arXiv subjects

Lea F. Santos

Publications and source records attributed to Lea F. Santos.

At least 37 records · Page 2Linked to original sources

arXiv2025

Proposal for many-body quantum chaos detection

In this work, the term ``quantum chaos'' refers to spectral correlations similar to those found in the random matrix theory. Quantum chaos can be diagnosed through the analysis of level statistics using e.g.~the spectral form factor, which detects both short- and long-range level correlations. The spectral form factor corresponds to the Fourier transform of the two-point spectral correlation function and exhibits a typical slope-dip-ramp-plateau structure (aka correlation hole) when the system is chaotic. We discuss how this structure could be detected through the quench dynamics of two physical quantities accessible to experimental many-body quantum systems: the survival probability and the spin autocorrelation function. The survival probability is equivalent to the spectral form factor with an additional filter. When the system is small, the dip of the correlation hole reaches sufficiently large values at times which are short enough to be detected with current experimental platforms. As the system is pushed away from chaos, the correlation hole disappears, signaling integrability or localization. We also provide a relatively shallow circuit with which the correlation hole could be detected with commercially available quantum computers.

cond-mat.stat-mech↗

arXiv2025

A Roadmap for Simulating Chemical Dynamics on a Parametrically Driven Bosonic Quantum Device

Chemical reactions are commonly described by the reactive flux transferring population from reactants to products across a double-well free energy barrier. Dynamics often involves barrier recrossing and quantum effects like tunneling, zero-point energy motion and interference, which traditional rate theories, such as transition-state theory, do not consider. In this study, we investigate the feasibility of simulating reaction dynamics using a parametrically driven bosonic superconducting Kerr-cat device. This approach provides control over parameters defining the double-well free energy profile, as well as external factors like temperature and the coupling strength between the reaction coordinate and the thermal bath of non-reactive degrees of freedom. We demonstrate the effectiveness of this protocol by showing that the dynamics of proton transfer reactions in prototypical benchmark model systems, such as hydrogen bonded dimers of malonaldehyde and DNA base pairs, could be accurately simulated on currently accessible Kerr-cat devices.

quant-ph↗

arXiv2024

Breakdown of the Quantum Distinction of Regular and Chaotic Classical Dynamics in Dissipative Systems

Quantum chaos has recently received increasing attention due to its relationship with experimental and theoretical studies of nonequilibrium quantum dynamics, thermalization, and the scrambling of quantum information. In an isolated system, quantum chaos refers to properties of the spectrum that emerge when the classical counterpart of the system is chaotic. However, despite experimental progress leading to longer coherence times, interactions with an environment can never be neglected, which calls for a definition of quantum chaos in dissipative systems. Advances in this direction were brought by the Grobe-Haake-Sommers (GHS) conjecture, which connects chaos in a dissipative classical system with cubic repulsion of the eigenvalues of the quantum counterpart and regularity with linear level repulsion. Here, we show that the GHS conjecture does not hold for the open Dicke model, which is a spin-boson model of experimental interest. We show that the onset of cubic level repulsion in the open quantum model is not always related with chaotic structures in the classical limit. This result challenges the universality of the GHS conjecture and raises the question of what is the source of spectral correlations in open quantum systems.

quant-ph↗

arXiv2024

Timescales of quantum and classical chaotic spin models evolving toward equilibrium

We investigate quench dynamics in a one-dimensional spin model, comparing both quantum and classical descriptions. Our primary focus is on the different timescales involved in the evolution of the observables as they approach statistical relaxation. Numerical simulations, supported by semi-analytical analysis, reveal that the relaxation of single-particle energies (global quantity) and on-site magnetization (local observable) occurs on a timescale independent of the system size $L$. This relaxation process is equally well-described by classical equations of motion and quantum solutions, demonstrating excellent quantum-classical correspondence, provided the system be strongly chaotic. The correspondence persists even for small quantum spin values ($S=1$), where a semi-classical approximation is not applicable. Conversely, for the participation ratio, which characterizes the initial state spread in the many-body Hilbert space and which lacks a classical analogue, the relaxation timescale is system-size dependent.

cond-mat.stat-mech↗

arXiv2024

Quantum sensing in Kerr parametric oscillators

Quantum metrology and quantum sensing aim to use quantum properties to enhance measurement precision beyond what could be classically achieved. Here, we demonstrate how the analysis of the phase space structure of the classical limit of Kerr parametric oscillators can be used for determining control parameters values that lead to the squeezing of the uncertainty in position and the amplification of the quantum Fisher information. We also explore how quantum sensing can benefit from excited-state quantum phase transitions, even in the absence of a conventional quantum phase transition. The system that we consider models exciton-polariton condensates and superconducting circuits, making our study relevant for potential experimental applications.

quant-ph↗

arXiv2024

Characterizing conical intersections of nucleobases on quantum computers

Hybrid quantum-classical computing algorithms offer significant potential for accelerating the calculation of the electronic structure of strongly correlated molecules. In this work, we present the first quantum simulation of conical intersections (CIs) in a biomolecule, cytosine, using a superconducting quantum computer. We apply the Contracted Quantum Eigensolver (CQE) -- with comparisons to conventional Variational Quantum Deflation (VQD) -- to compute the near-degenerate ground and excited states associated with the conical intersection, a key feature governing the photostability of DNA and RNA. The CQE is based on an exact ansatz for many-electron molecules in the absence of noise -- a critically important property for resolving strongly correlated states at CIs. Both methods demonstrate promising accuracy when compared with exact diagonalization, even on noisy intermediate-scale quantum computers, highlighting their potential for advancing the understanding of photochemical and photobiological processes. The ability to simulate these intersections is critical for advancing our knowledge of biological processes like DNA repair and mutation, with potential implications for molecular biology and medical research.

quant-ph↗

arXiv2024

Subspace-Search Quantum Imaginary Time Evolution for Excited State Computations

Quantum systems in excited states are attracting significant interest with the advent of noisy intermediate scale quantum (NISQ) devices. While ground states of small molecular systems are typically explored using hybrid variational algorithms like the variational quantum eigensolver (VQE), the study of excited states has received much less attention, partly due to the absence of efficient algorithms. In this work, we introduce the subspace search quantum imaginary time evolution (SSQITE) method, which calculates excited states using quantum devices by integrating key elements of the subspace search variational quantum eigensolver (SSVQE) and the variational quantum imaginary time evolution (VarQITE) method. The effectiveness of SSQITE is demonstrated through calculations of low-lying excited states of benchmark model systems, including $\text{H}_2$ and $\text{LiH}$ molecules. A toy Hamiltonian is also employed to demonstrate that the robustness of VarQITE in avoiding local minima extends to its use in excited state algorithms. With this robustness in avoiding local minima, SSQITE shows promise for advancing quantum computations of excited states across a wide range of applications.

quant-ph↗

arXiv2024

Effects of stickiness on the quantum states of strongly chaotic open systems

We investigate the effects of classical stickiness (orbits temporarily confined to a region of the chaotic phase space) to the structures of the quantum states of an open system. We consider the standard map of the kicked rotor and verify that regions of stickiness survive in the strong chaotic regime of the closed classical map. By scanning the system's phase space with a leak, we analyze how stickiness affects the degree of localization of the states of the quantum system. We find an excellent correspondence between the classical dwell time and finite-time Lyapunov exponents with the quantum dwell time and Wehrl entropy of the quantum states. Our approach suggests that knowledge of the structure of the classically chaotic trajectories can be used to determine where to place the leak to enhance or decrease the degree of delocalization of the quantum states.

quant-ph↗

arXiv2024

Simulating Chemistry on Bosonic Quantum Devices

Bosonic quantum devices offer a novel approach to realize quantum computations, where the quantum two-level system (qubit) is replaced with the quantum (an)harmonic oscillator (qumode) as the fundamental building block of the quantum simulator. The simulation of chemical structure and dynamics can then be achieved by representing or mapping the system Hamiltonians in terms of bosonic operators. In this perspective, we review recent progress and future potential of using bosonic quantum devices for addressing a wide range of challenging chemical problems, including the calculation of molecular vibronic spectra, the simulation of gas-phase and solution-phase adiabatic and nonadiabatic chemical dynamics, the efficient solution of molecular graph theory problems, and the calculations of electronic structure.

quant-ph↗

arXiv2024

Reducing dynamical fluctuations and enforcing self-averaging by opening many-body quantum systems

We investigate how the dynamical fluctuations of many-body quantum systems out of equilibrium can be mitigated when they are opened to a dephasing environment. We consider the survival probability (spectral form factor with a filter) evolving under different kinds of random matrices and under a spin-1/2 model with weak and strong disorder. In isolated many-body quantum systems, the survival probability is non-self-averaging at any timescale, that is, the relative variance of its fluctuations does not decrease with system size. By opening the system, we find that the fluctuations are always reduced, but self-averaging can only be ensured away from critical points. Self-averaging is achieved for the long-time dynamics of full random matrices, power-law banded random matrices deep in the delocalized phase, and the Rosenzweig-Porter ensemble in all the phases except at the delocalization-localization transition point. For the spin model, the survival probability becomes self-averaging only in the chaotic regime provided the initial states are in the middle of the spectrum. Overall, a strongly non-self-averaging survival probability in open systems is an indicator of criticality.

cond-mat.str-el↗

arXiv2024

Degeneracy in excited-state quantum phase transitions of two-level bosonic models and its influence on system dynamics

Excited-state quantum phase transitions (ESQPTs) strongly influence the spectral properties of collective many-body quantum systems, changing degeneracy patterns in different quantum phases. Level degeneracies, in turn, affect the system's dynamics. We analyze the degeneracy dependence on the size of two-level boson models with a $u(n+1)$ dynamical algebra, where $n$ is the number of collective degrees of freedom. Below the ESQPT critical energy of these models, the energy gap between neighboring levels that belong to different symmetry sectors gets close to zero as the system size increases. We report and explain why this gap goes to zero exponentially for systems with one collective degree of freedom, but algebraically in models with more than one degree of freedom. As a consequence, we show that the infinite-time average of out-of-time-order correlators is an ESQPT order parameter in finite systems with $n=1$, but in systems with $n>1$, this average only works as an order parameter in the mean-field limit.

quant-ph↗

arXiv2024

Effective versus Floquet theory for the Kerr parametric oscillator

Parametric gates and processes engineered from the perspective of the static effective Hamiltonian of a driven system are central to quantum technology. However, the perturbative expansions used to derive static effective models may not be able to efficiently capture all the relevant physics of the original system. In this work, we investigate the conditions for the validity of the usual low-order static effective Hamiltonian used to describe a Kerr oscillator under a squeezing drive. This system is of fundamental and technological interest. In particular, it has been used to stabilize Schrödinger cat states, which have applications for quantum computing. We compare the states and energies of the effective static Hamiltonian with the exact Floquet states and quasi-energies of the driven system and determine the parameter regime where the two descriptions agree. Our work brings to light the physics that is left out by ordinary static effective treatments and that can be explored by state-of-the-art experiments.

quant-ph↗

arXiv2024

Driving superconducting qubits into chaos

Kerr parametric oscillators are potential building blocks for fault-tolerant quantum computers. They can stabilize Kerr-cat qubits, which offer advantages toward the encoding and manipulation of error-protected quantum information. The recent realization of Kerr-cat qubits made use of the nonlinearity of the SNAIL transmon superconducting circuit and a squeezing drive. Increasing nonlinearities can enable faster gate times, but, as shown here, can also induce chaos and melt the qubit away. We determine the region of validity of the Kerr-cat qubit and discuss how its disintegration could be experimentally detected. The danger zone for parametric quantum computation is also a potential playground for investigating quantum chaos with driven superconducting circuits.

quant-ph↗

arXiv2023

Unitarity breaking in self-averaging spectral form factors

The complex Fourier transform of the two-point correlator of the energy spectrum of a quantum system is known as the spectral form factor (SFF). It constitutes an essential diagnostic tool for phases of matter and quantum chaos. In black hole physics, it describes the survival probability (fidelity) of a thermofield double state under unitary time evolution. However, detailed properties of the SFF of isolated quantum systems with generic spectra are smeared out by large temporal fluctuations, whose minimization requires disorder or time averages. This requirement holds for any system size, that is, the SFF is non-self averaging. Exploiting the fidelity-based interpretation of this quantity, we prove that using filters, disorder and time averages of the SFF involve unitarity breaking, i.e., open quantum dynamics described by a quantum channel that suppresses quantum noise. Specifically, averaging over Hamiltonian ensembles, time averaging, and frequency filters can be described by the class of mixed-unitary quantum channels in which information loss can be recovered. Frequency filters are associated with a time-continuous master equation generalizing energy dephasing. We also discuss the use of eigenvalue filters. They are linked to non-Hermitian Hamiltonian evolution without quantum jumps, whose long-time behavior is described by a Hamiltonian deformation. We show that frequency and energy filters make the SFF self-averaging at long times.

quant-ph↗

arXiv2023

Symmetries of the squeeze-driven Kerr oscillator

We study the symmetries of the static effective Hamiltonian of a driven superconducting nonlinear oscillator, the so-called squeeze-driven Kerr Hamiltonian, and discover a remarkable quasi-spin symmetry $su(2)$ at integer values of the ratio $η=Δ/K$ of the detuning parameter $Δ$ to the Kerr coefficient $K$. We investigate the stability of this newly discovered symmetry to high-order perturbations arising from the static effective expansion of the driven Hamiltonian. Our finding may find applications in the generation and stabilization of states useful for quantum computing. Finally, we discuss other Hamiltonians with similar properties and within reach of current technologies.

quant-ph↗

arXiv2023

Temporal fluctuations of correlators in integrable and chaotic quantum systems

We provide bounds on temporal fluctuations around the infinite-time average of out-of-time-ordered and time-ordered correlators of many-body quantum systems without energy gap degeneracies. For physical initial states, our bounds predict the exponential decay of the temporal fluctuations as a function of the system size. We numerically verify this prediction for chaotic and interacting integrable spin-1/2 chains, which satisfy the assumption of our bounds. On the other hand, we show analytically and numerically that for the XX model, which is a noninteracting system with gap degeneracies, the temporal fluctuations decay polynomially with system size for operators that are local in the fermion representation and decrease exponentially in the system size for non-local operators. Our results demonstrate that the decay of the temporal fluctuations of correlators cannot be used as a reliable metric of chaos or lack thereof.

cond-mat.str-el↗

arXiv2023

Spectral kissing and its dynamical consequences in the squeeze-driven Kerr oscillator

Transmon qubits are the predominant element in circuit-based quantum information processing, such as existing quantum computers, due to their controllability and ease of engineering implementation. But more than qubits, transmons are multilevel nonlinear oscillators that can be used to investigate fundamental physics questions. Here, they are explored as simulators of excited state quantum phase transitions (ESQPTs), which are generalizations of quantum phase transitions to excited states. We show that the spectral kissing (coalescence of pairs of energy levels) experimentally observed in the effective Hamiltonian of a driven SNAIL-transmon is an ESQPT precursor. We explore the dynamical consequences of the ESQPT, which include the exponential growth of out-of-time-ordered correlators, followed by periodic revivals, and the slow evolution of the survival probability due to localization. These signatures of ESQPT are within reach for current superconducting circuits platforms and are of interest to experiments with cold atoms and ion traps.

quant-ph↗

arXiv2023

Periodically and quasiperiodically driven-anisotropic Dicke model

We analyze the anisotropic Dicke model in the presence of a periodic drive and under a quasiperiodic drive. The study of drive-induced phenomena in this experimentally accesible model is important since although it is simpler than full-fledged many-body quantum systems, it is still rich enough to exhibit many interesting features. We show that under a quasiperiodic Fibonacci (Thue-Morse) drive, the system features a prethermal plateau that increases as an exponential (stretched exponential) with the driving frequency before heating to an infinite-temperature state. In contrast, when the model is periodically driven, the dynamics reaches a plateau that is not followed by heating. In either case, the plateau value depends on the energy of the initial state and on the parameters of the undriven Hamiltonian. Surprisingly, this value does not always approach the infinite-temperature state monotonically as the frequency of the periodic drive decreases. We also show how the drive modifies the quantum critical point and discuss open questions associated with the analysis of level statistics at intermediate frequencies.

quant-ph↗