arXiv subjects

L. Testi

Publications and source records attributed to L. Testi.

At least 37 records · Page 2Linked to original sources

arXiv2025

ALMAGAL I. The ALMA evolutionary study of high-mass protocluster formation in the Galaxy. Presentation of the survey and early results

Fundamental questions about the physics responsible for fragmenting molecular parsec-scale clumps into cores of ~1000 au are still open, that only a statistically significant investigation with ALMA is able to address: what are the dominant agents that determine the core demographics, mass, and spatial distribution as a function of the physical properties of the hosting clumps, their evolutionary stage and the different Galactic environments in which they reside? To what extent extent is fragmentation driven by clumps dynamics or mass transport in filaments? With ALMAGAL we observed the 1.38 mm continuum and lines toward more than 1000 dense clumps in our Galaxy, with M>500M_sun, surface density > 0.1 g/cm2 and d<7.5 kpc. The ACA and two 12-m array setups were used to deliver a minimum resolution of ~1000 au over the entire sample distance range. The sample covers all evolutionary stages from infrared dark clouds (IRDCs) to HII regions from the tip of the Galactic bar to the outskirts of the Galaxy. The spectral setup includes several molecular lines to trace the multiscale physics and dynamics of gas, notably CH3CN, H2CO, SiO, CH3OH, DCN, HC3N, SO etc. We present an initial overview of the observations and the early science product and results, with a first characterization of the morphological properties of the continuum emission. We use "perimeter-versus-area" and convex hull-versus-area metrics to classify the different morphologies. More extended and morphologically complex shapes are found toward clumps that are relatively more evolved and have higher surface densities.

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arXiv2025

ALMAGAL III. Compact source catalog: Fragmentation statistics and physical evolution of the core population

The mechanisms behind the fragmentation of high-mass dense clumps into compact star-forming cores are fundamental topics in current astrophysical research. The ALMAGAL survey provides the opportunity to study this process at an unprecedented level of detail and statistical significance, featuring high-angular resolution $1.38$ mm ALMA observations of $1013$ massive dense clumps at various Galactic locations. These clumps cover a wide range of distances, masses, surface densities, and evolutionary stages. Here, we present the catalog of compact sources obtained with the CuTEx algorithm from continuum images of the full ALMAGAL clump sample combining ACA-$7$m and $12$m ALMA arrays, reaching a uniform high median spatial resolution of $\sim1400$ au. We discuss the fragmentation properties and the estimated physical parameters of the core population. The ALMAGAL compact source catalog includes $6348$ cores detected in $844$ clumps ($83\%$ of the total), with a number of cores per clump between $1$ and $49$ (median of $5$). The estimated core diameters are mostly within $\sim800-3000$ au (median of $1700$ au). We obtained core masses from $0.002$ to $345\,\mathrm{M_{\odot}}$. We evaluated the variation in the core mass function (CMF) with evolution as traced by the clump $L/M$, finding a clear, robust shift and change in slope among CMFs within subsamples at different stages. This finding suggests that the CMF shape is not constant throughout the star formation process, but rather it builds (and flattens) with evolution, with higher core masses reached at later stages. We found that all cores within a clump grow in mass on average with evolution, and the number of cores increases with the core masses. Our results favor a clump-fed scenario for high-mass star formation, in which cores form as low-mass seeds, and then gain mass while further fragmentation occurs in the clump.

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arXiv2025

HD 163296 and its Giant Planets: Creation of Exo-comets, Interstellar Objects and Transport of Volatile Material

The birth of giant planets in protoplanetary disks is known to alter the structure and evolution of the disk environment, but most of our knowledge focuses on its effects on the observable gas and dust. The impact on the evolution of the invisible planetesimal population is still limitedly studied, yet mounting evidence from the Solar System shows how the appearance of its giant planets played a key role in shaping the habitability of the terrestrial planets. We investigate the dynamical and collisional transport processes of volatile elements by planetesimals in protoplanetary disks that host young giant planets using the HD163296 system as our case study. HD163296 is one of the best characterised protoplanetary disks that has been proposed to host at least four giant planets on wide orbits as well as a massive planetesimal disk. The formation of giant planets in the HD163296 system creates a large population of dynamically excited planetesimals, the majority of which originate from beyond the CO snowline. The excited planetesimals are both transported to the inner disk regions and scattered outward beyond the protoplanetary disk and into interstellar space. Existing solid planets can be enriched in volatile elements to levels comparable or larger than those of the Earth, while giant planets can be enriched to the levels of Jupiter and Saturn. The formation of giant planets on wide orbits impacts the compositional evolution of protoplanetary disks and young planetary bodies on a global scale. The collisional enrichment of the atmospheres of giant planets can alter or mask the signatures of their formation environments, but can provide independent constraints on the disk mass. Protoplanetary disks with giant planets on wide orbits prove efficient factories of interstellar objects.

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arXiv2025

FAUST XX. The chemical structure and temperature profile of the IRAS 4A2 hot corino at 20-50 au

Young low-mass protostars often possess hot corinos, compact, hot and dense regions bright in interstellar Complex Organic Molecules (iCOMs). Besides of their prebiotic role, iCOMs can be used as a powerful tool to characterize the chemical and physical properties of hot corinos. Using ALMA/FAUST data we aim to explore the iCOMs emission at < 50 au scale around the Class 0 prototypical hot corino IRAS 4A2. We imaged IRAS 4A2 in six abundant, common iCOMs (CH$_3$OH, HCOOCH$_3$, CH$_3$CHO, CH$_3$CH$_2$OH, CH$_2$OHCHO, and NH$_2$CHO), and derived their emitting size. The column density and gas temperature for each species were derived at 1$σ$ from a multi-line analysis by applying a non-LTE approach for CH$_3$OH, and LTE population or rotational diagram analysis for the other iCOMs. Thanks to the unique estimates of the absorption from foreground millimeter dust toward IRAS 4A2, we derived for the first time unbiased gas temperatures and column densities. We resolved the IRAS 4A2 hot corino finding evidence for a chemical spatial distribution in the inner 50 au, with the outer emitting radius increasing from ~ 22-23 au for NH$_2$CHO and CH$_2$OHCHO, followed by CH$_3$CH$_2$OH (~ 27 au), CH$_3$CHO (~ 28 au), HCOOCH$_3$ (~ 36 au), and out to ~ 40 au for CH$_3$OH. Combining our estimate of the gas temperature probed by each iCOM with their beam-deconvolved emission sizes, we inferred the gas temperature profile of the hot corino on scales of 20-50 au in radius, finding a power-law index $q$ of approximately -1. We observed, for the first time, a chemical segregation in iCOMs of the IRAS 4A2 hot corino, and derived the gas temperature profile of its inner envelope. The derived profile is steeper than when considering a simple spherical collapsing and optically-thin envelope, hinting at a partially optically-thick envelope or a gravitationally unstable disk-like structure.

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arXiv2024

Dynamical Accretion Flows -- ALMAGAL: Flows along filamentary structures in high-mass star-forming clusters

We use data from the ALMA Evolutionary Study of High Mass Protocluster Formation in the Galaxy (ALMAGAL) survey to study 100 ALMAGAL regions at $\sim$ 1 arsecond resolution located between $\sim$ 2 and 6 kpc distance. Using ALMAGAL $\sim$ 1.3mm line and continuum data we estimate flow rates onto individual cores. We focus specifically on flow rates along filamentary structures associated with these cores. Our primary analysis is centered around position velocity cuts in H$_2$CO (3$_{0,3}$ - 2$_{0,2}$) which allow us to measure the velocity fields, surrounding these cores. Combining this work with column density estimates we derive the flow rates along the extended filamentary structures associated with cores in these regions. We select a sample of 100 ALMAGAL regions covering four evolutionary stages from quiescent to protostellar, Young Stellar Objects (YSOs), and HII regions (25 each). Using dendrogram and line analysis, we identify a final sample of 182 cores in 87 regions. In this paper, we present 728 flow rates for our sample (4 per core), analysed in the context of evolutionary stage, distance from the core, and core mass. On average, for the whole sample, we derive flow rates on the order of $\sim$10$^{-4}$ M$_{sun}$yr$^{-1}$ with estimated uncertainties of $\pm$50%. We see increasing differences in the values among evolutionary stages, most notably between the less evolved (quiescent/protostellar) and more evolved (YSO/HII region) sources. We also see an increasing trend as we move further away from the centre of these cores. We also find a clear relationship between the flow rates and core masses $\sim$M$^{2/3}$ which is in line with the result expected from the tidal-lobe accretion mechanism. Overall, we see increasing trends in the relationships between the flow rate and the three investigated parameters; evolutionary stage, distance from the core, and core mass.

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arXiv2024

FAUST. XVIII. Evidence for annular substructure in a very young Class 0 disk

When the planet formation process begins in the disks surrounding young stars is still an open question. Annular substructures such as rings and gaps in disks are intertwined with planet formation, and thus their presence or absence is commonly used to investigate the onset of this process. Current observations show a limited number of disks surrounding protostars exhibiting annular substructures, all of them in the Class I stage. The lack of observed features in most of these sources may indicate a late emergence of substructures, but it could also be an artifact of these disks being optically thick. To mitigate the problem of optical depth, we investigate substructures within a very young Class 0 disk characterized by a low inclination using observations at longer wavelengths. We use 3 mm ALMA observations tracing dust emission at a resolution of 7 au to search for evidence of annular substructures in the disk around the deeply embedded Class 0 protostar Oph A SM1. The observations reveal a nearly face-on disk (i$\sim$16$^{\circ}$) extending up to 40 au. The radial intensity profile shows a clear deviation from a smooth profile near 30 au, which we interpret as the presence of either a gap at 28 au or a ring at 34 au with Gaussian widths of $σ=1.4^{+2.3}_{-1.2}$ au and $σ=3.9^{+2.0}_{-1.9}$ au, respectively. The 3 mm emission at the location of the possible gap or ring is determined to be optically thin, precluding the possibility that this feature in the intensity profile is due to the emission being optically thick. Annular substructures resembling those in the more evolved Class I and II disks could indeed be present in the Class 0 stage, earlier than previous observations suggested. Similar observations of embedded disks in which the high optical depth problem can be mitigated are clearly needed to better constrain the onset of substructures in the embedded stages.

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arXiv2024

The chemistry of star and planet formation with SKA

In this contribution, we aim to summarise the efforts of the Italian SKA scientific community in conducting surveys of star-forming regions within our Galaxy, in the development of astrochemical research on protostellar envelopes and disks, and in studying the planet formation process itself. The objective is dual: Firstly, to investigate the accumulation and development of dust throughout the formation of planets, and secondly, to chemically examine protoplanetary disks and protostellar envelopes by studying heavy molecules, such as chains and rings containing over seven carbon atoms, which exhibit significantly reduced strength at millimeter wavelengths.

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arXiv2024

FAUST XVII: Super deuteration in the planet forming system IRS 63 where the streamer strikes the disk

Recent observations suggest that planets formation starts early, in protostellar disks of $\le10^5$ yrs, which are characterized by strong interactions with the environment, e.g., through accretion streamers and molecular outflows. To investigate the impact of such phenomena on disk physical and chemical properties it is key to understand what chemistry planets inherit from their natal environment. In the context of the ALMA Large Program Fifty AU STudy of the chemistry in the disk/envelope system of Solar-like protostars (FAUST), we present observations on scales from ~1500 au to ~60 au of H$_2$CO, HDCO, and D$_2$CO towards the young planet-forming disk IRS~63. H$_2$CO probes the gas in the disk as well as in a large scale streamer (~1500 au) impacting onto the South-East (SE) disk side. We detect for the first time deuterated formaldehyde, HDCO and D$_2$CO, in a planet-forming disk, and HDCO in the streamer that is feeding it. This allows us to estimate the deuterium fractionation of H$_2$CO in the disk: [HDCO]/[H$_2$CO]$\sim0.1-0.3$ and [D$_2$CO]/[H$_2$CO]$\sim0.1$. Interestingly, while HDCO follows the H$_2$CO distribution in the disk and in the streamer, the distribution of D$_2$CO is highly asymmetric, with a peak of the emission (and [D]/[H] ratio) in the SE disk side, where the streamer crashes onto the disk. In addition, D$_2$CO is detected in two spots along the blue- and red-shifted outflow. This suggests that: (i) in the disk, HDCO formation is dominated by gas-phase reactions similarly to H$_2$CO, while (ii) D$_2$CO was mainly formed on the grain mantles during the prestellar phase and/or in the disk itself, and is at present released in the gas-phase in the shocks driven by the streamer and the outflow. These findings testify on the key role of streamers in the build-up of the disk both concerning the final mass available for planet formation and its chemical composition.

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arXiv2024

Planet Formation and Disk Chemistry: Dust and Gas Evolution during Planet Formation

Over the past decade, progress in observational capabilities, combined with theoretical advancements, have transformed our comprehension of the physics and chemistry during planet formation. Despite these important steps forward, open questions persist on the chemical and physical evolution of solids in their journey from the collapsing molecular cores to disks and planetary bodies. This chapter is a repository of such burning questions. It has the ambition to identify the most promising avenues for future research based on current observational and modeling opportunities.

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arXiv2024

The GUAPOS project. V: The chemical ingredients of a massive stellar protocluster in the making

Most stars, including the Sun, are born in rich stellar clusters containing massive stars. Therefore, the study of the chemical reservoir of massive star-forming regions is crucial to understand the basic chemical ingredients available at the dawn of planetary systems. We present a detailed study of the molecular inventory of the hot molecular core G31.41+0.31 from the project GUAPOS (G31.41+0.31 Unbiased ALMA sPectral Observational Survey). We analyze 34 species for the first time plus 20 species analyzed in previous GUAPOS works, including oxygen, nitrogen, sulfur, phosphorus, and chlorine species. We compare the abundances derived in G31.41+0.31 with those observed in other chemically-rich sources that represent the initial and last stages of the formation of stars and planets: the hot corino in the Solar-like protostar IRAS 16293-2422 B, and the comets 67P/Churyumov-Gerasimenko and 46P/Wirtanen. The comparative analysis reveals that the chemical feedstock of the two star-forming regions are similar. The abundances of oxygen- and nitrogen-bearing molecules exhibit a good correlation for all pair of sources, including the two comets, suggesting a chemical heritage of these species during the process of star formation, and hence an early phase formation of the molecules. However, sulfur- and phosphorus-bearing species present worse correlations, being more abundant in comets. This suggests that while sulfur- and phosphorus-bearing species are predominantly trapped on the surface of icy grains in the hot close surroundings of protostars, they could be more easily released into gas phase in comets, allowing their cosmic abundances to be almost recovered.

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arXiv2024

FAUST XIII. Dusty cavity and molecular shock driven by IRS7B in the Corona Australis cluster

The origin of the chemical diversity observed around low-mass protostars probably resides in the earliest history of these systems. We aim to investigate the impact of protostellar feedback on the chemistry and grain growth in the circumstellar medium of multiple stellar systems. In the context of the ALMA Large Program FAUST, we present high-resolution (50 au) observations of CH$_3$OH, H$_2$CO, and SiO and continuum emission at 1.3 mm and 3 mm towards the Corona Australis star cluster. Methanol emission reveals an arc-like structure at $\sim$1800 au from the protostellar system IRS7B along the direction perpendicular to the major axis of the disc. The arc is located at the edge of two elongated continuum structures that define a cone emerging from IRS7B. The region inside the cone is probed by H$_2$CO, while the eastern wall of the arc shows bright emission in SiO, a typical shock tracer. Taking into account the association with a previously detected radio jet imaged with JVLA at 6 cm, the molecular arc reveals for the first time a bow shock driven by IRS7B and a two-sided dust cavity opened by the mass-loss process. For each cavity wall, we derive an average H$_2$ column density of $\sim$7$\times$10$^{21}$ cm$^{-2}$, a mass of $\sim$9$\times$10$^{-3}$ M$_\odot$, and a lower limit on the dust spectral index of $1.4$. These observations provide the first evidence of a shock and a conical dust cavity opened by the jet driven by IRS7B, with important implications for the chemical enrichment and grain growth in the envelope of Solar System analogues.

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arXiv2024

Evolution of the relation between the mass accretion rate and the stellar and disk mass from brown dwarfs to stars

The time evolution of the dependence of the mass accretion rate with the stellar mass and the disk mass represents a fundamental way to understand the evolution of protoplanetary disks and the formation of planets. In this work, we present observations with X-Shooter of 26 Class II very low-mass stars and brown dwarfs in the Ophiuchus, Cha-I, and Upper Scorpius star-forming regions (SFRs). These new observations extend down to SpT M9 ($\sim$0.02 $M_\odot$) the measurement of the mass accretion rate in Ophiuchus and Cha-I and add 11 very-low-mass stars to the sample of objects studied with broadband spectroscopy in Upper Scorpius. We obtained their SpT, extinction and physical parameters, and we used the intensity of various emission lines to derive their accretion luminosity and mass accretion rates. Combining these new observations with data from the literature, we compare relations between accretion and stellar and disk properties of four different SFRs with different ages: Ophiuchus (1 Myr), Lupus (2 Myr), Cha-I (3 Myr), and Upper Scorpius (5-12 Myr). We find the slopes of the $L_*-L\mathrm{_{acc}}$ and $M_*-\dot{M}\mathrm{_{acc}}$ relationships to steepen between Ophiuchus, Lupus, and Cha-I and that both relationships may be better described with a single power law. We also find the relationship between the disk mass and the mass accretion rate of the stellar population to steepen with time down to the age of Upper Scorpius. Overall, we observe hints of a faster evolution into low accretion rates of low-mass stars and brown dwarfs. We also find that brown dwarfs present higher $M\mathrm{_{disk}}/\dot{M}\mathrm{_{acc}}$ ratios (i.e., longer accretion depletion timescales) than stars in Ophiuchus, Lupus, and Cha-I. This apparently contradictory result may imply that the evolution of protoplanetary disks around brown dwarfs is different from what is seen in the stellar regime.

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arXiv2023

Influence of protostellar outflows on star and protoplanetary disk formation in a massive star-forming clump

Context. Due to the presence of magnetic fields, protostellar jets/outflows are a natural consequence of accretion onto protostars. They are expected to play an important role for star and protoplanetary disk formation. Aims. We aim to determine the influence of outflows on star and protoplanetary disk formation in star forming clumps. Methods. Using RAMSES, we perform the first magnetohydrodynamics calculation of massive star-forming clumps with ambipolar diffusion, radiative transfer including the radiative feedback of protostars and protostellar outflows while systematically resolving the disk scales. We compare it to a model without outflows. Results. We find that protostellar outflows have a significant impact on both star and disk formation. They provide significant additional kinetic energy to the clump, with typical velocities of a few 10 km/s, impact the clump and disk temperatures, reduce the accretion rate onto the protostars and enhance fragmentation in the filaments. We find that they promote a more numerous stellar population. They do not impact much the low mass end of the IMF, which is probably controlled by the mass of the first Larson core, however, that they have an influence on its peak and high-mass end. Conclusions. Protostellar outflows appear to have a significant influence on both star and disk formation and should therefore be included in realistic simulations of star-forming environments.

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arXiv2023

Protostellar chimney flues: are jets and outflows lifting submillimetre dust grains from discs into envelopes?

Low dust opacity spectral indices ($β< 1$) measured in the inner envelopes of class 0/I young stellar objects (age $\sim 10^{4-5}$ yr) have been interpreted as the presence of (sub-)millimetre dust grains in these environments. The density conditions and the lifetimes of collapsing envelopes have proven unfavorable for the growth of solids up to millimetre sizes. As an alternative, magneto-hydrodynamical simulations suggest that protostellar jets and outflows might lift grains from circumstellar discs and diffuse them in the envelope. We reframe available data for the CALYPSO sample of Class 0/I sources and show tentative evidence for an anti-correlation between the value of $β_{1-3mm}$ measured in the inner envelope and the mass loss rate of their jets and outflows, supporting a connection between the two. We discuss the implications that dust transport from the disc to the inner envelope might have for several aspects of planet formation. Finally, we urge for more accurate measurements of both correlated quantities and extension of this work to larger samples, necessary to further test the transport scenario.

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arXiv2023

A dusty streamer infalling onto the disk of a class I protostar. ALMA dual-band constraints on grain properties and mass infall rate

Observations of interstellar material infalling onto star- and planet-forming systems have become increasingly common thanks to recent advancements in radio interferometry. These structures replenish disks with fresh material, have the potential to significantly alter their dynamics, trigger the formation of substructures, induce shocks, and modify their physical and chemical properties. In this study, we combine new ALMA band 3 and archival band 6 observations to characterize the dust content and mass infall rate of a 4,000 au arc-like structure infalling onto M512, a class I young stellar object located in the Lynds 1641 region of the Orion A molecular cloud. We measure for the first time spectral index maps and derive a dust opacity index profile along a streamer, constraining grain properties and its dust mass. We measure a spectral index $α\sim$ 3.2 across the entire structure, and a dust opacity index $β\sim$ 1.6. Given grain properties consistent with the measured $β$, the structure can host up to 245 M$_{\oplus}$ of dust, being comparable or even exceeding the mass of the inner, unresolved 600 au, which contains the protoplanetary disk of M512. Such a massive streamer can strongly affect the evolution of the star- and planet-forming inner system. Assuming typical ISM dust-to-gas ratio of 1%, free-fall timescales (50 kyr) imply total mass infall rates up to 1.5 $\cdot$ 10$^{-6}$ M$_{\odot}$/yr. M512 has been classified as an outbursting source with multi-epoch photometry, thus representing an interesting case study to explore the possible connection between infalling streamers and accretion outbursts.

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arXiv2023

FAUST IX. Multi-band, multi-scale dust study of L1527 IRS. Evidence for dust properties variations within the envelope of a Class 0/I YSO

Early dust grain growth in protostellar envelopes infalling on young discs has been suggested in recent studies, supporting the hypothesis that dust particles start to agglomerate already during the Class 0/I phase of young stellar objects (YSOs). If this early evolution were confirmed, it would impact the usually assumed initial conditions of planet formation, where only particles with sizes $\lesssim 0.25 μ$m are usually considered for protostellar envelopes. We aim to determine the maximum grain size of the dust population in the envelope of the Class 0/I protostar L1527 IRS, located in the Taurus star-forming region (140 pc). We use Atacama Large millimetre/sub-millimetre Array (ALMA) and Atacama Compact Array (ACA) archival data and present new observations, in an effort to both enhance the signal-to-noise ratio of the faint extended continuum emission and properly account for the compact emission from the inner disc. Using observations performed in four wavelength bands and extending the spatial range of previous studies, we aim to place tight constraints on the spectral ($α$) and dust emissivity ($β$) indices in the envelope of L1527 IRS. We find a rather flat $α\sim$ 3.0 profile in the range 50-2000 au. Accounting for the envelope temperature profile, we derive values for the dust emissivity index, 0.9 < $β$ < 1.6, and reveal a tentative, positive outward gradient. This could be interpreted as a distribution of mainly ISM-like grains at 2000 au, gradually progressing to (sub-)millimetre-sized dust grains in the inner envelope, where at R=300 au, $β$ = 1.1 +/- 0.1. Our study supports a variation of the dust properties in the envelope of L1527 IRS. We discuss how this can be the result of in-situ grain growth, dust differential collapse from the parent core, or upward transport of disc large grains.

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arXiv2023

Synthetic populations of protoplanetary disks. Impact of magnetic fields and radiative transfer

Protostellar disks are the product of angular momentum conservation during the protostellar collapse. Understanding their formation is crucial because they are the birthplace of planets and because their formation is tightly related to star formation. Unfortunately, the initial properties of Class 0 disks and their evolution are still poorly constrained observationally and theoretically. We aim to better understand the mechanisms that set the statistics of disk properties as well as to study their formation in massive protostellar clumps. We also want to provide the community with synthetic disk populations to better interpret young disk observations. We use the ramses code to model star and disk formation in massive protostellar clumps with MHD including the effect of ambipolar diffusion and RT including the stellar radiative feedback. Those simulations, resolved up to the astronomical unit scale, allow to investigate the formation of disk populations. Magnetic fields play a crucial role in disk formation. A weaker initial field leads to larger and massive disks and weakens the stellar radiative feedback by increasing fragmentation. We find that ambipolar diffusion impacts disk and star formation and leads to very different disk magnetic properties. The stellar radiative feedback also have a strong influence, increasing the temperature and reducing fragmentation. Comparing our disk populations with observations reveals that our models with a mass-to-flux ratio of 10 seems to better reproduce observed disk sizes. This also sheds light on a tension between models and observations for the disk masses. The clump properties and physical modeling impact disk populations significantly. The tension between observations and models for disk mass estimates is critical to solve with synthetic observations in future years, in particular for our comprehension of planet formation.

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arXiv2023

The GUAPOS project:III. Characterization of the O- and N-bearing complex organic molecules content and search for chemical differentiation

The G31.41+0.31 Unbiased ALMA sPectral Observational Survey (GUAPOS) project targets the hot molecular core (HMC) G31.41+0.31 (G31), to unveil the complex chemistry of one of the most chemically rich high-mass star-forming regions outside the Galactic Center (GC). In the third paper of the project, we present a study of nine O-bearing (CH$_3$OH, $^{13}$CH$_3$OH, CH$_3^{18}$OH, CH$_3$CHO, CH$_3$OCH$_3$, CH$_3$COCH$_3$ , C$_2$H$_5$OH, aGg'-(CH$_2$OH)$_2$, and gGg'-(CH$_2$OH)$_2$) and six N-bearing (CH$_3$CN, $^{13}$CH$_3$CN, CH$_3^{13}$CN, C$_2$H$_3$CN, C$_2$H$_5$CN, and C$_2$H$_5^{13}$CN) complex organic molecules toward G31. The aim of this work is to characterize the abundances in one of the most chemically-rich hot molecular cores outside the GC and to search for a possible chemical segregation between O-bearing and N-bearing species in G31, which hosts four compact sources as seen with higher angular resolution data. Observations were carried out with the interferometer ALMA and covered the entire Band 3 from 84 to 116 GHz ($\sim 32$ GHz bandwidth) with an angular resolution of $1.2''$ ($\sim4400\,\mathrm{au}$). The spectrum has been analyzed with the tool SLIM of MADCUBA to determine the physical parameters of the emitting gas. Moreover, we have analyzed the morphology of the emission of the molecular species. We have compared the abundances w.r.t methanol of COMs in G31 with other twenty-seven sources, including other hot molecular cores inside and outside the Galactic Center, hot corinos, shocked regions, envelopes around young stellar objects, and quiescent molecular clouds, and with chemical models. Different species peak at slightly different positions, and this, together with the different central velocities of the lines obtained from the spectral fitting, point to chemical differentiation of selected O-bearing species.

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