arXiv subjects

Lixin Cao

Publications and source records attributed to Lixin Cao.

4 recordsLinked to original sources

arXiv2026

Thermodynamic-Kinetic Decoupling Enables Stable Excitonic Emission in Defect-Tolerant Cu-Based Quantum Dots

Colloidal quantum dots that simultaneously offer room-temperature single-photon purity and high photoluminescence quantum yield are sought for quantum optics, but remain elusive in environmentally benign materials. We introduce a thermodynamic-kinetic decoupling strategy that transforms defect-tolerant CuInS2 quantum dots into bright, narrowband, and photostable single-photon emitters. Zn2+ alloying strains the lattice, thermodynamically suppressing native copper vacancies and narrowing the emission from a broad defect band of approximately 300 meV to an excitonic line of approximately 120 meV. Ga3+ incorporation then kinetically pins the cation sublattice against Cu+ migration, preventing defect regeneration during ZnS shell growth. The resulting Cd-free core/shell dots achieve near-unity quantum yield of approximately 98% while retaining narrow excitonic emission. Critically, room-temperature single-dot spectroscopy reveals homogeneous linewidths as low as approximately 58 meV, strongly suppressed blinking, and high-purity single-photon emission with g2(0) = 0.06. This stabilized excitonic emission directly reduces reabsorption losses in luminescent solar concentrators, yielding an external optical efficiency of 12.68%. Our work establishes a generalizable framework to unlock intrinsic excitonic photophysics in ion-mobile, defect-prone semiconductors, opening a viable path toward high-performance heavy-metal-free emitters for quantum light sources.

physics.optics↗

arXiv2025

Superconducting-insulating phase transition in pressurized Ba1-xKxBiO3

We report the first observation of a pressure-induced transition from a superconducting (SC) to an insulating (I) phase in single-crystal Ba1-xKxBiO3 (x = 0.4, 0.43, 0.52, and 0.58) superconductors. X-ray diffraction measurements conducted at 20 K reveal a direct relationship between this SC-I transition and a pressure-induced distortion of crystal structure. With increasing pressure, the lattice parameters a and c of the ambient-pressure superconducting tetragonal (T) phase are compressed continuously below a critical pressure (Pc1), wherein the pressure (P) dependence of superconducting transition temperature (Tc) displays a small variation. However, upon further compression, the lattice of the compressed T phase displays an anisotropic change, and Tc shows a monotonous decrease. When the pressure reaches Pc2 (Pc2 > Pc1), the compressed T phase collapses along the c axis, followed by the disappearance of superconductivity and the appearance of the insulating phase. This SC-I transition is fully reversible, with the critical pressure increasing alongside K doping concentration. These findings are strikingly similar to the SC-I transition observed in hole-doped high-Tc cuprate superconductors under pressure. Identifying their commonalities could deepen our understanding of the mechanisms that underlie high- Tc superconductivity in these two oxide superconductors with a perovskite structure.

cond-mat.supr-con↗

arXiv2023

TriNet: stabilizing self-supervised learning from complete or slow collapse on ASR

Self-supervised learning (SSL) models confront challenges of abrupt informational collapse or slow dimensional collapse. We propose TriNet, which introduces a novel triple-branch architecture for preventing collapse and stabilizing the pre-training. TriNet learns the SSL latent embedding space and incorporates it to a higher level space for predicting pseudo target vectors generated by a frozen teacher. Our experimental results show that the proposed method notably stabilizes and accelerates pre-training and achieves a relative word error rate reduction (WERR) of 6.06% compared to the state-of-the-art (SOTA) Data2vec for a downstream benchmark ASR task. We will release our code at https://github.com/tencent-ailab/.

eess.AS↗

arXiv2017

Out-of-plane easy-axis in thin films of diluted magnetic semiconductor Ba1-xKx(Zn1-yMny)2As2

Single-phased, single-oriented thin films of Mn-doped ZnAs-based diluted magnetic semiconductor (DMS) Ba1-xKx(Zn1-yMny)2As2 (x = 0.03, 0.08; y = 0.15) have been deposited on Si, SrTiO3, LaAlO3, (La,Sr)(Al,Ta)O3, and MgAl2O4 substrates, respectively. Utilizing a combined synthesis and characterization system excluding the air and further optimizing the deposition parameters, high-quality thin films could be obtained and be measured showing that they can keep inactive-in-air up to more than 90 hours characterized by electrical transport measurements. In comparison with films of x = 0.03 which possess relatively higher resistivity, weaker magnetic performances, and larger energy gap, thin films of x = 0.08 show better electrical and magnetic performances. Strong magnetic anisotropy was found in films of x = 0.08 grown on (La,Sr)(Al,Ta)O3 substrate with their magnetic polarization aligned almost solely on the film growth direction.

cond-mat.mtrl-sci↗