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Lili Alderson

Publications and source records attributed to Lili Alderson.

At least 19 recordsLinked to original sources

TESS Photometry and Radial Velocity Analysis of the sub-Neptune Exoplanet π Mensae c and the Wider π Mensae Planetary System

Exoplanet characterization relies on precise measurements of planetary orbital and physical parameters. This is particularly important for planetary dynamics and atmospheric evolution, as orbital parameters help constrain system evolution, resolve ambiguities, and gauge atmospheric retention. The first exoplanet discovered by the Transiting Exoplanet Survey Satellite (TESS), $π$ Men c, is a warm sub-Neptune orbiting a bright Sun-like star in a system containing (at least) one other planet with a wildly different period and size. Lying near the 1.5-2.0 $R_{\oplus}$ radius gap, $π$ Men c is expected to have lost its primordial hydrogen and helium, but kept heavier compounds like H$_2$O and CO$_2$. The $π$ Men system is well observed with decades of radial velocity measurements, and TESS has continued to observe $π$ Men c, yielding six years and 21 sectors of photometry. We present a comprehensive analysis of these TESS data and 22 years of radial velocity measurements to provide updated orbital ephemerides for $π$ Men b, c, and the proposed third planet, $π$ Men d. Our newly derived $π$ Men c period error margins are an order of magnitude improved from previous estimates, and we estimate the mass range of $π$ Men d to be 13.4 $\leq$ M$_d$ $<$ 20 M$_{\oplus}$. We find that $π$ Men c is a uniquely interesting target for future transmission spectroscopy studies with JWST, and that existing radial velocity data are consistent with the existence of a third planet.

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The HST/WFC3 Transmission Spectrum of AU Mic b Part I: An Atmosphere Obscured by Contamination and Systematics

Young sub-Neptune progenitors around M dwarfs offer an excellent opportunity to probe the formation of their abundant, older cousins. At $\sim$20 Myr and only 9.7 pc away, AU Mic b is an ideal candidate for this effort, with its density and observations of escaping hydrogen pointing to a significant primordial atmosphere. Here we present the 0.8-1.6 $\micron$ transmission spectrum of AU Mic b observed with the Wide Field Camera 3 on the Hubble Space Telescope (HST). We find that HST experienced unstable scanning during its visits, resulting in a variable PSF that dramatically affects the orbit-to-orbit baseline of the observations. While we were able to somewhat mitigate this problem through spectral binning, the effects cannot be completely eliminated, limiting the precision of our results. Our data is further impacted by the intense magnetic activity of AU Mic, which introduced significant rotational variability along with spot crossings and the transit light source (TLS) effect into the light curves and spectrum, respectively. Through decomposition of the out-of-transit stellar SED, we are able to constrain AU Mic's photospheric and spot temperatures to 3891$\pm$37 and 3020$\pm$69 K, respectively, with a spot filling factor of $0.33\pm0.05$. Using Bayesian atmospheric retrievals, we show that the spectrum is dominated by the TLS effect with weak atmospheric constraints, with the data preferring a relatively small scale height of $<$185 km to 3$σ$. Extrapolation of our retrieved spectra shows that the TLS effect dominates over atmospheric features at optical and infrared wavelengths.

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Characterizing Transiting Exoplanet Atmospheres in the 2030s with the Hubble Space Telescope

The Hubble Space Telescope inaugurated the era of exoplanet atmospheric characterization. While the James Webb Space Telescope has largely taken up the mantle of infrared atmospheric characterization, Hubble's unique short-wavelength capabilities remain unmatched. Recent theoretical advances in exoplanet atmospheric science combined with new observing strategies, like those offered by WFC3-UVIS/G280, have opened science cases that only Hubble can address for the foreseeable future. In this white paper, we discuss these new windows into the atmospheres of other worlds, focusing on characterization of their hydrostatic lower atmosphere, and identify the critical capabilities necessary for future observations. We highlight three overall science cases that will depend on the continued short-wavelength capabilities of Hubble: measuring aerosol scattering slopes, characterizing metal absorption in ultra-hot Jupiters, and understanding stellar activity with Transit Light Source effect decontamination and flare monitoring. Throughout, we highlight useful synergies between HST and JWST. This article is a response to the call for white papers by the Space Telescope Science Institute on "Building a Roadmap for Hubble science into the 2030s."

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Magnesium Silicate Clouds in the Atmosphere of HD 209458b from a Rule-Based Tree-Structured Data Reduction

HD 209458b is the canonical hot Jupiter: the first to have its atmosphere measured and the first to hint at the role of aerosols in exoplanet atmospheres through the muting of Na absorption signatures in the optical. Here we present JWST MIRI/LRS transmission observations of HD 209458b from 5-12 microns, directly measuring the absorption signatures of its clouds for the first time. The observations indicate the presence of magnesium silicates, most likely Mg2SiO4 or a mixture of Mg2SiO4 and MgSiO3. We also present a new methodology to reduce observational data, whereby the analysis is formulated as a rule-based model with a tree structure, enabling key decisions to be identified and uncertain decisions to be incorporated into subsequent modeling. With this data reduction, and using a combination of ARCiS free retrievals and PICASO+Virga self consistent forward models, we are able to show that amorphous Mg2SiO4 clouds explain the LRS data to high significance over either a clear (Delta ln(Z)=16.63) or gray cloud atmosphere (Delta ln(Z)=22.26). By combining the LRS dataset with archival JWST NIRCam and HST optical and near-infrared observations, we are able to more robustly constrain the properties of the magnesium silicate condensates, finding particle sizes of approximately 0.1 microns and atmospheric pressures of the clouds of roughly 1-10 millibar. Our results add to the growing detections of silicate clouds as a dominant atmospheric component of hot Jupiters, with the exact silicate species contextualizing the atmospheric chemistry and potentially formation conditions of these planets.

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JWST COMPASS Program: The 3--5$μ$m transmission spectrum of LTT 1445 A b

The search for an atmosphere on the closest rocky M dwarf planet, LTT 1445 A b, has been the subject of intense investigation from both the ground and space. Here, we present the first JWST transmission spectrum of LTT 1445 A b using a single visit spanning 3-5~$μ$m using NIRSpec/G395H. We conduct two independent reductions of the data using both the Eureka! and ExoTiC-JEDI pipelines. Overall, we measure the NRS1 transit depths to a median precision of $\sim23$~ppm in 41 spectroscopic channels with uniform widths of 30 pixels ($\sim$ 0.02 $μ$m), and the NRS2 transit depths to $\sim36$~ppm precision in 65 spectroscopic channels, also with uniform widths of 30 pixels. We rule out any statistically significant spectral features at this precision and place limits on atmospheric metallicity using a grid of chemical equilibrium models with grey opaque clouds. Using NIRSpec/G395H alone, we can place limits on the atmospheric metallicity of $\gtrsim350~\times$ Solar when the opaque pressure level is greater than 0.01~bars. We also conduct a combined analysis of JWST/NIRSpec and HST/WFC3 transmission data and find our atmospheric limits can be extended $\gtrsim500~\times$ Solar when considering both datasets. Future analyses both in transit and emission will uncover whether there are detectable atmospheric features.

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BOWIE-ALIGN: Exploring degeneracies in the muted transmission spectrum of the aligned hot Jupiter NGTS-2b with NIRSpec/G395H

We present the first atmospheric observation and characterisation of the aligned, 1468 K hot Jupiter, NGTS-2b, with one JWST NIRSpec/G395H transit. These observations complete the GO 3838 observing campaign of the BOWIE-ALIGN program, which aims to investigate the link between hot Jupiter atmospheric composition and formation history through the atmospheric analysis of planets orbiting F stars that are aligned and misaligned with the host stellar spin axis. The 2.84-5.18 micron spectrum shows weak absorption features attributed to H$_2$O and CO$_2$ absorption, which our free chemistry retrievals fit with posteriors that converge on high mean molecular weight solutions attained through significant H$_2$O mixing ratios. By comparing our results to interior modelling, we show that some of these solutions exceed the 43.5x solar upper limit we obtained from our interior structure models. Such solutions are likely due to cloud-metallicity degeneracies and insufficient wavelength coverage to resolve them. We show that, in the case of our observations, the likelihood distribution of H$_2$O abundances is flat and uninformative, such that our retrievals are biased by the prior. Additionally, our statistically favoured atmospheric solution contains absorption from SO. The chemical abundances retrieved with this model are likely not astrophysically feasible and we demonstrate that the presence of SO is driven by only two data points. Our equilibrium chemistry retrievals hint at a subsolar C/O ratio and supersolar metallicity; however, we find wide posterior distributions that extend to solar values.

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JWST COMPASS: NIRSpec/G395H Transmission Observations of the Sub-Neptune HD 15337 c

We present the 3-5 $μ$m transmission spectrum of HD 15337 c (TOI-402.02), a sub-Neptune (2.526 R$_{\oplus}$, 6.792 M$_{\oplus}$, T$_{\rm eq}$$\sim$656 K) around a K1V star observed as part of the JWST COMPASS program. We reduce these observations with two pipelines and find consistent transmission spectra. The resulting median precisions in 30 pixel spectroscopic bins for visit 1 are $\sim$40 ppm and $\sim$70 ppm and for visit 2 are $\sim$30 ppm and $\sim$54 ppm for NRS1 and NRS2, respectively. We attribute the differing precisions to the lack of adequate pre-transit baseline in visit 1 from an early transit arrival caused by previously undetected transit timing variations (TTVs), hinting at a potential exterior companion. Our median JWST timing precision is 10 seconds, revealing TTVs $>$20 minutes when combined with previous TESS and CHEOPS data, highlighting JWST's TTV measurement capabilities. The transmission spectrum of HD 15337 c is featureless and can best be described by a step function with an offset between the NRS1 and NRS2 detectors, likely caused by instrumental systematics. From thermochemical equilibrium retrievals we find that, to $>$3$σ$, the data can rule out atmospheres with metallicities $<$600 or $<$310 $\times$ solar, depending on the reduction, for opaque pressures greater than a few millibars. HD 15337 c joins other sub-Neptunes with similar masses, radii, and temperatures in possessing a featureless transmission spectrum indicative of high metallicity and/or high-altitude aerosols and adds support to recent studies showing that aerosol opacity reaches a maximum for planets with equilibrium temperatures of 500-700 K.

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JWST COMPASS: A NIRSpec G395H Transmission Spectrum of Radius Valley-Dweller TOI-260 b

We present a JWST/NIRSpec G395H transmission spectrum of TOI-260 b, a $T_\mathrm{eq}\sim 490$ K, $R_\mathrm{p} = 1.76\,R_\oplus$ planet. The transmission spectrum is derived by combining two transit observations, collected as part of the JWST COMPASS program. We achieved the same median transit depth precision of 37 ppm in both visits, and a median precision of 26 ppm when combining the spectroscopic light curves from the two visits. Implementing a 30-pixel-wide ($R\sim 200$) spectroscopic binning scheme, we find that the transmission spectrum is mostly featureless, with a possible feature around 3.17 $μ$m. We assess the significance of any features in the transmission spectrum with a suite of non-parametric models, which confirm the presence of a potential feature in the NRS1 bandpass and an offset between the NRS1 and NRS2 detectors. To investigate the atmospheric composition of TOI-260 b, we run a series of PLATON retrievals. We do not detect any clear molecular signatures, but the combined data from the two visits are sufficient to constrain the atmospheric metallicity to greater than $200\times$ solar, assuming no opaque deck $\lesssim2.5$ mbar. We also investigate causes of the potential feature near 3.17 $μ$m; while we find some compatible gaseous species and cannot fully discard an astrophysical origin, we suspect a systematics origin due to the variance in strength and position of the feature. Overall, this look at TOI-260 b adds to the small sample of radius-valley planets, which already seem to show a diversity in their atmospheric compositions. Determining the true nature of these enigmatic planets will require a larger telescope time investment.

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BOWIE-ALIGN: Sub-solar C/O ratio and metallicity atmosphere of the misaligned hot Jupiter HAT-P-30b

We present the JWST NIRSpec/G395H transmission spectrum of the misaligned hot Jupiter HAT-P-30b from 2.8--5.2 $μ$m as part of the BOWIE-ALIGN survey, a comparative survey designed to probe the link between planet formation and atmospheric composition in samples of misaligned and aligned hot Jupiters orbiting F-type stars. Through independent data reductions and retrieval analyses, we find evidence for absorption features of H$_2$O and CO$_2$ in the atmosphere of HAT-P-30b. Our retrieved abundances are consistent with equilibrium chemistry, from which we infer a sub-solar C/O ratio (0.16--0.45), and sub-solar and sub-stellar metallicity (0.2--0.8$\times$solar, compared to a stellar metallicity of 1.1--1.6$\times$solar), with muted spectral features. This composition challenges formation models of continuous migration and accretion within a steady disc of stellar metallicity, and could be the result of low C/O ratio gas accretion within the water ice line, low metallicity accretion due to the trapping of volatiles further out in the disc, or the combined accretion of low metallicity gas and carbon-poor solids.

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JWST-TST DREAMS: The Nightside Emission and Chemistry of WASP-17b

Theoretical studies have suggested using planetary infrared excess (PIE) to detect and characterize the thermal emission of transiting and non-transiting exoplanets, however the PIE technique requires empirical validation. Here we apply the PIE technique to a combination of JWST NIRSpec G395H transit and eclipse measurements of WASP-17b, a hot Jupiter orbiting an F-type star, obtained consecutively (0.5 phase or 1.8 days apart) as part of the JWST-TST program to perform Deep Reconnaissance of Exoplanet Atmospheres through Multi-instrument Spectroscopy (DREAMS). Using the in-eclipse measured stellar spectrum to circumvent the need for ultra-precise stellar models, we extract the first JWST nightside emission spectrum of WASP-17b using only transit and eclipse data thereby performing a controlled test of the PIE technique. From the WASP-17b nightside spectrum, we measure a nightside equilibrium temperature of $1005 \pm 256$ K and find tentative evidence for nightside SO2 absorption ($\ln B = 1.45$, $2.3σ$). In context with the dayside, the temperature of the nightside is consistent with (1) previous eclipse mapping findings that suggest relatively inefficient day-night heat transport, and (2) a non-zero bond albedo of $0.42^{+0.06}_{-0.10}$. SO2 on the nightside, if confirmed, would represent the first direct evidence for transport-induced chemistry, matching previous model predictions, and opening a new door into the 3D nature of giant exoplanets. Our results suggest that PIE is feasible with JWST/NIRSpec for two epochs separated in time by significantly less than the rotation period of the host star.

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JWST-TST DREAMS: Sulfur dioxide in the atmosphere of the Neptune-mass planet HAT-P-26 b from NIRSpec G395H transmission spectroscopy

We present the James Webb Space Telescope (JWST) transmission spectrum of the exoplanet HAT-P-26 b (18.6 Earth masses, 6.33 Earth radii), based on a single transit observed with the JWST NIRSpec G395H grating. We detect water vapor (ln B = 4.1), carbon dioxide (ln B = 85.6), and sulfur dioxide (ln B = 13.5) with high confidence, along with marginal indications for hydrogen sulfide and carbon monoxide (ln B < 0.5). The detection of SO2 in a warm super-Neptune sized exoplanet (radius about 6 Earth radii) bridges the gap between previous detections in hot Jupiters and sub-Neptunes, highlighting the role of disequilibrium photochemistry across a broad range of exoplanet atmospheres, including those cooler than 1000 K. Our precise measurements of carbon, oxygen, and sulfur indicate an atmospheric metallicity of about 10 times solar and a sub-solar C/O ratio. Retrieved molecular abundances are consistent within 2 sigma with predictions from self-consistent models including photochemistry. The elevated CO2 abundance and possible H2S signal may also reflect sensitivities to the thermal structure, cloud properties, or additional disequilibrium processes such as vertical mixing. We compare the SO2 abundance in HAT-P-26 b with that of ten other JWST-observed giant exoplanets, and find a correlation with atmospheric metallicity. The trend is consistent with the prediction from Crossfield (2023), showing a steep rise in SO2 abundance at low metallicities, and a more gradual increase beyond 30 times solar. This work is part of a series of studies by our JWST Telescope Scientist Team (JWST-TST), in which we use Guaranteed Time Observations to perform Deep Reconnaissance of Exoplanet Atmospheres through Multi-instrument Spectroscopy (DREAMS).

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BOWIE-ALIGN: Weak spectral features in KELT-7b's JWST NIRSpec/G395H transmission spectrum imply a high cloud deck or a low-metallicity atmosphere

Hot Jupiters and their atmospheres are prime targets for transmission spectroscopy due to their extended atmospheres and the corresponding large signal-to-noise, providing the best possible constraints for the atmospheric carbon-to-oxygen (C/O) ratio and metallicity of exoplanets. Within BOWIE-ALIGN, we aim to compare JWST spectra of a sample of orbitally aligned and misaligned hot Jupiters orbiting F-type stars to probe the link between hot Jupiter atmospheres and planet formation history. Here, we present a near-infrared transmission spectrum of the aligned planet KELT-7b using one transit observed with JWST NIRSpec/G395H. We find weak features, only tentative evidence for H$_2$O and CO$_2$ in the atmosphere of KELT-7b. This poses a challenge to constrain the atmospheric properties of KELT-7b and two possible scenarios emerge from equilibrium chemistry and free chemistry retrievals: a high-altitude cloud deck muting all features or an extremely low metallicity atmosphere, respectively. The retrieved C/O ratios from our data reductions range from $0.43 - 0.74$, while the atmospheric metallicity is suggested to be solar to super-solar ($1-16 \times$ solar). Although these wide constraints prevent detailed conclusions about KELT-7b's formation history, a solar-to-super-solar metallicity would imply the accretion of solid material during its formation, which is valuable information for the survey's wider goals of understanding the relative importance of gaseous to solid accretion.

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JWST-TST DREAMS: NIRSpec/PRISM Transmission Spectroscopy of the Habitable Zone Planet TRAPPIST-1 e

TRAPPIST-1 e is one of the very few rocky exoplanets that is both amenable to atmospheric characterization and that resides in the habitable zone of its star -- located at a distance from its star such that it might, with the right atmosphere, sustain liquid water on its surface. Here, we present a set of 4 JWST/NIRSpec PRISM transmission spectra of TRAPPIST-1 e obtained from mid to late 2023. Our transmission spectra exhibit similar levels of stellar contamination as observed in prior works for other planets in the TRAPPIST-1 system (Lim et al, 2023; Radica et al., 2024), but over a wider wavelength range, showcasing the challenge of characterizing the TRAPPIST-1 planets even at relatively long wavelengths (3-5 um). While we show that current stellar modeling frameworks are unable to explain the stellar contamination features in our spectra, we demonstrate that we can marginalize over those features instead using Gaussian Processes, which enables us to perform novel exoplanet atmospheric inferences with our transmission spectra. In particular, we are able to rule out cloudy, primary H$_2$-dominated ($\gtrsim$ 80$\%$ by volume) atmospheres at better than a 3$σ$ level. Constraints on possible secondary atmospheres on TRAPPIST-1 e are presented in a companion paper (Glidden et al., 2025). Our work showcases how JWST is breaking ground into the precisions needed to constrain the atmospheric composition of habitable-zone rocky exoplanets.

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JWST-TST DREAMS: Secondary Atmosphere Constraints for the Habitable Zone Planet TRAPPIST-1 e

The TRAPPIST-1 system offers one of the best opportunities to characterize temperate terrestrial planets beyond our own solar system. Within the TRAPPIST-1 system, planet e stands out as highly likely to sustain surface liquid water if it possesses an atmosphere. Recently, we reported the first JWST/NIRSpec PRISM transmission spectra of TRAPPIST-1 e, revealing significant stellar contamination, which varied between the four visits. Here, we assess the range of planetary atmospheres consistent with our transmission spectrum. We explore a wide range of atmospheric scenarios via a hierarchy of forward modeling and retrievals. We do not obtain strong evidence for or against an atmosphere. Our results weakly disfavor CO$_2$-rich atmospheres for pressures corresponding to the surface of Venus and Mars and the cloud tops of Venus at 2$σ$. We exclude H$_2$-rich atmospheres containing CO$_2$ and CH$_4$ in agreement with past work, but find that higher mean molecular weight, N$_2$-rich atmospheres with trace CO$_2$ and CH$_4$ are permitted by the data. Both a bare rock and N$_2$-rich atmospheric scenario provide adequate fits to the data, but do not fully explain all features, which may be due to either uncorrected stellar contamination or atmospheric signals. Ongoing JWST observations of TRAPPIST-1 e, exploiting consecutive transits with TRAPPIST-1 b, will offer stronger constraints via a more effective stellar contamination correction. The present work is part of the JWST Telescope Scientist Team (JWST-TST) Guaranteed Time Observations, which is performing a Deep Reconnaissance of Exoplanet Atmospheres through Multi-instrument Spectroscopy (DREAMS).

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Additional JWST/NIRSpec Transits of the Rocky M Dwarf Exoplanet GJ 1132 b Reveal a Featureless Spectrum

As an archetypal M-dwarf rocky exoplanet, GJ 1132 b has a varied history of atmospheric measurements. At 1.13 $\rm R_{\oplus}$, 1.66 $\rm M_{\oplus}$, and 580 K, it orbits a bright, slowly rotating M dwarf in a 1.6-day period, making it a prime target for characterization. In this study, we combine two JWST NIRSpec/G395H transits previously reported by May and MacDonald et al. 2023 with two new NIRSpec/G395M transits to constrain the presence of an atmosphere. This marks the first time the G395H and G395M modes have been combined for a single target, and we report no difference in the quality of data between the two modes. For rocky M-dwarf studies, G395H may still be preferred if stacking transits to utilize the high-resolution flux-calibrated stellar spectra and assess evolving stellar heterogeneity. GJ 1132 b's co-added transmission spectrum is best-fit with a flat line. A thin steam atmosphere is also consistent with the data, but this interpretation is driven almost entirely by the first transit, which suggests an increase in cool spot coverage-fraction derived from the flux-calibrated stellar spectra. This demonstrates the importance of always considering stellar heterogeneity evolution in multi-visit transits, and also the importance of a "leave-one-transit-out" approach in modeling efforts of co-added transits. We combine these results with MIRI/LRS emission data (Xue et al. 2024) to show that together, transmission and emission are consistent with only the thinnest of atmospheres. Given GJ 1132 b's age and distance from the star, a thin atmosphere is not likely stable. Therefore, the simplest explanation is that GJ 1132 b is indeed a bare rock.

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JWST COMPASS: A NIRSpec G395H Transmission Spectrum of the Super-Earth GJ 357 b

We present JWST NIRSpec/G395H transmission spectroscopy observations of GJ 357 b, a warm ($T_{\mathrm{eq}} \approx 525$ K) super-Earth ($1.2\ \mathrm{R_{\oplus}} $, $1.84\ \mathrm{M_{\oplus}} $) orbiting a nearby M3-type star, with a median precision of 18 ppm and 27 ppm in NRS1 and NRS2, respectively. These precisions are obtained by binning the spectrum into 53 spectroscopic channels with a resolution of 60 pixels (around 0.02 $μ$m) each. Our analysis of the transmission spectrum reveals no detectable atmospheric spectral features. By comparing the observed spectrum with 1D forward models, we rule out atmospheres with mean molecular weights (MMW) lower than 8 g/mol to $3 σ$, as well as atmospheres with metallicities less than 300x solar. The lack of a low MMW primary atmosphere is consistent with a primordial H$_2$ rich atmosphere having escaped, given the planet's $\gtrsim5$ Gyr age, relatively low surface gravity (log g = 3.09), and its likely history of substantial incident extreme ultraviolet radiation. We conclude that GJ 357 b most likely possesses either a high-MMW secondary atmosphere, perhaps rich in oxidized gases like CO$_2$, or is a bare rock with no atmosphere. Upcoming scheduled JWST thermal emission observations could help distinguish between these scenarios by detecting signatures indicative of atmospheric heat redistribution or molecular absorption.

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The HUSTLE Program: The UV to Near-IR Transmission Spectrum of the Hot Jupiter KELT-7b

The ultraviolet and optical wavelength ranges have proven to be a key addition to infrared observations of exoplanet atmospheres, as they offer unique insights into the properties of clouds and hazes and are sensitive to signatures of disequilibrium chemistry. Here we present the 0.2-0.8 $μ$m transmission spectrum of the Teq = 2000 K Jupiter KELT-7b, acquired with HST WFC3/UVIS G280 as part of the HUSTLE Treasury program. We combined this new spectrum with the previously published HST WFC3/IR G141 (1.1-1.7 $μ$m) spectrum and Spitzer photometric points at 3.6$μ$m and 4.5$μ$m, to reveal a generally featureless transmission spectrum between 0.2 and 1.7 $μ$m, with a slight downward slope towards bluer wavelengths, and a asymmetric water feature in the 1.1-1.7 $μ$m band. Retrieval models conclude that the 0.2 - 1.7$μ$m spectrum is primarily explained by a high H- abundance ($\sim 10^{-5}$), significantly above the equilibrium chemistry prediction ($\sim 10^{-12}$), suggesting disequilibrium in KELT-7b's upper atmosphere. Our retrievals also suggest the presence of bright inhomogeneities in the stellar surface, and tentative evidence of CO2 at the Spitzer wavelengths. We demonstrate that with the UV-optical coverage provided by WFC3 UVIS/G280, we are able to confirm the presence and constrain the abundance of H-, and obtain evidence for bright stellar inhomogeneities that would have been overlooked using infrared data alone. Observations redward of 1$μ$m with JWST should be able to further constrain the abundance of H-, as well as confirm the presence of CO2 inferred by the two Spitzer datapoints.

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Tracing the formation and migration history: molecular signatures in the atmosphere of misaligned hot Jupiter WASP-94Ab using JWST NIRSpec/G395H

The discovery of hot Jupiters that orbit very close to their host stars has long challenged traditional models of planetary formation and migration. Characterising their atmospheric composition - mainly in the form of the carbon-to-oxygen (C/O) ratio and metallicity - can provide insights into their formation locations and evolution pathways. With JWST we can characterise the atmospheres of these types of planets more precisely than previously possible, primarily because it allows us to determine both their atmospheric oxygen and carbon composition. Here, we present a JWST NIRSpec/G395H transmission spectrum from 2.8-5.1$μm$ of WASP-94Ab, an inflated hot Jupiter with a retrograde misaligned orbit around its F-type host star. We find a relatively cloud-free atmosphere, with absorption features of H$_2$O and CO$_2$ at detection significances of $\sim 4σ$ and $\sim 11σ$, respectively. In addition, we detect tentative evidence of CO absorption at $\sim3σ$, as well as hints of sulphur with the detection of H$_2$S at a $\sim 2.5σ$ confidence level. Our favoured equilibrium chemistry model determines a C/O ratio of $0.49^{+0.08}_{-0.13}$ for WASP-94Ab's atmosphere, which is substellar compared to the star's C/O ratio of $0.68 \pm 0.10$. The retrieved atmospheric metallicity is similar to the star's metallicity as both are $\sim 2\times$ solar. We find that this sub-stellar C/O ratio and stellar metallicity can be best explained by pebble accretion or planetesimal accretion in combination with large-distance migration of the planet.

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