arXiv subjects

L. Slumstrup

Publications and source records attributed to L. Slumstrup.

2 recordsLinked to original sources

arXiv2026

Infrared photoprocessing of porous amorphous solid water with a free electron laser

Water ice is the most abundant ice in the interstellar medium (ISM). Previous studies on porous amorphous solid water (pASW) have shown that the infrared radiation field in the ISM modeled with infrared free electron laser (FEL) irradiation can result in changes in the ice towards a more ordered structure, characterized by a change in the OH-stretching vibration band. This paper aims to study the restructuring in more detail by varying the irradiation intensity and irradiation time for irradiations on-resonance with the OH-stretching, bending and libration modes. In addition, desorption of H2O is monitored during the irradiations. The research presented in this paper considers 42 infrared FEL irradiations on pASW samples deposited at two different rates, using the infrared FELs of the HFML-FELIX laboratory. Restructuring is studied using reflection absorption infrared (RAIR) spectroscopy, with a mass spectrometer monitoring the desorption of H2O in an ultra-high vacuum system. Desorption and restructuring occur in parallel, with the strongest effects observed for irradiation on-resonance with the OH-stretching vibration. Both processes exhibit two distinct regimes: an initial strong restructuring and desorption, characterized by an exponential decrease in the intensity of the desorption peaks within the first 5 s of irradiation, followed by a second regime of less efficient, yet continued restructuring and constant desorption in an extended area, involving energy dissipation through the hydrogen-bonding network. The trends in restructuring and desorption, depending on the absorbed energy during irradiation, are significantly different, suggesting separate processes. The astrophysical relevance of in particular the second regime of constant desorption and restructuring is discussed.

astro-ph.GA↗

arXiv2025

CO desorption from interstellar icy grains induced by IR excitation of superhydrogenated PAHs

Infrared (IR) radiation dominates dense, interstellar clouds, yet its effect on icy grains remains largely unexplored. Its potential role in driving the photodesorption of volatile species from such grains has recently been demonstrated, providing a crucial link between the solid state reservoir of molecules and the gas phase. In this work, we investigate IR-induced photodesorption of CO for astrophysically relevant ice systems containing perhydropyrene (PHP). This fully superhydrogenated version of pyrene is used as an analogue for large carbonaceous molecules such as polycyclic aromatic hydrocarbons (PAHs) and related species, as well as hydrogenated carbonaceous grains. The abundance and range of strong IR absorption bands of these carbonaceous species make them interesting candidates for IR-induced effects. We present IR spectroscopic and mass spectrometric measurements probing the effects of IR radiation on two ice systems: a layered ice with CO on top of PHP, and a CO:PHP mixed ice. These ices were irradiated with IR radiation from the FELIX IR Free Electron Laser (FEL) FEL-2. In accordance with previous studies, we confirm that direct excitation of CO is not an efficient pathway to CO desorption, indicating that another energy dissipation mechanism exists. We demonstrate that vibrational excitation of the PHP CH stretching modes leads to efficient CO photodesorption. The derived photodesorption yields are an order of magnitude higher for the layered than the mixed system and comparable to those previously obtained for CO photodesorption from CO on amorphous solid water upon excitation of H$_2$O vibrational modes. Our results indicate that IR excitation of carbonaceous molecules and grains in dense clouds could potentially play an important role in the desorption of volatile species such as CO from icy grains.

astro-ph.GA↗