SearcharxivSearch

arXiv subjects

Lincoln Paik

Publications and source records attributed to Lincoln Paik.

4 recordsLinked to original sources

Theory of hybrid defects, with coupled orientational order parameters, on flat and curved surfaces

Many physical systems involve two types of orientational order, which are coupled together. For example, ferroelectric nematic liquid crystals have coupled polar and nematic order, and tilted hexatic phases have coupled polar and hexatic order. In these systems, defect structures can be quite complex. Here, we investigate phases with two types of two-dimensional orientational order, $m$-atic and $n$-atic, where $m$ and $n$ are two distinct integers. We simulate these phases in a flat disk with strong radial anchoring, and on a spherical surface, because both of these geometries require the presence of defects. If the coupling between the two types of order is weak, then the defects are connected by a network of diffuse walls, and the system forms a stable domain structure. As the coupling increases, the domain walls become sharper and shorter. For very strong coupling, the higher-order defects merge into the lower-order defects, forming stretched defect cores.

cond-mat.soft

Spontaneous Cholesteric Phase in Ferroelectric Nematic Liquid Crystals: Preference for Integer Number of Pitches

In a ferroelectric nematic liquid crystal, the electrostatic interaction can induce a spontaneous cholesteric helix, even if the material is not chiral. If the liquid-crystal cell is infinitely thick, then the predicted pitch depends continuously on material parameters. Here, we consider how the prediction must be modified in a cell of finite thickness. If the Debye screening length is large enough, we find that the free energy has multiple minima. In these minima, the cholesteric pitch is locked to the cell thickness, so that the cell contains an integer number of pitches. However, if the screening length is smaller, then the cholesteric pitch can vary continuously.

cond-mat.soft

Flexoelectricity versus Electrostatics in Polar Nematic Liquid Crystals

Polar nematic liquid crystals have two special features, compared with conventional nematic liquid crystals. First, because of flexoelectricity, the combination of polar order and splay reduces the free energy. Second, because of electrostatics, any splay generates a bound charge density, which increases the free energy. To assess the competition between these two effects, we develop a theory that combines flexoelectricity and electrostatics. The theory predicts a phase diagram that includes ferroelectric, antiferroelectric, and conventional nematic phases.

cond-mat.soft

Preparation and characterization of Fe-incorporated TiO$_2$ thin films: A study of optical constants and dispersion energy parameters

In this study, we have delineated the preparation and influence of Fe doping on microstructural and optical properties of the pristine and Fe incorporated TiO$_2$ thin film with different Fe concentrations (0, 2, 4, 6, and 8 at.% ). The samples are prepared by easier and cost-saving way of spray pyrolysis technique (SPT) using Ti(OCH$_2$CH$_2$CH$_2$CH$_3$)$_4$ as a precursor of mother material. The effect of Fe in the microstructure and phase formation of TiO$_2$ thin films is investigated by XRD analysis. XRD investigation depicts that the pristine product corresponds to anatase phase of TiO$_2$ and remains uncontaminated with addition of 2 at.% Fe impurity. It is also observed that Fe introduces a phase transition from anatase to rutile after adulterating more Fe contents (4, 6 and 8 at.%). In order to study optical characteristics, UVvis spectroscopy has been employed which revels that UV absorption for the Fe incorporated TiO$_2$ products are noticed to move to a longer wavelength (red shift) and Fe contents lessen bandgap energy from 3.81eV (0 at.% Fe) to 3.70 eV (8 at.% Fe) of the TiO$_2$ thin films. The impact of Fe on the optical constants such as refractive index, complex dielectric constants, $\tanδ$, VELF and SELF, dispersion parameters of obtained titanium dioxide samples has been studied. The results display that Fe influences the structural and optical characteristics significantly.

physics.app-ph