 eclipsing binaries, including 3 previously-uncataloged detached eclipsing binary stars.

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arXiv2025

A Multi-line Analysis of the Distribution and Excitation of CS and H$_2$CS in the HD 163296 Disk

The abundance and distribution of sulfur-bearing molecules in protoplanetary disks directly influences the composition and potential habitability of nascent planets in addition to providing powerful probes of the physical gas conditions in the disks themselves. Here, we present new and archival ALMA and SMA observations of CS and H$_2$CS, and their C$^{34}$S and H$_2$C$^{34}$S isotopologues, at high-angular resolution (${\approx}$0."2-0."4; 20-40 au) in the HD 163296 disk, which reveal a central cavity and multi-ringed emission structure. These observations comprise the most comprehensive, multi-line CS data in a planet-forming disk to date, spanning a wide range of excitation conditions from E$_{\rm{u}}$=7.1 K to 129.3 K, and include new detections of C$^{34}$S, H$_2$CS, and H$_2$C$^{34}$S in this system. Using these data, we derive spatially-resolved rotational temperature and column density profiles for all species. We find a column density ratio N(H$_2$CS)/N(CS) $\approx$ 0.5, which is comparable to that of the similar MWC 480 disk and suggests that organic sulfur compounds may constitute a large fraction of the volatile sulfur reservoir in disks around Herbig stars generally. We derive $^{32}$S/$^{34}$S ratios of ${\approx}$5 (CS/C$^{34}$S) and ${\approx}$2 (H$_2$CS/H$_2$C$^{34}$S) based on disk-averaged and spatially-resolved analyses. Both values are consistent across these two pairs of optically-thin molecules and are well-below the expected ISM ratio of ${\approx}$22, suggesting significant sulfur fractionation. We also constrain the CS emitting layer ($z/r\lesssim 0.1$) using the vertical separations of the disk surfaces in the channel maps and based on the known 2D gas structure of the HD 163296 disk combined with our excitation analysis.

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arXiv2025

Discovery of Radio Recombination Lines from Proplyds in the Orion Nebula Cluster

We present new Atacama Large Millimeter/submillimeter Array observations that, for the first time, detect hydrogen and helium radio recombination lines from a protoplanetary disk. We imaged the Orion Nebula Cluster at 3.1 mm with a spectral setup that covered the $n=42 \rightarrow 41$ transitions of hydrogen (H41$α$) and helium (He41$α$). The unprecedented sensitivity of these observations enables us to search for radio recombination lines toward the positions of ${\sim}200$ protoplanetary disks. We detect H41$α$ from 17 disks, all of which are HST-identified `proplyds.' The detected H41$α$ emission is spatially coincident with the locations of proplyd ionization fronts, indicating that proplyd H41$α$ emission is produced by gas that has been photoevaporated off the disk and ionized by UV radiation from massive stars. We measure the fluxes and widths of the detected H41$α$ lines and find line fluxes of ${\sim}30-800$ mJy km s$^{-1}$ and line widths of ${\sim}30-90$ km s$^{-1}$. The derived line widths indicate that the broadening of proplyd H41$α$ emission is dominated by outflowing gas motions associated with external photoevaporation. The derived line fluxes, when compared with measurements of 3.1 mm free-free flux, imply that the ionization fronts of H41$α$-detected proplyds have electron temperatures of ${\sim}6,000-11,000$ K and electron densities of ${\sim}10^6-10^7$ cm$^{-3}$. Finally, we detect He41$α$ towards one H41$α$-detected source and find evidence that this system is helium-rich. Our study demonstrates that radio recombination lines are readily detectable in ionized photoevaporating disks, providing a new way to measure disk properties in clustered star-forming regions.

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arXiv2025

Water Ice in the Edge-On Orion Silhouette Disk 114--426 from JWST NIRCam Images

We examine images of the protoplanetary disk 114--426 with JWST/NIRCam in 12 bands. This large disk is oriented edge-on with a dark midplane flanked by lobes of scattered light. The outer edges of the midplane are seen in silhouette against the Orion Nebula, providing a unique opportunity to study planet-forming material in absorption. We discover a dip in the scattered light of the disk at 3\,$\micron$ -- compelling evidence for the presence of water ice. The 3\,$\micron$ dip is also seen in the silhouette of the disk, where we quantify the ice abundance with models of pure absorption and avoid the complications of disk scattering effects. We find grain ice-to-refractory mass ratios of up to $\sim$0.2, maximum grain sizes of 0.25 to 5\,$\micron$, and a total dust plus ice mass of 0.46\,$M_\oplus$ in the silhouette region. We also discover excess absorption in the NIRCam bands that include the Paschen $α$ line, suggesting there may be excited atomic hydrogen in the disk. Examining the morphology of the scattered light lobes reveals that they are laterally offset from each other and exhibit a brightness asymmetry that flips with wavelength -- both evidence for a tilted inner disk in this system.

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arXiv2025

Modeling the Impact of Moderate External UV Irradiation on Disk Chemistry

The chemistry within a protoplanetary disk is greatly affected by external radiation from the local stellar environment. Previous work has focused on extreme radiation fields, representative of the center of something like the Orion Nebula Cluster. However, even in such environments, many disks exist at the edges of a cluster where the lower stellar density leads to radiation fields weaker by orders of magnitude compared to the center. We present new chemical models of a T-Tauri disk in the presence of a moderately increased interstellar radiation field (ISRF). Such an environment has a background UV strength of 10 to 100 times higher than the galactic average ISRF. Moderate radiation fields are among the most prevalent disk-harboring environments and have interesting implications for the chemistry of the outer disk radii. We find that the external UV radiation creates an outer ionization front that impacts the cold disk chemistry to varying degrees, depending on outer disk structure. Certain molecules like C$^+$, N$_2$H$^+$, C, and CS are more strongly impacted by the ISRF in their abundance, column density, and observable emission. Other abundant species like HCO$^+$ and CO are less affected by the external UV flux in the outer disk under such moderate UV conditions. Further, we demonstrate that the chemistry occurring in the inner tens of au is relatively unchanged, which suggests that even in moderately externally irradiated disks, the inner disk chemistry may be more similar to isolated disks like those in, e.g., the Taurus and Lupus star-forming regions.

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arXiv2025

Multi-Observatory Study of Young Stellar Energetic Flares (MORYSEF): No Evidence For Abnormally Strong Stellar Magnetic Fields After Powerful X-ray Flares

We explore the empirical power-law relationship between X-ray luminosity (Lx) and total surface magnetic flux (Phi), established across solar magnetic elements, time- and disk-averaged emission from the Sun, older active stars, and pre-main-sequence (PMS) stars. Previous models of large PMS X-ray flares, lacking direct magnetic field measurements, showed discrepancies from this baseline law, which MHD simulations attribute to unusually strong magnetic fields during flares. To test this, we used nearly simultaneous Chandra X-ray and HET-HPF near-infrared observations of four young Orion stars, measuring surface magnetic fields during or just after powerful PMS X-ray flares. We also modeled these PMS X-ray flares, incorporating their measured magnetic field strengths. Our findings reveal magnetic field strengths at the stellar surface typical of non-flaring PMS stars, ruling out the need for abnormally strong fields during flares. Both PMS and solar flares deviate from the Lx-Phi law, with PMS flares exhibiting a more pronounced deviation, primarily due to their much larger active regions on the surface and larger flaring loop volumes above the surface compared to their solar counterparts. These deviations likely stem from the fact that powerful flares are driven by magnetic reconnection, while baseline X-ray emission may involve less efficient mechanisms like Alfven wave heating. Our results also indicate a preference for dipolar magnetic loops in PMS flares, consistent with Zeeman-Doppler imaging of fully convective stars. This requirement for giant dipolar loops aligns with MHD predictions of strong dipoles supported by polar magnetic surface active regions in fast-rotating, fully convective stars.

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arXiv2024

Water in protoplanetary disks with JWST-MIRI: spectral excitation atlas and radial distribution from temperature diagnostic diagrams and Doppler mapping

This work aims at providing fundamental general tools for the analysis of water spectra as observed in protoplanetary disks with JWST-MIRI. We analyze 25 high-quality spectra from the JDISC Survey reduced with asteroid calibrators as presented in Pontoppidan et al. (2024). First, we present a spectral atlas to illustrate the clustering of H$_2$O transitions from different upper level energies ($E_u$) and identify single (un-blended) transitions that provide the most reliable measurements. With that, we demonstrate two important excitation effects: the opacity saturation of ortho-para line pairs that overlap, and the non-LTE excitation of $v=1-1$ lines scattered across the $v=0-0$ rotational band. Second, we define a shorter list of fundamental lines spanning $E_u=$ 1500-6000 K to develop simple line-ratio diagnostic diagrams for the radial temperature distribution of water in inner disks, which can be interpreted using discrete temperature components or a radial gradient. Third, we report the detection of disk-rotation Doppler broadening of molecular lines, which confirms the radial distribution of water emission including, for the first time, the radially-extended $\approx$ 170-220 K reservoir close to the snowline. The combination of measured line ratios and broadening suggests that drift-dominated disks have shallower temperature gradients with an extended cooler disk surface enriched by ice sublimation. We also report the first detection of a H$_2$O-rich inner disk wind from narrow blue-shifted absorption in the ro-vibrational lines. We summarize these findings and tools into a general recipe to make the study of water in planet-forming regions reliable, effective, and sustainable for samples of $> 100$ disks.

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arXiv2024

A tell-tale tracer for externally irradiated protoplanetary disks: comparing the [CI] 8727 A line and ALMA observations in proplyds

The evolution of protoplanetary disks in regions with massive OB stars is influenced by externally driven winds that deplete the outer parts of disks. These winds have previously been studied via forbidden oxygen emission lines, which also arise in isolated disks in low-mass star forming-regions (SFRs) with weak external UV fields in photoevaporative or magnetic (internal) disk winds. It is crucial to determine how to disentangle external winds from internal ones. Here, we report a proxy for unambiguously identifying externally driven winds with a forbidden line of neutral atomic carbon, [C i] 8727 A. We compare for the first time the spatial location of the emission in the [O i] 5577 A, [O i] 6300 A, and [C i] 8727 A lines traced by VLT/MUSE-NFM, with the ALMA Band 7 continuum disk emission in a sample of 12 proplyds in the Orion Nebula Cluster (ONC). We confirm that the [O i] 5577 A emission is co-spatial with the disk emission, whereas the [O i] 6300 A is emitted both on the disk surface and on the ionization front of the proplyds. We show for the first time that the [C i] 8727 A line is also co-spatial with the disk surface in proplyds, as seen in the MUSE and ALMA data comparison. To verify whether the [C i] 8727 A line is detected in regions where external photoevaporation is not expected, we examine VLT/X-Shooter spectra for young stars in low-mass SFRs. Although the [O i] lines are well detected in all these targets, there is <<10% detection rate in the case of the [C i] 8727 A line. This number increases substantially to a ~40% detection rate in sigma-Orionis, a region with intermediate UV radiation. The spatial location of the [C i] 8727 A line emission and the lack of its detection in isolated disks in low-mass SFRs strongly suggest that this line is a tell-tale tracer of externally driven photoevaporative winds, which agrees with recent excitation models.

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arXiv2024

A Wideband Chemical Survey of Massive Star-forming Regions at Subarcsecond Resolution with the Submillimeter Array

Massive star-forming regions exhibit a rich chemistry with complex gas distributions, especially on small scales. While surveys have yielded constraints on typical gas conditions, they often have coarse spatial resolution and limited bandwidths. Thus, to establish an interpretative framework for these efforts, detailed observations that simultaneously provide high sensitivity, spatial resolution, and large bandwidths for a subset of diverse sources are needed. Here, we present wideband (32 GHz) Submillimeter Array observations of four high-mass star-forming regions (G28.20-0.05, G20.08-0.14 N, G35.58-0.03, W33 Main) at subarcsecond resolution, where we detect and spatially-resolve 100s of lines from over 60 molecules, including many complex organic molecules (COMs). The chemical richness of our sample is consistent with an evolutionary sequence from the line-rich hot cores and HC HII regions of G28.20-0.05 and G20.08-0.14 N to the more chemically-modest UC HII regions in G35.58-0.03, followed by the molecule-poor HII region W33 Main. We detect lines across a range of excitation conditions (Eu=20 to >800 K) and from numerous isotopologues, which enables robust estimates of gas properties. We derive nearly constant COM column density ratios that agree with literature values in other low- and high-mass protostellar cores, supporting the idea that COM abundances are set during the pre-stellar phase. In all regions, we identify spatial offsets among different molecular families, due to a combination of source physical structure and chemistry. In particular, we find potential evidence of carbon grain sublimation in G28.20-0.05 and identify an elemental oxygen gradient and rich sulfur-chemistry in G35.58-0.03. Overall, these results demonstrate that the SMA's wide bandwidth is a powerful tool to untangle the complex molecular gas structures associated with massive star formation.

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arXiv2024

Multi-Observatory Research of Young Stellar Energetic Flares (MORYSEF): X-ray Flare Related Phenomena and Multi-epoch Behavior

The most powerful stellar flares driven by magnetic energy occur during the early pre-main sequence (PMS) phase. The Orion Nebula represents the nearest region populated by young stars, showing the greatest number of flares accessible to a single pointing of Chandra. This study is part of a multi-observatory project to explore stellar surface magnetic fields (with HET-HPF), particle ejections (VLBA), and disk ionization (ALMA) immediately following the detection of PMS super-flares with Chandra. In December 2023, we successfully conducted such a multi-telescope campaign. Additionally, by analyzing Chandra data from 2003, 2012, and 2016, we examine the multi-epoch behavior of PMS X-ray emission related to PMS magnetic cyclic activity and ubiquitous versus sample-confined mega-flaring. Our findings follow. 1) We report detailed stellar quiescent and flare X-ray properties for numerous HET/ALMA/VLBA targets, facilitating ongoing multi-wavelength analyses. 2) For numerous moderately energetic flares, we report correlations (or lack thereof) between flare energies and stellar mass/size (presence/absence of disks) for the first time. The former is attributed to the correlation between convection-driven dynamo and stellar volume, while the latter suggests the operation of solar-type flare mechanisms in PMS stars. 3) We find that most PMS stars exhibit minor long-term baseline variations, indicating the absence of intrinsic magnetic dynamo cycles or observational mitigation of cycles by saturated PMS X-rays. 4) We conclude that X-ray mega-flares are ubiquitous phenomena in PMS stars, which suggests that all protoplanetary disks and nascent planets are subject to violent high-energy emission and particle irradiation events.

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arXiv2024

Variable, circularly polarized radio emission from the Young Stellar Object [BHB2007]-1: another ingredient of a unique system

The young stellar object [BHB2007]-1 has been extensively studied in the past at radio, millimeter, and infrared wavelengths. It shows a gap in the disk and previous observations claimed the possible emission from a forming sub-stellar object, in correspondence to the disk gap. Here, we analyze a set of 8 Karl Jansky Very Large Array (VLA) observations at 15 GHz and spread over a month. We infer a slowly variable emission from the star, with a $\sim 15 \text{-} 20\%$ circular polarization detected in two of the eight observations. The latter can be related to the magnetic fields in the system, while the unpolarized and moderately varying component can be indicative of free-free emission associated with jet induced shocks or interaction of the stellar wind with dense surrounding material. We discard any relevant short flaring activities when sampling the radio light curves down to 10 seconds and find no clear evidence of emission from the sub-stellar object inferred from past observations, although deeper observations could shed further light on this.

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arXiv2024

Exploring the Complex Ionization Environment of the Turbulent DM Tau Disk

Ionization drives important chemical and dynamical processes within protoplanetary disks, including the formation of organics and water in the cold midplane and the transportation of material via accretion and magneto-hydrodynamic (MHD) flows. Understanding these ionization-driven processes is crucial for understanding disk evolution and planet formation. We use new and archival ALMA observations of HCO+, H13CO+, and N2H+ to produce the first forward-modeled 2D ionization constraints for the DM Tau protoplanetary disk. We include ionization from multiple sources and explore the disk chemistry under a range of ionizing conditions. Abundances from our 2D chemical models are post-processed using non-LTE radiative transfer, visibility sampling, and imaging, and are compared directly to the observed radial emission profiles. The observations are best fit by a modestly reduced CR ionization rate ($ζ_{CR}$ ~ 10$^{-18}$ s$^{-1}$) and a hard X-ray spectrum (hardness ratio [HR] = 0.3), which we associate with stellar flaring conditions. Our best-fit model under-produces emission in the inner disk, suggesting that there may be an additional mechanism enhancing ionization in DM Tau's inner disk. Overall, our findings highlight the complexity of ionization in protoplanetary disks and the need for high resolution multi-line studies.

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arXiv2024

Radial and vertical constraints on the icy origin of H$_{2}$CO in the HD 163296 Protoplanetary Disk

H$_2$CO is a small organic molecule widely detected in protoplanetary disks. As a precursor to grain-surface formation of CH$_3$OH, H$_2$CO is considered an important precursor of O-bearing organic molecules that are locked in ices. Still, since gas-phase reactions can also form H$_2$CO, there remains an open question on the channels by which organics form in disks, and how much the grain versus the gas pathways impact the overall organic reservoir. We present spectrally and spatially resolved Atacama Large Millimeter/submillimeter Array observations of several ortho- and para-H$_2$CO transitions toward the bright protoplanetary disk around the Herbig Ae star HD 163296. We derive column density, excitation temperature, and ortho-to-para ratio (OPR) radial profiles for H$_2$CO, as well as disk-averaged values of $N_{\mathrm{T}}\sim4\times 10^{12}$ cm$^{-2}$, $T_{\mathrm{ex}}\sim20$ K, and $\mathrm{OPR}\sim2.7$, respectively. We empirically determine the vertical structure of the emission, finding vertical heights of $z/r\sim0.1$. From the profiles, we find a relatively constant $\mathrm{OPR}\sim2.7$ with radius, but still consistent with $3.0$ among the uncertainties, a secondary increase of $N_{\mathrm{T}}$ in the outer disk, and low $T_{\mathrm{ex}}$ values that decrease with disk radius. Our resulting radial, vertical, and OPR constraints suggest an increased UV penetration beyond the dust millimeter edge, consistent with an icy origin but also with cold gas-phase chemistry. This Herbig disk contrasts previous results for the T Tauri disk, TW Hya, which had a larger contribution from cold gas-phase chemistry. More observations of other sources are needed to disentangle the dominant formation pathway of H$_2$CO in protoplanetary disks.

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arXiv2024

Chemistry in externally FUV irradiated disks in the outskirts of the Orion Nebula

Most stars are born in stellar clusters and their protoplanetary disks, which are the birthplaces of planets, can therefore be affected by the radiation of nearby massive stars. However, little is known about the chemistry of externally irradiated disks, including whether or not their properties are similar to the so-far better-studied isolated disks. Motivated by this question, we present ALMA Band 6 observations of two irradiated Class II protoplanetary disks in the outskirts of the Orion Nebula Cluster (ONC) to explore the chemical composition of disks exposed to (external) FUV radiation fields: the 216-0939 disk and the binary system 253-1536A/B, which are exposed to radiation fields of $10^2-10^3$ times the average interstellar radiation field. We detect lines from CO isotopologues, HCN, H$_2$CO, and C$_2$H toward both protoplanetary disks. Based on the observed disk-integrated line fluxes and flux ratios, we do not find significant differences between isolated and irradiated disks. The observed differences seem to be more closely related to the different stellar masses than to the external radiation field. This suggests that these disks are far enough away from the massive Trapezium stars, that their chemistry is no longer affected by external FUV radiation. Additional observations towards lower-mass disks and disks closer to the massive Trapezium stars are required to elucidate the level of external radiation required to make an impact on the chemistry of planet formation in different kinds of disks.

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arXiv2024

The Carbon Isotopic Ratio and Planet Formation

We present the first detection of 13CCH in a protoplanetary disk (TW Hya). Using observations of C2H we measure CCH/13CCH = 65 +/- 20 in gas with a CO isotopic ratio of 12CO/13CO = 21 +/- 5 (Yoshida et al. 2022a). The TW Hya disk exhibits a gas phase C/O that exceeds unity and C2H is the tracer of this excess carbon. We confirm that the TW Hya gaseous disk exhibits two separate carbon isotopic reservoirs as noted previously (Yoshida et al. 2022a). We explore two theoretical solutions for the development of this dichotomy. One model represents TW Hya today with a protoplanetary disk exposed to a cosmic ray ionization rate that is below interstellar as consistent with current estimates. We find that this model does not have sufficient ionization in cold (T < 40 K) layers to activate carbon isotopic fractionation. The second model investigates a younger TW Hya protostellar disk exposed to an interstellar cosmic ray ionization rate. We find that the younger model has sources of ionization deeper in a colder disk that generates two independent isotopic reservoirs. One reservoir is 12C-enriched carried by methane/hydrocarbon ices and the other is 13C-enriched carried by gaseous CO. The former potentially provides a source of methane/hydrocarbon ices to power the chemistry that generates the anomalously strong C$_2$H emission in this (and other) disk systems in later stages. The latter provides a source of gaseous 13C-rich material to generate isotopic enrichments in forming giant planets as recently detected in the super-Jupiter TYC 8998-760-1 b by Zhang et al. (2021).

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arXiv2024

Molecular Gas Tracers in Young and Old Protoplanetary Disks

Molecular emission is used to investigate both the physical and chemical properties of protoplanetary disks. Therefore, to accurately derive disk properties, we need a thorough understanding of the behavior of the molecular probes we rely on. Here we investigate how the molecular line emission of N$_2$H$^+$, HCO$^+$, HCN, and C$^{18}$O compare to other measured quantities in a set of 20 protoplanetary disks. Overall, we find positive correlations between multiple line fluxes and the disk dust mass and radius. We also generally find strong positive correlations between the line fluxes of different molecular species. However, some disks do show noticeable differences in the relative fluxes of N$_2$H$^+$, HCO$^+$, HCN, and C$^{18}$O. These differences occur even within a single star-forming region. This results in a potentially large range of different disk masses and chemical compositions for systems of similar age and birth environment. While we make preliminary comparisons of molecular fluxes across different star-forming regions, more complete and uniform samples are needed in the future to search for trends with birth environment or age.

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arXiv2024

JWST-MIRI Spectroscopy of Warm Molecular Emission and Variability in the AS 209 Disk

We present MIRI MRS observations of the large, multi-gapped protoplanetary disk around the T-Tauri star AS 209. The observations reveal hundreds of water vapor lines from 4.9 to 25.5 $μ$m towards the inner $\sim1$ au in the disk, including the first detection of ro-vibrational water emission in this disk. The spectrum is dominated by hot ($\sim800$ K) water vapor and OH gas, with only marginal detections of CO$_2$, HCN, and a possible colder water vapor component. Using slab models with a detailed treatment of opacities and line overlap, we retrieve the column density, emitting area, and excitation temperature of water vapor and OH, and provide upper limits for the observable mass of other molecules. Compared to MIRI spectra of other T-Tauri disks, the inner disk of AS 209 does not appear to be atypically depleted in CO$_2$ nor HCN. Based on \textit{Spitzer IRS} observations, we further find evidence for molecular emission variability over a 10-year baseline. Water, OH, and CO$_2$ line luminosities have decreased by factors 2-4 in the new MIRI epoch, yet there are minimal continuum emission variations. The origin of this variability is yet to be understood.

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arXiv2023

Spatially resolving the volatile sulfur abundance in the HD 100546 protoplanetary disk

Volatile elements play a crucial role in the formation of planetary systems. Their abundance and distribution in protoplanetary disks provide vital insights into the connection between formation processes and the atmospheric composition of individual planets. Sulfur, being one of the most abundant elements in planet-forming environments, is of great significance, and now observable in exoplanets with JWST. However, planetary formation models currently lack vital knowledge regarding sulfur chemistry in protoplanetary disks. Developing a deeper understanding of the major volatile sulfur carriers in disks is essential to building models that can meaningfully predict planetary atmospheric composition, and reconstruct planetary formation pathways. In this work, we combine archival observations with new data from ALMA and APEX, covering a range of sulfur-bearing species/isotopologs. We interpret this data using the DALI thermo-chemical code, for which our model is highly refined and disk-specific. We find that volatile sulfur is heavily depleted from the cosmic value by a factor of 1000, with a disk-averaged abundance of S/H = 1e-8. We show that the gas-phase sulfur abundance varies radially by 3 orders of magnitude, with the highest abundances inside the inner dust ring and coincident with the outer dust ring at 150 to 230 au. Extracting chemical abundances from our models, we find OCS, H2CS, and CS to be the dominant molecular carriers in the gas phase. We also infer the presence of a substantial OCS ice reservoir. We relate our results to the potential atmospheric composition of planets in HD 100546, and the wider exoplanet population

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