arXiv2018
The establishment of a rigorous theory on thermodynamics of light management in photovoltaics that accommodates various loss mechanisms as well as wave-optical effects in the absorption and reemission of light is at stake in this contribution. To this end, we propose a theoretical framework to calculate the open-circuit voltage enhancement resulting from photon recycling ($ΔV^{\mathrm{PR}}_{\mathrm{oc}}$) with rigorous wave-optical treatment. It can be applied to both planar thin-film and nanostructured single-junction solar cells. We derive an explicit expression for $ΔV^{\mathrm{PR}}_{\mathrm{oc}}$, which reveals its dependence on internal quantum luminescence efficiency, parasitic reabsorption, and on photon escape probabilities of reemmited photons. While the internal quantum luminescence efficiency is an intrinsic material property, both latter quantities can be determined rigorously for an arbitrary solar cell architecture by three-dimensional electrodynamic dipole emission calculations. We demonstrate the strengths and validity of our framework by determining the impact of photon recycling on the $V_{\mathrm{oc}}$ of a conventional planar organo-metal halide perovskite thin-film solar cell and compare it to established reference cases with perfect antireflection and Lambertian light scattering. Our calculations reveal $ΔV^{\mathrm{PR}}_{\mathrm{oc}}$ values of up to 80 mV for the considered device stack in the absence of angular restriction and up to 240 mV when the escape cone above the cell is restricted to $θ_{\mathrm{out}}=2.5^\circ$ around the cell normal. These improvements impose severe constraints on the parasitic absorption as a parasitic reabsorption probability of only 2\% reduces the $ΔV^{\mathrm{PR}}_{\mathrm{oc}}$ to 100 mV for the same angular restriction. Our work here can be used to provide design guidelines.