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L. S. Schulman

Publications and source records attributed to L. S. Schulman.

At least 19 recordsLinked to original sources

Need for "special" states in a deterministic theory of quantum mechanics

There are several theories or processes which may underlie quantum mechanics and make it deterministic. Some references are given in the main text. Any such theory, plus a number of reasonable assumptions, implies the existence of what I have called ``special" states. The assumptions are conservation laws, obedience (up to a point) of Schrodinger's equation, and a single world, in the sense of the many worlds interpretation (the last one a consequence of any deterministic theory). This article also, for clarity, gives an example of a ``special" state. There is an experimental test of the ``special" state theory.

quant-ph↗

Relative entropy, interaction energy and the nature of dissipation

Many thermodynamic relations involve inequalities, with equality if a process does not involve dissipation. In this article we provide equalities in which the dissipative contribution is shown to involve the relative entropy (a.k.a. Kullback-Leibler divergence). The processes considered are general time evolutions both in classical and quantum mechanics, and the initial state is sometimes thermal, sometimes partially so. By calculating a transport coefficient we show that indeed---at least in this case---the source of dissipation in that coefficient is the relative entropy.

cond-mat.stat-mech↗

Experimental test of the "special state" theory of quantum measurement

An experimental test of the "special state" theory of quantum measurement is proposed. It should be feasible with present-day laboratory equipment and involves a slightly elaborated Stern-Gerlach setup. The "special state" theory is conservative with respect to quantum mechanics, but radical with respect to statistical mechanics, in particular regarding the arrow of time. In this article background material is given on both quantum measurement and statistical mechanics aspects. For example, it is shown that future boundary conditions would not contradict experience, indicating that the fundamental equal-a-priori-probability assumption at the foundations of statistical mechanics is far too strong (since future conditioning reduces the class of allowed states). The test is based on a feature of this theory that was found necessary in order to recover standard (Born) probabilities in quantum measurements. Specifically, certain systems should have "noise" whose amplitude follows the long-tailed Cauchy distribution. This distribution is marked by the occasional occurrence of extremely large signals as well as a non-self-averaging property. The proposed test is a variant of the Stern-Gerlach experiment in which protocols are devised, some of which will require the presence of this noise, some of which will not. The likely observational schemes would involve the distinction between detection and non-detection of that "noise". The signal to be detected (or not) would be either single photons in the visible and UV range or electric fields (and related excitations) in the neighborhood of the ends of the magnets.

quant-ph↗

Dissipation, interaction and relative entropy

Many thermodynamic relations involve inequalities, with equality if a process does not involve dissipation. In this article we provide equalities in which the dissipative contribution is shown to involve the relative entropy (a.k.a. Kullback-Leibler divergence). The processes considered are general time evolutions both in classical and quantum mechanics, and the initial state is sometimes thermal, sometimes partially so. As an application, the relative entropy is related to transport coefficients.

cond-mat.stat-mech↗

Spectral properties of zero temperature dynamics in a model of a compacting granular column

The compacting of a column of grains has been studied using a one-dimensional Ising model with long range directed interactions in which down and up spins represent orientations of the grain having or not having an associated void. When the column is not shaken (zero 'temperature') the motion becomes highly constrained and under most circumstances we find that the generator of the stochastic dynamics assumes an unusual form: many eigenvalues become degenerate, but the associated multi-dimensional invariant spaces have but a single eigenvector. There is no spectral expansion and a Jordan form must be used. Many properties of the dynamics are established here analytically; some are not. General issues associated with the Jordan form are also taken up.

cond-mat.stat-mech↗

Efficiency of a thermodynamic motor at maximum power

Several recent theories address the efficiency of a macroscopic thermodynamic motor at maximum power and question the so-called "Curzon-Ahlborn (CA) efficiency." Considering the entropy exchanges and productions in an n-sources motor, we study the maximization of its power and show that the controversies are partly due to some imprecision in the maximization variables. When power is maximized with respect to the system temperatures, these temperatures are proportional to the square root of the corresponding source temperatures, which leads to the CA formula for a bi-thermal motor. On the other hand, when power is maximized with respect to the transitions durations, the Carnot efficiency of a bi-thermal motor admits the CA efficiency as a lower bound, which is attained if the duration of the adiabatic transitions can be neglected. Additionally, we compute the energetic efficiency, or "sustainable efficiency," which can be defined for n sources, and we show that it has no other universal upper bound than 1, but that in certain situations, favorable for power production, it does not exceed 1/2.

cond-mat.stat-mech↗

Violation of the zeroth law of thermodynamics for a non-ergodic interaction

The phenomenon described by our title should surprise no one. What may be surprising though is how easy it is to produce a quantum system with this feature; moreover, that system is one that is often used for the purpose of showing how systems equilibrate. The violation can be variously manifested. In our detailed example, bringing a detuned 2-level system into contact with a monochromatic reservoir does not cause it to relax to the reservoir temperature; rather, the system acquires the reservoir's level-occupation-ratio.

cond-mat.stat-mech↗

Clusters from higher order correlations

Given a set of variables and the correlations among them, we develop a method for finding clustering among the variables. The method takes advantage of information implicit in higher-order (not just pairwise) correlations. The idea is to define a Potts model whose energy is based on the correlations. Each state of this model is a partition of the variables and a Monte Carlo method is used to identify states of lowest energy, those most consistent with the correlations. A set of the 100 or so lowest such partitions is then used to construct a stochastic dynamics (using the adjacency matrix of each partition) whose observable representation gives the clustering. Three examples are studied. For two of them the 3$^\mathrm{rd}$ order correlations are significant for getting the clusters right. The last of these is a toy model of a biological system in which the joint action of several genes or proteins is necessary to accomplish a given process.

cond-mat.stat-mech↗

Source of the observed thermodynamic arrow

The puzzle of the thermodynamic arrow of time reduces to the question of how the universe could have had lower entropy in the past. I show that no special entropy lowering mechanism (or fluctuation) is necessary. As a consequence of expansion, at a particular epoch in the history of the universe a state that was near maximum entropy under the dominant short range forces becomes extremely unlikely, due to a switchover to newly dominant long range forces. This happened at about the time of decoupling, prior to which I make no statement about arrows. The role of cosmology in thermodynamics was first suggested by T. Gold.

cond-mat.stat-mech↗

Generalized Clausius relation and power dissipation in non equilibrium stochastic systems

We extend certain basic and general concepts of thermodynamics to discrete Markov systems exchanging work and heat with reservoirs. In this framework we show that the celebrated Clausius inequality can be generalized and becomes an equality, significantly extending several recent results. We further show that achieving zero dissipation in a system implies that detailed balance obtains, and as a consequence there is zero power production. We obtain inequalities for power production under more general circumstances and show that near equilibrium obtaining maximum power production requires dissipation to be of the same order of magnitude.

cond-mat.stat-mech↗

Quantum Hamilton-Jacobi Theory

Quantum canonical transformations have attracted interest since the beginning of quantum theory. Based on their classical analogues, one would expect them to provide a powerful quantum tool. However, the difficulty of solving a nonlinear operator partial differential equation such as the quantum Hamilton-Jacobi equation (QHJE) has hindered progress along this otherwise promising avenue. We overcome this difficulty. We show that solutions to the QHJE can be constructed by a simple prescription starting from the propagator of the associated Schroedinger equation. Our result opens the possibility of practical use of quantum Hamilton-Jacobi theory. As an application we develop a surprising relation between operator ordering and the density of paths around a semiclassical trajectory.

quant-ph↗

Mean Field Spin Glass in the Observable Representation

The state space for the $N$-spin mean field (SK) spin glass--nominally an $N$-cube--is embedded in a low dimensional continuous space in such a way that metastable and stable phases can easily be discerned, a concept of nearness of configurations defined, and peaks in the Parisi $q$-parameter overlap distribution identified. The dynamical and partly hierarchical interrelation of these phases can be directly imaged.

cond-mat.stat-mech↗

Ratcheting up energy by means of measurement

The destruction of quantum coherence can pump energy into a system. For our examples this is paradoxical since the destroyed correlations are ordinarily considered negligible. Mathematically the explanation is straightforward and physically one can identify the degrees of freedom supplying this energy. Nevertheless, the energy input can be calculated without specific reference to those degrees of freedom.

quant-ph↗

Multiple phases in stochastic dynamics: geometry and probabilities

Stochastic dynamics is generated by a matrix of transition probabilities. Certain eigenvectors of this matrix provide observables, and when these are plotted in the appropriate multi-dimensional space the phases (in the sense of phase transitions) of the underlying system become manifest as extremal points. This geometrical construction, which we call an \textit{observable-representation of state space}, can allow hierarchical structure to be observed. It also provides a method for the calculation of the probability that an initial points ends in one or another asymptotic state.

cond-mat.stat-mech↗

Stability of quantum breathers

Using two methods we show that a quantized discrete breather in a 1-D lattice is stable. One method uses path integrals and compares correlations for a (linear) local mode with those of the quantum breather. The other takes a local mode as the zeroth order system relative to which numerical, cutoff-insensitive diagonalization of the Hamiltonian is performed.

cond-mat.stat-mech↗

Structure and time-dependence of quantum breathers

Quantum states of a discrete breather are studied in two ways. One method involves numerical diagonalization of the Hamiltonian, the other uses the path integral to examine correlations in the eigenstates. In both cases only the central nonlinearity is retained. To reduce truncation effects in the numerical diagonalization, a basis is used that involves a quadratic local mode. A similar device is used in the path integral method for deducing localization. Both approaches lead to the conclusion that aside from quantum tunneling the quantized discrete breather is stable.

cond-mat.stat-mech↗