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Lise Boitard-Crépeau

Publications and source records attributed to Lise Boitard-Crépeau.

2 recordsLinked to original sources

Astrochemical Inheritance of Terrestrial Planets Water from Local Wet Silicates

The delivery of water to the inner Solar System rocky planets, including Earth, remains debated, as standard models assume that they formed from dry grains, inside the snowline of the protosolar nebula. However, a recent work showed that a not-negligible amount of water formed during the prestellar phase could have been retained by pebbles and planetesimals at the Earth's orbit in enough quantities to reproduce its water content. This study was based based on quantum mechanics (QM) calculations of the binding energy (BE) of water on amorphous ice and on a kinetic approach. Here, we present new QM calculations of the BE of water frozen on the surface of silicate grains, and show that it is on average about twice larger than that on the amorphous ice. The contribution of this first layer of frozen water increases the dust temperature at which frozen water can be retained. This provides a local source of water not only for the Earth, but also for the inner rocky planets. The predictions from our model are in agreement with the available estimates of water content in terrestrial planets. This suggests that water delivery from the outer Solar System may not be required.

astro-ph.EP↗

Was Earth's water acquired locally during the earliest phases of the Solar System formation?

The origin of the terrestrial water remains debated, as standard Solar System formation models suggest that Earth formed from dry grains, inside the snowline of the Proto-Solar Nebula (PSN). Here, we revisit this issue through the lens of computational chemistry. While the classically used snowline relies on a single condensation temperature, recent work in quantum chemistry shows that the binding energy of water on icy grains has a gaussian distribution, which implies a gradual sublimation of water rather than a sharp transition. We use the computed distribution of binding energies to estimate the radial distribution of adsorbed ice on the dust grains across the PSN protoplanetary disk. Our model reproduces the full range of estimated water abundances on Earth and matches the hydration trends observed in chondrite groups at their predicted formation distances. Thus, we suggest that a significant fraction of Earth's water may have been acquired locally at early stages of the Solar System formation, without requiring delivery from beyond the classical snowline.

astro-ph.EP↗