arXiv subjects

L. Majumdar

Publications and source records attributed to L. Majumdar.

17 recordsLinked to original sources

arXiv2025

Edge-On Disk Study (EODS) II: HCO$^+$ and CO vertical stratification in the disk surrounding SSTTau042021

Context. Edge-on disks offer a unique opportunity to directly examine their vertical structure, providing valuable insights into planet formation processes. We investigate the dust properties, as well as the CO and HCO$^+$ gas properties, in the edge-on disk surrounding the T Tauri star 2MASS J04202144+281349 (SSTTau042021). Aims. We estimate the radial and vertical temperature and density profile for the gas and the dust. Methods. We use ALMA archival data of CO isotopologues and continuum emission at 2, 1.3 and 0.9 mm together with new NOEMA HCO$^+$ 3-2 observations. We retrieve the gas and dust disk properties using the tomographic method and the \textsc{DiskFit} model. Results. The vertical CO emission appears very extended, partly tracing the H$_2$ wind observed by JWST. C$^{18}$O, $^{13}$CO and HCO$^+$ emission characterize the bulk of the molecular layer. The dust and gas have a mid-plane temperatures of $\sim 7-11$ K. The temperature of the molecular layer (derived from $^{13}$CO and HCO$^+$) is on the order of 16 K. HCO$^+$ 3-2 being thermalized, we derive a lower limit for the H$_2$ volume density of $\sim 3 \times 10^6$ cm$^{-3}$ at radius 100-200 au between 1 and 2 scale heights. The atmosphere temperature of the CO gas is of the order $\sim$ 31 K at a radius of 100 au. We directly observe CO and HCO$^+$ gas onto the mid-plane beyond the dust outer radius ($\ge 300$ au). The (gas+dust) disk mass estimated up to a radius of 300 au is on the order of $4.6 \times 10^{-2} \mathrm{M}_\odot$. Conclusions. Thanks to the favorable disk inclination, we present the first quantitative evidence for vertical molecular stratification with direct observation of CO and HCO$^+$ gas along the mid-plane. We estimate the temperature profile with temperature of 7-11 K near the mid-plane, and 15-20 K in the dense part of the molecular layer up to $\sim$ 35 K above.

astro-ph.EP↗

arXiv2025

Edge-On Disk Study (EODS) III: Molecular Stratification in the Flying Saucer Disk

Context: Investigating the vertical distribution of molecular content in protoplanetary disks remains difficult in most disks mildly inclined along the line of sight. In contrast, edge-on disks provide a direct (tomographic) view of the 2D molecular brightness. Aims: We study the radial and vertical molecular distribution as well as the gas temperature and density by observing the Keplerian edge-on disk surrounding the Flying Saucer, a Class II object located in Ophiuchus. Methods: We use new and archival ALMA data to perform a tomography of $^{12}$CO, $^{13}$CO, C$^{18}$O, CN, HCN, CS, H$_2$CO, c-C$_3$H$_2$, N$_2$D$^+$, DCN and $^{13}$CS. We analyze molecular tomographies and model data using the radiative transfer code DiskFit. Results: We directly measure the altitude above the mid-plane for each observed species. For the first time, we unambiguously demonstrate the presence of a common molecular layer and measure its thickness: most molecules are located at the same altitude versus radius. Beyond CO, as predicted by chemical models, the CN emission traces the upper boundary of the molecular layer, whereas the deuterated species (DCN and N2D+) resides below one scale-height. Our best fits from DiskFit show that most observed transitions in the molecular layer are thermalized because their excitation temperature is the same, around 17-20 K. Conclusions: These long-integration observations clearly reveal a molecular layer predominantly located around 1-2 scale height, at a temperature above the CO freeze-out temperature. The deuterated molecules are closer to the mid-plane and N2D+ may be a good proxy for the CO snowline. Some molecules, such as CN and H2CO, are likely influenced by the disk environment, at least beyond the mm dust disk radius. The direct observation of the molecular stratification opens the door to detailed chemical modeling in this disk which appears representative of T Tauri disks.

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arXiv2025

Edge-On Disk Study (EODS) II: Thermal Structure of the Flying Saucer Disk

Context. The dust and gas temperature in proto-planetary disks play critical roles in determining their chemical evolution and influencing planet formation processes. Aims. We attempted an accurate measurement of the dust and CO temperature profile in the edge-on disk of the Flying Saucer. Methods. We used the unique properties of the Flying Saucer, its edge-on geometry and its fortunate position in front of CO clouds with different brightness temperatures to provide independent constraints on the dust temperature. We compared it with the dust temperature derived using the radiative transfer code DiskFit and the CO gas temperature. Results. We find clear evidence for a substantial gas temperature vertical gradient, with a cold (10 K) disk mid-plane and a warmer CO layer where T(r) is 27 K at 100 au, dropping with exponent 0.3. Direct evidence for CO depletion in the mid-plane, below about 1 scale height, is also found. At this height, the gas temperature is 15-20 K, consistent with the expected CO freeze out temperature. The dust disk appears optically thin at 345 GHz, and exhibits moderate settling.

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arXiv2024

JOYS+ study of solid state $^{12}$C/$^{13}$C isotope ratios in protostellar envelopes: Observations of CO and CO$_2$ ice with JWST

The carbon isotope ratio is a powerful tool for studying the evolution of stellar systems. Recent detections of CO isotopologues in disks and exoplanet atmospheres pointed towards significant fractionation in these systems. In order to understand the evolution of this quantity, it is crucial to trace the isotope abundance from stellar nurseries to planetary systems. During the protostellar stage the multiple vibrational modes of CO$_2$ and CO ice provide a unique opportunity to examine the carbon isotope ratio in the solid state. Now with the sensitivity of the \textit{James Webb Space Telescope}, these absorption features have become accessible at high S/N in Solar-mass systems. We quantify the $^{12}$CO$_2$/$^{13}$CO$_2$ and the $^{12}$CO/$^{13}$CO isotope ratios in 17 class 0/I low mass protostars from the $^{12}$CO$_2$ combination modes (2.70 $μ$m and 2.77 $μ$m), the $^{12}$CO$_2$ stretching mode (4.27 $μ$m), the $^{13}$CO$_2$ stretching mode (4.39 $μ$m), the $^{12}$CO$_2$ bending mode (15.2 $μ$m), the $^{12}$CO stretching mode (4.67 $μ$m) and the $^{13}$CO stretching mode (4.78 $μ$m) using JWST observations. We also report a detection of the $^{12}$CO overtone mode at 2.35 $μ$m. The $^{12}$CO$_2$/$^{13}$CO$_2$ ratios are in agreement and we find mean ratios of 85 $\pm$ 23, 76 $\pm$ 12 and 97 $\pm$ 17 for the 2.70 $μ$m, 4.27 $μ$m and the 15.2 $μ$m bands, respectively. The main source of uncertainty stem from the error on the band strengths. The $^{12}$CO/$^{13}$CO ratios derived from the 4.67 $μ$m bands are consistent, albeit elevated with respect to the $^{12}$CO$_2$/$^{13}$CO$_2$ ratios and we find a mean ratio of 165 $\pm$ 52. These findings indicate that ices leave the pre-stellar stage with elevated carbon isotope ratios relative to the interstellar medium and that fractionation becomes significant during the later stages.

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arXiv2024

JOYS+: link between ice and gas of complex organic molecules. Comparing JWST and ALMA data of two low-mass protostars

A rich inventory of complex organic molecules (COMs) has been observed in high abundances in the gas phase toward Class 0 protostars. These molecules are suggested to be formed in ices and sublimate in the warm inner envelope close to the protostar. However, only the most abundant COM, methanol (CH3OH), has been firmly detected in ices before the era of James Webb Space Telescope (JWST). Now it is possible to detect the interstellar ices of other COMs and constrain their ice column densities quantitatively. We aim to determine the column densities of several oxygen-bearing COMs (O-COMs) in both gas and ice for two low-mass protostellar sources, NGC 1333 IRAS 2A and B1-c, as case studies in our JWST Observations of Young protoStars (JOYS+) program. By comparing the column density ratios w.r.t. CH3OH between both phases measured in the same sources, we can probe into the evolution of COMs from ice to gas in the early stages of star formation. We are able to fit the fingerprints range of COM ices between 6.8 and 8.8 um in the JWST/MIRI-MRS spectra of B1-c using similar components as recently used for IRAS 2A. We claim detection of CH4, OCN-, HCOO-, HCOOH, CH3CHO, C2H5OH, CH3OCH3, CH3OCHO, and CH3COCH3 in B1-c, and upper limits are estimated for SO2, CH3COOH, and CH3CN. The comparison of O-COM ratios w.r.t CH3OH between ice and gas shows two different cases. 1) the column density ratios of CH3OCHO and CH3OCH3 match well between the two phases, which may be attributed to a direct inheritance from ice to gas or strong chemical links with CH3OH. 2) the ice ratios of CH3CHO and C2H5OH w.r.t. CH3OH are higher than the gas ratios by 1-2 orders of magnitudes. This difference can be explained by the gas-phase reprocessing following sublimation, or different spatial distributions of COMs in the envelope.

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arXiv2023

JWST Observations of Young protoStars (JOYS+): Detection of icy complex organic molecules and ions. I. CH$_4$, SO$_2$, HCOO$^-$, OCN$^-$, H$_2$CO, HCOOH, CH$_3$CH$_2$OH, CH$_3$CHO, CH$_3$OCHO, CH$_3$COOH

Complex organic molecules (COMs) detected in the gas phase are thought to be mostly formed on icy grains, but no unambiguous detection of icy COMs larger than CH3OH has been reported so far. Exploring this matter in more detail has become possible with the JWST the critical 5-10 $μ$m range. In the JOYS+ program, more than 30 protostars are being observed with the MIRI/MRS. This study explores the COMs ice signatures in the low and high-mass protostar, IRAS 2A and IRAS 23385, respectively. We fit continuum and silicate subtracted observational data with IR laboratory ice spectra. We use the ENIIGMA fitting tool to find the best fit between the lab data and the observations and to performs statistical analysis of the solutions. We report the best fits for the spectral ranges between 6.8 and 8.6 $μ$m in IRAS 2A and IRAS 23385, originating from simple molecules, COMs, and negative ions. The strongest feature in this range (7.7 $μ$m) is dominated by CH4 and has contributions of SO2 and OCN-. Our results indicate that the 7.2 and 7.4 $μ$m bands are mostly dominated by HCOO-. We find statistically robust detections of COMs based on multiple bands, most notably CH3CHO, CH3CH2OH, and CH3OCHO. The likely detection of CH3COOH is also reported. The ice column density ratios between CH3CH2OH and CH3CHO of IRAS 2A and IRAS 23385, suggests that these COMs are formed on icy grains. Finally, the derived ice abundances for IRAS 2A correlate well with those in comet 67P/GC within a factor of 5. Based on the MIRI/MRS data, we conclude that COMs are present in interstellar ices, thus providing additional proof for a solid-state origin of these species in star-forming regions. The good correlation between the ice abundances in comet 67P and IRAS 2A is in line with the idea that cometary COMs can be inherited from the early protostellar phases.

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arXiv2023

JOYS+: mid-infrared detection of gas-phase SO$_2$ emission in a low-mass protostar. The case of NGC 1333 IRAS2A: hot core or accretion shock?

JWST/MIRI has sharpened our infrared eyes toward the star formation process. This paper presents the first mid-infrared detection of gaseous SO$_2$ emission in an embedded low-mass protostellar system. MIRI-MRS observations of the low-mass protostellar binary NGC 1333 IRAS2A are presented from the JWST Observations of Young protoStars (JOYS+) program, revealing emission from the SO$_2~ν_3$ asymmetric stretching mode at 7.35 micron. The results are compared to those derived from high-angular resolution SO$_2$ data obtained with ALMA. The SO$_2$ emission from the $ν_3$ band is predominantly located on $\sim50-100$ au scales around the main component of the binary, IRAS2A1. A rotational temperature of $92\pm8$ K is derived from the $ν_3$ lines. This is in good agreement with the rotational temperature derived from pure rotational lines in the vibrational ground state (i.e., $ν=0$) with ALMA ($104\pm5$ K). However, the emission of the $ν_3$ lines is not in LTE given that the total number of molecules predicted by a LTE model is found to be a factor $2\times10^4$ higher than what is derived for the $ν=0$ state. This difference can be explained by a vibrational temperature that is $\sim100$ K higher than the derived rotational temperature of the $ν=0$ state. The brightness temperature derived from the continuum around the $ν_3$ band of SO$_2$ is $\sim180$ K, which confirms that the $ν_3=1$ level is not collisionally populated but rather infrared pumped by scattered radiation. This is also consistent with the non-detection of the $ν_2$ bending mode at 18-20 micron. Given the rotational temperature, the extent of the emission ($\sim100$ au in radius), and the narrow line widths in the ALMA data (3.5 km/s), the SO$_2$ in IRAS2A likely originates from ice sublimation in the central hot core around the protostar rather than from an accretion shock at the disk-envelope boundary.

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arXiv2022

Gas phase Elemental abundances in Molecular cloudS (GEMS) VI. A sulphur journey across star-forming regions: study of thioformaldehyde emission

In the context of the IRAM 30m Large Program GEMS, we present a study of thioformaldehyde in several starless cores located in star-forming filaments of Taurus, Perseus, and Orion. We investigate the influence of the environmental conditions on the abundances of these molecules in the cores, and the effect of time evolution. We have modelled the observed lines of H2CS, HDCS, and D2CS using the radiative transfer code RADEX. We have also used the chemical code Nautilus to model the evolution of these species depending on the characteristics of the starless cores. We derive column densities and abundances for all the cores. We also derive deuterium fractionation ratios, Dfrac, to determine and compare the evolutionary stage between different parts of each star-forming region. Our results indicate that the north region of the B213 filament in Taurus is more evolved than the south, while the north-eastern part of Perseus presents an earlier evolutionary stage than the south-western zone. Model results also show that Dfrac decreases with the cosmic-ray ionisation rate, while it increases with density and with the degree of sulphur depletion. In particular, we only reproduce the observations when the initial sulphur abundance in the starless cores is at least one order of magnitude lower than the solar elemental sulphur abundance. The progressive increase in HDCS/H2CS and D2CS/H2CS with time makes these ratios powerful tools for deriving the chemical evolutionary stage of starless cores. However, they cannot be used to derive the temperature of these regions, since both ratios present a similar evolution at two different temperature ranges (7-11 K and 15-19 K). Regarding chemistry, (deuterated) thioformaldehyde is mainly formed through gas-phase reactions (double-replacement and neutral-neutral displacement reactions), while surface chemistry plays an important role as a destruction mechanism.

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arXiv2021

An unbiased NOEMA 2.6 to 4 mm survey of the GG Tau ring: First detection of CCS in a protoplanetary disk

Molecular line surveys are among the main tools to probe the structure and physical conditions in protoplanetary disks (PPDs), the birthplace of planets. The large radial and vertical temperature as well as density gradients in these PPDs lead to a complex chemical composition, making chemistry an important step to understand the variety of planetary systems. We aimed to study the chemical content of the protoplanetary disk surrounding GG Tau A, a well-known triple T Tauri system. We used NOEMA with the new correlator PolyFix to observe rotational lines at 2.6 to 4 mm from a few dozen molecules. We analysed the data with a radiative transfer code to derive molecular densities and the abundance relative to $^{13}$CO, which we compare to those of the TMC1 cloud and LkCa15 disk. We report the first detection of CCS in PPDs. We also marginally detect OCS and find 16 other molecules in the GG Tauri outer disk. Ten of them had been found previously, while seven others ($^{13}$CN, N$_2$H$^+$, HNC, DNC, HC$_3$N, CCS, and C$^{34}$S) are new detections in this disk. The analysis confirms that sulphur chemistry is not yet properly understood. The D/H ratio, derived from DCO$^{+}$/HCO$^{+}$, DCN/HCN, and DNC/HNC ratios, points towards a low temperature chemistry. The detection of the rare species CCS confirms that GG Tau is a good laboratory to study the protoplanetary disk chemistry, thanks to its large disk size and mass.

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arXiv2021

Evolutionary view through the starless cores in Taurus: deuteration in TMC 1-C and TMC 1-CP

The chemical and physical evolution of starless and pre-stellar cores are of paramount importance to understanding the process of star formation. The Taurus Molecular Cloud cores TMC 1-C and TMC 1-CP share similar initial conditions and provide an excellent opportunity to understand the evolution of the pre-stellar core phase. We investigated the evolutionary stage of starless cores based on observations towards the prototypical dark cores TMC 1-C and TMC 1-CP, mapping them in the CS $3\rightarrow 2$, C$^{34}$S $3\rightarrow 2$, $^{13}$CS $2\rightarrow 1$, DCN $1\rightarrow 0$, DCN $2\rightarrow 1$, DNC $1\rightarrow 0$, DNC $2\rightarrow 1$, DN$^{13}$C $1\rightarrow 0$, DN$^{13}$C $2\rightarrow 1$, N$_2$H$^+$ $1\rightarrow 0$, and N$_2$D$^+$ $1\rightarrow 0$ transitions. We performed a multi-transitional study of CS and its isotopologs, DCN, and DNC lines to characterize the physical and chemical properties of these cores. We studied their chemistry using the state-of-the-art gas-grain chemical code Nautilus and pseudo time-dependent models to determine their evolutionary stage. Observational diagnostics seem to indicate that TMC 1-C is in a later evolutionary stage than TMC 1-CP, with a chemical age $\sim$1 Myr. TMC 1-C shows signs of being an evolved core at the onset of star formation, while TMC 1-CP appears to be in an earlier evolutionary stage due to a more recent formation or, alternatively, a collapse slowed down by a magnetic support.

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arXiv2021

Chemical compositions of five Planck cold clumps

Aims: Interstellar molecules form early in the evolutionary sequence of interstellar material that eventually forms stars and planets. To understand this evolutionary sequence, it is important to characterize the chemical composition of its first steps. Methods: In this paper, we present the result of a 2 and 3 mm survey of five cold clumps identified by the Planck mission. We carried out a radiative transfer analysis on the detected lines in order to put some constraints on the physical conditions within the cores and on the molecular column densities. We also performed chemical models to reproduce the observed abundances in each source using the gas-grain model Nautilus. Results: Twelve molecules were detected: H2CO, CS, SO, NO, HNO, HCO+, HCN, HNC, CN, CCH, CH3OH, and CO. Here, CCH is the only carbon chain we detected in two sources. Radiative transfer analyses of HCN, SO, CS, and CO were performed to constrain the physical conditions of each cloud with limited success. The sources have a density larger than $10^4$ cm$^{-3}$ and a temperature lower than 15 K. The derived species column densities are not very sensitive to the uncertainties in the physical conditions, within a factor of 2. The different sources seem to present significant chemical differences with species abundances spreading over one order of magnitude. The chemical composition of these clumps is poorer than the one of Taurus Molecular Cloud 1 Cyanopolyyne Peak (TMC-1 CP) cold core. Our chemical model reproduces the observational abundances and upper limits for 79 to 83\% of the species in our sources. The "best" times for our sources seem to be smaller than those of TMC-1, indicating that our sources may be less evolved and explaining the smaller abundances and the numerous non-detections. Also, CS and HCN are always overestimated by our models.

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arXiv2018

First detection of H$_2$S in a protoplanetary disk. The dense GG Tau A ring

Studying molecular species in protoplanetary disks is very useful to characterize the properties of these objects, which are the site of planet formation. We attempt to constrain the chemistry of S-bearing molecules in the cold parts of circumstellar disk of GG Tau A. We searched for H$_2$S, CS, SO, and SO$_2$ in the dense disk around GG Tau A with the NOrthem Extended Millimeter Array (NOEMA) interferometer. We detected H$_2$S emission from the dense and cold ring orbiting around GG Tau A. This is the first detection of H$_2$S in a protoplanetary disk. We also detected HCO$^+$, H$^{13}$CO$^+$, and DCO$^+$ in the disk. Upper limits for other molecules, CCS, SO$_2$, SO, HC$_3$N, and $c$-C$_3$H$_2$ are also obtained. The observed DCO$^+$/HCO$^+$ ratio is similar to those in other disks. The observed column densities, derived using our radiative transfer code DiskFit, are then compared with those from our chemical code Nautilus. The column densities are in reasonable agreement for DCO$^{+}$, CS, CCS, and SO$_2$. For H$_2$S and SO, our predicted vertical integrated column densities are more than a factor of 10 higher than the measured values. Our results reinforce the hypothesis that only a strong sulfur depletion may explain the low observed H$_2$S column density in the disk. The H$_2$S detection in GG Tau A is most likely linked to the much larger mass of this disk compared to that in other T Tauri systems.

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arXiv2017

A study of singly deuterated cyclopropenylidene c-C3HD in protostar IRAS 16293-2422

Cyclic-C3HD (c-C3HD) is a singly deuterated isotopologue of c-C3H2, which is one of the most abundant and widespread molecules in our Galaxy. We observed IRAS 16293-2422 in the 3 mm band with a single frequency setup using the EMIR heterodyne 3 mm receiver of the IRAM 30m telescope. We observed seven lines of c-C3HD and three lines of c-C3H2. Observed abundances are compared with astrochemical simulations using the NAUTILUS gas-grain chemical model. Our results clearly show that c-C3HD can be used as an important supplement for studying chemistry and physical conditions for cold environments. Assuming that the size of the protostellar envelope is 3000 AU and same excitation temperatures for both c-C3H2 and c-C3HD, we obtain a deuterium fraction of $14_{-3}^{+4}\%$.

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arXiv2016

Chemistry of TMC-1 with multiply deuterated species and spin chemistry of H2, H2+, H3+ and their isotopologues

Deuterated species are unique and powerful tools in astronomy since they can probe the physical conditions, chemistry, and ionization level of various astrophysical media. Recent observations of several deuterated species along with some of their spin isomeric forms have rekindled the interest for more accurate studies on deuterium fractionation. This paper presents the first publicly available chemical network of multiply deuterated species along with spin chemistry implemented on the latest state-of-the-art gas-grain chemical code `NAUTILUS'. D/H ratios for all deuterated species observed at different positions of TMC-1 are compared with the results of our model, which considers multiply deuterated species along with the spin chemistry of light hydrogen bearing species H2, H2+, H3+ and their isotopologues. We also show the differences in the modeled abundances of non-deuterated species after the inclusion of deuteration and spin chemistry in the model. Finally, we present a list of potentially observable deuterated species in TMC-1 awaiting detection.

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arXiv2016

A New Reference Chemical Composition for TMC-1

Recent detections of complex organic molecules in dark clouds have rekindled interest in the astrochemical modeling of these environments. Because of its relative closeness and rich molecular complexity, TMC-1 has been extensively observed to study the chemical processes taking place in dark clouds. We use local thermodynamical equilibrium radiative transfer modeling coupled with a Bayesian statistical method which takes into account outliers to analyze the data from the Nobeyama spectral survey of TMC-1 between 8 and 50 GHz. We compute the abundance relative to molecular hydrogen of 57 molecules, including 19 isotopologues in TMC-1 along with their associated uncertainty. The new results are in general agreement with previous abundance determination from Ohishi & Kaifu and the values reported in the review from Agundez & Wakelam. However, in some cases, large opacity and low signal to noise effects allow only upper or lower limits to be derived, respectively.

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arXiv2016

Importance of the H2 abundance in protoplanetary disk ices for the molecular layer chemical composition

Protoplanetary disks are the target of many chemical studies (both observational and theoretical) as they contain the building material for planets. Their large vertical and radial gradients in density and temperature make them challenging objects for chemical models. In the outer part of these disks, the large densities and low temperatures provide a particular environment where the binding of species onto the dust grains can be very efficient and can affect the gas-phase chemical composition. We attempt to quantify to what extent the vertical abundance profiles and the integrated column densities of molecules predicted by a detailed gas-grain code are affected by the treatment of the molecular hydrogen physisorption at the surface of the grains. We performed three different models using the Nautilus gas-grain code. One model uses a H2 binding energy on the surface of water (440 K) and produces strong sticking of H2. Another model uses a small binding energy of 23 K (as if there were already a monolayer of H2), and the sticking of H$_2$ is almost negligible. Finally, the remaining model is an intermediate solution known as the encounter desorption mechanism. We show that the efficiency of molecular hydrogen binding (and thus its abundance at the surface of the grains) can have a quantitative effect on the predicted column densities in the gas phase of major species such as CO, CS, CN, and HCN.

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arXiv2014

Infrared Spectra and Chemical Abundance of Methyl Propionate in Icy Astrochemical Conditions

We carried out an experiment in order to obtain the InfraRed (IR) spectra of methyl propionate (CH3CH2COOCH3) in astrochemical conditions and present the IR spectra for future identification of this molecule in the InterStellar Medium (ISM). The experimental IR spectrum is compared with the theoretical spectrum and an attempt was made to assign the observed peak positions to their corresponding molecular vibrations in condensed phase. Moreover, our calculations suggest that methyl propionate must be synthesized efficiently within the complex chemical network of the ISM and therefore be present in cold dust grains, awaiting identification.

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