Searcharxiv⌕ Search

arXiv subjects

Lamberto Rondoni

Publications and source records attributed to Lamberto Rondoni.

79 records · Page 5Linked to original sources

Fluctuations in Nonequilibrium Statistical Mechanics: Models, Mathematical Theory, Physical Mechanisms

The fluctuations in nonequilibrium systems are under intense theoretical and experimental investigation. Topical ``fluctuation relations'' describe symmetries of the statistical properties of certain observables, in a variety of models and phenomena. They have been derived in deterministic and, later, in stochastic frameworks. Other results first obtained for stochastic processes, and later considered in deterministic dynamics, describe the temporal evolution of fluctuations. The field has grown beyond expectation: research works and different perspectives are proposed at an ever faster pace. Indeed, understanding fluctuations is important for the emerging theory of nonequilibrium phenomena, as well as for applications, such as those of nanotechnological and biophysical interest. However, the links among the different approaches and the limitations of these approaches are not fully understood. We focus on these issues, providing: a) analysis of the theoretical models; b) discussion of the rigorous mathematical results; c) identification of the physical mechanisms underlying the validity of the theoretical predictions, for a wide range of phenomena.

cond-mat.stat-mech↗

The Steady State Fluctuation Relation for the Dissipation Function

We give a proof of transient fluctuation relations for the entropy production (dissipation function) in nonequilibrium systems, which is valid for most time reversible dynamics. We then consider the conditions under which a transient fluctuation relation yields a steady state fluctuation relation for driven nonequilibrium systems whose transients relax, producing a unique nonequilibrium steady state. Although the necessary and sufficient conditions for the production of a unique nonequilibrium steady state are unknown, if such a steady state exists, the generation of the steady state fluctuation relation from the transient relation is shown to be very general. It is essentially a consequence of time reversibility and of a form of decay of correlations in the dissipation, which is needed also for, e.g., the existence of transport coefficients. Because of this generality the resulting steady state fluctuation relation has the same degree of robustness as do equilibrium thermodynamic equalities. The steady state fluctuation relation for the dissipation stands in contrast with the one for the phase space compression factor, whose convergence is problematic, for systems close to equilibrium. We examine some model dynamics that have been considered previously, and show how they are described in the context of this work.

cond-mat.stat-mech↗

Relevance of initial and final conditions for the Fluctuation Relation in Markov processes

Numerical observations on a Markov chain and on the continuous Markov process performed by a granular tracer show that the ``usual'' fluctuation relation for a given observable is not verified for finite (but arbitrarily large) times. This suggests that some terms which are usually expected to be negligible, i.e. ``border terms'' dependent only on initial and final states, in fact cannot be neglected. Furthermore, the Markov chain and the granular tracer behave in a quite similar fashion.

cond-mat.stat-mech↗

Boltzmann entropy and chaos in a large assembly of weakly interacting systems

We introduce a high dimensional symplectic map, modeling a large system consisting of weakly interacting chaotic subsystems, as a toy model to analyze the interplay between single-particle chaotic dynamics and particles interactions in thermodynamic systems. We study the growth with time of the Boltzmann entropy, S_B, in this system as a function of the coarse graining resolution. We show that a characteristic scale emerges, and that the behavior of S_B vs t, at variance with the Gibbs entropy, does not depend on the coarse graining resolution, as far as it is finer than this scale. The interaction among particles is crucial to achieve this result, while the rate of entropy growth depends essentially on the single-particle chaotic dynamics (for t not too small). It is possible to interpret the basic features of the dynamics in terms of a suitable Markov approximation.

nlin.CD↗

On the Application of the Gallavotti-Cohen Fluctuation Relation to Thermostatted Steady States Near Equilibrium

The fluctuation relation of the Gallavotti-Cohen Fluctuation Theorem (GCFT) concerns fluctuations in the phase space compression rate of dissipative, reversible dynamical systems. It has been proven for Anosov systems, but it is expected to apply more generally. This raises the question of which non-Anosov systems satisfy the fluctuation relation. We analyze time dependent fluctuations in the phase space compression rate of a class of N-particle systems that are at equilibrium or in near equilibrium steady states. This class does not include Anosov systems or isoenergetic systems, however, it includes most steady state systems considered in molecular dynamics simulations of realistic systems. We argue that the fluctuations of the phase space compression rate of these systems at or near equilibrium do not satisfy the fluctuation relation of the GCFT, although the discrepancies become somewhat smaller as the systems move further from equilibrium. In contrast, similar fluctuation relations for an appropriately defined dissipation function appear to hold both near and far from equilibrium.

cond-mat.stat-mech↗

Lyapunov spectra and nonequilibrium ensembles equivalence in 2D fluid mechanics

We perform numerical experiments to study the Lyapunov spectra of dynamical systems associated with the Navier--Stokes (NS) equation in two spatial dimensions truncated over the Fourier basis. Recently new equations, called GNS equations, have been introduced and conjectured to be equivalent to the NS equations at large Reynolds numbers. The Lyapunov spectra of the NS and of the corresponding GNS systems overlap, adding evidence in favor of the conjectured equivalence already studied and partially extended in previous papers. We make use of the Lyapunov spectra to study a fluctuation relation which had been proposed to extend the ``fluctuation theorem'' to strongly dissipative systems. Preliminary results towards the formulation of a local version of the fluctuation formula are also presented.

nlin.CD↗

Fluctuations in 2D reversibly-damped turbulence

Gallavotti proposed an equivalence principle in hydrodynamics, which states that forced-damped fluids can be equally well represented by means of the Navier-Stokes equations and by means of time reversible dynamical systems called GNS. In the GNS systems, the usual viscosity is replaced by a state-dependent dissipation term which fixes one global quantity. The principle states that the mean values of properly chosen observables are the same for both representations of the fluid. In the same paper, the chaotic hypothesis of Gallavotti and Cohen is applied to hydrodynamics, leading to the conjecture that entropy fluctuations in the GNS system verify a relation first observed in nonequilibrium molecular dynamics. We tested these ideas in the case of two-dimensional fluids. We examined the fluctuations of global quadratic quantities in the statistically stationary state of a) the Navier-Stokes equations; b) the GNS equations. Our results are consistent with the validity of the fluctuation relation, and of the equivalence principle, indicating possible extensions thereof. Moreover, in these results the difference between the Gallavotti-Cohen fluctuation theorem and the Evans-Searles identity is evident.

chao-dyn↗