arXiv subjects

Laurence Brassart

Publications and source records attributed to Laurence Brassart.

4 recordsLinked to original sources

arXiv2026

Conformation-Mediated Kinetics of Polymer Chain Scission under Tension

Chain scission is a key molecular process underlying damage and fracture in polymer networks. In this Letter, we develop a statistical-mechanical framework for predicting chain-scission kinetics while accounting for three-dimensional (3D) conformational fluctuations. Within transition-state theory, scission is formulated as a multichannel first-rupture problem, with bond-specific rates governed primarily by self-consistent potentials of mean force. In the freely jointed limit, the additional 3D configurational freedom enhances rupture relative to the collinear 1D reference. Finite bending stiffness introduces orientational correlations that can reverse this enhancement and, at high stiffness, reduce rupture rates by orders of magnitude. These correlations also make rupture bond-position dependent, with higher rates near the chain ends and a common interior rate. For sufficiently long chains, the interior contribution dominates, yielding linear scaling of the chain-scission rate with chain length. These molecularly resolved rates provide physically grounded inputs for future network-scale models of polymer damage and fracture.

cond-mat.soft↗

arXiv2025

Stretching Response of a Polymer Chain with Deformable Bonds

The stretching response of polymer chains fundamentally determines the mechanical properties of polymer networks. In this Letter, we develop a statistical mechanics model that incorporates both bond stretching and bond angle deformation, enabling accurate predictions of chain behavior up to large forces. We further propose a semianalytical deformable freely rotating chain (dFRC) model, which represents the chain as a freely rotating chain with effective bond stretch and bond angle that depend on the chain stretch. Using physical parameters without fitting, both the statistical and dFRC models achieve excellent agreement with experimental data for carbon chains across all force regimes. Additionally, the dFRC model provides a direct estimate of the bond force, which is important to predict chain scission. By capturing key bond deformations while remaining computationally efficient, our work lays the foundation for future modeling of polymer network elasticity and failure.

cond-mat.soft↗

arXiv2018

Effective transient behaviour of heterogeneous media in diffusion problems with a large contrast in the phase diffusivities

This paper presents a homogenisation-based constitutive model to describe the effective tran- sient diffusion behaviour in heterogeneous media in which there is a large contrast between the phase diffusivities. In this case mobile species can diffuse over long distances through the fast phase in the time scale of diffusion in the slow phase. At macroscopic scale, contrasted phase diffusivities lead to a memory effect that cannot be properly described by classical Fick's second law. Here we obtain effective governing equations through a two-scale approach for composite materials consisting of a fast matrix and slow inclusions. The micro-macro transition is similar to first-order computational homogenisation, and involves the solution of a transient diffusion boundary-value problem in a Representative Volume Element of the microstructure. Different from computational homogenisation, we propose a semi-analytical mean-field estimate of the composite response based on the exact solution for a single inclusion developed in our previous work [Brassart, L., Stainier, L., 2018. Effective transient behaviour of inclusions in diffusion problems. Z. Angew Math. Mech. 98, 981-998]. A key outcome of the model is that the macroscopic concentration is not one-to-one related to the macroscopic chemical potential, but obeys a local kinetic equation associated with diffusion in the slow phase. The history-dependent macroscopic response admits a representation based on internal variables, enabling efficient time integration. We show that the local chemical kinetics can result in non-Fickian behaviour in macroscale boundary-value problems.

physics.comp-ph↗

arXiv2017

Effective transient behaviour of inclusions in diffusion problems

This paper is concerned with the effective transport properties of heterogeneous media in which there is a high contrast between the phase diffusivities. In this case the transient response of the slow phase induces a memory effect at the macroscopic scale, which needs to be included in a macroscopic continuum description. This paper focuses on the slow phase, which we take as a dispersion of inclusions of arbitrary shape. We revisit the linear diffusion problem in such inclusions in order to identify the structure of the effective (average) inclusion response to a chemical load applied on the inclusion boundary. We identify a chemical creep function (similar to the creep function of viscoelasticity), from which we construct estimates with a reduced number of relaxation modes. The proposed estimates admit an equivalent representation based on a finite number of internal variables. These estimates allow us to predict the average inclusion response under arbitrary time-varying boundary conditions at very low computational cost. A heuristic generalisation to concentration-dependent diffusion coefficient is also presented. The proposed estimates for the effective transient response of an inclusion can serve as a building block for the formulation of multi-inclusion homogenisation schemes.

physics.comp-ph↗