arXiv subjects

Laurent Pagani

Publications and source records attributed to Laurent Pagani.

At least 19 recordsLinked to original sources

arXiv2026

Local constraints on alcohol--thioalcohol analogs in G35.2N

The chemistry of sulfur-bearing complex organic molecules in dense star-forming environments remains uncertain, partly because the dominant sulfur reservoirs in dense gas and ices are poorly identified. Alcohol--thioalcohol pairs allow direct comparisons of structurally related O- and S-bearing molecules. We present ALMA Band 6 observations of CH$_3$OH/CH$_3$SH and C$_2$H$_5$OH/C$_2$H$_5$SH toward three spectral-extraction positions (MM3-pos, MM4-pos, and MM5-pos) in the MM3--MM5 region of G35.2N. Local thermodynamic equilibrium modeling yields column densities and abundance ratios. CH$_3$OH column densities were inferred from $^{13}$CH$_3$OH assuming $^{12}$C/$^{13}$C = 50 to mitigate optical-depth effects. CH$_3$OH, CH$_3$SH, and C$_2$H$_5$OH are robustly constrained at all three positions; C$_2$H$_5$SH is robustly constrained at MM3-pos and MM5-pos but remains tentative at MM4-pos. The corresponding adopted column-density ranges are $(1.8-2.7)\times10^{18}$, $(1.7-2.6)\times10^{16}$, $(5.7-8.5)\times10^{16}$, and $(2.4-4.6)\times10^{15}$ cm$^{-2}$. The CH$_3$OH/C$_2$H$_5$OH and CH$_3$OH/CH$_3$SH ratios are consistent across the positions within uncertainties, with nominal values of 31--32 and 100--110, respectively. Comparisons with chemically rich sources and warm-up chemical models show that CH$_3$OH/C$_2$H$_5$OH lies within the range measured elsewhere, whereas CH$_3$OH/CH$_3$SH exhibits greater source-to-source variation. The ethyl-level O/S comparison remains less certain because many literature C$_2$H$_5$SH measurements provide only lower limits. CH$_3$OH/CH$_3$SH is thus the best-constrained O/S alcohol--thioalcohol ratio in these data and provides an empirical probe of source-dependent sulfur-bearing organic chemistry. More sensitive C$_2$H$_5$SH observations are needed to test C$_2$H$_5$OH/C$_2$H$_5$SH.

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arXiv2026

Molecule-dependent Abundance Behavior of Oxygen-bearing Complex Organics in High-Mass Star-Forming Regions: A Uniform 50-source Survey

We present a uniform IRAM-30\,m survey analysis of four oxygen-bearing complex organic molecules (COMs), methanol (CH$_3$OH), acetaldehyde (CH$_3$CHO), methyl formate (CH$_3$OCHO), and dimethyl ether (CH$_3$OCH$_3$), toward 50 high-mass star-forming regions (HMSFRs) associated with 6.7\,GHz methanol masers. Column densities were derived through a homogeneous rotation-diagram approach, with CH$_3$CN used as a proxy excitation-temperature reference when needed. In CH$_3$OH-normalized abundance-ratio space, CH$_3$OCHO/CH$_3$OH and CH$_3$OCH$_3$/CH$_3$OH show the strongest pairwise correlation, whereas the correlations involving CH$_3$CHO are weaker. No clear monotonic trends are found with Galactocentric distance or beam-averaged H$_2$ column density. Comparison with previous observations places the CH$_3$OCHO--CH$_3$OCH$_3$ behavior within the range of earlier abundance-ratio measurements, while CH$_3$CHO shows larger inter-study variation. A representative warm-up chemical model is used only for qualitative comparison with the observed abundance ranges, which are most closely matched during the decline from the post-desorption abundance peaks in the model. These results provide homogeneous beam-averaged abundance-ratio constraints for common O-bearing COMs in high-mass star-forming regions and show that their source-to-source behavior is molecule-dependent rather than fully described by a single common abundance pattern.

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arXiv2026

First Interstellar Detection of Methyl Carbamate: A New Observational Anchor for Glycine Chemistry

Glycine-the simplest amino acid-has remained undetected in the interstellar medium despite decades of sensitive searches, motivating alternative approaches to constrain its astrochemical origin. A promising strategy is to investigate the broader $\rm C_{2}H_{5}O_{2}N$ isomer family and identify detectable members that can serve as observational anchors for glycine-related chemistry. Herein, we report the first robust interstellar detection of methyl carbamate toward the hot molecular core G358.93-0.03 MM1 using ALMA 1 mm observations. Ten unblended rotational transitions are identified, yielding a column density of (4.21$\pm0.84)\times10^{15} \rm cm^{-2}$ and an excitation temperature of $204\pm10$ K. We also searched for other $\rm C_{2}H_{5}O_{2}N$ isomers with available rotational spectroscopic data, including glycine, but none were detected, allowing us to derive upper limits on their column densities. The resulting abundance pattern deviates significantly from the Minimum Energy Principle predictions, highlighting that the $\rm C_{2}H_{5}O_{2}N$ family is shaped primarily by kinetic chemical process rather than thermodynamic equilibrium. The observed methyl carbamate abundance is consistent with a grain-surface formation scenario involving radical-radical recombination ($\rm CH_{3}$O + $\rm NH_{2}$CO), further supported by its correlated abundances with its proposed precursors, methanol and formamide, across diverse astrophysical environments. This detection establishes methyl carbamate as a new observational anchor for glycine chemistry, providing critical constraints on the formation pathways of amino-acid-related molecules in star-forming regions.

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arXiv2026

Tentative Detection of the Glycine Isomer Glycolamide in Hot Molecular Core

Understanding whether prebiotic molecules can endure and reform through the energetic stages of star formation is essential for tracing the continuity of interstellar chemistry toward life. Glycolamide, an isomer of glycine, was recently detected in the molecular cloud G+0.693-0.027. However, establishing its presence in warm, high-density environments is crucial to evaluate the chemical continuity of amides. Here we report the tentative detection of glycolamide in a hot molecular core, G358.93-0.03 MM1, using ALMA 1 mm observations. Seven unblended or only mildly blended emission lines were identified, yielding an abundance of (1.7$\pm$0.2)$\times 10^{-10}$ relative to H$_{2}$. The comparable formamide/glycolamide and acetamide/glycolamide abundance ratios in both sources suggest a chemically connected amide network across different environments. These results demonstrate that amides can persist and chemically evolve during massive star formation, tracing the chemical continuity from interstellar to protostellar environments.

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arXiv2025

Unveiling Central ortho-H2D+ Depletion at Sub-kau Scales in Prestellar Core G205.46-14.56M3: The First Interferometric Evidence and Implications for Deuterium Chemistry

Prestellar cores represent the initial conditions of star formation, but heavy molecules such as CO are strongly depleted in their cold, dense interiors, limiting the ability to probe core centers. Deuterated molecular ions therefore emerge as key tracers because deuterium fractionation is enhanced at low temperatures. We present the first direct observation of ortho-H2D+ depletion in the prestellar core G205.46-14.56M3 using ALMA 820um continuum and ortho-H2D+(110-111) data at ~300-au resolution. We confirm the previously reported two substructures, B1 and B2, and identify a central ortho-H2D+ depletion zone toward B1 with ~6$σ$ contrast and an inferred diameter $\lesssim$600au, together with a peak $x$(N2D+)/$x$(N2H+)=$1.03^{+0.07}_{-0.56}$. The observationally inferred profiles of $x$(ortho-H2D+) and $x$(N2D+)/$x$(N2H+) are reproduced by a deuteration-focused chemo-dynamical model; however, the central ortho-H2D+ depletion is only marginally matched within the $2σ$ upper limit, likely suggesting additional deuteration in the depletion zone. From these models we infer a core age of ~0.42Ma, comparable to the free-fall time, suggesting that the substructures formed via rapid, turbulence-dominated fragmentation rather than slow, quasi-static contraction. Our observations also reveal that ortho-H2D+ velocity dispersions are largely subsonic in the core and nearly thermal between B1 and B2, consistent with turbulence dissipating within a few free-fall times. These results highlight the critical role of deuterated ions for both chemical evolution and dynamics in dense cores.

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arXiv2025

The ALMA-QUARKS survey: Extensive detection of acetamide in multiple high-mass star-forming regions

Acetamide (CH$_{3}$CONH$_{2}$), a key interstellar amide and a methyl derivative of formamide (NH$_{2}$CHO), has been sparsely detected, limiting insights into its prebiotic relevance. We present the first systematic survey for acetamide toward 52 hot molecular cores using ALMA Band 6 data. Acetamide has been detected in 10 cores, markedly expanding the inventory of known emitters. The derived column densities of acetamide range from $(2.5\pm0.9)\times10^{14}$ to $(1.5\pm0.6)\times10^{16}$ cm$^{-2}$, compared to formamide's $(1.1\pm0.1)\times10^{15}$ to $(6.9\pm0.4)\times10^{16}$ cm$^{-2}$. The nearly constant abundance ratios (~3-9) and strong abundance correlation between the two amides across sources suggest a chemically linked formation pathway, likely on grain surfaces. The presence of peptide-like molecules in these regions implies that complex organic species can survive star formation processes, offering a potential pathway toward prebiotic chemistry. These findings constrain the dominant grain surface formation routes of acetamide, confirm its broader prevalence in highmass star-forming regions, and underscore the importance of targeted amide surveys in tracing the chemical evolution toward prebiotic complexity.

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arXiv2025

An ALMA Study of Molecular Complexity in the Hot Core G336.99-00.03 MM1

High-mass star formation involves complex processes, with the hot core phase playing a crucial role in chemical enrichment and the formation of complex organic molecules. However, molecular inventories in hot cores remain limited. Using data from the ALMA Three-millimeter Observations of Massive Star-forming regions survey (ATOMS), the molecular composition and evolutionary stages of two distinct millimeter continuum sources in the high-mass star forming region G336.99-00.03 have been characterized. MM1, with 19 distinct molecular species detected, along with 8 isotopologues and several vibrationally/torsionally excited states, has been identified as a hot core. MM2 with only 5 species identified, was defined as a HII region. Isotopic ratios in MM1 were derived, with $^{12}$C/$^{13}$C ranging from 16.0 to 29.2, $^{16}$O/$^{18}$O at 47.7, and $^{32}$S/$^{34}$S at 19.2. Molecular abundances in MM1 show strong agreement with other sources and three-phase warm-up chemical models within an order of magnitude for most species. Formation pathways of key molecules were explored, revealing chemical links and reaction networks. This study provides a detailed molecular inventory of two millimeter continuum sources, shedding light on the chemical diversity and evolutionary processes in high-mass star-forming regions. The derived molecular parameters and isotopic ratios offer benchmarks for astrochemical models, paving the way for further investigation into the formation and evolution of complex organic molecules during the hot core phase.

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arXiv2024

Deuterium fractionation of the starless core L 1498

Molecular deuteration is commonly seen in starless cores and is expected to occur on a timescale comparable to that of the core contraction. Thus, the deuteration serves as a chemical clock, allowing us to investigate dynamical theories of core formation. We aim to provide a 3D cloud description for the starless core L 1498 located in the nearby low-mass star-forming region Taurus, and explore the possible core formation mechanism of L 1498. We carried out non-local thermal equilibrium radiative transfer with multi-transition observations of the high-density tracer N$_2$H$^+$ to derive the density and temperature profiles of the L 1498 core. Combining with the spectral observations of the deuterated species, ortho-H$_2$D$^+$, N$_2$D$^+$, and DCO$^+$, we derived the abundance profiles for observed species and performed chemical modeling of the deuteration profiles across L 1498 to constrain the contraction timescale. We present the first ortho-H$_2$D$^+$ (1$_{10}$-1$_{11}$) detection toward L 1498. We find a peak molecular hydrogen density of $1.6_{-0.3}^{+3.0}\times10^{5}$~cm$^{-3}$, a temperature of 7.5$_{-0.5}^{+0.7}$~K, and a N$_2$H$^+$ deuteration of 0.27$_{-0.15}^{+0.12}$ in the center. We derive a lower limit of the core age for L 1498 of 0.16~Ma which is compatible with the typical free-fall time, indicating that L 1498 likely formed rapidly.

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arXiv2023

Magnetic fields of the starless core L 1512

We present JCMT POL-2 850 um dust polarization observations and Mimir H band stellar polarization observations toward the starless core L1512. We detect the highly-ordered core-scale magnetic field traced by the POL-2 data, of which the field orientation is consistent with the parsec-scale magnetic fields traced by Planck data, suggesting the large-scale fields thread from the low-density region to the dense core region in this cloud. The surrounding magnetic field traced by the Mimir data shows a wider variation in the field orientation, suggesting there could be a transition of magnetic field morphology at the envelope scale. L1512 was suggested to be presumably older than 1.4 Myr in a previous study via time-dependent chemical analysis, hinting that the magnetic field could be strong enough to slow the collapse of L1512. In this study, we use the Davis-Chandrasekhar-Fermi method to derive a plane-of-sky magnetic field strength ($B_{pos}$) of 18$\pm$7 uG and an observed mass-to-flux ratio ($λ_{obs}$) of 3.5$\pm$2.4, suggesting that L1512 is magnetically supercritical. However, the absence of significant infall motion and the presence of an oscillating envelope are inconsistent with the magnetically supercritical condition. Using a Virial analysis, we suggest the presence of a hitherto hidden line-of-sight magnetic field strength of ~27 uG with a mass-to-flux ratio ($λ_{tot}$) of ~1.6, in which case both magnetic and kinetic pressures are important in supporting the L1512 core. On the other hand, L1512 may have just reached supercriticality and will collapse at any time.

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arXiv2023

Updated Inventory of Carbon Monoxide in The Taurus Molecular Cloud

The most extensive survey of carbon monoxide (CO) gas in the Taurus molecular cloud relied on $^{12}$CO and $^{13}$CO $J=1 \rightarrow 0$ emission only, distinguishing the region where $^{12}$CO is detected without $^{13}$CO (named mask 1 region) from the one where both are detected (mask 2 region). We have taken advantage of recent $^{12}$CO $J=3\rightarrow2$ JCMT observations where they include mask 1 regions to estimate density, temperature, and $N$(CO) with a LVG model. This represents 1395 pixels out of $\sim$1.2 million in the mark 1 region. Compared to Pineda et al. (2010) results, and assuming a $T_\textrm{kin}$ of 30 K, we find a higher volume density of molecular hydrogen of 3.3$\rm \times\ 10^3$ $\textrm{cm}^{-3}$, compared to their 250-700 $\textrm{cm}^{-3}$ and a CO column density of 5.7$\rm \times\ 10^{15}\ \textrm{cm}^{-2}$, about a quarter of their value. The differences are important and show the necessity to observe several CO transitions to better describe the intermediate region between the dense cloud and the diffuse atomic medium. Future observations to extend the $^{12}$CO $J=3\rightarrow2$ mapping further away from the $^{13}$CO-detected region comprising mask 1 are needed to revisit our understanding of the diffuse portions of dark clouds.

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arXiv2023

Discovery of a New Molecular Bubble-Outflow Structure in the Taurus B18 Cloud

Star formation can produce bubbles and outflows, as a result of stellar feedback. Outflows and bubbles inject momentum and energy into the surrounding interstellar medium, and so are related to the overall energy balance of the molecular cloud. Molecular bubbles can be resolved by higher-resolution radio telescopes to quantify the effect of star formation on molecular clouds. We report here the identification of a new molecular bubble with an outflow, and an Herbig Haro object, HH319, located at the bubble center. Multi-wavelength data have been utilized to study its spatial structure, energy injection, and dynamical timescale. This bubble has a kinetic energy of $\rm 5.8 \times 10^{43}$ erg within the smallest radius of a bubble in Taurus, 0.077 pc. The bubble formed $\sim$70,000 years ago. According to the proper motion velocities of protostars from $Gaia$ EDR3, the T Tauri binary stars (FY Tau and FZ Tau) at the southwest edge of the bubble may have produced the outflow-bubble structure. This is an unusual new structure found in low- and intermediate-mass star formation regions. Only a bubble in Orion A, driven by V380 Ori, has a similar structure. The bubble-outflow structure provides additional observational evidence for the theory of stellar wind from T Tauri stars. It enhances our understanding of how stellar feedback acts on molecular clouds.

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arXiv2021

Evolution of dust porosity through coagulation and shattering in the interstellar medium

The properties of interstellar grains, such as grain size distribution and grain porosity, are affected by interstellar processing, in particular, coagulation and shattering, which take place in the dense and diffuse interstellar medium (ISM), respectively. In this paper, we formulate and calculate the evolution of grain size distribution and grain porosity through shattering and coagulation. For coagulation, we treat the grain evolution depending on the collision energy. Shattering is treated as a mechanism of forming small compact fragments. The balance between these processes are determined by the dense-gas mass fraction $η_\mathrm{dense}$, which determines the time fraction of coagulation relative to shattering. We find that the interplay between shattering supplying small grains and coagulation forming porous grains from shattered grains is fundamentally important in creating and maintaining porosity. The porosity rises to 0.7--0.9 (or the filling factor 0.3--0.1) around grain radii $a\sim 0.1~μ$m. We also find that, in the case of $η_\mathrm{dense}=0.1$ (very efficient shattering with weak coagulation) porosity significantly enhances coagulation, creating fluffy submicron grains with filling factors lower than 0.1. The porosity enhances the extinction by 10--20 per cent at all wavelengths for amorphous carbon and at ultraviolet wavelengths for silicate. The extinction curve shape of silicate becomes steeper if we take porosity into account. We conclude that the interplay between shattering and coagulation is essential in creating porous grains in the interstellar medium and that the resulting porosity can impact the grain size distributions and extinction curves.

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arXiv2020

Radio telescope total power mode: improving observation efficiency

Aims. Radio observing efficiency can be improved by calibrating and reducing the observations in total power mode rather than in frequency, beam, or position-switching modes. Methods. We selected a sample of spectra obtained from the Institut de Radio-Astronomie Millimétrique (IRAM) 30-m telescope and the Green Bank Telescope (GBT) to test the feasibility of the method. Given that modern front-end amplifiers for the GBT and direct Local Oscillator injection for the 30 m telescope provide smooth pass bands that are a few tens of megahertz in width, the spectra from standard observations can be cleaned (baseline removal) separately and then co-added directly when the lines are narrow enough (a few km/s), instead of performing the traditional ON minus OFF data reduction. This technique works for frequency-switched observations as well as for position- and beam-switched observations when the ON and OFF data are saved separately. Results. The method works best when the lines are narrow enough and not too numerous so that a secure baseline removal can be achieved. A signal-to-noise ratio improvement of a factor of sqrt(2) is found in most cases, consistent with theoretical expectations. Conclusions. By keeping the traditional observing mode, the fallback solution of the standard reduction technique is still available in cases of suboptimal baseline behavior, sky instability, or wide lines, and to confirm the line intensities. These techniques of total-power-mode reduction can be applied to any radio telescope with stable baselines as long as they record and deliver the ONs and OFFs separately, as is the case for the GBT.

astro-ph.IM↗

arXiv2020

Space Project for Astrophysical and Cosmological Exploration (SPACE), an ESA stand-alone mission and a possible contribution to the Origins Space Telescope

We propose a new mission called Space Project for Astrophysical and Cosmological Exploration (SPACE) as part on the ESA long term planning Voyage 2050 programme. SPACE will study galaxy evolution at the earliest times, with the key goals of charting the formation of the heavy elements, measuring the evolution of the galaxy luminosity function, tracing the build-up of stellar mass in galaxies over cosmic time, and finding the first super-massive black holes (SMBHs) to form. The mission will exploit a unique region of the parameter space, between the narrow ultra-deep surveys with HST and JWST, and shallow wide-field surveys such as Roman Space Telescope and EUCLID, and should yield by far the largest sample of any current or planned mission of very high redshift galaxies at z > 10 which are sufficiently bright for detailed follow-up spectroscopy. Crucially, we propose a wide-field spectroscopic near-IR + mid-IR capability which will greatly enhance our understanding of the first galaxies by detecting and identifying a statistical sample of the first galaxies and the first SMBH, and to chart the metal enrichment history of galaxies in the early Universe - potentially finding signatures of the very first stars to form from metal-free primordial gas. The wide-field and wavelength range of SPACE will also provide us a unique opportunity to study star formation by performing a wide survey of the Milky Way in the near-IR + mid-IR. This science project can be enabled either by a stand-alone ESA-led M mission or by an instrument for an L mission (with ESA and/or NASA, JAXA and other international space agencies) with a wide-field (sub-)millimetre capability at wavelength > 500 microns.

astro-ph.IM↗

arXiv2020

Physical and chemical modeling of the starless core L1512

The deuterium fractionation in starless cores gives us a clue to estimate their lifetime scales, thus allowing us to distinguish between different dynamical theories of core formation. Cores also seem to be subject to a differential N2 and CO depletion which was not expected from models. We aim to make a survey of 10 cores to estimate their lifetime scales and depletion profiles in detail. After L183, in Serpens, we present the second cloud of the series, L1512 in Auriga. To constrain the lifetime scale, we perform chemical modeling of the deuteration profiles across L1512 based on dust extinction measurements from near-infrared observations and non-local thermal equilibrium radiative transfer with multiple line observations of N2H+, N2D+, DCO+, C18O, and 13CO, plus H2D+ (1$_{10}$--1$_{11}$). We find a peak density of 1.1$\times$10$^5$ cm$^{-3}$ and a central temperature of 7.5$\pm$1 K, which are respectively higher and lower compared with previous dust emission studies. The depletion factors of N2H+ and N2D+ are 27$^{+17}_{-13}$ and 4$^{+2}_{-1}$ in L1512, intermediate between the two other more advanced and denser starless core cases, L183 and L1544. These factors also indicate a similar freeze-out of N2 in L1512, compared to the two others despite a peak density one to two orders of magnitude lower. Retrieving CO and N2 abundance profiles with the chemical model, we find that CO has a depletion factor of $\sim$430-870 and the N2 profile is similar to that of CO unlike towards L183. Therefore, L1512 has probably been living long enough so that N2 chemistry has reached steady state. N2H+ modeling remains compulsory to assess the precise physical conditions in the center of cold starless cores, rather than dust emission. L1512 is presumably older than 1.4 Myr. Therefore, the dominating core formation mechanism should be ambipolar diffusion for this source.

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arXiv2019

Dust evolution in pre-stellar cores

Dust grains are the building {blocks} of future planets. They evolve in size, shape and composition during the life cycle of the interstellar medium. We seek to understand the process which leads from diffuse medium grains to dust grains in the vicinity of protostars inside disks. As a first step, we propose to characterize the dust evolution inside pre-stellar cores thanks to multi-wavelength observations. We will present how NIKA2 maps are crucial to better constrain dust properties and {we will} introduce SIGMA: a new flexible dust model in open access.

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arXiv2017

The complexity of Orion: an ALMA view. II. gGg'-Ethylene Glycol and Acetic Acid

We report the first detection and high angular resolution (1.8" $\times$ 1.1") imaging of acetic acid (CH$_3$COOH) and gGg$^{\prime}$--ethylene glycol (gGg$^{\prime}$(CH$_2$OH)$_2$) towards the Orion Kleinmann--Low nebula. The observations were carried out at $\sim$1.3mm with ALMA during the Cycle~2. A notable result is that the spatial distribution of the acetic acid and ethylene glycol emission differs from that of the other O-bearing molecules within Orion-KL. Indeed, while the typical emission of O-bearing species harbors a morphology associated with a "V-shape" linking the Hot Core region to the Compact Ridge (with an extension towards the BN object), that of acetic acid and ethylene glycol mainly peaks at about 2" southwest from the hot core region (near sources I and n). We find that the measured CH$_3$COOH:aGg$^{\prime}$(CH$_2$OH)$_2$ and CH$_3$COOH:gGg$^{\prime}$(CH$_2$OH)$_2$ ratios differ from the ones measured towards the low-mass protostar IRAS 16293--2422 by more than one order of magnitude. Our best hypothesis to explain these findings is that CH$_3$COOH, aGg$^{\prime}$(CH$_2$OH)$_2$ and gGg$^{\prime}$(CH$_2$OH)$_2$ are formed on the icy-surface of grains and then released into the gas-phase, via co-desorption with water, due to a bullet of matter ejected during the explosive event that occurred in the heart of the Nebula about 500-700 years ago.

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arXiv2015

On the importance of scattering at 8 microns: Brighter than you think

Context. Extinction and emission of dust models need for observational constraints to be validated. The coreshine phenomenon has already shown the importance of scattering in the 3 to 5 micron range and its ability to validate dust properties for dense cores. Aims. We want to investigate whether scattering can also play a role at longer wavelengths and to place even tighter constraints on the dust properties. Methods. We analyze the inversion of the Spitzer 8 micron map of the dense molecular cloud L183, to examine the importance of scattering as a potential contributor to the line-of-sight extinction. Results. The column density deduced from the inversion of the 8 micron map, when we neglect scattering, disagrees with all the other column density measurements of the same region. Modeling confirms that scattering at 8 microns is not negligible with an intensity of several hundred kJy per sr. This demonstrates the need of efficiently scattering dust grains at MIR wavelengths up to 8 microns. Coagulated aggregates are good candidates and might also explain the discrepancy at high extinction between E(J-K) et tau(9.7) toward dense molecular clouds. Further investigation requires considering efficiently scattering dust grains including ices as realistic dust models.

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