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Lidong Chen

Publications and source records attributed to Lidong Chen.

6 recordsLinked to original sources

Homojunction-induced thermopower enhancement in polymer films

It has been more than twenty years since conductive polymers began to receive attention as an emerging thermoelectric material. However, the trade-off between electrical conductivity ({\sigma}) and thermopower (S) has proven to be a major challenge that has obstructed their use in actual devices. Here we report the discovery that the thermopower of the p- and n-type legs of organic thermogenerators can be substantially enhanced, without significant deterioration of {\sigma}, by constructing an in-plane segmented structure consisting of a homojunction with different doping levels on either side. In such segmented layers, the S is abnormally higher than the average value of the constituent parts when applying a forward temperature gradient (heating the heavily doped counterpart), while it is lower upon a reverse temperature gradient. Typically, for a two-stage segmented film of p-type PDPP-Se, an abnormally large S of 210 uV K-1 and {\sigma} of 2.5*10^4 S m-1 are obtained, resulting in a large power factor (PF) of 1100 uW m-1 K-2 and a record ZT of 1.36 at room temperature. The enhanced thermopower is attributed to an additional voltage developed at the homojunction under heating as explained by kinetic Monte Carlo simulations. This finding provides a breakthrough approach to the modulation of thermoelectric transport properties of conductive polymers.

cond-mat.mtrl-sci

CM-EVS: Sparse Panoramic RGB-D-Pose Data for Complete Scene Coverage

Modern 3D visual learning relies on observations sampled from metric 3D assets, yet existing scans, meshes, point clouds, simulations, and reconstructions do not directly provide a sparse, comparable, and geometry-consistent panoramic training interface. Dense trajectories duplicate nearby views, source-specific rendering policies yield heterogeneous annotations, and sparse heuristics may miss important regions or introduce depth-inconsistent observations. We study how to convert 3D assets into sparse panoramic RGB-D-pose data that preserves complete scene coverage with low redundancy and auditable provenance. We propose COVER (Coverage-Oriented Viewpoint curation with ERP Range-depth warping), a training-free ERP viewpoint curator that projects geometry observed from selected views into candidate ERP probes, scores incremental coverage, and penalizes depth conflicts. Under bounded proxy error, its greedy coverage proxy preserves the standard coverage-style approximation behavior up to an additive error term. Using COVER, we build CM-EVS (Coverage-curated Metric ERP View Set), a panoramic RGB-D-pose dataset with 36,373 curated ERP frames from 1,275 indoor scenes across Blender indoor, HM3D, and ScanNet++, complemented by outdoor panoramas from TartanGround and OB3D re-encoded into the same schema. Each frame provides full-sphere RGB, metric range depth, calibrated pose; COVER-produced indoor frames include per-step provenance logs. With a median of only 25 frames per indoor scene, CM-EVS covers all 13 unified room types while maintaining compact scene-level coverage. Experiments show that COVER improves the coverage-conflict trade-off, making CM-EVS a sparse, compact, and auditable RGB-D-pose resource for geometry-consistent panoramic 3D learning.

cs.CV

Hybrid Tribo/piezoelectic Electrospun Nanofibers for Energy Harvesting Enhancement in Flexible Electronics

Triboelectric nanogenerators or TENGs and piezoelectric nanogenerators or PENGs have emerged as promising platforms for harvesting mechanical energy and converting it into electrical energy for powering flexible electronic devices. However, the material selection and structure design of such hybrid nanogenerator, and mechanisms of energy output still remain challenges. In this work, electrospinning is employed for the fabrication of nanofibers, particularly polyvinylidene fluoride or PVDF based nanofibers, due to its capability to generate high beta phase contents that effectively increase the piezoelectric performance of the PVDF friction layer, thereby enhancing the overall electrical performance for flexible electronics by merging tribo-piezoelectric power. Furthermore, various concentrations carbon nanotubes or CNT or graphene nanosheets or GNS are individually incorporated into the PVDF solution as nanofillers or NF to enhance the piezoelectric responses of the PVDF based nanofibers. The introduction of nanofillers is found to not only alter the fiber diameter but also modify the surface roughness of the electrospun nanofibers, and thus, enhancing the triboelectric effect. In addition, the output performance of the fabricated nanogenerator is predominantly governed by the piezoelectric effect rather than triboelectric effect, as the electrical output shows a strong positive correlation with the beta phase content of PVDF based nanofibers: the highest beta phase content reached to 85.3 percent and consistently resulted in the optimal energy output of 1.133 watt per meter square. Notably, the power density achieved by the prototype device reaches to the level of watt/m2, representing a substantial improvement compared with that of the conventional TENGs or PENGs reported to date, providing expanded opportunities for flexible electronic devices

cond-mat.mtrl-sci

Colossal Nernst power factor in topological semimetal NbSb$_2$

Today solid-state cooling technologies below liquid nitrogen boiling temperature (77 K), crucial to quantum information technology and probing quantum state of matter, are greatly limited due to the lack of good thermoelectric and/or thermomagnetic materials. Here, we report the discovery of colossal Nernst power factor of 3800$\times$10$^{-4}$ W m$^{-1}$ K$^{-2}$ under 5 T at 25 K and high Nernst figure-of-merit of 71$\times$10$^{-4}$ K$^{-1}$ under 5 T at 20 K in topological semimetal NbSb$_2$ single crystals. The observed high thermomagnetic performance is attributed to large Nernst thermopower and longitudinal electrical conductivity, and relatively low transverse thermal conductivity. The large and unsaturated Nernst thermopower is the result of the combination of highly desirable electronic structures of NbSb$_2$ having compensated high mobility electrons and holes near Fermi level and strong phonon-drag effect. This discovery opens an avenue for exploring material option for the solid-state heat pumping below liquid nitrogen temperature.

cond-mat.mtrl-sci

Electronic Origin for the Enhanced Thermoelectric Efficiency of Cu2Se

Thermoelectric materials (TMs) can uniquely convert waste heat into electricity, which provides a potential solution for the global energy crisis that is increasingly severe. Bulk Cu2Se, with ionic conductivity of Cu ions, exhibits a significant enhancement of its thermoelectric figure of merit zT by a factor of ~3 near its structural transition around 400 K. Here, we show a systematic study of the electronic structure of Cu2Se and its temperature evolution using high-resolution angle-resolved photoemission spectroscopy. Upon heating across the structural transition, the electronic states near the corner of the Brillouin zone gradually disappear, while the bands near the centre of Brillouin zone shift abruptly towards high binding energies and develop an energy gap. Interestingly, the observed band reconstruction well reproduces the temperature evolution of the Seebeck coefficient of Cu2Se, providing an electronic origin for the drastic enhancement of the thermoelectric performance near 400 K. The current results not only bridge among structural phase transition, electronic structures, and thermoelectric properties in a condensed matter system, but also provide valuable insights into the search and design of new generation of thermoelectric materials.

cond-mat.mtrl-sci

A micrometer-thick oxide film with high thermoelectric performance at temperature ranging from 20-400 K

Thermoelectric (TE) materials achieve localised conversion between thermal and electric energies, and the conversion efficiency is determined by a figure of merit zT. Up to date, two-dimensional electron gas (2DEG) related TE materials hold the records for zT near room-temperature. A sharp increase in zT up to ~2.0 was observed previously for superlattice materials such as PbSeTe, Bi2Te3/Sb2Te3 and SrNb0.2Ti0.8O3/SrTiO3, when the thicknesses of these TE materials were spatially confine within sub-nanometre scale. The two-dimensional confinement of carriers enlarges the density of states near the Fermi energy3-6 and triggers electron phonon coupling. This overcomes the conventional σ-S trade-off to more independently improve S, and thereby further increases thermoelectric power factors (PF=S2σ). Nevertheless, practical applications of the present 2DEG materials for high power energy conversions are impeded by the prerequisite of spatial confinement, as the amount of TE material is insufficient. Here, we report similar TE properties to 2DEGs but achieved in SrNb0.2Ti0.8O3 films with thickness within sub-micrometer scale by regulating interfacial and lattice polarizations. High power factor (up to 103 μWcm-1K-2) and zT value (up to 1.6) were observed for the film materials near room-temperature and below. Even reckon in the thickness of the substrate, an integrated power factor of both film and substrate approaching to be 102 μWcm-1K-2 was achieved in a 2 μm-thick SrNb0.2Ti0.8O3 film grown on a 100 μm-thick SrTiO3 substrate. The dependence of high TE performances on size-confinement is reduced by ~103 compared to the conventional 2DEG-related TE materials. As-grown oxide films are less toxic and not dependent on large amounts of heavy elements, potentially paving the way towards applications in localised refrigeration and electric power generations.

cond-mat.mtrl-sci