arXiv subjects

Laurent Limat

Publications and source records attributed to Laurent Limat.

16 recordsLinked to original sources

arXiv2025

Sliding of liquid droplets on thin viscoelastic soft layers

Soft substrates are deformed by liquid-vapor surface tension upon contact with liquid droplets, forming the well-known wetting ridge. This ridge dynamically propagates with the moving contact line and critically influences liquid spreading. Here, we experimentally investigate gravity-driven sliding dynamics of water droplets on vertically tilted silicone layers whose viscoleasticity is characterized by the Chasset-Thirion model with the exponent m. At low Bond numbers, the sliding velocity scales with droplet size as V S $\sim$ D 2 m . While in the thin-film limit, velocity exhibits a pronounced power-law dependence on nominal substrate thickness, V S $\sim$ $Π$(h) -1 m . We rationalize these observations by quantifying viscoelastic dissipation within the soft layer and balancing it against the gravitational driving force using an energy-conservation framework. Our findings offer novel avenues for designing advanced soft coatings, anti-fouling and self-cleaning surfaces, and biomedical devices.

cond-mat.soft↗

arXiv2023

Morphology and stability of droplets sliding on soft viscoelastic substrates

We show that energy dissipation partition between a liquid and a solid controls the shape and stability of droplets sliding on viscoelastic gels. When both phases dissipate energy equally, droplet dynamics is similar to that on rigid solids. When only the solid dissipate, we observe an apparent contact angle hysteresis, of viscoelastic origin. We find excellent agreement between our data and a non-linear model of the wetting of gels of our own that also indicates the presence of significant slip. Our work opens general questions on the dynamics of curved contact lines on compliant substrates.

cond-mat.soft↗

arXiv2021

Circular hydraulic jumps: where does surface tension matter?

Recently, an unusual scaling law has been observed in circular hydraulic jumps and has been attributed to a supposed missing term in the local energy balance of the flow [\cite{bhagat_2018}]. In this paper, we show that - though the experimental observation is valuable and interesting - this interpretation is presumably not the good one. When transposed to the case of a axial sheet formed by two impinging liquid jets, the assumed principle leads in fact to a velocity distribution in contradiction with the present knowledge for this kind of flows. We show here how to correct this approach by keeping consistency with surface tension thermodynamics: for Savart-Taylor sheets, when adequately corrected, we recover the well known $1/r$ liquid thickness with a constant and uniform velocity dictated by Bernoulli's principle. In the case of circular hydraulic jumps, we propose here a simple approach based on Watson description of the flow in the central region [\cite{Watson_JFM}]], combined with appropriate boundary conditions on the formed circular front. Depending on the specific condition, we find in turn the new scaling by \cite{bhagat_2018} and the more conventional scaling law found long ago by \cite{Bohr_1993}. We clarify here a few situations in which one should hold rather than the other, hoping to reconcile Bhagat et al. observations with the present knowledge of circular hydraulic jump modeling. However, the question of a possible critical Froude number imposed at the jump exit and dictating logarithmic corrections to scaling remains an opened and unsolved question.

physics.flu-dyn↗

arXiv2020

Spreading of granular suspensions on a solid surface

We examine the spreading of a suspension of non-Brownian spheres suspended in a Newtonian liquid on a solid substrate. We show that the spreading dynamics is well described by the classical Cox-Voinov law provided the value of the fluid viscosity that arises in the capillary number of the problem is adjusted to a value that depends on particle size and volume fraction in a non-trivial way. We demonstrate that this behavior is a signature of the ability of the particles to approach the contact line close enough to affect dissipation.

physics.flu-dyn↗

arXiv2020

A criterion for the pinning and depinning of an advancing contact line on a cold substrate

The influence of solidification on the spreading of liquids is addressed in the situation of an advancing liquid wedge on a cold substrate at $T_p < T_f$, of infinite thermal conductivity, where $T_f$ is the melting temperature. We propose a model derived from lubrication theory of contact-line dynamics, where an equilibrium between capillary pressure and viscous stress is at play, adapted here for the geometry of a quadruple line where the vapour, liquid, solidified liquid and basal substrate meet. The Stefan thermal problem is solved in an intermediate region between molecular and mesoscopic scales, allowing to predict the shape of the solidified liquid surface. The apparent contact angle versus advancing velocity $U$ exhibits a minimal value, which is set as the transition from continuous advancing to pinning. We postulate that this transition corresponds to the experimentally observed critical velocity, dependent on undercooling temperature $T_f-T_p$, below which the liquid is pinned and advances with stick-slip dynamics. The analytical solution of the model shows a qualitatively fair agreement with experimental data. We discuss on the way to get better quantitative agreement, which in particular can be obtained when the mesoscopic cut-off length is made temperature-dependent.

physics.flu-dyn↗

arXiv2019

Straight contact lines on a soft, incompressible solid

The deformation of a soft substrate by a straight contact line is calculated, and the result applied to a static rivulet between two parallel contact lines. The substrate is supposed to be incompressible (Stokes like description of elasticity), and having a non-zero surface tension, that eventually differs depending on whether its surface is dry or wet. For a single straight line separating two domains with the same substrate surface tension, the ridge profile is shown to be be very close to that of Shanahan and de Gennes, but shift from the contact line of a distance equal to the elastocapillary length built upon substrate surface tension and shear modulus. As a result, the divergence near contact line disappears and is replaced by a balance of surface tensions at the contact line (Neumann equilibrium), though the profile remains nearly logarithmic. In the rivulet case, using the previous solution as a Green function allows one to calculate analytically the geometry of the distorted substrate, and in particular its slope on each side (wet and dry) of the contact lines. These two slopes are shown to be nearly proportional to the inverse of substrate surface tensions, though the respective weight of each side (wet and dry) in the final expressions is difficult to establish because of the linear nature of standard elasticity. A simple argument combining Neumann and Young equations is however provided to overcome this limitation. The result may have surprising implications for the modelling of hysteresis on systems having both plastic and elastic properties, as initiated long ago by Extrand and Kumagai.

cond-mat.soft↗

arXiv2019

Nonlinear force balance at moving contact lines

The spreading of a liquid over a solid material is a key process in a wide range of applications. While this phenomenon is well understood when the solid is undeformable, its "soft" counterpart is still ill-understood and no consensus has been reached with regards to the physical mechanisms ruling the spreading of liquid drops over soft deformable materials. In this work we show that the motion of a triple line on a soft elastomer is opposed both by nonlinear localized capillary and visco-elastic forces. We give an explicit analytic formula relating the dynamic contact angle of a moving drop with its velocity for arbitrary rheology. We then specialize this formula to the experimentally relevant case of elastomers with Chasset-Thirion (power-law) type of rheologies. The theoretical prediction are in very good agreement with experimental data, without any adjustable parameters. Finally, we show that the nonlinear force balance presented in this work can also be used to recover the classical de Gennes model of wetting.

cond-mat.soft↗

arXiv2018

Corners in soft solids behave as defects in crystals

All phases of matter, solid, liquid or gas, present some excess energy, compared to their bulk, at their interfaces with other materials. This excess of energy, known as the surface energy, is a fundamental property of matter and is involved in virtually all interface problems in science, from the shape of bubbles, crystals and biological cells to the delicate motion of some insects on water or the fluttering of red blood cells. Because of their high cohesive internal energies, the surface energies of solids differ fundamentally from those of fluids and depend on the solid deformations. This effect, known as the Shuttleworth effect, is well established for metals but is highly debated for amorphous materials such as glasses, elastomers or biological tissues with recent experimental results yielding strictly opposite conclusions with regards to its very existence. Using a combination of analytical results and numerical simulations, we show in this paper that those seemingly opposite results can be reconciled due to the existence of an analog of the Peach-Koehler force acting on the elastocapillary ridge and conclude that: i) there is no large Shuttleworth effect in soft elastomers and ii) the Neumann construction does not hold in elastowetting.

cond-mat.soft↗

arXiv2017

Diffusiophoretic manipulation of particles in a drop deposited on a hydrogel

We report an experimental study on the manipulation of colloidal particles in a drop sitting on a hydrogel. The manipulation is achieved by diffusiophoresis, which describes a directed motion of particles induced by solute gradients. By letting the solute concentrations for the drop and the hydrogel be different, we control the motion of particles in a stable suspension, which is otherwise difficult to achieve. We show that diffusiophoresis can cause the particles to move either toward or away from the liquid-air interface depending on the direction of the solute gradient and the surface charge of the particles. We measure the particle adsorption experimentally and rationalize the results with a one-dimensional numerical model. We show that diffusiophoretic motion is significant at the lengthscale of a drop deposited on a hydrogel, which suggests a simple method for the deposition of particles on hydrogels.

cond-mat.soft↗

arXiv2016

Tuning the receding contact angle on hydrogels by addition of particles

Control of the swelling, chemical functionalization, and adhesivity of hydrogels are finding new applications in a wide range of material systems. We investigate experimentally the effect of adsorbed particles on hydrogels on the depinning of contact lines. In our experiments, a water drop containing polystyrene microspheres is deposited on a swelling hydrogel, which leads to the drop absorption and particle deposition. Two regimes are observed: a decreasing drop height with a pinned contact line followed by a receding contact line. We show that increasing the particles concentration increases the duration of the first regime and significantly decreases the total absorption time. The adsorbed particles increase the pinning force at the contact line. Finally, we develop a method to measure the receding contact angle with the consideration of the hydrogel swelling.

cond-mat.soft↗

arXiv2015

Homogeneous deposition of particles by absorption on hydrogels

When a drop containing colloidal particles evaporates on a surface, a circular stain made of these particles is often observed due to an internal flow toward the contact line. To hinder this effect, several approaches have been proposed such as flow modification by addition of surfactants or control of the interactions between the particles. All of these strategies involve the liquid phase while maintaining the drying process. However, substitution of evaporation by absorption into the substrate of the solvent has been investigated less. Here, we show that a droplet containing colloidal particles deposited on swelling hydrogels can lead to a nearly uniform coating. We report experiments and theory to explore the relation between the gel swelling, uniformity of deposition and the adsorption dynamics of the particles at the substrate. Our findings suggest that draining the solvent by absorption provides a robust route to homogeneous coatings.

cond-mat.soft↗

arXiv2015

A liquid contact line receding on a soft gel surface : dip-coating geometry investigation

We studied the dynamics of a liquid contact line receding on a hydrophobic soft gel (SBS-paraffin). In order to realize a well-defined geometry with an accurate control of velocity, a dip-coating setup was implemented. Provided that the elastic modulus is small enough, a significant deformation takes place near the contact line, which in turn drastically influences the wetting behaviour. Depending on the translation velocity of the substrate, the contact line exhibits different regimes of motions. Continuous motions are observed at high and low velocities, meanwhile two types of stick-slip motion, periodic and erratic, appear at intermediate velocities. We suggest that the observed transitions could be explained in terms of the competition between different frequencies, i.e., the frequency of the strain field variation induced by the contact line motion and the crossover frequency of the gel related to the material relaxation. Our results provide systematic views on how the wetting of liquid is modified by the rheological properties of a complex soft substrate.

physics.flu-dyn↗

arXiv2014

Constant Froude number in a circular hydraulic jump and its implication on the jump radius selection

The properties of a standard hydraulic jump depend critically on a Froude number Fr defined as the ratio of the flow velocity to the gravity waves speed. In the case of a horizontal circular jump, the question of the Froude number is not well documented. Our experiments show that Fr measured just after the jump is locked on a constant value that does not depend on flow rate Q, kinematic viscosity ν and surface tension γ. Combining this result to a lubrication description of the outer flow yields, under appropriate conditions, a new and simple law ruling the jump radius RJ : $R_J (ln (\frac{R_\infty}{R_J}))^{3/8} \sim Q^{5/8}ν^{-3/8}$, in excellent agreement with our experimental data. This unexpected RJ result asks an unsolved question to all available models.

physics.flu-dyn↗

arXiv2013

Orbits and reversals of a drop rolling inside a horizontal circular hydraulic jump

We explore the complex dynamics of a non-coalescing drop of moderate size inside a circular hydraulic jump of the same liquid formed on a horizontal disk. In this situation the drop is moving along the jump and one observes two different motions: a periodic one (it orbitates at constant speed) and an irregular one involving reversals of the orbital motion. Modeling the drop as a rigid sphere exchanging friction with liquid across a thin film of air, we recover the orbital motion and the internal rotation of the drop. This internal rotation is experimentally observed.

physics.flu-dyn↗

arXiv2006

Meandering rivulets on a plane: a simple balance between inertia and capillarity?

Experiments on streams of water flowing down a rigid substrate have been performed for various plate inclinations and flow rates, and we focused on the regime of stationary meanders. The outcome is that (i) the flow is highly hysteretic : the shape of the meanders varies with flow rate only for increasing flow rates, and the straight rivulet regime does not appear for decreasing flow rate. (ii) A simple force balance, including inertia, capillary forces, and also hysteresis of wetting, accounts well for the experimental instability threshold flow rate and for the final radius of curvature of the meanders.

physics.flu-dyn↗

arXiv2003

Elastic properties of cellular dissipative structure

Transition towards spatio-temporal chaos in one-dimensional interfacial patterns often involves two degrees of freedom: drift and out-of-phase oscillations of cells, respectively associated to parity breaking and vacillating-breathing secondary bifurcations. In this paper, the interaction between these two modes is investigated in the case of a single domain propagating along a circular array of liquid jets. As observed by Michalland and Rabaud for the printer's instability \cite{Rabaud92}, the velocity $V_g$ of a constant width domain is linked to the angular frequency $ω$ of oscillations and to the spacing between columns $λ_0$ by the relationship $ V_g = αλ_0 ω$. We show by a simple geometrical argument that $α$ should be close to $1/ π$ instead of the initial value $α= 1/2$ deduced from their analogy with phonons. This fact is in quantitative agreement with our data, with a slight deviation increasing with flow rate.

cond-mat↗