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Leonardo A. Pachon

Publications and source records attributed to Leonardo A. Pachon.

At least 19 recordsLinked to original sources

Newton-Cartan limit of Klein-Gordon AQFT: gravitational atoms and the loss of vacuum entanglement

We take the non-relativistic limit $c\to\infty$ of the free Klein-Gordon field on static spacetimes at three levels: one-particle resolvents, quasi-free states and the time-zero net. After subtraction of the rest energy, the one-particle Hamiltonian is an explicit function of a Schrödinger-type operator whose potential on the Schwarzschild exterior is exactly Newtonian. On regular static stars it converges to the Newtonian Schrödinger operator in norm-resolvent sense at rate $c^{-2}$, with convergence of eigenvalues and an explicit first post-Newtonian correction. On the Schwarzschild exterior the Boulware one-particle spectrum has no eigenvalues for any $c$; the convergence is strong but not in norm, the limit selects the Friedrichs realisation of the gravitational hydrogen atom, and its bound states emerge by spectral concentration. The same holds on the Reissner-Nordström exterior. In all cases the rescaled two-point functions converge to those of the Schrödinger-Fock vacuum. The hydrogenic states are limits of resonances: in each partial wave there is exactly one near each hydrogenic level, its real part carries the first post-Newtonian correction, and its width, proportional to $c^{-(4l+3)}$, is the one found for gravitational atoms by matched asymptotics. At the level of nets the time-zero Weyl algebra is the same for every $c$, and the vacuum and the dynamics converge on it, yet for smooth metrics the algebra of each bounded region with smooth boundary is a type III$_1$ factor at finite $c$ and a type I factor with a pure product vacuum in the limit. What collapses is the entanglement of the vacuum; thermal states in flat space and on stars survive the limit. With positivity of the energy imposed modulo the central charge, the axioms of Galilean nets hold in the limit for every static star and for Schwarzschild, and the vacuum is not separating.

quant-ph↗

Algebraic quantum kinematics: Galilean covariance with positive energy confines unequal-time commutation to null sets

We ask which kinematical groups allow local algebras of canonical quantum fields to commute at unequal times. The Galilei group acts transitively on pairs of non-simultaneous events with a given time separation, so a Galilean-invariant commutation relation between sharp-time algebras at unequal times also holds at coincident positions; at arbitrarily short separations it contradicts the canonical commutation relations, with no spectral assumption. Under unitary Bargmann covariance and positivity of the energy modulo the central mass, the vacuum is annihilated by the annihilation fields, hence not separating for local algebras, and the vacuum two-point function of a canonical field factorises into the free Schrödinger propagator and the characteristic function of an internal-energy distribution. Sharp-time algebras at unequal times then commute only at a closed null set of time separations, bounded below by the Mandelstam-Tamm and Margolus-Levitin times and empty for sharp or generic internal energy; any finite set of separations occurs. Algebras of open spacetime regions containing time-smeared fields never commute. Positivity cannot be dropped: without it, commutation can hold at all separations beyond any given one. Among spatially isotropic homogeneous spacetimes with absolute time, only the galilean ones are transitive at fixed time separation, up to discrete exceptions in the two oscillating cases, realised by a harmonic trap in the Newton-Hooke one. Non-commutation transfers from the vacuum to every representation of a simple C*-algebra on which the dynamics acts by automorphisms, including free Bose and Fermi gases at all temperatures and the Galilei-covariant cutoff dynamics of interacting fermions of Narnhofer and Thirring; without such a vacuum representation it can fail even in thermal equilibrium.

quant-ph↗

Path integral formulation of finite-dimensional quantum mechanics in discrete phase space

We develop a path integral representation for the dynamics of quantum systems with a finite-dimensional Hilbert space, formulated entirely within a discrete phase space. Starting from the discrete Wigner function on ${\mathbb{Z}_d} \times {\mathbb{Z}_d}$ ($d$ an odd prime) and the associated Weyl transform built from generalized displacement operators, we derive an exact kernel that propagates the discrete Wigner function in time and, by iterating its composition law through a short-time approximation, obtain a sum-over-paths expression weighted by a discrete phase-space action -- the natural finite-dimensional counterpart of Marinov's functional. For Hamiltonians linear in the phase-space coordinates and at times strictly commensurate with the lattice, the fluctuation sum collapses to a deterministic shift, realizing the discrete analog of classical Hamiltonian flow. Applying the formalism to one and to two interacting qutrits ($d=3$), we show that the full entanglement dynamics -- captured by a closed-form linear entropy valid for all times -- requires the coherent contribution of all fluctuation sectors; the boundary-term (mean-field) sector alone fails to reproduce it. For a non-stabilizer Hamiltonian, where the short-time kernel is only approximate, the time-sliced path integral converges to the exact dynamics, including the dynamical generation of Wigner negativity. We discuss implications for the semiclassical simulation of many-body spin systems and for the characterization of non-classicality through Wigner negativity.

quant-ph↗

Galilean Reeh--Schlieder Obstruction

We prove that the standard Galilean Haag--Kastler axioms, augmented by Bargmann mass superselection, are inconsistent with the Reeh--Schlieder property: no such net admits a vacuum that is cyclic and separating for every local field algebra. Two ingredients combine: Galilean Schrödinger fields annihilate the Fock vacuum, and Bargmann mass superselection forbids the Hermitian-combination evasion that keeps relativistic axioms consistent. The result extends beyond the Fock-representation hypothesis: any Galilean Haag--Kastler net whose canonical fields carry definite Bargmann mass charges and admit time-zero restrictions on a field-algebra-stable common dense domain is incompatible with Reeh--Schlieder. The bounded-below mass spectrum and the vacuum-at-spectral-minimum, usually imposed as separate axioms, are derived consequences -- of positive-energy boost positivity and a Bose-CCR algebraic descent, respectively. The Tomita--Takesaki modular flow is consequently unavailable on Galilean local field algebras. We identify the Reeh--Schlieder property as the precise structural ingredient distinguishing relativistic from Galilean algebraic quantum field theory: relativistic AQFT has it as a theorem, Galilean AQFT cannot.

quant-ph↗

The Origin of the Dynamical Quantum Non-locality

Non-locality is one of the hallmarks of quantum mechanics and is responsible for paradigmatic features such as entanglement and the Aharonov-Bohm effect. Non-locality comes in two flavours: a \emph{kinematic} non-locality -- arising from the structure of the Hilbert space -- and a \emph{dynamical} non-locality -- arising from the quantum equations of motion. Recently, the origin of kinematic non-locality was traced to the uncertainty principle; here we rigorously trace the origin of dynamical non-locality to the superposition principle. We prove, via deformation quantization and Marinov's phase-space path integrals, that the exact Wigner propagator reduces to the classical Liouville propagator if and only if the Hamiltonian has at-most-quadratic Weyl symbol. This unified theorem covers both continuous-variable and finite-dimensional Hilbert spaces, aligning the Gaussian (CV) and Clifford (finite-$d$) boundaries of classical simulability into a single algebraic criterion. We introduce a macroscopic, experimentally accessible measure of dynamical non-locality -- the signed divergence $\mathcal{D}(t)$ -- and show that it governs five phenomena: (i) the dynamical penalty incurred by quantum non-local games under post-measurement evolution; (ii) the quantum corrections to out-of-time-order correlators; (iii) the metrological gain beyond the shot-noise limit; (iv) the generation of non-Gaussian entanglement from product states; and (v) the non-Clifford / magic-state content of finite-dimensional dynamics. A concrete experimental protocol in circuit QED is proposed and complemented by a three-qubit CCZ protocol accessible on current qubit platforms.

quant-ph↗

Rank-2 Electromagnetic Backgrounds and Angular Momentum Barriers in Gravitomagnetic Spin-Quadrupole Searches

We present a complete analysis of the angular momentum selection rules and electromagnetic backgrounds that constrain any spectroscopic search for the gravitomagnetic spin-quadrupole coupling in highly charged ions. A sequence of four barriers is identified: (i)~the Wigner-Eckart theorem mandates $j \geq 3/2$ electronic states for sensitivity to the rank-2 gravitomagnetic operator, excluding the deformation-immune $j=1/2$ states; (ii)~the nuclear electric quadrupole hyperfine interaction (HFS-E2) generates an $\sim 18$-orders-of-magnitude electromagnetic background in the required $j=3/2$ channel; (iii)~second-order HFS mixing between fine-structure levels leaves a residual $\sim 10^{-6}$ eV even after centroid extraction; (iv)~tensor nuclear polarizability (TNP), scaling with $B(E2)$ rather than $Q_s$, introduces an independent rank-2 background of $\sim 10^{-12}$ eV. We derive the algebraic conditions under which a multi-isotope, multi-transition Generalized King Plot can separate these backgrounds from the gravitational signal, and show that the minimum experimental topology requires three transitions and $N_{\text{odd}} \geq N_{\text{bkg}} + 1$ odd-spin isotopes with linearly independent nuclear parameters. For the molybdenum chain, this yields a first laboratory-derivable bound $|χ- 1| \lesssim 10^{8} - 10^9$ on the gyrogravitational ratio, limited by current precision on nuclear quadrupole moments and transition rates. We quantify the experimental milestones needed to improve this bound by each order of magnitude, providing a roadmap for future searches.

quant-ph↗

Predicting Beta Decay Energy with Machine Learning

$Q_β$ represents one of the most important factors characterizing unstable nuclei, as it can lead to a better understanding of nuclei behavior and the origin of heavy atoms. Recently, machine learning methods have been shown to be a powerful tool to increase accuracy in the prediction of diverse atomic properties such as energies, atomic charges, volumes, among others. Nonetheless, these methods are often used as a black box not allowing unraveling insights into the phenomena under analysis. Here, the state-of-the-art precision of the $β$-decay energy on experimental data is outperformed by means of an ensemble of machine-learning models. The explainability tools implemented to eliminate the black box concern allowed to identify uncertainty and atomic number as the most relevant characteristics to predict $Q_β$ energies. Furthermore, physics-informed feature addition improved models' robustness and raised vital characteristics of theoretical models of the nuclear structure.

nucl-th↗

Gang Confrontation: The case of Medellin (Colombia)

Protracted conflict is one of the largest human challenges that have persistently undermined economic and social progress. In recent years, there has been increased emphasis on using statistical and physical science models to better understand both the universal patterns and the underlying mechanics of conflict. Whilst macroscopic power-law fractal patterns have been shown for death-toll in wars and self-excitation models have been shown for roadside ambush attacks, very few works deal with the challenge of complex dynamics between gangs at the intra-city scale. Here, based on contributions to the historical memory of the conflict in Colombia, Medellin's gang-confrontation-network is presented. It is shown that socio-economic and violence indexes are moderate to highly correlated to the structure of the network. Specifically, the death-toll of conflict is strongly influenced by the leading eigenvalues of the gangs' conflict adjacency matrix, which serves a proxy for unstable self-excitation from revenge attacks. The distribution of links based on the geographic distance between gangs in confrontation leads to the confirmation that territorial control is a main catalyst of violence and retaliation among gangs. Additionally, the Boltzmann-Lotka-Volterra (BLV) dynamic interaction network analysis is applied to quantify the spatial embeddedness of the dynamic relationship between conflicting gangs in Medellin, results suggest that more involved and comprehensive models are needed to described the dynamics of Medellin's armed conflict.

physics.soc-ph↗

Equilibrium Coherence in the Multi-level Spin-boson Model

Interaction between a quantum system and its environment can induce stationary coherences -- off-diagonal elements in the reduced system density matrix -- even at equilibrium. This work investigates the ``quantumness'' of such phenomena by examining the ability of classical and semiclassical models to describe equilibrium stationary coherence in the multi-level spin boson (MLSB) model, a common model for light-harvesting systems. A well justified classical harmonic oscillator model is found to fail to capture equilibrium coherence. This failure is attributed to the effective weakness of classical system-bath interactions due to the absence of a discrete system energy spectrum and, consequently, of quantized shifts in oscillator coordinates. Semiclassical coherences also vanish for a dimeric model with parameters typical of biological light-harvesting, i.e., where both system sites couple to the bath with the same reorganization energy. In contrast, equilibrium coherence persists in a fully quantum description of the same system, suggesting a uniquely quantum-mechanical origin for equilibrium stationary coherence in, e.g., photosynthetic systems. Finally, as a computational tool, a perturbative expansion is introduced that, at third order in $\hbar$, gives qualitatively correct behavior at ambient temperatures for all configurations examined.

quant-ph↗

Influence of Non-Markovian Dynamics in Thermal-Equilibrium Uncertainty-Relations

Contrary to the conventional wisdom that deviations from standard thermodynamics originate from the strong coupling to the bath, it is shown that in quantum mechanics, these deviations originate from the uncertainty principle and are supported by the non-Markovian character of the dynamics. Specifically, it is shown that the lower bound of the dispersion of the total energy of the system, imposed by the uncertainty principle, is dominated by the bath power spectrum and therefore, quantum mechanics inhibits the system thermal-equilibrium-state from being described by the canonical Boltzmann's distribution. We show that for a wide class of systems, systems interacting via central forces with pairwise-self-interacting environments, this general observation is in sharp contrast to the classical case, for which the thermal equilibrium distribution, irrespective of the interaction strength, is \emph{exactly} characterized by the canonical Boltzmann distribution and therefore, no dependence on the bath power spectrum is present. We define an \emph{effective coupling} to the environment that depends on all energy scales in the system and reservoir interaction. Sample computations in regimes predicted by this effective coupling are demonstrated. For example, for the case of strong effective coupling, deviations from standard thermodynamics are present and, for the case of weak effective coupling, quantum features such as stationary entanglement are possible at high temperatures.

quant-ph↗

The exact dynamical Chern Simons metric for a spinning black hole possesses a fourth constant of motion: A Dynamical-Systems-Based Conjecture

The recent gravitational wave observations by the LIGO/Virgo collaboration have allowed the first tests of General Relativity in the extreme gravity regime, when comparable-mass black holes and neutron stars collide. Future space-based detectors, such as the Laser Interferometer Space Antenna, will allow tests of Einstein's theory with gravitational waves emitted when a small black hole falls into a supermassive one in an extreme mass-ratio inspiral. One particular test that is tailor-made for such inspirals is the search for chaos in extreme gravity. We here study whether chaos is present in the motion of test particles around spinning black holes of parity-violating modified gravity, focusing in particular on dynamical Chern-Simons gravity. We develop a resummation strategy that restores all spin terms in the General Relativity limit, while retaining up to fifth-order-in-spin terms in the dynamical Chern-Simons corrections to the Kerr metric. We then calculate Poincaré surfaces of section and rotation numbers of a wide family of geodesics of this resummed metric. We find no evidence for geodesic chaos, with at most deformations of the resonant torii that shrink as terms of higher-order in spin are included in the dynamical Chern-Simons corrections to the Kerr metric. Our numerical findings suggest that the geodesics of the as-of-yet unknown exact solution for spinning black holes in this theory may be integrable, and that there may thus exist a fourth integral of motion associated with this exact solution. The studies presented here begin to lay the foundations for chaotic tests of General Relativity with the observation of extreme mass ratio inspirals with the Laser Interferometer Space Antenna.

gr-qc↗

Open System Perspective on Incoherent Excitation of Light Harvesting Systems

The nature of excited states of open quantum systems produced by incoherent natural thermal light is analyzed based on a description of the generator of the dynamics. Natural thermal light is shown to generate long-lasting coherent dynamics because of (i) the super-Ohmic character of the radiation, and (ii) the absence of pure dephasing dynamics. In the presence of an environment, the long-lasting coherences induced by suddenly turned-on incoherent light dissipate and stationary coherences are established. As a particular application, dynamics in a subunit of the PC-645 light-harvesting complex is considered where it is further shown that aspects of the energy pathways landscape depend on the nature of the exciting light and number of chromophores excited. Specifically, pulsed laser and natural broadband incoherent excitation induce significantly different energy transfer pathways. In addition, we discuss differences in perspective associated with the eigenstate vs site basis, and note an important difference in the phase of system coherences when coupled to blackbody radiation or when coupled to a phonon background. Finally, an Appendix contains an open systems example of the loss of coherence as the turn on time of the light assumes natural time scales.

quant-ph↗

Origin of the $1/f^α$-Spectral-Noise in Chaotic and Regular Quantum Systems

Based on the connection between the spectral form factor and the probability to return, the origin of the $1/f^α$-noise in fully chaotic and fully integrable systems is traced to the quantum interference between invariant manifolds of the classical dynamics and the dimensionality of those invariant manifolds. This connection and the order-to-chaos transition are analyzed in terms of the statistics of Floquet's quasienergies of a classically chaotic driving non-linear system. An immediate prediction of the connection established here is that in the presence of decoherence, the spectral exponent $α$ takes the same value, $α=2$, for both, fully chaotic and fully integrable systems.

quant-ph↗

Ultrafast Optimal Sideband Cooling under Non-Markovian Evolution

A sideband cooling strategy that incorporates (i) the dynamics induced by structured (non-Markovian) environments in the target and auxiliary systems and (ii) the optimally-time-modulated interaction between them is developed. For the context of cavity optomechanics, when non-Markovian dynamics are considered in the target system, ground state cooling is reached at much faster rates and at much lower phonon occupation number than previously reported. In constrast to similar current strategies, ground state cooling is reached here for coupling-strength rates that are experimentally accesible for the state-of-the-art implementations. After the ultrafast optimal-ground-state-cooling protocol is accomplished, an additional optimal control strategy is considered to maintain the phonon number as closer as possible to the one obtained in the cooling procedure. Contrary to the conventional expectation, when non-Markovian dynamics are considered in the auxiliary system, the efficiency of the cooling protocol is undermined.

quant-ph↗

Classical Approach to Multichromophoric Resonance Energy Transfer

A classical formulation of the quantum multichromophoric theory of resonance energy transfer is developed on the basis of classical electrodynamics. The theory allows for the identification of a variety of processes of different order-in-the-interactions that contribute to the energy transfer in molecular aggregates with intra-coupling in donors and acceptor chromophores. Enhanced rates in multichromophoric resonance energy transfer are shown to be well described by this theory. Specifically, in a coupling configuration between N_{\mathrm{A}}$ acceptors and $N_{\mathrm{D}}$ donors, the theory correctly predicts an enhancement of the energy transfer rate dependent on the total number of donor-acceptor pairs. As an example, the theory, applied to the transfer rate in LH~II, gives results in excellent agreement with experiment. Finally, it is explicitly shown that as long as linear response theory holds, the classical multichromophoric theory formally coincides with the quantum formulation.

physics.bio-ph↗

Quantum Process Tomography by 2D Fluorescence Spectroscopy

Reconstruction of the dynamics (quantum process tomography) of the single-exciton manifold in energy transfer systems is proposed here on the basis of two-dimensional fluorescence spectroscopy (2D-FS) with phase-modulation. The quantum-process-tomography protocol introduced here benefits from, e.g., the sensitivity enhancement ascribed to 2D-FS. Although the isotropically averaged spectroscopic signals depend on the quantum yield parameter $Γ$ of the doubly-excited-exciton manifold, it is shown that the reconstruction of the dynamics is insensitive to this parameter. Applications to foundational and applied problems, as well as further extensions, are discussed.

quant-ph↗

Quantum Limit for Driven Linear Non-Markovian Open-Quantum-Systems

The interplay between non-Markovian dynamics and driving fields in the survival of entanglement between two non-degenerate oscillators is considered here. Based on exact analytical results for the non-Markovian dynamics of two parametrically coupled non-degenerate oscillators in contact to non-identical independent thermal baths, the out-of-equilibrium quantum limit derived in [Phys. Rev. Lett. 105, 180501 (2010)] is generalized to the non-Markovian regime. Specifically, it is shown that non-Markovian dynamics, when compared to the Markovian case, allow for the survival of stationary entanglement at higher temperatures, with larger coupling strength to the baths and at smaller driving rates. The effect of the asymmetry of the (i) coupled oscillators, (ii) coupling strength to the baths at equal temperature and (iii) temperature at equal coupling strength is discussed.

quant-ph↗

Direct Experimental Determination of Spectral Densities of Molecular Complexes

Determining the spectral density of a molecular system immersed in a proteomic scaffold and in contact to a solvent is a fundamental challenge in the coarse-grained description of, e.g., electron and energy transfer dynamics. Once the spectral density is characterized, all the time scales are captured and no artificial separation between fast and slow processes need be invoked. Based on the fluorescence Stokes shift function, we utilize a simple and robust strategy to extract the spectral density of a number of molecular complexes from available experimental data. Specifically, we show that experimental data for dye molecules in several solvents, amino acid proteins in water, and some photochemical systems (e.g., rhodopsin and green fluorescence proteins), are well described by a three-parameter family of sub-Ohmic spectral densities that are characterized by a fast initial Gaussian-like decay followed by a slow algebraic-like decay rate at long times.

quant-ph↗