arXiv subjects
Publications and source records attributed to Lei Gu.
In an effort to understand the glass transition, the kinetics of a spin model with frustration but no quenched randomness has been analyzed. The phenomenology of the spin model is remarkably similiar to that of structural glasses. Analysis of the model suggests that defects play a major role in dictating the dynamics as the glass transition is approached.
We propose a simple dynamical model of the glass transition based on the results from a non-randomly frustrated spin model which is known to form a glassy state below a characteristic quench temperature. The model is characterized by a multi-valleyed free-energy surface which is modulated by an overall curvature. The transition associated with the vanishing of this overall curvature is reminiscent of the glass transition. In particular, the frequency-dependent response evolves from a Debye relaxation peak to a function whose high-frequency behavior is characterized by a non-trivial power law. We present both an analytical form for the response function and numerical results from Langevin simulations.
We have analyzed a non-randomly frustrated spin model which exhibits behavior remarkably similar to the phenomenology of structural glasses. The high-temperature disordered phase undergoes a strong first-order transition to a long-range ordered structure. Using Monte Carlo simulations, we have studied the behavior of the supercooled state by quenching to temperatures below this transition temperature. For a range of supercooling, the system remains ergodic and exhibits dynamics characteristic of supercooled liquids. Below a certain characteristic temperature, however, the system freezes into a "glassy" phase. In this phase, the system is non-ergodic and evolves through a distribution of traps characterized by a power-law distribution of trapping times. This change in the dynamic behavior is concurrent with the appearance of a shear instability.