arXiv subjects

Leigh N. Fletcher

Publications and source records attributed to Leigh N. Fletcher.

At least 91 records · Page 5Linked to original sources

arXiv2016

Probing Saturn's tropospheric cloud with Cassini/VIMS

In its decade of operation the Cassini mission has allowed us to look deep into Saturn's atmosphere and investigate the processes occurring below its enshrouding haze. We use Visual and Infrared Mapping Spectrometer (VIMS) 4.6-5.2 micron data from early in the mission to investigate the location and properties of Saturn's cloud structure between 0.6 and 5 bars. We average nightside spectra from 2006 over latitude circles and model the spectral limb darkening using the NEMESIS radiative transfer and retrieval tool. We present our best-fit deep cloud model for latitudes between -40 and 50 degrees, along with retrieved abundances for NH3, PH3 and AsH3. We find an increase in NH3 abundance at the equator, a cloud base at ~2.3 bar and no evidence for cloud particles with strong absorption features in the 4.6-5.2 micron wavelength range, all of which are consistent with previous work. Non-scattering cloud models assuming a composition of either NH3 or NH4SH, with a scattering haze overlying, fit limb darkening curves and spectra at all latitudes well; the retrieved optical depth for the tropospheric haze is decreased in the northern (winter) hemisphere, implying that the haze has a photochemical origin. Our ability to test this hypothesis by examining spectra at different seasons is restricted by the varying geometry of VIMS observations over the life of the mission, and the appearance of the Saturn storm towards the end of 2010.

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arXiv2015

Giant Planet Observations with the James Webb Space Telescope

This white paper examines the benefit of the upcoming James Webb Space Telescope for studies of the Solar System's four giant planets: Jupiter, Saturn, Uranus, and Neptune. JWST's superior sensitivity, combined with high spatial and spectral resolution, will enable near- and mid-infrared imaging and spectroscopy of these objects with unprecedented quality. In this paper we discuss some of the myriad scientific investigations possible with JWST regarding the giant planets. This discussion is preceded by the specifics of JWST instrumentation most relevant to giant planet observations. We conclude with identification of desired pre-launch testing and operational aspects of JWST that would greatly benefit future studies of the giant planets.

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arXiv2015

Saturn's Seasonally Changing Atmosphere: Thermal Structure, Composition and Aerosols

The longevity of Cassini's exploration of Saturn's atmosphere (a third of a Saturnian year) means that we have been able to track the seasonal evolution of atmospheric temperatures, chemistry and cloud opacity over almost every season, from solstice to solstice and from perihelion to aphelion. Cassini has built upon the decades-long ground-based record to observe seasonal shifts in atmospheric temperature, finding a thermal response that lags behind the seasonal insolation with a lag time that increases with depth into the atmosphere, in agreement with radiative climate models. Seasonal hemispheric contrasts are perturbed at smaller scales by atmospheric circulation, such as belt/zone dynamics, the equatorial oscillations and the polar vortices. Temperature asymmetries are largest in the middle stratosphere and become insignificant near the radiative-convective boundary. Cassini has also measured southern-summertime asymmetries in atmospheric composition, including ammonia (the key species for the topmost clouds), phosphine and para-hydrogen (both disequilibrium species) in the upper troposphere; and hydrocarbons deriving from the UV photolysis of methane in the stratosphere (principally ethane and acetylene). These chemical asymmetries are now altering in subtle ways due to (i) the changing chemical efficiencies with temperature and insolation; and (ii) vertical motions associated with large-scale overturning in response to the seasonal temperature contrasts. Similarly, hemispheric contrasts in tropospheric aerosol opacity and coloration that were identified during the earliest phases of Cassini's exploration have now reversed, suggesting an intricate link between the clouds and the temperatures. [Abridged]

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arXiv2015

Spectral analysis of Uranus' 2014 bright storm with VLT/SINFONI

An extremely bright storm system observed in Uranus' atmosphere by amateur observers in September 2014 triggered an international campaign to observe this feature with many telescopes across the world. Observations of the storm system in the near infrared were acquired in October and November 2014 with SINFONI on ESO's Very Large Telescope (VLT) in Chile. SINFONI is an Integral Field Unit spectrometer returning 64x64 pixel images with 2048 wavelengths. Image cubes in the H-band (1.43 - 1.87 microns) were obtained at spatial resolutions of ~0.1". The observations show that the centre of the storm feature shifts markedly with increasing altitude, moving in the retrograde direction and slightly poleward with increasing altitude. We also see a faint 'tail' of more reflective material to the immediate south of the storm, which again trails in the retrograde direction. The observed spectra were analysed with the radiative transfer and retrieval code, NEMESIS. We find that the storm is well-modelled using either two main cloud layers of a 5-layer aerosol model based on Sromovsky et al. (2011) or by the simpler two-cloud-layer model of Tice et al. (2013). The deep component appears to be due to an increase in reflectivity and altitude of the main tropospheric cloud deck at 2 - 3 bars for both models, while the upper component of the feature was modelled as being due to either a thickening of the tropospheric haze of the 2-layer model or a vertical extension of the upper tropospheric cloud of the 5-layer model, assumed to be composed of methane ice and based at the methane condensation level at 1.23 bar. During the twelve days between our sets of observations the higher-altitude component of the feature was observed to have brightened significantly and extended to even higher altitudes, while the deeper component faded.

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arXiv2015

Seasonal Variability of Saturn's Tropospheric Temperatures, Winds and Para-H$_2$ from Cassini Far-IR Spectroscopy

Far-IR 16-1000 $μ$m spectra of Saturn's hydrogen-helium continuum measured by Cassini's Composite Infrared Spectrometer (CIRS) are inverted to construct a near-continuous record of upper tropospheric (70-700 mbar) temperatures and para-H$_2$ fraction as a function of latitude, pressure and time for a third of a Saturnian year (2004-2014, from northern winter to northern spring). The thermal field reveals evidence of reversing summertime asymmetries superimposed onto the belt/zone structure. The temperature structure that is almost symmetric about the equator by 2014, with seasonal lag times that increase with depth and are qualitatively consistent with radiative climate models. Localised heating of the tropospheric hazes (100-250 mbar) create a distinct perturbation to the temperature profile that shifts in magnitude and location, declining in the autumn hemisphere and growing in the spring. Changes in the para-H$_2$ ($f_p$) distribution are subtle, with a 0.02-0.03 rise over the spring hemisphere (200-500 mbar) perturbed by (i) low-$f_p$ air advected by both the springtime storm of 2010 and equatorial upwelling; and (ii) subsidence of high-$f_p$ air at northern high latitudes, responsible for a developing north-south asymmetry in $f_p$. Conversely, the shifting asymmetry in the para-H$_2$ disequilibrium primarily reflects the changing temperature structure (and the equilibrium distribution of $f_p$), rather than actual changes in $f_p$ induced by chemical conversion or transport. CIRS results interpolated to the same point in the seasonal cycle as re-analysed Voyager-1 observations show qualitative consistency, with the exception of the tropical tropopause near the equatorial zones and belts, where downward propagation of a cool temperature anomaly associated with Saturn's stratospheric oscillation could potentially perturb tropopause temperatures, para-H$_2$ and winds. [ABRIDGED]

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arXiv2015

Cloud structure and composition of Jupiter's troposphere from 5-μm Cassini VIMS spectroscopy

Jupiter's tropospheric composition and cloud structure are studied using Cassini VIMS 4.5-5.1 μm thermal emission spectra from the 2000-2001 flyby. We make use of both nadir and limb darkening observations on the planet's nightside, and compare these with dayside observations. Although there is significant spatial variability in the 5-μm brightness temperatures, the shape of the spectra remain very similar across the planet, suggesting the presence of a spectrally-flat, spatially inhomogeneous cloud deck. We find that a simple cloud model consisting of a single, compact cloud is able to reproduce both nightside and dayside spectra, subject to the following constraints: (i) the cloud base is located at pressures of 1.2 bar or lower; (ii) the cloud particles are highly scattering; (iii) the cloud is sufficiently spectrally flat. Using this cloud model, we search for global variability in the cloud opacity and the phosphine deep volume mixing ratio. We find that the vast majority of the 5-μm inhomogeneity can be accounted for by variations in the thickness of the cloud decks, with huge differences between the cloudy zones and the relatively cloud-free belts. The relatively low spectral resolution of VIMS limits reliable retrievals of gaseous species, but some evidence is found for an enhancement in the abundance of phosphine at high latitudes.

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arXiv2015

Transit spectroscopy with JWST: Systematics, starspots and stitching

The James Webb Space Telescope (JWST) is predicted to make great advances in the field of exoplanet atmospheres. Its 25 m2 mirror means that it can reach unprecedented levels of precision in observations of transit spectra, and can thus characterise the atmospheres of planets orbiting stars several hundred pc away. Its coverage of the infrared spectral region between 0.6 and 28 μm allows the abundances of key molecules to be probed during the transit of a planet in front of the host star, and when the same planet is eclipsed constraints can be placed on its temperature structure. In this work, we explore the possibility of using low-spectral-resolution observations by JWST/NIRSpec and JWST/MIRI-LRS together to optimise wavelength coverage and break degeneracies in the atmospheric retrieval problem for a range of exoplanets from hot Jupiters to super Earths. This approach involves stitching together non-simultaneous observations in different wavelength regions, rendering it necessary to consider the effect of time-varying instrumental and astrophysical systematics. We present the results of a series of retrieval feasibility tests examining the effects of instrument systematics and star spots on the recoverability of the true atmospheric state, and demonstrate that correcting for these systematics is key for successful exoplanet science with JWST.

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arXiv2014

Seasonal Evolution of Saturn's Polar Temperatures and Composition

The seasonal evolution of Saturn's polar atmospheric temperatures and hydrocarbon composition is derived from a decade of Cassini Composite Infrared Spectrometer (CIRS) 7-16 $μ$m thermal infrared spectroscopy. We construct a near-continuous record of atmospheric variability poleward of 60$^\circ$ from northern winter/southern summer (2004, $L_s=293^\circ$) through the equinox (2009, $L_s=0^\circ$) to northern spring/southern autumn (2014, $L_s=56^\circ$). The hot tropospheric polar cyclones and the hexagonal shape of the north polar belt are both persistent features throughout the decade of observations. The hexagon vertices rotated westward by $\approx30^\circ$ longitude between March 2007 and April 2013, confirming that they are not stationary in the Voyager-defined System III longitude system as previously thought. The extended region of south polar stratospheric emission has cooled dramatically poleward of the sharp temperature gradient near 75$^\circ$S, coinciding with a depletion in the abundances of acetylene and ethane, and suggestive of stratospheric upwelling with vertical wind speeds of $w\approx+0.1$ mm/s. This is mirrored by a general warming of the northern polar stratosphere and an enhancement in acetylene and ethane abundances that appears to be most intense poleward of 75$^\circ$N, suggesting subsidence at $w\approx-0.15$ mm/s. However, the sharp gradient in stratospheric emission expected to form near 75$^\circ$N by northern summer solstice (2017, $L_s=90^\circ$) has not yet been observed, so we continue to await the development of a northern summer stratospheric vortex. North polar minima in tropospheric and stratospheric temperatures were detected in 2008-2010 (lagging one season, or 6-8 years, behind winter solstice); south polar maxima appear to have occurred before the start of the Cassini observations (1-2 years after summer solstice). [Abridged]

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arXiv2014

New insights on Saturn's formation from its nitrogen isotopic composition

The recent derivation of a lower limit for the $^{14}$N/$^{15}$N ratio in Saturn's ammonia, which is found to be consistent with the Jovian value, prompted us to revise models of Saturn's formation using as constraints the supersolar abundances of heavy elements measured in its atmosphere. Here we find that it is possible to account for both Saturn's chemical and isotopic compositions if one assumes the formation of its building blocks at $\sim$45 K in the protosolar nebula, provided that the O abundance was $\sim$2.6 times protosolar in its feeding zone. To do so, we used a statistical thermodynamic model to investigate the composition of the clathrate phase that formed during the cooling of the protosolar nebula and from which the building blocks of Saturn were agglomerated. We find that Saturn's O/H is at least $\sim$34.9 times protosolar and that the corresponding mass of heavy elements ($\sim$43.1 \Mearth) is within the range predicted by semi-convective interior models.

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arXiv2014

Ideas for Citizen Science in Astronomy

We review the relatively new, internet-enabled, and rapidly-evolving field of citizen science, focusing on research projects in stellar, extragalactic and solar system astronomy that have benefited from the participation of members of the public, often in large numbers. We find these volunteers making contributions to astronomy in a variety of ways: making and analyzing new observations, visually classifying features in images and light curves, exploring models constrained by astronomical datasets, and initiating new scientific enquiries. The most productive citizen astronomy projects involve close collaboration between the professionals and amateurs involved, and occupy scientific niches not easily filled by great observatories or machine learning methods: citizen astronomers are most strongly motivated by being of service to science. In the coming years we expect participation and productivity in citizen astronomy to increase, as survey datasets get larger and citizen science platforms become more efficient. Opportunities include engaging the public in ever more advanced analyses, and facilitating citizen-led enquiry by designing professional user interfaces and analysis tools with citizens in mind.

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arXiv2014

The Transit Spectra of Earth and Jupiter

In recent years, a number of observations have been made of the transits of 'Hot Jupiters', such as HD 189733b, which have been modelled to derive atmospheric structure and composition. As measurement techniques improve, the transit spectra of 'Super-Earths' such as GJ 1214b are becoming better constrained, allowing model atmospheres to be fitted for this class of planet also. While it is not yet possible to constrain the atmospheric states of small planets such as the Earth or cold planets like Jupiter, this may become practical in the coming decades and if so, it is of interest to determine what we might infer from such measurements. Here we have constructed atmospheric models of the Solar System planets from 0.4 - 15.5 microns that are consistent with ground-based and satellite observations and from these calculate the primary transit and secondary eclipse spectra (with respect to the Sun and typical M-dwarfs) that would be observed by a 'remote observer', many light years away. From these spectra we test what current retrieval models might infer about their atmospheres and compare these with the 'ground truths' in order to assess: a) the inherent uncertainties in transit spectra observations; b) the relative merits of primary transit and secondary eclipse spectra; and c) the advantages of directly imaged spectra. We find that secondary eclipses would not give sufficient information, but that primary transits give much better determination. We find that a single transit of Jupiter in front of the Sun could potentially be used to determine temperature and stratospheric composition, but for the Earth the mean atmospheric composition could only be determined if it were orbiting an M-dwarf. For both planets we note that direct imaging with sufficient nulling of the light from the parent star provides the best method of determining the atmospheric properties of such planets.

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arXiv2014

Mid-Infrared Spectroscopy of Uranus from the Spitzer Infrared Spectrometer: 1. Determination of the Mean Temperature Structure of the Upper Troposphere and Stratosphere

On 2007 December 16-17, spectra were acquired of the disk of Uranus by the Spitzer Infrared Spectrometer (IRS) when its equator was close to the sub-earth point. This spectrum provides the highest-resolution broad-band spectrum ever obtained for Uranus from space, allowing a determination of the disk-averaged temperature and molecule composition to a greater degree of accuracy than ever before. The temperature profiles derived from the Voyager radio occultation experiments that match these data best are those that assume a high abundance of methane in the deep atmosphere, but none of these models provides a satisfactory fit over the full spectral range. This be the result of spatial differences between global and low-latitudinal regions, changes in time, missing continuum opacity sources such as stratospheric hazes or unknown tropospheric constituents, or undiagnosed systematic problems with either the radio-occultation or the Spitzer IRS data sets. The spectrum is compatible with the stratospheric temperatures derived from the Voyager ultraviolet occultations measurements. Thermospheric temperatures determined from the analysis of the observed H2 quadrupole emission features are colder than those derived by Herbert et al. at pressures less than ~1 microbar. Extrapolation of the nominal model spectrum to far-infrared through millimeter wavelengths shows that the spectrum arising solely from H2 collision-induced absorption is too warm to reproduce observations between wavelengths of 0.8 and 3.3 mm. Adding an additional absorber such as H2S provides a reasonable match to the spectrum, although a unique identification of the responsible absorber is not yet possible with available data. An immediate practical use for the spectrum resulting from this model is to establish a high-precision continuum flux model for use as an absolute radiometric standard for future astronomical observations.

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arXiv2014

Mid-Infrared Spectroscopy of Uranus from the Spitzer Infrared Spectrometer: 2. Determination of the Mean Composition of the Upper Troposphere and Stratosphere

Mid-infrared spectral observations Uranus acquired with the Infrared Spectrometer (IRS) on the Spitzer Space Telescope are used to determine the abundances of C2H2, C2H6, CH3C2H, C4H2, CO2, and tentatively CH3 on Uranus at the time of the 2007 equinox. For vertically uniform eddy diffusion coefficients in the range 2200-2600 cm2 s-1, photochemical models that reproduce the observed methane emission also predict C2H6 profiles that compare well with emission in the 11.6-12.5 micron wavelength region, where the nu9 band of C2H6 is prominent. Our nominal model with a uniform eddy diffusion coefficient Kzz = 2430 cm2 sec-1 and a CH4 tropopause mole fraction of 1.6x10-5 provides a good fit to other hydrocarbon emission features, such as those of C2H2 and C4H2, but the model profile for CH3C2H must be scaled by a factor of 0.43, suggesting that improvements are needed in the chemical reaction mechanism for C3Hx species. The nominal model is consistent with a CH3D/CH4 ratio of 3.0+-0.2x10-4. From the best-fit scaling of these photochemical-model profiles, we derive column abundances above the 10-mbar level of 4.5+01.1/-0.8 x 10+19 molecule-cm-2 for CH4, 6.2 +- 1.0 x 10+16 molecule-cm-2 for C2H2 (with a value 24% higher from a different longitudinal sampling), 3.1 +- 0.3 x 10+16 molecule-cm-2 for C2H6, 8.6 +- 2.6 x 10+13 molecule-cm-2 for CH3C2H, 1.8 +- 0.3 x 10+13 molecule-cm-2 for C4H2, and 1.7 +- 0.4 x 10+13 molecule-cm-2 for CO2 on Uranus. Our results have implications with respect to the influx rate of exogenic oxygen species and the production rate of stratospheric hazes on Uranus, as well as the C4H2 vapor pressure over C4H2 ice at low temperatures.

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arXiv2014

Exoplanet atmospheres with EChO: spectral retrievals using EChOSim

We demonstrate the effectiveness of the Exoplanet Characterisation Observatory mission concept for constraining the atmospheric properties of hot and warm gas giants and super Earths. Synthetic primary and secondary transit spectra for a range of planets are passed through EChOSim (Waldmann & Pascale 2014) to obtain the expected level of noise for different observational scenarios; these are then used as inputs for the NEMESIS atmospheric retrieval code and the retrieved atmospheric properties (temperature structure, composition and cloud properties) compared with the known input values, following the method of Barstow et al. (2013a). To correctly retrieve the temperature structure and composition of the atmosphere to within 2 σ, we find that we require: a single transit or eclipse of a hot Jupiter orbiting a sun-like (G2) star at 35 pc to constrain the terminator and dayside atmospheres; 20 transits or eclipses of a warm Jupiter orbiting a similar star; 10 transits/eclipses of a hot Neptune orbiting an M dwarf at 6 pc; and 30 transits or eclipses of a GJ1214b-like planet.

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arXiv2014

The Origin of Nitrogen on Jupiter and Saturn from the $^{15}$N/$^{14}$N Ratio

The Texas Echelon cross Echelle Spectrograph (TEXES), mounted on NASA's Infrared Telescope Facility (IRTF), was used to map mid-infrared ammonia absorption features on both Jupiter and Saturn in February 2013. Ammonia is the principle reservoir of nitrogen on the giant planets, and the ratio of isotopologues ($^{15}$N/$^{14}$N) can reveal insights into the molecular carrier (e.g., as N$_2$ or NH$_3$) of nitrogen to the forming protoplanets, and hence the source reservoirs from which these worlds accreted. We targeted two spectral intervals (900 and 960 cm$^{-1}$) that were relatively clear of terrestrial atmospheric contamination and contained close features of $^{14}$NH$_3$ and $^{15}$NH$_3$, allowing us to derive the ratio from a single spectrum without ambiguity due to radiometric calibration (the primary source of uncertainty in this study). We present the first ground-based determination of Jupiter's $^{15}$N/$^{14}$N ratio (in the range from $1.4\times10^{-3}$ to $2.5\times10^{-3}$), which is consistent with both previous space-based studies and with the primordial value of the protosolar nebula. On Saturn, we present the first upper limit on the $^{15}$N/$^{14}$N ratio of no larger than $2.0\times10^{-3}$ for the 900-cm$^{-1}$ channel and a less stringent requirement that the ratio be no larger than $2.8\times10^{-3}$ for the 960-cm$^{-1}$ channel ($1σ$ confidence). Specifically, the data rule out strong $^{15}$N-enrichments such as those observed in Titan's atmosphere and in cometary nitrogen compounds. To the extent possible with ground-based radiometric uncertainties, the saturnian and jovian $^{15}$N/$^{14}$N ratios appear indistinguishable, implying that $^{15}$N-enriched ammonia ices could not have been a substantial contributor to the bulk nitrogen inventory of either planet, favouring the accretion of primordial N$_2$ from the gas phase or as low-temperature ices.

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arXiv2014

Constraining the Atmospheric Composition of the Day-Night Terminators of HD 189733b : Atmospheric Retrieval with Aerosols

A number of observations have shown that Rayleigh scattering by aerosols dominates the transmission spectrum of HD 189733b at wavelengths shortward of 1 $μ$m. In this study, we retrieve a range of aerosol distributions consistent with transmission spectroscopy between 0.3-24 $μ$m that were recently re-analyzed by Pont et al. (2013). To constrain the particle size and the optical depth of the aerosol layer, we investigate the degeneracies between aerosol composition, temperature, planetary radius, and molecular abundances that prevent unique solutions for transit spectroscopy. Assuming that the aerosol is composed of MgSiO$_3$, we suggest that a vertically uniform aerosol layer over all pressures with a monodisperse particle size smaller than about 0.1 $μ$m and an optical depth in the range 0.002-0.02 at 1 $μ$m provides statistically meaningful solutions for the day/night terminator regions of HD 189733b. Generally, we find that a uniform aerosol layer provide adequate fits to the data if the optical depth is less than 0.1 and the particle size is smaller than 0.1 $μ$m, irrespective of the atmospheric temperature, planetary radius, aerosol composition, and gaseous molecules. Strong constraints on the aerosol properties are provided by spectra at wavelengths shortward of 1 $μ$m as well as longward of 8 $μ$m, if the aerosol material has absorption features in this region. We show that these are the optimal wavelengths for quantifying the effects of aerosols, which may guide the design of future space observations. The present investigation indicates that the current data offer sufficient information to constrain some of the aerosol properties of HD189733b, but the chemistry in the terminator regions remains uncertain.

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arXiv2014

Clouds on the hot Jupiter HD189733b: constraints from the reflection spectrum

The hot Jupiter HD 189733b is probably the best studied of the known extrasolar planets, with published transit and eclipse spectra covering the near UV to mid-IR range. Recent work on the transmission spectrum has shown clear evidence for the presence of clouds in its atmosphere, which significantly increases the model atmosphere parameter space that must be explored in order to fully characterise this planet. In this work, we apply the NEMESIS atmospheric retrieval code to the recently published HST/STIS reflection spectrum, and also to the dayside thermal emission spectrum in the light of new Spitzer/IRAC measurements, as well as our own re-analysis of the HST/NICMOS data. We first use the STIS data to place some constraints on the nature of the cloud on HD189733b, and explore solution degeneracy between different cloud properties and the abundance of Na in the atmosphere; as already noted in previous work, absorption due to Na plays a significant role in determining the shape of the reflection spectrum. We then perform a new retrieval of the temperature profile and abundances of H2O, CO2, CO and CH4 from the dayside thermal emission spectrum. Finally, we investigate the effect of including cloud in the model on this retrieval process. We find that the current quality of data does not warrant the extra complexity introduced by including cloud in the model; however, future data are likely to be of sufficient resolution and signal-to-noise that a more complete model, including scattering particles, will be required.

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arXiv2014

Exploring the Diversity of Jupiter-Class Planets (Discussion Meeting Contribution)

Royal Society Discussion Meeting (2013) `Characterizing exoplanets'. Of the 900+ confirmed exoplanets discovered since 1995 for which we have constraints on their mass (i.e., not including Kepler candidates), 75% have masses larger than Saturn (0.3MJ), 53% are more massive than Jupiter, and 67% are within 1 AU of their host stars. And yet the term `hot Jupiter' fails to account for the incredible diversity of this class of object, which exists on a continuum of giant planets from the cool jovians of our own solar system to the highly-irradiated, tidally-locked hot roasters. We review theoretical expectations for the temperatures, molecular composition and cloud properties of Jupiter-class objects under a variety of different conditions. We discuss the classification schemes for these Jupiter-class planets proposed to date, including the implications for our own Solar System giant planets and the pitfalls associated with classification at this early stage of exoplanetary spectroscopy. We discuss the range of planetary types described by previous authors, accounting for: (i) thermochemical equilibrium expectations for cloud condensation and favoured chemical stability fields; (ii) the metallicity and formation mechanism for these giant planets; (iii) the importance of optical absorbers for energy partitioning and the generation of a temperature inversion; (iv) the favoured photochemical pathways and expectations for minor species (e.g., saturated hydrocarbons and nitriles); (v) the unexpected presence of molecules due to vertical mixing of species above their quench levels; and (vi) methods for energy and material redistribution throughout the atmosphere (e.g., away from the highly irradiated daysides of close-in giants). Finally, we will discuss the benefits and flaws of retrieval techniques for establishing a family of atmospheric solutions that reproduce the available data.

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